Evaluation of the macroalga,muskgrass, for the phytoremediation of selenium-contaminated agricultural drainage water by microcosms

Previous field studies suggested that the macroalga, muskgrass (Chara canescens Desv. & Lois), plays an important role in the removal of selenium (Se) from agricultural drainage water. This study evaluated the efficiency of Se removal from drainage water by muskgrass-vegetated wetland microcosms, and determined the extent to which muskgrass removed Se through phytoextraction and biovolatilization. Six flow-through wetland microcosms were continuously supplied with drainage water containing an average Se concentration of 22 microg L(-1) over a 24-d experimental period. The Se mass input and outflow and the rate of Se volatilization were monitored daily for each microcosm. Three microcosms containing muskgrass reduced the daily mass Se input in the inflow drainage water by 72.1%; this compared with a reduction of 50.6% of the mass Se input for three unvegetated control microcosms. Selenium accumulated in muskgrass tissues accounted for 1.9% of the total mass Se input in the microcosm, followed by 0.5% via biological volatilization. The low rates of Se volatilization from selenate-supplied muskgrass, which were 10-fold less than from selenite, were probably due to a major rate limitation in the reduction of selenate to organic forms of Se in muskgrass. This conclusion was derived from X-ray absorption spectroscopy speciation analysis, which showed that muskgrass treated with selenite contained 91% of the total Se in organic forms (selenoethers and diselenides), compared with 47% in muskgrass treated with selenate.     

Anaerobic degradation of atrazine and metolachlor and metabolite formation in wetland soil and water microcosms

The half-lives, degradation rates, and metabolite formation patterns of atrazine (6-chloro-N2-ethyl-N4-isopropyl-1,3,5-triazine-2,4-diamine) and metolachlor [2-chloro-N-(2-ethyl-6-methylphenyl)-N-(2-methoxy-1-methylethyl) acetamide] were determined in an anaerobic wetland soil incubated at 24 degrees C for 112 d. At 0, 7, 14, 28, 42, 56, and 112 d, the soil and water were analyzed for atrazine and metolachlor, and their major metabolites. The soil oxidation-reduction potential reached -200 mV after 14 d. Degradation reaction rates were first-order for atrazine in anaerobic soil and for metolachlor in the aqueous phase. Zero-order reaction rates were best fit for atrazine in the aqueous phase and metolachlor in anaerobic soil. In anaerobic soil, the half-life was 38 d for atrazine and 62 d for metolachlor. In the aqueous phase above the soil, the half-life was 86 d for atrazine and 40 d for metolachlor. Metabolites detected in the anaerobic soil were hydroxyatrazine and deethylatrazine for atrazine, and relatively small amounts of ethanesulfonic acid and oxanilic acid for metolachlor. Metabolites detected in the aqueous phase above the soil were hydroxyatrazine, deethylatrazine, and deisopropylatrazine for atrazine, and ethanesulfonic acid and oxanilic acid for metolachlor. Concentrations of metabolites in the aqueous phase generally peaked within the first 25 d and then declined. Results indicate that atrazine and metolachlor can degrade under strongly reducing conditions found in wetland soils. Metolachlor metabolites, ethanesulfonic acid, and oxanilic acid are not significantly formed under anaerobic conditions.     

Cadmium in aquatic microcosms: Implications for screening the ecological effects of toxic substances

A two-phase set of experiments was conducted to address some of the problems inherent in ecological screening of toxic substances in aquatic microcosms. Phase I was a 4×4 factorial experiment dealing with the interactive effects of cadmium and nutrients in static microcosms. Phase II was a 2×4 factorial experiment using flowthrough microcosms to study temporal aspects of system behavior in response to nutrient loading and chronic versus acute cadmium perturbations. Nutrient enrichment resulted in increased biomass and metabolic activity in both static and flowthrough microcosms. Cadmium treatments generally resulted in a decrease in abundance of grazing crustaceans and a subsequent increase in community respiration, suggesting a change in community structure from a grazing to a detritus food chain. Of the variables measured, community metabolism, community composition, and output/input ratios of nitrate-nitrogen were the most useful indicators of system response to cadmium. Nutrient enrichment significantly influenced cadmium effects with respect to most of the variables measured; high levels of enrichment reduced the effects of cadmium. For screening the ecological effects of toxic chemicals, a series of experiments is proposed, including 1) relatively simple static microcosms, 2) flow through microcosms, and 3) more detailed but selective studies in microcosms derived from specific ecosystems. Each step yields increasingly more information and serves as a guide for subsequent experiments; in addition, each step more closely approximates natural ecosystems.     

The real water consumption behind drinking water: the case of Italy

The real amount of drinking water available per capita is a topic of great interest for human health and the economic and political management of resources. The global market of bottled drinking water, for instance, has shown exponential growth in the last twenty years, mainly due to reductions in production costs and investment in promotion. This paper aims to evaluate how much freshwater is actually consumed when water is drunk in Italy, which can be considered a mature bottled-water market. A Water Footprint (WF) calculation was used to compare the alternatives: bottled and tap water. Six Italian brands of water sold in PET bottles were inventoried, analysed and compared with the public tap water of the city of Siena, as representative of the Italian context. Results showed that more than 3 L of water were needed to provide consumers with 1.50 L of drinking water. In particular, a volume of 1.50 L of PET-bottled water required an extra virtual volume of 1.93 L of water while an extra 2.13 L was necessary to supply the same volume of tap water. These values had very different composition and origin. The WF of tap water was mainly due to losses of water during pipeline distribution and usage, while WF of bottled water was greatly influenced by the production of plastic materials. When the contribution of cooling water was added to the calculation, the WF of bottled water rose from 3.43 to 6.92 L. Different strategies to reduce total water footprint are discussed.     

Application of groundwater thresholds for trace elements on percolation water: a case study on percolation water from Northern German lowlands

The German insignificance thresholds (GFS) for groundwater, derived with an added risk approach, will soon be adopted as trigger values for percolation water entering groundwater. The physicochemical properties of the vadose zone differ considerably from those of groundwater, which may lead to difficulties in the applicability of groundwater-derived GFS to percolation water. To test the applicability of the GFS to percolation water regarding the concentration level and the field-scale variability, 46 sites in Northern Germany were sampled, including arable land, grassland, and forest, situated on three spatially dominant parent materials: sand, glacial loam, and loess. Concentrations of As, Ba, Cd, Co, Cr, Cu, Mo, Ni, Pb, Sb, Sn, V, Zn, and F were analyzed in percolation water from the transition between the unsaturated to the saturated zone. We compared median and 90th percentile values of the background concentrations with the GFS. In more than 10% of all samples, background concentrations of Cd, Co, Ni, V, or Zn exceeded the GFS. We evaluated the applicability of the GFS on field-scale medians of background concentrations taking field-scale interquartile distance and the bootstrap percentile confidence interval of the field scale median of trace element background concentrations into consideration. Statements about exceedance or nonexceedance of GFS values could only be made with acceptable statistical uncertainty (α ≤ 0.1) when operational median concentrations were about one third higher or lower than the corresponding GFS.     

Quantification of potable water savings by residential water conservation and reuse - A case study

To demonstrate the benefits of water conservation at the household level in regional Victoria in Australia, a family house “Sharland Oasis” was designed and built according to an ecologically sustainable design for improved water and energy efficiency. This study has demonstrated that the combined use of alternative water supplies together with water efficient appliances can save up to 77% of total potable water use compared to the average 1990s household water use in the same region considering the location and differing in water use approach. The use of rainwater inside the home alone saved up to 40% of potable water use. In addition to the water savings, there is a significant wastewater discharge saving achieved through the use of water conservation strategies and greywater reuse. A community survey undertaken in regional Victoria revealed that community receptivity for reusing greywater is highest for uses, such as watering gardens and flushing toilets; but it progressively decreased with increasing personal contact with greywater. Positive perception of greywater reuse needs to be encouraged through programs targeted at developing resources, skills and motivation for new water reuse practices and technologies, across a diverse range of social groups.     

Evaluation of alternative water sources for commercial buildings: A case study in Brisbane,Australia

Commercial buildings are central to cities and contribute significantly to the urban demand for natural resources, including freshwater. Green building benchmarking tools include more efficient water use as key indicator of sustainability. This paper explores options for substituting mains drinking water with an alternative, non-potable water source on a fit for purpose basis. The research findings are based on a monitoring study of a commercial building in Brisbane, Australia that is harvesting rainwater for meeting non-potable water demand. The results demonstrated that the system is only achieving moderate reliability in meeting demand due to operational problems. The case study analysis has highlighted the need to include validation and monitoring to ensure the system is operating as per design intent. The paper also investigates the potential of other local, non-potable water sources for high-rise commercial buildings, in particular air conditioning condensate and groundwater inflow to a basement wet well. The paper concludes by comparing the advantages and disadvantages of different local water sources which highlights the need to undertake a site specific investigation to identify a suitable alternative water source, which considers O&M complexity and the capacity of facilities management.     

A multicriteria approach for mapping risks of agricultural pollution for water resources: The Venice Lagoon watershed case study

A multicriteria analysis system was developed for producing risk maps of agricultural pollution due to alternative cultivation systems in the Watershed of the Lagoon of Venice (WLV) in Italy. Results of a field-scale simulation model for agricultural diffuse pollution were used to compile a matrix of environmental impacts, in terms of pollution indices. The most widespread combinations of typical environments (as defined by combinations of soil and climate variables) and alternative land uses (types of crops and cultivation systems) were described in the impact matrix. Land use in terms of crop distribution was based on census data. Two alternative cultivation systems were defined on the basis of the recent changes to the European Common Agricultural Policy: ordinary and eco-compatible. The effects of alternative scenarios were evaluated in terms of pollution risks for water resources. The evaluation procedure was built into the framework of a geographical information system to take into account the spatial features of pollution phenomena, vulnerability of the land and risk for water resources. The results demonstrated the great potential of eco-compatible practices for reducing the risks for surface and groundwater (−15 and −50%, respectively).     

The evolution of regional cross-border water regimes,the case of Deltarhine

In this study, we look at the evolution of a cooperative water regime in the delta of the Rhine catchment. In a Dutch–German case study, we focus on cross-border cooperation on the local and regional scale, describing and analyzing how a remarkably resilient and robust transboundary water regime has evolved over the course of 50 years. Context-, interest- and knowledge-based explanations contribute important insights into the evolution of the Deltarhine regime, and it is shown that the legal, institutional and socio-economic context shapes and constrains regional cross-border cooperation. Surprisingly in this regard, we find that European water directives have not yet played a decisive, catalyzing role for policy harmonization across borders. Finally, we show that key individuals play a crucial role in regime formation and development. We suggest that the presence of entrepreneurs and leaders adds explanatory power to current conceptual frameworks in international river basin management, thus meriting further research.     

An improved water footprint methodology linking global consumption to local water resources: a case of Spanish tomatoes

A water footprint (WF) measures the total water consumed by a nation, business or individual by calculating the total water used during the production of goods and services. This paper extends the existing methods for WF to more localised levels for crops grown partly in open systems and partly in plastic-covered houses with multi-seasonal harvesting, such as the horticulture industry in Spain. This improvement makes it possible to visualise the links of EU tomato consumption to precise production sites in Spain and opens a debate to the usefulness of such findings. This paper also compares existing ecological methodologies with WF and argues that both life cycle analysis (LCA) and ecological footprint (EF) models could benefit from WF methods. Our results show that the EU consumes 957,000 tons of Spanish fresh tomatoes annually, which evaporates 71 Mm(3)/yr of water and would require 7 Mm(3)/yr of water to dilute leached nitrates in Spain. In Spain, tomato production alone evaporates 297 Mm(3)/yr and pollutes 29 Mm(3)/yr of freshwater. Depending upon the local agro-climatic character, status of water resources, total tomato production volumes and production system, the impact of EU consumption of fresh tomatoes on Spanish freshwater is very location specific. The authors suggest that business now seek to report and address negative impacts on the environment. WF opens the door to complex water relationships and provides vital information for policy actors, business leaders, regulators and managers to their draw, dependence and responsibilities on this increasingly scarce resource.     

Drinking water risk assessment in practice: the case of Swedish drinking water producers at risk from floods

To achieve a safe and reliable drinking water supply, water producers need to manage a large range of risks regarding both water quality and quantity. A risk management approach where risks are systematically identified and handled in a preventive manner is promoted by the World Health Organization and supported by researchers and drinking water experts worldwide. Risk assessment is an important part of such a management approach, and a variety of tools for risk assessment are described in the literature. There is, however, little knowledge of how drinking water risk assessment is performed in practice, including which tools that are actually used. This study investigates the use of risk assessment tools, and the approach to risk management, on a local level in the Swedish water sector. It is based on interviews with key persons from a targeted selection of water producers. We find that the application of tools as well as the approach to risk assessment and management differs considerably between the water producers. The tools most frequently used are mainly the ones promoted or required by Swedish national organizations. Although many of the water producers have done some kind of risk assessment, most have not implemented a risk management approach. Furthermore, their knowledge of the concepts of risk and risk management is often limited. The largest challenge identified is to prioritize risk assessment, so that it is actually performed and then used as a basis for managing risk in a systematic way.     

A new and integrated hydro-economic accounting and analytical framework for water resources: a case study for North China

Water is a critical issue in China for a variety of reasons. China is poor of water resources with 2300m(3) of per capita availability, which is less than 13 of the world average. This is exacerbated by regional differences; e.g. North China's water availability is only about 271m(3) of per capita value, which is only 125 of the world's average. Furthermore, pollution contributes to water scarcity and is a major source for diseases, particularly for the poor. The Ministry of Hydrology [1997. China's Regional Water Bullets. Water Resource and Hydro-power Publishing House, Beijing, China] reports that about 65-80% of rivers in North China no longer support any economic activities. Previous studies have emphasized the amount of water withdrawn but rarely take water quality into consideration. The quality of the return flows usually changes; the water quality being lower than the water flows that entered the production process initially. It is especially important to measure the impacts of wastewater to the hydro-ecosystem. Thus, water consumption should not only account for the amount of water inputs but also the amount of water contaminated in the hydro-ecosystem by the discharged wastewater. In this paper we present a new accounting and analytical approach based on economic input-output modelling combined with a mass balanced hydrological model that links interactions in the economic system with interactions in the hydrological system. We thus follow the tradition of integrated economic-ecologic input-output modelling. Our hydro-economic accounting framework and analysis tool allows tracking water consumption on the input side, water pollution leaving the economic system and water flows passing through the hydrological system thus enabling us to deal with water resources of different qualities. Following this method, the results illustrate that North China requires 96% of its annual available water, including both water inputs for the economy and contaminated water that is ineligible for any uses.     

A process integration approach to industrial water conservation: a case study for a Chinese steel plant

A systematic approach to optimizing water network has traditionally been utilized to exam and plan water conservation in industrial processes. In the present case study, water-pinch technology was used to analyze and optimize the water network of a steel plant near China's Zhangjiakou city. A system design was developed and a limiting constraint (Cl(-) concentration) was identified based on investigations of water quality then the minimum freshwater and wastewater targets were determined without considering water losses. The analysis was then extended by calculating the additional input of freshwater required to balance the actual water losses. A nearest-neighbor algorithm (NNA) was used to distribute the freshwater and recycled water among each of the plant's operations. The results showed that with some reconstruction of the water network, the flow rates of freshwater and wastewater could be decreased by 57.5% and 81.9%, respectively.     

Multi-criteria analysis for improving strategic environmental assessment of water programmes. A case study in semi-arid region of Brazil

Multi-criteria analysis (MCA) is a family of decision-making tools that can be used in strategic environmental assessment (SEA) procedures to ensure that environmental, social and economic aspects are integrated into the design of human development strategies and planning, in order to increase the contribution of the environment and natural resources to poverty reduction. The aim of this paper is to highlight the contribution of a particular multi-criteria technique, the analytic hierarchy process (AHP), in two stages of the SEA procedure applied to water programmes in developing countries: the comparison of alternatives and monitoring. This proposal was validated through its application to a case study in Brazilian semi-arid region. The objective was to select and subsequently monitor the most appropriate programme for safe water availability. On the basis of the SEA results, a project was identified and implemented with successful results. In terms of comparisons of alternatives, AHP meets the requirements of human development programme assessment, including the importance of simplicity, a multidisciplinary and flexible approach, and a focus on the beneficiaries' concerns. With respect to monitoring, the study shows that AHP contributes to SEA by identifying the most appropriate indicators, in order to control the impacts of a project.     

Design of an institutional decision-making process: the case of urban water management

Urban water infrastructure expenditures cause a major financial burden to municipalities. In the opinion of many policy-makers, public funds may alleviate this burden and facilitate environmental policies. However, practice has shown that despite ambitious policies, funding often follows traditional cost-dominated thinking. In Austria, national policy-makers were interested in new guidelines for funding that increase the transparency of the planning, ensure the adequate treatment of ecological problems, and foster stakeholder involvement, but keep the process as simple as possible, and require minimal changes of the current guidelines. An interdisciplinary project team conducted such a study. Its outcome was tested in two pilot projects. Based on these experiences, policy-makers finally implemented the recommended guidelines for the funding of communal urban water infrastructure projects. A general observation about the policy-making process was a conservative attitude of policy-makers. They prefer simple constraints (precautionary principle) and flexible negotiations (delegation) to complex assessment and decision-aid methodologies.     

Interaction of ions in water affects water quality of freshwater lake: a case study of major lakes of North India

The influence of ionic composition on the water chemistry and thereby on aquatic flora was investigated. Two major wetlands of North India were taken for the study. Quality parameters of the lakes showed the enrichment of the water especially in the month of September with higher values of P and BOD in almost all of the lakes viz., LSJ, LCH, LSN, and LHT as <5.0, 9.0, 1.0, 1.7 and <7.3, 6.0, 6.3, and 4.0, respectively. Statistically correlated values of the ions in the water quality showed an effect of one on another. An attempt has also been made to investigate if ionic constituent is one of the major causes affecting the aquatic floral diversity.     

Discharge of oilfield-produced water in nueces bay,texas: A case study

During oil and gas production, water is often extracted from geological formations along with the hydrocarbons. These "produced waters" have been discharged to Nueces Bay since the turn of the century. These effluents were found to be highly toxic, and sediments in the vicinity of the discharges were also toxic. We developed a map of wells and produced-water discharge sites in the vicinity of Nueces Bay and identified numerous unplugged wells suitable for conversion to produced water disposal wells. An economic analysis of conversion to subterranean injection of produced water indicates that most of the wells currently in production could pay out the cost of conversion to injection in one to three years. The use of one injection well for two or more water-producing wells could yield greater savings. Wells that could not support the cost of injection are small producers, and their loss would not constitute a major loss of jobs or dollars to the area. This study could serve as a useful model for evaluating the economic feasibility of conversion to injection in other areas of Texas and Louisiana.     

离心场环境下液压振动台试验设备的研制

本文主要介绍了离心机液压振动台系统的设计思想、构成和工作原理以及主要技术指标、特点和意义.     

A case for urban liveability from below: exploring the politics of water and land access for greater liveability in Kampala,Uganda

ABSTRACT

Improving urban liveability and prosperity is commonly set as a priority in urban development plans and policy around the world. Several annual reports produced by international consulting firms, media, and global agencies rank the liveability of cities based on a set of indicators, to represent the quality of life in these cities. The higher is the ranking, the more liveable is the city. In this paper, we argue that such quantitative approaches to framing and addressing urban liveability challenges leave little room to reflect on people's experiences of this liveability, which cannot be expressed through numbers. To illustrate our argument, we draw on empirical evidence of urban liveability challenges in access to water and land in Kampala, the capital city of Uganda, ranked recently as the most liveable East African city by various global agencies and media outlets. By showing that increasing the number of water connections does not guarantee improved access to water and sanitation in the long run, first, we demonstrate how urban liveability challenges are tightly linked with land-title issues in the city. Second, we highlight the political game-playing between the central government, the opposition, the traditional leadership, and the slum dwellers in governance processes of service delivery. Finally, by arguing that urban liveability can be enhanced by broadening political participation in city development planning, we discuss some of the strategies that can be used by communities to make collective claims towards improving their quality of life and the environment.