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1.
近年来汉江中下游早春频繁暴发硅藻水华,为探明汉江早春硅藻水华暴发过程及原因,2010年1月1日~3月6日,对汉江干流及部分支流进行了浮游植物采样调查。结果表明,早春期间汉江干、支流的浮游植物密度分布具有明显的空间差异性:襄樊及以上各个站点浮游植物密度明显低于襄樊以下,汉江干流各个站点的浮游植物密度明显低于入汉江支流--唐白河。1月7日,唐白河站点浮游植物的密度最高,达5050×106个/L,冠盘藻的比例占9609%;从1月27日开始,汉江干流开始出现水华(1442×106个/L),2月23日达到峰值(2466×106个/L),到3月3日,水华开始消退(666×106个/L),前后共持续了1个多月。相关分析表明,汉江早春期间藻体密度与DO(溶解氧)、STN(溶解性总氮)、STP(溶解性总磷)有着极显著的正相关(Pearson (DO),r=063,p<001; Pearson (STN),r=085,p<001;Pearson (STP),r=077,p〖WTBZ〗<001),与SD(透明度)有极显著的负相关关系(Pearson,r=-044,p<001),而与水体中的SSi(溶解性硅)呈显著的负相关(Pearson,〖WTBX〗r=-035,p〖WTBZ〗<005)。依据汉江干、支流优势硅藻密度的时空差异,可以推测,唐白河中高密度的冠盘藻可能是汉江中下游水华暴发的种源之一;同时分析指出,2010年早春汉江中下游干流水华生消与气象因素密切关联  相似文献   

2.
洞庭湖渔业水域氮磷时空分布分析   总被引:3,自引:0,他引:3  
根据2000~2011 年对洞庭湖渔业环境监测数据,对东洞庭湖、南洞庭湖、西洞庭湖和三江口4 个不同渔业水域的总氮、总磷、氨氮和硝酸盐氮浓度的时空分布进行分析。结果表明:(1)洞庭湖总氮、总磷、氨氮和硝酸盐氮浓度均值分别为143±041、009±003、032±005和063±011 mg/L,总氮最大值为2009 年5 月丰水期东洞庭湖的鹿角采样点,为480 mg/L,总磷最大值为2008 年1 月枯水期鹿角采样点,为0417 mg/L,分析得知,所有采样点中鹿角采样点较其它采样点污染严重;(2)洞庭湖氮、磷浓度年均值间差异性显著(P<005),除总磷变化规律不明显外,总氮、氨氮和硝酸盐氮的年浓度均值总体呈上升趋势,与此同时,洞庭湖在丰水期、平水期和枯水期的氮、磷浓度均值间也存在显著性差异(P<005),平水期总氮平均浓度最高,枯水期总磷浓度均值最高;(3)东洞庭湖、南洞庭湖、西洞庭湖和三江口4 个湖区氮磷浓度均值间也存在显著性差异(P<005),总氮、总磷和硝酸盐氮均值以三江口最高,氨氮均值以东洞庭湖最高,主要受城市污水和工业污水影响严重;(4)面源污染是洞庭湖主要污染方式,也是造成洞庭湖水体富营养化程度加剧的主要因素,面源污染占洞庭湖污染总量的94%~99%,主要包括农业污染、城市生活污水和畜牧水产养殖业污染;点源污染占洞庭湖污染总量的1%~6%,主要为工业污水和城市生活污水的排放,虽然排放量相对于面源污染较小,但是工业污水含有高浓度的有毒物质,且瞬时排放量大,很容易造成渔业污染事故,严重时会影响到人类的健康;(5)参照《地表水质量标准》(GB3838 2002)中的水质分类标准,所有监测年份中,仅2000 年水质为III 类,其它年份水质类型多为IV 类,部分年份为V 类,推断洞庭湖渔业水域大部分处于中度污染状态,部分湖区处于重度污染,根据《渔业水质标准》和鱼类对水环境质量的需求,洞庭湖水质不利于鱼类繁殖、早期发育、索饵和越冬等行为,势必会造成洞庭湖渔业资源的衰退  相似文献   

3.
灌溉和降雨条件下生态沟渠氮、磷输出特征研究   总被引:5,自引:0,他引:5  
为了研究长沙县金井河流域农业源头生态沟渠氮和磷的输出特征,对灌溉和降雨条件下及不同季节生态沟渠水体氮、磷的变化特征进行监测研究。研究结果表明:灌溉和降雨期间,生态沟渠中总氮的输出最大值为270 mg/L,其输出的主要形态为氨态氮和硝态氮,总磷的最大值达032 mg/L。灌溉后,生态沟渠氮、磷的输出均呈单调递减变化,在灌溉初期均最高。降雨后,总氮、总磷沿程变化趋势均呈递减变化;生态沟渠对水体总氮、总磷去除率分别达64%、70%;各断面氮、磷的输出随着时间的增加呈先增加后降低的趋势,其中总氮、氨态氮含量在雨后第3 d达到最高,总磷含量在雨后第2 d达到最高。在不同季节中水体氮、磷的变化以冬季总氮、氨态氮和磷浓度最高  相似文献   

4.
长江干流的渔业捕捞量从1954年的43万t下降到2011年的8万t,降幅达81%,而两湖(洞庭湖和鄱阳湖)的渔业捕捞量分别在2~4万t之间波动。三峡大坝对洞庭湖三口径流量的影响有限,但使江水倒灌鄱阳湖的天数和水量进一步降低。长江来水占洞庭湖径流量的30%,而在鄱阳湖中仅有0.1%,因此,对维持长江干流的渔业资源(特别是产漂流性卵鱼类)来说,洞庭湖的重要性远超鄱阳湖。干流渔业资源的衰退主要是江湖阻隔的结果,虽然过度捕捞起到了推波助澜的作用,因此,即使在干流休渔十年,也未必能使长江的渔业资源大幅回升。如果在两湖建闸,长江渔业资源的衰退将会进一步加剧,江豚的灭绝可能难以避免,因此,维持两湖与长江的生态联系,对长江干流生物多样性的维持至关重要。  相似文献   

5.
太湖主体湖区对梅梁湾藻类影响定量化研究   总被引:1,自引:0,他引:1  
针对太湖梅梁湾独特的地理位置和富营养化严重的问题,利用太湖水量水质模型和梅梁湾藻类生长模型,在对模型进行了率定、验证的基础下,模拟了在东南风和西北风两种常见风向的条件下,太湖主体湖区对梅梁湾内营养盐浓度和藻类浓度的影响情况,并将其影响定量化。本次模拟较好地反映了太湖主体湖区在两种常见风场的条件下对梅梁湾内水质影响情况。模拟得到以下结果:在不考虑风场和流场的情况下,梅梁湾内部2001年8月藻类平均浓度为43.18 mg/m3,总氮浓度为2.48 mg/L,总磷浓度为0.248 mg/L,只考虑东南风引起流场的情况下,藻类浓度为41.92 mg/m3,总氮浓度为2.07 mg/L,总磷浓度为0.231 mg/L;考虑东南风风场和流场两个因素的情况下,藻类浓度为53.86 mg/m3,总氮浓度为2.06 mg/L,总磷浓度为0.229 mg/L;同期,只考虑西北风风场的情况下,藻类浓度为42.55 mg/m3,总氮浓度为2.19 mg/L,总磷浓度为0.232 mg/L;考虑西北风风场和流场两个因素的情况下,藻类浓度为50.71 mg/m3,总氮浓度为2.17 mg/L,总磷浓度为0.233 mg/L。结果表明,梅梁湾内部的氮、磷等营养盐浓度受到由太湖主体湖区的风场变化引起的湖流扰动的一定影响;太湖主体湖区对梅梁湾内部藻类浓度的影响主要是由藻类漂移引起的,由营养盐浓度改变而引起的藻类浓度变化非常小。  相似文献   

6.
通过监测鄱阳湖枯水期的主湖区、五河入湖口以及碟形湖表层水体氮、磷等营养浓度以及重金属含量变化,对鄱阳湖全湖的营养状况以及重金属污染现状进行了系统分析。结果表明:2010年枯水期的鄱阳湖流域表层水体总氮、总磷、化学需氧量等含量较高,达富营养化水平,湖泊水质受总氮、氨态氮、总磷和pH的影响较大。且鄱阳湖水域的氮、磷等营养存在明显的空间差异。研究结果进一步显示,饶河入湖口水体N、P污染最严重(TN 314 mg/L;TP 025 mg/L),修河入湖口污染程度次之(TN 134 mg/L;TP 009 mg/L),而南矶山碟形湖水体污染最小(TN 049 mg/L;TP 005 mg/L)。鄱阳湖表层水体重金属Pb、Cd的含量较低,符合国家渔业水质标准要求,尤其是湖泊Cd含量低于地表水I类标准。但鄱阳湖流域Cu、Zn污染较严重  相似文献   

7.
丰水期鄱阳湖氮磷含量变化及来源分析   总被引:11,自引:0,他引:11  
通过系统测定丰水期鄱阳湖湖水、主要支流水、长江水及部分农田水、地下水及城市污水的氮磷含量,对其氮磷含量变化及来源进行了分析,结果表明,鄱阳湖水体中主要的氮素形式是硝酸盐氮(090 mg/L),赣江是其主要贡献者。鄱阳湖五大支流氮磷含量存在着较大的差异,赣江NO-3 N含量明显高于鄱阳湖其它主干流,而NH+4 N和TN含量以饶河的最高,TP以信江的最高。农田水、城市废水以及地下水含有较高的氮磷含量,是鄱阳湖及其五大支流氮磷的主要来源。农田水TN和TP含量最高,分别为1347、2863 mg/L。高含量的NO-3 N(735 mg/L)和NH+4 N(548 mg/L)分别出现在地下水和城市污水中。鄱阳湖水体氮负荷较大,N/P比值远大于7〖DK〗∶1。受滞留区及赣江和修水补给的影响,鄱阳湖主河道氮含量变化从上游至下游呈总体上升趋势。鄱阳湖湖体氮含量以下游最高,滞留区次之,上游主河道最低,TP含量呈相反的趋势变化。底层沉积有机物的降解和扰动导致鄱阳湖水体底层NO-3 N、NH+4 N、TN、TP的含量高于表层。  相似文献   

8.
汉江是长江中游最大的支流,近年来水质污染日趋严重,且范围有逐渐扩大趋势。随着流域内经济社会发展用水量增长以及2014年南水北调中线一期工程建成引水,汉江中下游流域水资源、水生态环境压力日益显现,流域管理面临较大挑战。利用汉江中下游干流襄阳、仙桃和汉口3个主要的水质监测控制断面1998~2011年实测水质资料中5个水质项目,采用季节性肯达尔检验法对其项目进行了变化趋势检验与分析,并用叠加型指数法验证趋势分析的合理性;结合Hurst指数分析了趋势变化的持续性,结果表明季节性肯达尔检验法方法合理,持续性分析结果可预测未来水质变化,并为水环境保护和管理提供技术参考。  相似文献   

9.
丹江口库区典型小流域水体氮素分布特征研究   总被引:1,自引:0,他引:1  
丹江口水库水质总体良好,但总氮浓度超标问题突出。为明确不同类型小流域氮素的分布和输出特征,优化制定库区控氮措施,选择库周典型小流域,开展水体氮素浓度系统观测和分析。结果显示:(1)余家湾(养殖型)总氮浓度平均为21.23 mg/L,五龙池(村落型)总氮浓度平均为4.00 mg/L,高于钱家沟(自然型)和张沟(农田型);五龙池(村落型)硝态氮浓度最高,平均为2.37 mg/L,张沟最低,平均为1.06 mg/L;余家湾(养殖型)氨氮浓度远高于钱家沟(自然型)、五龙池(村落型)和张沟(农田型)。(2)钱家沟(自然型)氨氮浓度沿程下降趋势显著(p0.05);张沟(农田型)硝态氮(p0.01)和总氮浓度(p0.01)沿程上升趋势显著,坑塘湿地等微地形结构可能是影响小流域氮素的沿程变化的主要因素。(3)钱家沟(自然型)和五龙池(村落型)氮素冬季(12~2月)浓度较高,夏秋季(6~11月)浓度较低,春季(3~5月)波动最大;张沟(农田型)氮素高值出现在6月;余家湾(养殖型)氮素浓度高值出现在8月。(4)余家湾(养殖型)氮素以氨氮为主,五龙池(村落型)、张沟(农田型)和钱家沟(自然型)以硝态氮为主。基于上述结论,后续丹江口库区氮素控制应系统梳理不同类型小流域的分布和数量,重点关注养殖型小流域的氨氮污染和村落型小流域的硝态氮污染。  相似文献   

10.
了解不同介质的营养盐分布可以全面掌握河流的环境现状。为了调查西苕溪干流的营养盐分布特征和水质现状,沿着干流采集了11个点位的水体、悬浮物和表层沉积物样品,并对水体、悬浮物和表层沉积物中的营养盐特征进行了分析,拟为苕溪流域的水污染防治提供基础数据。研究表明:整个西苕溪干流,水体和沉积物中总氮(TN)和总磷(TP)浓度均存在丰水期明显高于枯水期的季节变化特征,水体中总氮的浓度均超出地表水环境质量Ⅴ类的标准,显示氮污染是西苕溪流域的特点。相关性分析结果表明,悬浮物中的TN和有机质(OM)呈极显著性正相关(r=0.974,p0.01);水体中的TN和悬浮物的各营养盐指标之间的相关性均达到了极显著水平,但沉积物营养盐指标与水体的TN和TP相关性不明显,显示沉积物并不能很好反映流域水质的现状。  相似文献   

11.
十一五期间中央环境保护专项资金下达近91亿元,为我国环境污染防治和监管基础能力建设提供了强有力的资金保障。随着财政资金使用改革的不断深入,财政部和环保部对中央环境保护专项资金的管理已从过去以评审为中心转变为以绩效为中心,无论在资金投向、分配方式、过程管理、绩效评估等方面都紧密围绕环境绩效这一中心开展。本文在对十一五期间中央环境保护专项资金资金分配总体情况总结归纳的基础上,分析了资金分配方式制约绩效发挥的主要问题,以改革创新资金分配方式、提高环境绩效为目的,对中央统筹法、项目申报法、因素分配法等三种分配方式提出了若干改革优化的建议。  相似文献   

12.
Refrigerants used in refrigerators are an important source of ozone depleting substances released into the atmosphere, and can have a significantly negative effect on the hole in the ozone layer. But most-emission of refrigerants is man-made, unreasonable and needless. Since in most emission cases the refrigerants are contained in the refrigerators, we can retrieve them by some technique that changes the 'manual emission' into manual retrieving. To promote the retrieval action and diminish the pollution, society can use economic, administrative and technical countermeasures, which can create a 'good-cycle' both 'harnessing pollution and earning income simultaneously', reinforce the motive of retrieving, and retrieve most proportion of refrigerants used by'all refrigerators. This 'good-cycle' method can be easily promoted, and also a valuable way to promote other forms of environmental protection. The three countermeasures have almost no social cost, even no cost at all.  相似文献   

13.
Abstract

Refrigerants used in refrigerators are an important source of ozone depleting substances released into the atmosphere, and can have a significantly negative effect on the hole in the ozone layer. But most emission of refrigerants is man-made, unreasonable and needless. Since in most emission cases the refrigerants are contained in the refrigerators, we can retrieve them by some technique that changes the ‘manual emission’ into manual retrieving. To promote the retrieval action and diminish the pollution, society can use economic, administrative and technical countermeasures, which can create a ‘good-cycle’ both ‘harnessing pollution and earning income simultaneously’, reinforce the motive of retrieving, and retrieve most proportion of refrigerants used by all refrigerators. This ‘good-cycle’ method can be easily promoted, and also a valuable way to promote other forms of environmental protection. The three countermeasures have almost no social cost, even no cost at all.  相似文献   

14.
The results of more than 1 yr of air monitoring inside and outside of five homes in each of two communities are presented for SO2, NO2, mass respirable particles, SO4, Al, Br, Cl, Mn, Na, and V. Outdoor measurements across the home site in each city are consistent with proximity to outdoor sources. Looking across indoor residential sites in each city, the home appears to alter outdoor concentrations in several ways. Indoor level of SO2, SO4, Mn, and V are lower than those measured outdoors. These constituents are thought generally to result from outdoor sources. The other constituents studied are at times found in excess within homes. In some cases the source or sources of excess concentration of a particular constituent could be identified; often, however, the source of excess indoor concentration could not be identified.  相似文献   

15.
The proposed conversion from gasoline powered automobiles to diesel powered vehicels has prompted the Environmental Protection Agency to evaluate the potential health effects associated with exposure to diesel emissions. At present, there is no direct epidemiological link between this exposure and human health. Therefore, a research program was constructed to compare the health effects associated with diesel emissions with those from other emission sources for which epidemiological information was available. The emission sources chosen were cigarette smoke, roofing tar, and coke oven. An additional comparative emission source which was a gasoline catalyst engine. Respirable particles from a variety of combustion sources have the potential of being carcinogenic and mutagenic. The objective of these studies was to determine the relative biological activity of the organic material adsorbed on these particles in both in vitro mutagenesis and in vitro and in vivo bioassays. The organic extracts from the following series of emission sources were quantitatively bioassayed in a matrix of tests for their carcinogenic and mutagenic activity: (1) a light-duty Oldsmobile diesel 350 engine; (2) a heavy-duty Caterpillar diesel engine; (3) a light-duty Nissan engine; (4) a Volkswagen Rabbit diesel engine; (5) cigarette smoke; (6) roofing tar; (7) coke oven; and (8) a gasoline catalyst Mustang. The test matrix consisted of the following bioassay: reverse mutation in Salmonella typhimurium; mitotic recombination in Saccharomyces cerevisiae; DNA damage in Syrian hamster embryo cells (SHE); sister chromatid exchange in CHO cells; gene mutation in L5178Y mouse lymphoma cells, Balb/c 3T3 mouse embryo fibroblasts and CHO cells; viral enhancement of SHE cells; oncogenic transformation in Balb/c 3T3 cells; and skin tumor initiation in SENCAR and C57 black mice. The results of this test matrix are discussed.  相似文献   

16.
The widespread use of brominated flame-retarded products in the last two decades has resulted in an increasing presence of bromine in thermal processes such as waste combustion and accidental fires. Brominated and brominated-chlorinated dibenzodioxins and dibenzofurans (PBDDs/PBDFs, PXDDs/PXDFs) are micropollutants of concern arising from such processes. The present review aims to evaluate the relevance of these compound classes in actual thermal processes. Four categories of thermal processes are discussed in this respect according to their potential for PBDD/PBDF and PXDD/PXDF generation: thermal stress, pyrolysis/gasification, insufficient combustion conditions and controlled combustion conditions. Under thermal stress situations, as they may occur in production or recycling processes, PBDDs/PBDFs precursors like polybrominated diphenylethers (PBDE) can have a relevant potential for PBDD/PBDF formation via a simple elimination. Under insufficient combustion conditions as they are present in, e.g. accidental fires and uncontrolled burning as well as gasification/pyrolysis processes, considerable amounts of PBDDs/PBDFs can be formed from BFRs, preferably via the precursor pathway. In contrast, under controlled combustion conditions, BFRs and PBDDs/PBDFs can be destroyed with high efficiency. The relevance of de novo synthesis of PXDDs/PXDFs is discussed for this condition.Providing a basis for the understanding of PXDD/PXDF formation in actual thermal processes, the present paper also summarises the formation pathways of brominated and brominated-chlorinated PXDDs/PXDFs from brominated flame retardants (BFRs) investigated during laboratory thermolysis experiments. Relevant mechanistic steps for PBDD/PBDF formation from brominated precursors are discussed including elimination reactions, condensation steps and debromination/hydrogenation reactions.In addition, chlorination/bromination and halogen exchange reactions are briefly discussed with respect for their relevance on the final distribution of PBDDs/PBDFs, mixed chlorinated PXDDs/PXDFs and PCDDs/PCDFs resulting from thermal processes.  相似文献   

17.
Harbour seals (Phoca vitulina) and harbour porpoises (Phocoena phocoena) are top predators in the North Sea and consequently accumulate a variety of pollutants in their tissues. Concentrations of polychlorinated biphenyls (PCBs), polybrominated diphenyl ethers (PBDEs) and their hydroxylated metabolites (HO-PCBs and HO-PBDEs) were measured in serum of wild harbour seals (n = 47) and captive harbour porpoises (n = 21). Both species exhibit long life spans and do not have extreme situations, such as complete fasting during periods of lactation, in their annual cycles. For PCBs, concentrations in adult males were slightly higher than in juveniles and lowest in juvenile females. For PBDEs, juveniles have higher levels than adult males and females, probably as a consequence of lactational transfer. However, differences between these age–gender groups were not statistical significant, indicating that individual variation was limited within each species, even without knowing the feeding status of the animals. Body condition, particularly emaciation, has a major influence on the levels of chlorinated and brominated contaminants in serum. Profiles of PCBs were CB 153 > CB 138 > CB 187 > CB 180 and CB 153 > CB 138 > CB 149 > CB 187 > CB 180 for harbour seals and porpoises respectively. For PBDEs, BDE 47 was the predominant congener followed by BDE 100 and 99 in both species. In harbour seals, concentrations of sum PCBs (median: 39,200 pg/ml) were more than 200 times higher than levels of sum PBDEs (median: 130 pg/ml) and almost 10 times higher than concentrations of sum HO-PCBs (4350 pg/ml). In harbour porpoises, concentrations of sum PCBs (median: 24,300 pg/ml) were about 20 times higher than concentrations of PBDEs (median: 1300 pg/ml). HO-PCBs were detected in only 4 harbour porpoises and this at very low concentrations. Naturally-produced MeO-PBDEs were only found in harbour porpoises at concentrations ranging from 120 to 810 pg/ml. HO-PBDEs were not found in any species. In general, harbour seals accumulate less compounds and have mostly lower concentrations than harbour porpoises possibly as a result of a better developed metabolism.  相似文献   

18.
探矿权资产化、证券化是我国改革探矿业投融资体制,解决探矿业资金瓶颈问题的关键。本文从制度建设、机构投资者的发展状况等方面分析了我国初步推行探矿权资产化、证券化的有利条件.指出了探矿权资产化、证券化的三种模式。并以基金模式和股权模式为例提出了实施探矿权资产化、证券化的步骤设想。  相似文献   

19.
中国工业化进程与能源矿产供需均衡的研究   总被引:2,自引:0,他引:2  
工业化与能源需求的均衡关系及解决工业化进程中能源供需失衡的战略途径是中国工业化进程中需要探讨的重大问题.文章运用协整技术,就1990-2008年间中国工业化进程与能源需求协整关系的检验,认为中国工业化与能源需求增长具有长期稳定的均衡关系,能源需求将继续保持增长,能源利用效率也将持续提高.然而工业化进程中重工业化高能耗结构特征与能源低效利用并存的困境以及能源供需矛盾不利于能源供需平衡的平稳发展.我国应适应工业化进程的基本规律,转变能源消费方式;走新型工业化道路,适当限制低附加值产业发展,鼓励产业向离附加值、低能耗、高技术产业转移;在实现能源开发利用技术进步和创新的同时.有效利用国内外能源资源;建立能源应急机制等战略途径来实现工业化进程中能源供需平衡发展.  相似文献   

20.
Fate and transport of pathogens in lakes and reservoirs   总被引:3,自引:0,他引:3  
Outbreaks of water-borne disease via public water supplies continue to be reported in developed countries even though there is increased awareness of, and treatment for, pathogen contamination. Pathogen episodes in lakes and reservoirs are often associated with rain events, and the riverine inflow is considered to be major source of pathogens. Consequently, the behaviour of these inflows is of particular importance in determining pathogen transport and distribution. Inflows are controlled by their density relative to that of the lake, such that warm inflows will flow over the surface of the lake as a buoyant surface flow and cold, dense inflows will sink beneath the lake water where they will flow along the bathymetry towards the deepest point. The fate of pathogens is determined by loss processes including settling and inactivation by temperature, UV and grazing. The general trend is for the insertion timescale to be shortest, followed by sedimentation losses and temperature inactivity. The fate of Cryptosporidium due to UV light inactivation can occur at opposite ends of the scale, depending on the location of the oocysts in the water column and the extinction coefficient for UV light. For this reason, the extinction coefficient for UV light appears to be a vitally important parameter for determining the risk of Cryptosporidium contamination. For risk assessment of pathogens in supply reservoirs, it is important to understand the role of hydrodynamics in determining the timescale of transport to the off-take relative to the timescale of inactivation. The characteristics of the riverine intrusion must also be considered when designing a sampling program for pathogens. A risk management framework is presented that accounts for pathogen fate and transport for reservoirs.  相似文献   

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