活性污泥法数学模型的发展与展望

活性污泥法数学模型在污水处理厂的设计、运行控制和工艺优化等方面发挥着日益重要的作用,目前已成为了污水处理领域的研究热点。本文综述了活性污泥法数学模型的研究和发展过程,重点介绍了IWA模型的特点及其在国内外的研究现状。最后对模型的研究和应用进行了展望,认为今后可以在完善机理,模块化模型,混合模型等方面作进一步的研究。     

工业污水可生物降解性评价方法研究

针对生化系统经常遭受异常进水或毒性物质冲击的情况,提出了以耗氧速率(OUR)和相对耗氧速率(SOUR)快速评价污水可生物降解性的方法,以提高活性污泥系统的处理效率和运行管理水平。试验结果表明:OUR和SOUR对异常pH值水质条件以及苯酚、甲醛和甲醇等毒性物质的存在都非常敏感。对于大庆石化公司水气厂化工污水处理场的活性污泥来说,甲醛对微生物的毒性最强,甲醇次之,而苯酚则最弱。化工污水处理场活性污泥对三者的允许浓度分别为70、170、350 mg/L。     

间歇式活性污泥法处理1-4丁二醇废水的研究

用间歇式活性污泥法(SBR法)对高浓度1-4丁二醇废水进行了处理研究。实验测定了污泥沉降性能,测试了最佳曝气时间、最佳pH值范围以及SBR处理系统耐污染的负荷。实验结果表明:SBR法的污泥沉降比为15%～30%,完全符合活性污泥正常运行时的沉降标准。处理污水的最佳曝气时间为5h,最佳pH值范围为7～8。该处理系统耐冲击,能承受较高的污染负荷,对水质的波动有较强的承受能力。利用SBR法可以处理1-4丁二醇、聚丙烯酰胺和顺丁烯二酸酐三套装置排放的混合污水。     

数学模拟在污水处理厂节能减排中的应用和发展

在国内外节能减排的大背景下,污水处理厂面临着巨大的提标改造和节能减排压力。基于活性污泥数学模型的数学模拟技术在国内外许多污水处理厂的模拟仿真、运行诊断与工艺优化、升级评估、节能减排等方面得到广泛的应用,文章主要介绍了数学模拟技术在污水处理厂节能减排方面的发展和应用情况,并提出今后国内的主要研究方向。     

活性污泥工艺中污水毒性研究的现状

活性污泥法是污水处理中应用最为广泛的技术之一,但目前国内外活性污泥工艺中污水毒性研究还很少。本文从目前活性污泥的工艺选择和污水回用的现状出发,对活性污泥工艺中污水毒性测试方法以及毒性研究的现状进行了综述,并对现存问题给出了分析和建议。     

BBR系统低温脱氮简析

BBR工艺是一种新型的污水生物处理方法,采用生物膜法(BBR装置)和活性污泥法(BBR生化池)相结合的组合生化处理工艺。文章以海晏城镇污水处理厂为例,污水厂采用BBR工艺,通过对现场运行数据的检测分析,对BBR工艺在低温条件下处理城镇污水的工艺原理进行了分析探讨。     

间歇曝气法对AB工艺污泥膨胀的控制

以某污水处理厂发生污泥膨胀事故造成出水水质超标为例，介绍了AB活性污泥法发生污泥膨胀现象的原因、控制方法及处理过程。     

循环式活性污泥法在污水处理厂的应用

城市污水处理是一项重要而艰巨的工作,循环式活性污泥法能有效处理城市生活污水和工业废水。文章分析了循环式活性污泥法(CAST)工艺构成和工艺特点,以工程实例介绍了工艺路线并计算调试参数,为城市污水处理厂CAST工艺的调试提供理论依据。     

大型污水处理厂收理处费的合理性探讨

活性污泥法的处理系统具有日处理量大、处理成本低、可处理污水的种类多等优点而为各大型污水处理厂所应用。然而大型的活性污泥污水处理厂,对各污水排放厂收费的合理性上却存在不少问题,通俗地讲,就是未能严格地实行“按质定价”。     

石化废水处理模式研究

集中式污水处理厂核心工艺基本上都是生化处理工艺,在末端处理已有生化处理工艺时,生化法预处理是否必要,是文章讨论的重点。文章通过对石化废水典型特征污染物活性污泥生物毒性测试结果的统计分析,以污水处理数学模拟软件Biowin为平台,建立了集中式污水处理厂及点源预处理的数学模型,构建了废水直接排入污水处理厂和经预处理后再入污水处理厂两种处理模式,实验研究得出:对于某些污染物,通过生物法点源预处理,延长停留时间,将提高去除效果。为该类废水的高效处置提供借鉴。     

‘强化一级物化法’处理生活污水技术

以广州电池厂及华南缝纫机公司的生活污水治理工程为例,介绍了用EWP高效污水净化器的强化一级物化法处理城市生活污水的技术特点、工艺流程和工程实践。该物化法比常规的生化法降低投资成本1／2以上,占地面积减少2／3以上,处理效果较好。     

Fenton氧化法在废水处理中的应用

Fenton氧化技术在水处理中的运用正得到越来越多的关注，本文总结了Fenton氧化技术的发展和研究现状，包括Fenton试剂反应机理，影响因素（pH,[Fe^2 ]/[H2O2],反应温度，投加方式，化学絮凝），反应动力学，改良形式等，并认为Fenton氧化技术是一种很有应用前景的废水处理技术。     

Modeling of real scale waste activated sludge anaerobic digestion process by Anaerobic Digestion Model 1 (ADM1)

In this study, real-scale wastewater treatment plant (Hurma WWTP) sludge anaerobic digestion process was modeled by Anaerobic Digestion Model (ADM1) with the purpose of generating the data to understand the process better by contributing to the prediction of the process operational conditions and process performance, which will be a base for future anaerobic sludge stabilization process investments.

Real-scale anaerobic sludge digestion process data was evaluated in terms of known process and state variables and also process yields. Average VS removal yield, methane production yield, and methane production rate values of the anaerobic sludge digestion unit were calculated as 46.4%, 0.49 m³CH₄/kg VS_removed, and 0.33 m³ CH₄/m³day, respectively. In this study, ADM1 was intended to predict the behavior of real-scale anaerobic digester processing sewage sludge under dynamic conditions. To estimate the variables of real-scale sludge anaerobic digestion process with high accuracy and to provide high model prediction performance, values of the four parameters (disintegration rate constant, carbohydrate hydrolysis rate constant, protein hydrolysis rate constant, and lipid hydrolysis rate constant) that have strong effects on structured ADM1 were estimated by using the parameter estimation module in Aquasim program and their values were found as 0.101, 10, 10, and 9.99, respectively. When the numbers of kinetic parameters with the processes included in ADM1 along with the dynamic and non-linear structure of the real scale anaerobic digestion were taken into consideration, model simulations were in good agreement with measured results of the biogas flow rate, methane flow rate, pH, total alkalinity, and volatile fatty acids.     

Prediction of groundwater contamination with multivariate regression and probabilistic capture zones

Probabilistic capture zones are combined with a regression model and used as buffer zones around wells for Tobit regression analysis to predict contaminant concentration of groundwater in an agricultural region. A backward transport equation, which is a mathematical model based on the physical processes of solute transport, is used to delineate probabilistic capture zones. The probabilistic capture zone defines the area where contaminant discharge can have a direct influence, with pertinent probability, on the quality of groundwater pumped from a well. Tobit regression analysis is used to find the relationship between independent regression variables and a dependent variable, which is contaminant concentration in this study. The capture zone and the regression are combined into a model, and its applicability for prediction of nitrate concentration is tested in a small agricultural basin in Chuncheon, Korea, which is occupied mainly by vegetation fields, orchards, and small barns. Three cases of Model 1, Model 2, and Model 3 are compared in which buffer zones are circles, capture zones with probability over 0.1, and capture zones divided into sections with different probabilities, respectively. The resulting regression model describes nitrate concentration in terms of selected independent variables. When the concentrations are calculated with the model, the best fit with the observed concentrations was in Model 3. This result supports the applicability of the method proposed in this study to prediction of contaminant concentration of groundwater.     

A MATHEMATICAL MODEL FOR OPTIMUM DESIGN AND CONTROL OF METROPOLITAN WASTEWATER MANAGEMENT SYSTEMS1

ABSTRACT: A comprehensive mathematical model (Urban Wastewater Management Model) has been developed to continuously simulate time-varying wastewater flows and qualities in complex metropolitan combined sewerage systems. The model serves three functions: (1) assessment of existing or planned system performance in relation to other wastewater discharges in either a metropolitan or river basin area; (2) determination of the optium operation or automatic control of existing or planned systems during rainstorms; and (3) determination of the most economically feasible combination of design alternatives for improving or expanding existing systems to meet specified performance criteria. The model provides an efficient engineering tool for evaluating and controlling pollutant discharges from combined sewerage systems (including treatment plants) to receiving waters, while considering the time and spacial variations of rainfall and dry-weather flows and qualities as well as economic constraints.     

Modelling Escherichia coli concentration in a wastewater reservoir using an operational parameter MRT%FE and first order kinetics

The operational parameter MRT%FE, representing the mean residence time of different ages fractions of effluent within a completely mixed reactor, was evaluated and integrated with first order kinetics. The parameter was used to model Escherichia coli concentrations in a municipal wastewater reservoir managed under different operating conditions (continuous and discontinuous). The study was conducted during 2004-2005 in a reservoir receiving effluents from the activated sludge treatment plant of Caltagirone (Eastern Sicily - Italy). The analytical approach is applied to the hydraulic state variables of the system (daily stored volumes, inlet and outlet flows), and the physical-chemical (pH, temperature, EC, TSS, BOD(5), COD) and bacteriological wastewater parameters (E. coli, FC, FS). In order to evaluate the reliability of the proposed approach, predicted E. coli concentrations within the reservoir were compared with measured ones by the correlation coefficient, F-test and Sperman's index. The study included the evaluation of die-off coefficient K(T) (d(-1)), light extinction coefficient K (m(-1)) and their relationships with climatic factors. Results of the study confirm that E. coli removal is related to the fractions of fresh effluent remaining each day within the reservoir with MRT%FE of about 5-8d, significantly lower than the nominal detention time (about 27d). The E. coli die-off coefficient (K(T)) was higher during system discontinuous operations and correlated with incident solar radiation and water temperature.     

珠江三角洲经济区污水系统设计原则

分析了珠江三角洲经济区水环境现状；阐述了城市污水分散处理与集中处理的利弊；指出污水深度处理与回用是形成良性水循环的有效途径，更是经济可持续发展的必然要求；通过对已建排水系统存在问题的分析，探讨了珠江三角洲经济开发区污水系统的设计原则，认为污水系统规划要改变传统设计方法，应方便再生水回用，由经济、技术、地理等综合因素确定排水分区、污水厂厂址与数量，选择适合各排水区域水质水量的工艺流程，预留污水厂与再生水回用管线分期发展的空间，应优先选用国产污水处理设备，尽可能维持城市河涌自然生态。     

生物化学法处理含酚废水的研究进展

含酚废水来源广、数量多，对人体和动植物都有很大的危害，因此．．必须对舍酚废水进行有效的处理。综述了含酚废水的处理技术和处理结果，特别是对生物法处理含酚废水的现状与发展进行了介绍和评述。     

用超声气浮—BAF组合工艺处理油田稠油污水

利用超声气浮处理机对稠油油田污水进行的室内试验研究结果表明,超声气浮工艺对污水中COD的去除效果不明显,去除率只有23.0%。但是,经超声气浮处理后,污水的可生化性明显得到改善,BOD5/CODcr值由0.18上升到0.31,这为稠油污水的二级生化处理创造了条件。稠油污水经超声气浮-BAF组合工艺处理后,出水水质可达到国家GB8978-1996一级标准的水质要求。     

含油污水中硫化物的处理技术

含油污水中的S2-穿透力强,易使管壁穿孔,破坏管线系统,干扰正常生产。介绍了油田污水中硫化物的处理方法,如加氯法、中和法、曝气法、氧化法、沉淀法。选用氧化法与沉淀法对双河站含硫污水进行了除硫实验,在实验中加入了自制的氧化型药剂Y-1、Y-2及沉淀型药剂F-1、F-2。实验结果表明,采用氧化法时,用Y-1处理剂的效果更好,除硫率均达到93%以上;而采用沉淀法时,用F-1与F-2处理剂的效果相当。当加药量达到最大时,除硫率全部达到99%以上。