Heavy metals: their pathway from the ground,groundwater and springs to Lake Góreckie (Poland)

The migration pathways of heavy metals derived from an area previously in agricultural use was investigated in the Wielkopolski National Park (mid-western Poland). The heavy metals involved (Cd, Cu, Cr, Pb, Ni and Zn) were determined in groundwater, the springs that feed Lake Góreckie and the lake itself. In order to show how the heavy metals may be set free and what is their biological availability, soil and sediment samples were subjected to single-stage extraction, using 0.01 M CaCl₂, 0.02 M EDTA, 0.005 M DTPA, 0.1 M HCl, 1 M HCl and de-ionised water. Varying metal concentrations were recorded in the water samples during the study period (from November 2009 to July 2010), usually with higher values in winter and lower ones in summer. The seasonal changes may be ascribed to natural processes taking place in the ground- and surface waters of Lake Góreckie. On the other hand, the concentration levels (mostly of Cd, Pb and Cr) are indicative of anthropogenic activity. It should be mentioned in this context that the highest metal concentrations were found in the soil layer. The concentrations were also found to exceed both the Polish and the World Health Organization water-quality standards. It appears that the soils are highly contaminated, mostly with cadmium. The long-lasting effect of acid precipitation in the area makes it possible for immobile forms to become mobile, thus facilitating further migration into the environment.     

Spatial and seasonal distribution of nitrate-N in groundwater beneath the rice�Cwheat cropping system of India: a geospatial analysis

Increased use of nitrogenous fertilizers in the intensively cultivated rice (Oryza sativa)?Cwheat (Triticum aestivum) cropping system (covers a 13.5-ha m area in South Asia) has led to the concentration of nitrates (NO₃-N) in the groundwater (GW) in Haryana State of India. Six districts from the freshwater zone were selected to identify factors affecting NO₃-N enrichment in GW. Water and soil samples were collected from 1,580 locations and analyzed for their chemical properties. About 3% (26,796, and 10,588 ha) of the area was estimated to be under moderately high (7.5?C10 mg l^???1) and high (>10 mg l^???1) risk categories, respectively. The results revealed that NO₃-N was 10?C50% higher during the pre-monsoon season than in the monsoon season. Nitrate-N decreased with the increase in aquifer depth (r ²?=?0.99). Spatial and proximity analyses using ArcGIS (9.2) revealed that (1) clay material in surface and sub-surface texture restricts N leaching, (2) piedmont and rolling plains act as an N sink, and (3) perennial rivers bring a dilution effect whereas seasonal rivers provide favorable conditions for NO₃ ^? enrichment. The study concludes that chemical N fertilizers applied in agro-ecosystems are not the sole factor determining the NO₃ in groundwater; rather, it is an integrated process governed by several other factors including physical and chemical properties of soils, proximity and type of river, and geomorphologic and geographical aspects. Therefore, future studies should adopt larger area (at least watershed scale) to understand the mechanistic pathways of NO₃ enrichment in groundwater and interactive role of the natural drainage system and surrounding physical features. In addition, the study also presents a conceptual framework to describe the process of nitrate formation and leaching in piedmont plains and its transportation to the mid-plain zone.     

CLFUG: A GIS‐scaleable model of pesticide fate in the soil–groundwater system based on clearance and fugacity paradigms

A model of pesticide transport through the soil profile based on clearance and fugacity paradigms is presented, and an example of its application in a GIS environment is shown. A validation of the model at the field plot scale is presented using data obtained at a crop in a semiarid irrigated agricultural basin which was treated with Lindane. The adequacy at the regional scale is tested by inspection of the model predictions and the measured concentrations of the pesticide obtained from a regional phreatimetric net. The clearance concept is used to obtain estimates of the volumes of some environmental phases. These are further used to solve the equations of thermodynamic equilibrium at equal fugacity and obtain concentration estimates. The model closely reproduces the observed percolation trends, and is consistent with the regional pattern of Lindane distribution in groundwater. An application of the model as unitary module for the simulation of non‐point pesticide sources in a raster GIS frame is shown. Its performance (run time, data needed, etc.) is comparable to that of other existing algorithms, and presents some advantages to planners and evaluators of environmental quality in that it incorporates an explicit 2‐D approach and allows the identification of polluted areas downslope with respect to those directly treated with the pesticides. Further, it can be implemented in a variety of GIS and spatial data processors.     

An Optimization Model for Integrated Coastal Management: Development and a Case Study Using Italy’s Comacchio Municipality

In this paper, I develop an optimization model for integrated coastal management in which decisions arise from an area-based algorithm that minimizes predicted damage caused by beach erosion and inshore flooding, while accounting for economic, social, and environmental losses. The model favors the involvement of stakeholders in coastal management, but does not use complicated assessment procedures for non-economic indicators or relative weights to combine economic, social, and environmental indicators. Instead, the integration between economic activities or properties and the environmental status and landscape is represented objectively and non-linearly by referring to initial and sustainability conditions, combined with budgetary and environmental constraints. The model successfully accounted for both human and environmental dynamics by depicting delayed effects, neighborhood externalities, and feedback effects. It calculated a single optimal value for each integrated coastal management strategy, which permitted the support of future decisions and the evaluation of past decisions. The model’s insights were based on reliable estimates, with reliability determined by calculating the confidence level. The model was successfully applied to Italy’s Comacchio coastal municipality, where it revealed the priorities for optimal beach nourishment, dune fixation, and residential and holiday housing development based on budget constraints, beach losses, flood damage, pollution impacts, and land-use constraints.     

Consequences and Correctives Related to Lake Acidification, Liming and Mercury in Fish – A Case-Study for Lake Huljesjön, Sweden, Using the LakeWeb-model

This work exemplifies how a given lake (Lake Huljesjön, Sweden) would likely respond to changes in pH-values and to liming (a standard measure against anthropogenic acidification). The basic questions are: How would a liming influence pH? How long would the changes last? How would the changes influence the structure and function of lake ecosystems? The work uses a comprehensive lake ecosystem model, LakeWeb, which accounts for production, biomasses, predation, abiotic/biotic interactions of nine key functional groups of organisms, phytoplankton, bacterioplankton, two types of zooplankton (herbivorous and predatory), two types of fish (prey and predatory), zoobenthos, macrophytes and benthic algae. LakeWeb is a dynamic model and gives weekly variations. It has been critically tested using empirical data and regressions from many lakes. Those tests are not presented here but have shown that the model can capture typical functional and structural patterns in lakes very well. This gives credibility to the results presented in this work, which would be very costly to obtain in the traditional manner by extensive field studies in one or a few lakes. This work presents for the first time predictions at the ecosystem level of how functional groups of organisms (and not individual species) are likely to respond to acidification and liming. Two existing dynamic models, one for liming, the other for Hg-concentrations in fish, have been added to the LakeWeb-model. These two models have previously been tested and proven to yield good predictions. The results presented here indicate that there are several probable changes in the structure and function of the lake foodweb related to acidification and liming. The predicted changes in macrophyte cover will influence the predation pressure on fish, and thereby the fish biomass. Reductions in primary production at low pH-values will cause reductions in fish biomass. There are several interesting compensatory effects between factors that increase fish biomass and factors that tend to decrease the biomass. Such matters can be handled quantitatively by the LakeWeb-model.     

Pollution caused by peoples�� use for socio-economic purposes (agricultural, recreation and tourism) in the G?lc��k Plain Settlement at Bozda? Plateau (?demi?-?zmir/Turkey): a case study

Mountainous areas, which form the largest geography of our country and are called reserves of resources owing to their difficulty of accessibility, have been increasingly under threat of exploitation and overuse in recent years. The area in question from among the mountainous areas, which are sensitive ecosystems with their environmental components, is the Bozda? mass located in Gölcük Plateau Settlement, which has been subject to intensive construction and use. This study is intended to reveal the current uses of Gölcük Plateau (agricultural, recreation, and tourism) and determine the sources and effects of pollution as a result of these uses and aims at revealing how the permanent residents of Gölcük Plateau Settlement on Bozda? Plateau, which is a center of attraction with respect of recreation and tourism activities, and those who go there only in certain periods, use the environment for tourism and recreational purposes, and determine their positive and negative impacts on environment through SWOT analysis.     

Determination of selected microbial volatile organic compounds by diffusive sampling and dual-column capillary GC-FID--a new feasible approach for the detection of an exposure to indoor mould fungi?

A new, analytically valid procedure is described to assess the exposure of human beings to the so-called microbial volatile organic compounds (MVOCs) in air. The method can be used routinely for large sample numbers and is especially valuable as a basis for further research on the correlation between single MVOCs and indoor mould growth. The procedure is based on the fact that fungi produce a variety of volatile organic compounds, such as 3-methylbutan-1-ol, 3-methylbutan-2-ol, fenchone, heptan-2-one, hexan-2-one, octan-3-one, octan-3-ol, pentan-2-ol, alpha-terpineol, and thujopsene, which they emit into the indoor environment. Using diffusive samplers, these MVOCs are adsorbed onto charcoal during a sampling interval of four weeks. The described method is thus superior to existing methods which use short-term active sampling. After desorption with carbon disulfide, the MVOCs were determined by dual-column gas chromatography with flame ionization detection using the large-volume injection technique for sample introduction. The detection limits ranged between 0.15 and 0.53 microgram m-3, within-series precision was found to range between 6.5 and 19.0%, and recovery was between 77 and 118%. The procedure has been successfully applied in the context of a large field study to measure the indoor MVOC exposure in children's rooms of 132 dwellings. The objective of the study was to examine the relation between indoor mould growth, the indoor MVOC exposure and the prevalence of adverse health effects. Information about mould formation has been obtained by a questionnaire and by the determination of colony forming units of mould fungi in mattress dust. With the exception of 3-methylbutan-2-ol, fenchone, nonan-2-one, octan-2-one, and thujopsene, indoor air concentrations of all MVOCs under investigation were significantly higher inside damp and mouldy dwellings. From the primary MVOCs under investigation, 3-methylbutan-1-ol, hexan-2-one, heptan-2-one, and octan-3-ol were found to be most reliable indicators for mould formation. A correlation was also found between selected MVOCs and the occurrence of mould species in mattress dust. Aspergillus sp. correlated with heptan-2-one, hexan-2-one, octan-3-ol, octan-3-one, and alpha-terpineol, while the occurrence of Eurotium sp. was correlated with higher indoor air concentrations of 3-methylbutan-1-ol, 3-methylbutan-2-ol, heptan-2-one, hexan-2-one, octan-3-ol, and thujopsene. Children living in dwellings with elevated MVOC levels had a higher prevalence of asthma, hay fever, wheezing, and irritations of the eyes. These positive associations persisted after controlling for confounding factors such as age, sex, body-mass index, number of siblings, social status, passive smoking, type of heating, and ventilation habits. However, they were not statistically significant. This lack of significance may be a result of the small number of investigated samples.     

An Evaluation of Selenium Concentrations in Water, Sediment, Invertebrates, and Fish from the Republican River Basin: 1997–1999

The Republican River Basin of Colorado,Nebraska, and Kansas lies in a valley which contains PierreShale as part of its geological substrata. Selenium is anindigenous constituent in the shale and is readily leached intosurrounding groundwater. The Basin is heavily irrigated throughthe pumping of groundwater, some of which is selenium-contaminated, onto fields in agricultural production. Water,sediment, benthic invertebrates, and/or fish were collected from46 sites in the Basin and were analyzed for selenium to determinethe potential for food-chain bioaccumulation, dietary toxicity,and reproductive effects of selenium in biota. Resultingselenium concentrations were compared to published guidelines orbiological effects thresholds. Water from 38% of the sites (n = 18) contained selenium concentrations exceeding 5 g L^-1, which is reported to be a high hazard for selenium accumulation into the planktonic food chain. An additional 12 sites (26% of the sites) contained selenium in water between 3–5 g L^-1, constituting a moderate hazard. Selenium concentrations in sedimentindicated little to no hazard for selenium accumulation fromsediments into the benthic food chain. Ninety-five percent ofbenthic invertebrates collected exhibited selenium concentrationsexceeding 3 g g^-1, a level reported as potentially lethal to fish and birds that consume them. Seventy-five percent of fish collected in 1997, 90% in 1998, and 64% in 1999 exceeded 4 g g^-1selenium, indicating a high potential for toxicity andreproductive effects. However, examination of weight profilesof various species of collected individual fish suggestedsuccessful recruitment in spite of selenium concentrations thatexceeded published biological effects thresholds for health andreproductive success. This finding suggested that universalapplication of published guidelines for selenium may beinappropriate or at least may need refinement for systems similarto the Republican River Basin. Additional research is needed todetermine the true impact of selenium on fish and wildliferesources in the Basin.     

Using Compliance Analysis for PPP to bridge the gap between SEA and EIA: Lessons from the Turcot Interchange reconstruction in Montréal,Québec

There is increasing concern about the disjunct between the intent of higher level government goals and actual projects “on the ground” in Canada. Although strategic environmental assessment (SEA) and a wide variety of plans, policies and programmes (PPP) contain and promote goals that envision a movement towards social, economic and environmental sustainability, these goals are not necessarily upheld by large-scale projects and their environmental impact assessments (EIAs). This disconnect is often illustrated through anecdotal observations. However, to be able to overcome this disjunct it is imperative to come to a clearer understanding of the degree of sustainability or unsustainability of large-scale developments and the way in which they “measure up” in terms of the goals when compared to alternative options.This article proposes a Compliance Analysis method for investigating the level of harmonization between SEA, PPP and proposed projects and their possible alternatives (CAPPP). This method is quantified through a Likert scale which allows for comparison of alternatives for decision making and analytical purposes. The 2009 proposal for the Turcot Exchange redevelopment in Montréal, Québec, put forward by the Ministry of Transport of Québec (MTQ), as well as two alternative proposals, were utilized as a case study to clearly demonstrate the CAPPP methodology and its applicability.The approved plan for the Turcot redevelopment proposed by MTQ was found to be in poor compliance with the majority of the 178 goals in the six sectors that were examined (air quality, climate change, health, noise, socioeconomic, transport), while alternative proposals were found to be in greater accordance with the intentions of governmental SEA and PPP.Synthesis and applications: The CAPPP methodology is a versatile “watchdog” tool for the examination of the level of compliance between stated goals for regions, industrial sectors, or governments and the EIAs of concrete projects “on the ground”. CAPPP can be used as a tool for comparative analysis in decision-making situations at various scales. CAPPP is a fairly straight-forward method that can be used by policy makers, EIA experts, and members of the general public alike.     

Future Trends and Mitigation Options for Energy Consumption and Greenhouse Gas Emissions in a Developing Country of the Middle East Region: a Case Study of Lebanon’s Road Transport Sector

The road transport system in Lebanon is one of the most unsustainable in the Middle East region due to, in large part, the absence of a national transportation strategy. This study proposes mitigation measures based on Lebanon’s commitments for reducing fossil fuel use and CO₂ emissions from road transport by increasing the share of fuel-efficient and hybrid electric vehicles and increasing the utilization of the existing bus service. Results show that increasing the market share of fuel-efficient vehicles to 35% in 2040 stabilizes energy use and emissions. The addition of hybrid vehicles to the first strategy, with a target of 10% market share by 2040, leads to 11% additional savings. Increasing the share of bus passenger kilometers traveled to 45% in 2040 leads to a reversal of adverse impacts. A combined strategy of all three measures leads to 63% reductions in 2040 compared to 2010, which is even superior to their cumulative savings.