Degradation and mobility of linear alkylbenzene sulfonate and nonylphenol in sludge-amended soil

Degradation and mobility of the surfactants linear alkylbenzene sulfonate (LAS) and nonylphenol (NP) were investigated in a lysimeter study using a sandy loam soil and 45-cm soil columns. Anaerobically digested sewage sludge was incorporated in the top-15-cm soil layer to an initial content of 38 mg LAS and 0.56 mg NP kg(-1) dry wt., respectively. Spring barley (Hordeum vulgare L.) was sown onto the columns. The lysimeters were placed outdoors and therefore received natural precipitation, but were also irrigated to a total amount of water equivalent to 700 mm of precipitation. Leachate and soil samples from three soil layers were collected continuously during a growth period of 110 d. Leachate samples and soil extracts were concentrated by solid-phase extraction (SPE) and analyzed using high performance liquid chromatography (HPLC) with fluorescence detection. The concentrations in the top-15-cm soil layer declined to 25 and 45% of the initial contents for LAS and NP, respectively, within the first 10 d of the study. At the end of the study, less than 1% LAS was left, while the NP content was below the detection limit. Assuming first-order degradation kinetics, half-lives of 20 and 37 d were estimated for LAS and NP, respectively. The surfactants were not measured in leachate samples in concentrations above the analytical detection limits of 4.0 and 0.5 microg L(-1) for LAS and NP, respectively. In addition, neither LAS nor NP were measured in concentrations above the detection limits of 150 and 50 microg kg(-1) dry wt., respectively, in soil layers below the 15 cm of sludge incorporation, indicating negligible downward transport of the surfactants in the lysimeters.     

Carbon sequestration in dryland soils and plant residue as influenced by tillage and crop rotation

Long-term use of conventional tillage and wheat (Triticum aestivum L.)-fallow systems in the northern Great Plains have resulted in low soil organic carbon (SOC) levels. We examined the effects of two tillage practices [conventional till (CT) and no-till (NT)], five crop rotations [continuous spring wheat (CW), spring wheat-fallow (W-F), spring wheat-lentil (Lens culinaris Medic.) (W-L), spring wheat-spring wheat-fallow (W-W-F), and spring wheat-pea (Pisum sativum L.)-fallow (W-P-F)], and Conservation Reserve Program (CRP) planting on plant C input, SOC, and particulate organic carbon (POC). A field experiment was conducted in a mixture of Scobey clay loam (fine-loamy, mixed, Aridic Argiborolls) and Kevin clay loam (fine, montmorillonitic, Aridic Argiborolls) from 1998 to 2003 in Havre, MT. Total plant biomass returned to the soil from 1998 to 2003 was greater in CW (15.5 Mg ha(-1)) than in other rotations. Residue cover, amount, and C content in 2004 were 33 to 86% greater in NT than in CT and greater in CRP than in crop rotations. Residue amount (2.47 Mg ha(-1)) and C content (0.96 Mg ha(-1)) were greater in NT with CW than in other treatments, except in CT with CRP and W-F and in NT with CRP and W-W-F. The SOC at the 0- to 5-cm depth was 23% greater in NT (6.4 Mg ha(-1)) than in CT. The POC was not influenced by tillage and crop rotation, but POC to SOC ratio at the 0- to 20-cm depth was greater in NT with W-L (369 g kg(-1) SOC) than in CT with CW, W-F, and W-L. From 1998 to 2003, SOC at the 0- to 20-cm depth decreased by 4% in CT but increased by 3% in NT. Carbon can be sequestered in dryland soils and plant residue in areas previously under CRP using reduced tillage and increased cropping intensity, such as NT with CW, compared with traditional practice, such as CT with W-F system, and the content can be similar to that in CRP planting.     

Interactions between soil texture and placement of dairy slurry application: I. Flow characteristics and leaching of nonreactive components

Land application of manure can exacerbate nutrient and contaminant transfers to the aquatic environment. This study examined the effect of injecting a dairy cattle (Bostaurus L.) manure slurry on mobilization and leaching of dissolved, nonreactive slurry components across a range of agricultural soils. We compared leaching of slurry-applied bromide through intact soil columns (20 cm diam., 20 cm high) of differing textures following surface application or injection of slurry. The volumetric fraction of soil pores >30 microm ranged from 43% in a loamy sand to 28% in a sandy loam and 15% in a loam-textured soil. Smaller active flow volumes and higher proportions of preferential flow were observed with increasing soil clay content. Injection of slurry in the loam soil significantly enhanced diffusion of applied bromide into the large fraction of small pores compared with surface application. The resulting physical protection against leaching of bromide was reflected by 60.2% of the bromide tracer was recovered in the effluent after injection, compared with 80.6% recovery after surface application. No effect of slurry injection was observed in the loamy sand and sandy loam soils. Our findings point to soil texture as an important factor influencing leaching of dissolved, nonreactive slurry components in soils amended with manure slurry.     

Application of flow field-flow fractionation and laser sizing to characterize soil colloids in drained and undrained lysimeters

This paper reports the use of a new technique, flow field-flow fractionation (FlFFF), for the characterization of soil sampled under grassland. FlFFF can be used to determine the fine colloidal material in the <1 microm fraction obtained by gravitational settling of 1% m/v soil suspensions. The aim of this work was to determine the potential of FIFFF to characterize soil colloids in drained and undrained field lysimeters from soil cores sampled at different depths. Two different grassland lysimeter plots of 1 ha, one drained and one undrained, were investigated, and the soil was sampled at 20-m intervals along a single diagonal transect at three different depths (0-2, 10-12, and 30-32 cm). The results showed that there was a statistically significant (P = 0.05) increase in colloidal material at 30- to 32-cm depth along the transect under the drained lysimeter, which correlates with disturbance of the soil at this depth due to the installation of tile drains at 85-cm depth backfilled to 30-cm depth with gravel. Laser sizing was also used to determine the particles in the size range 1 to 2000 microm and complement the data obtained using FlFFF because laser sizing lacks resolution for the finer colloidal material (0.1-1.0 microm). The laser sizing data showed increased heterogeneity at 30- to 32-cm depth, particularly in the 50 to 250 microm size fraction. Therefore FIFFF characterized the finer material and laser sizing the coarser soil fraction (<2000 microm) at depth in drained and undrained grassland. This is of importance as colloidal material is more mobile than the larger material and consequently an important vector for contaminant transport from agricultural land to catchments.     

Transformation of a landfill covering amended with municipal waste compost, Perugia, Italy

This research deals with the transformation of an anthropomorphous landfill covering composed of a fill soil mixed with mechanically separated municipal waste compost. The study site was a municipal landfill near Perugia, Italy. Throughout the years, waste disposal in the landfill was performed by burial in horizontal layers, each one representing a yearly disposal. The external front of the landfill thus represented the yearly disposal over a 10-yr period starting in 1993. Temporal changes in the anthropomorphous soil over this period were studied by examining and describing soil profiles, and by collecting and analyzing soil samples from the 1993, 1994, 1997, and 2001 disposals. The samples were subjected to a series of physical, chemical, and biochemical analyses. The results obtained suggest that over a 10-yr period the top layer gained a pedological structure (subangular blocky and/or crumb) giving rise to an A horizon. Improved soil structure was confirmed by an increase in macroporosity, particularly for pores larger than 50 microm, measured by image analysis of soil thin sections. Total extractable carbon showed an increase in the content of humic substances, evidenced by parameters of humification. Enzymatic activities in the A and C1 horizons were also indicative of soil evolution and may serve as a valid indicator for monitoring the evolution of anthropogenic soils containing municipal waste compost.     

Soil carbon dioxide emission and carbon content as affected by irrigation, tillage, cropping system, and nitrogen fertilization

Management practices can influence soil CO(2) emission and C content in cropland, which can effect global warming. We examined the effects of combinations of irrigation, tillage, cropping systems, and N fertilization on soil CO(2) flux, temperature, water, and C content at the 0- to 20-cm depth from May to November 2005 at two sites in the northern Great Plains. Treatments were two irrigation systems (irrigated vs. non-irrigated) and six management practices that contained tilled and no-tilled malt barley (Hordeum vulgaris L.) with 0 to 134 kg N ha(-1), no-tilled pea (Pisum sativum L.), and a conservation reserve program (CRP) planting applied in Lihen sandy loam (sandy, mixed, frigid, Entic Haplustolls) in western North Dakota. In eastern Montana, treatments were no-tilled malt barley with 78 kg N ha(-1), no-tilled rye (Secale cereale L.), no-tilled Austrian winter pea, no-tilled fallow, and tilled fallow applied in dryland Williams loam (fine-loamy, mixed Typic Argiborolls). Irrigation increased CO(2) flux by 13% compared with non-irrigation by increasing soil water content in North Dakota. Tillage increased CO(2) flux by 62 to 118% compared with no-tillage at both places. The flux was 1.5- to 2.5-fold greater with tilled than with non-tilled treatments following heavy rain or irrigation in North Dakota and 1.5- to 2.0-fold greater with crops than with fallow following substantial rain in Montana. Nitrogen fertilization increased CO(2) flux by 14% compared with no N fertilization in North Dakota and cropping increased the flux by 79% compared with fallow in no-till and 0 kg N ha(-1) in Montana. The CO(2) flux in undisturbed CRP was similar to that in no-tilled crops. Although soil C content was not altered, management practices influenced CO(2) flux within a short period due to changes in soil temperature, water, and nutrient contents. Regardless of irrigation, CO(2) flux can be reduced from croplands to a level similar to that in CRP planting using no-tilled crops with or without N fertilization compared with other management practices.     

Effect of turfgrass cover and irrigation on soil mobility and dissipation of mefenoxam and propiconazole

Irrigation effects on pesticide mobility have been studied, but few direct comparisons of pesticide mobility or persistence have been conducted on turfgrass versus bare soil. The interaction of irrigation practices and the presence of turfgrass on the mobility and dissipation of mefenoxam [N-(2,6-dimethylphenyl)-N-(methoxyacetyl)-D-alanine methyl ester] and propiconazole (1-[[2-(2,4-dichlorophenyl)-4-propyl-1,3-dioxolan-2-yl]methyl]-1H-1,2,4-triazole) was studied. Sampling cylinders (20-cm diam.) were placed in either creeping bentgrass [Agrostis stolonifera L. var. palustris (Huds.) Farw.] or bare soil. Mefenoxam was applied at 770 g a.i. ha(-1) and propiconazole was applied at 1540 g a.i. ha(-1) on 14 June 1999. Sampling cylinders were removed 2 h after treatment and 4,8,16, 32, and 64 days after treatment (DAT) and the cores were sectioned by depth. Dissipation of mefenoxam was rapid, regardless of the amount of surface organic matter or irrigation. The half-life (t1/2) of mefenoxam was 5 to 6 d in turf and 7 to 8 d in bare soil. Most mefenoxam residues found in soil under turfgrass were in the 0- to 1-cm section at 0, 4, and 8 DAT. Residues were found in the 15- to 30-cm section at 4, 8, 16, 32, and 64 DAT, regardless of turf cover or irrigation. The t1/2 of propiconazole was 12 to 15 d in turfgrass and 29 d in bare soil. Little movement of propiconazole was observed in either bare soil or turf.     

Use of physical properties to predict the effects of tillage practices on organic matter dynamics in three Illinois soils

This work builds on a previous study of long-term tillage trials that found use of no-tillage (NT) practices increased soil organic carbon (SOC) sequestration at Monmouth, IL (silt loam soil) by increasing the soil's protective capacity, but did not alter SOC storage in DeKalb, IL (silty clay loam), where higher clay contents provided a protective capacity not affected by tillage. The least limiting water range (LLWR), a multi-factor index of structural quality, predicted observed soil CO2 efflux patterns. Here we consider whether LLWR can predict sequestration trends at a third site, Perry, IL (silt loam soil) where SOC content is lower and bulk density is higher than in previously considered sites, and determine whether pore size characteristics can help explain the influence use of NT practices has had on SOC sequestration at all three locations. At Perry, LLWR was again related with differences in specific soil organic carbon mineralization rates (RESPsp) (2000-2001). Reduced RESPsp rates explain increases in SOC storage under NT management observed only after 17 yr. Trends in RESPsp suggest use of NT practices only enhance physical protection of SOC where soil bulk density is relatively high (approximately 1.4 g cm(-3)). In those soils (Monmouth and Perry), use of NT management reduced the volume of small macropores (15-150 microm) thought to be important for microbial activity. Physical properties appear to determine whether or not use of NT practices will enhance C storage by increasing physical protection of SOC. By refining the functions used to compute the LLWR and our understanding of the interactions between management, pore structure, and SOC mineralization, we should be able to predict the influence of tillage practices on SOC sequestration.     

Long-term cropping system effects on carbon sequestration in eastern Oregon

Soil organic carbon (SOC) has beneficial effects on soil quality and productivity. Cropping systems that maintain and/or improve levels of SOC may lead to sustainable crop production. This study evaluated the effects of long-term cropping systems on C sequestration. Soil samples were taken at 0- to 10-, 10- to 20-, 20- to 30-, and 30- to 40-cm soil depth profiles from grass pasture (GP), conventional tillage (CT) winter wheat (Triticum aestivum L.)-fallow (CTWF), and fertilized and unfertilized plots of continuous winter wheat (WW), spring wheat (SW), and spring barley (Hordeum vulgare L.) (SB) monocultures under CT and no-till (NT). The samples were analyzed for soil organic matter (SOM) and SOC was derived. Ages of experiments ranged from 6 to 73 yr. Compared to 1931 SOC levels (initial year), CTWF reduced SOC by 9 to 12 Mg ha(-1) in the 0- to 30-cm zone. Grass pasture increased SOC by 6 Mg ha(-1) in the 0- to 10-cm zone but decreased SOC by 3 Mg ha(-1) in the 20- to 30-cm zone. Continuous CT monocultures depleted SOC in the top 0- to 10-cm zone and the bottom 20- to 40-cm zone but maintained SOC levels close to 1931 SOC levels in the 10- to 20-cm layer. Continuous NT monocultures accumulated more SOC in the 0- to 10-cm zone than in deeper zones. Total SOC (0- to 40-cm zone) was highest under GP and continuous cropping and lowest under CTWF. Fertilizer increased total SOC only under CTWW and CTSB by 13 and 7 Mg ha(-1) in 13 yr, respectively. Practicing NT for only 6 yr had started to reverse the effect of 73 yr of CTWF. Compared to CTWF, NTWW and NTSW sequestered C at rates of 2.6 and 1.7 Mg ha(-1) yr(-1), respectively, in the 0- to 40-cm zone. This study showed that the potential to sequester C can be enhanced by increasing cropping frequency and eliminating tillage.     

Relationship between soil test phosphorus and phosphorus in runoff: effects of soil series variability

Phosphorus loss in runoff from agricultural fields has been identified as an important contributor to eutrophication. The objective of this research was to determine the relationship between phosphorus (P) in runoff from a benchmark soil (Cecil sandy loam; fine, kaolinitic, thermic Typic Kanhapludult) and Mehlich III-, deionized water-, and Fe(2)O(3)-extractable soil P, and degree of phosphorus saturation (DPS). Additionally, the value of including other soil properties in P loss prediction equations was evaluated. Simulated rainfall was applied (75 mm h(-1)) to 54 1-m(2) plots installed on six fields with different soil test phosphorus (STP) levels. Runoff was collected in its entirety for 30 min and analyzed for total P and dissolved reactive phosphorus (DRP). Soil samples were collected from 0- to 2-, 0- to 5-, and 0- to 10-cm depths. The strongest correlation for total P and DRP occurred with DPS (r(2) = 0.72). Normalizing DRP by runoff depth resulted in improved correlation with deionized water-extractable P for the 0- to 10-cm sampling depth (r(2) = 0.81). The STP levels were not different among sampling depths and analysis of the regression equations revealed that soil sampling depth had no effect on the relationship between STP and P in runoff. For all forms of P in runoff and STP measures, the relationship between STP and runoff P was much stronger when the data were split into groups based on the ratio of oxalate-extractable Fe to Al. For all forms of P in runoff and all STP methods, R(2) increased with the inclusion of oxalate-extractable Al and Fe in the regression equation. The results of this study indicate that inclusion of site-specific information about soil Al and Fe content can improve the relationship between STP and runoff P.     

Soil quality at a national scale in New Zealand

New Zealand is a signatory to international conventions on environmental performance, and soil quality information is needed for reporting both at a national and regional level. Soil quality was measured at 222 sites in five regions of New Zealand (12 soil orders and 9 land-use categories). Topsoil (0-100 mm) properties measured were total carbon and nitrogen, potentially mineralizable N, pH, Olsen P, cation exchange capacity, bulk density, total porosity, macroporosity, and total available and readily available water. Our objectives were to gauge the representativeness of the sample, determine the contribution from land use or soil order to variability, rationalize the data set, and identify concerns for long-term sustainable land use. Soil and land use combinations were both under- or overrepresented in the data set compared with national distribution. Soil order and land-use categories explained 55 to 76% of the variance in soil properties. Total C contents of pastures were comparable with indigenous forest soils, but pastures were less acidic and with higher N and P contents. Plantation forests had characteristics similar to indigenous forests on comparable soils. Cropland soils comprised <1% of the national land cover and generally had high inorganic fertility and low organic matter, with evidence of compaction. Seven characteristics (total C, total N, mineralizable N, pH, Olsen P, bulk density, and macroporosity) explained 87% of the total variability. The findings are being used by monitoring agencies to raise awareness about soil quality in the wider community, set land management guidelines, and develop policies.     

Leaching of dissolved organic carbon and carbon dioxide emission after compost application to six nutrient-depleted forest soils

The objective of this study was to assess the effect of compost application on soil respiration and dissolved organic carbon (DOC) output of nutrient-depleted forest soils. An amount of 6.3 kg m(-2) mature compost was applied to the forest floor of European beech (Fagus sylvatica L.), Norway spruce (Picea abies Karst.), and Scots pine (Pinus sylvestris L.) stands at Soiling and Unterlüss, Germany. Cumulative soil respiration significantly increased by 499 g C m(-2) in the spruce stand at Unterlüss and by 274 g C m(-2) in the beech stand at Soiling following compost application whereas soil respiration of the other four stands was not affected. The increases in soil respiration of the two stands were explained by improved microbial decomposition of soil organic matter. The DOC concentrations and fluxes in throughfall and seepage water at 10- and 100-cm depths were determined from August 1997 to March 2000. In the control plots, cumulative DOC outputs at 10 cm ranged between 57 and 95 g C m(-2), with the highest rates in the pine stands. Compost treatment significantly increased cumulative DOC outputs by 31 to 69 g C m(-2) at 10 cm and by 0.3 to 6.6 g C m(-2) at 100 cm. The mineral soils between the 10- and 100-cm depths acted as significant sinks for DOC, as shown by much lower cumulative outputs at 100 cm of 3 to 11 g C m(-2) in the control and 6 to 16 g C m(-2) in the compost plots. Our results suggest that a single, moderate application of mature compost to nutrient-depleted forest soils has little effect on C losses to the atmosphere and ground water.     

Carbon storage of different soil-size fractions in Florida silvopastoral systems

Compared with open (treeless) pasture systems, silvopastoral agroforestry systems that integrate trees into pasture production systems are likely to enhance soil carbon (C) sequestration in deeper soil layers. To test this hypothesis, total soil C contents at six soil depths (0-5, 5-15, 15-30, 30-50, 50-75, and 75-125 cm) were determined in silvopastoral systems with slash pine (Pinus elliottii) + bahiagrass (Paspalum notatum) and an adjacent open pasture (OP) with bahiagrass at four sites, representing Spodosols and Ultisols, in Florida. Soil samples from each layer were fractionated into three classes (250-2000, 53-250, and <53 microm), and the C contents in each were determined. Averaged across four sites and all depths, the total soil organic carbon (SOC) content was higher by 33% in silvopastures near trees (SP-T) and by 28% in the alleys between tree rows (SP-A) than in adjacent open pastures. It was higher by 39% in SP-A and 20% in SP-T than in open pastures in the largest fraction size (250-2000 microm) and by 12.3 and 18.8%, respectively, in the intermediate size fraction (53-250 microm). The highest SOC increase (up to 45 kg m(-2)) in whole soil of silvopasture compared with OP was at the 75- to 125-cm depth at the Spodosol sites. The results support the hypothesis that, compared with open pastures, silvopastures contain more C in deeper soil layers under similar ecological settings, possibly as a consequence of a major input to soil organic matter from decomposition of dead tree-roots.     

Hydrological properties of a clay loam soil after long-term cattle manure application

Limited information exists on the effect of long-term application of beef cattle (Bos taurus) manure on soil hydrological properties in the Great Plains region of North America. A site on a clay loam soil (Typic Haploboroll) was used to examine the effect of manure addition on selected soil hydrological properties in 1997 and 1998. The manure was annually applied in the fall for 24 yr at one, two, and three times the recommended rates (in 1973) under dryland (0, 30, 60, and 90 Mg ha(-1) wet basis) and irrigation (0, 60, 120, and 180 Mg ha(-1)). Manure significantly (P < or = 0.05) increased soil water retention (0-5 and 10-15 cm) by 5 to 48% compared with the control at most potentials between 0 and -1500 kPa. Field soil water content (0-5 and 10-15 cm) was increased by 10 to 22% in the summers of 1997 and 1998. Manure increased ponded infiltration by more than 200% at 90 Mg ha(-1) under dryland (1998) and at rates > or = 120 Mg ha(-1) under irrigation (1997). Field-saturated hydraulic conductivity (Kfs) of surface soil (1-cm depth) was significantly increased by 76 to 128% under dryland (1998) and irrigation (1997), as were number of pores > 1120 microm in diameter (37-128% increase). In contrast, manure rate had little or no effect on unsaturated hydraulic conductivity [K(psi)] values (-0.3, -0.5, -0.7, and -1.0 kPa) in 1997 and 1998. Overall, soil hydrological parameters generally had a neutral or positive response to 24 yr of annual manure addition.     

Field-Level Financial Assessment of Contour Prairie Strips for Enhancement of Environmental Quality

The impacts of strategically located contour prairie strips on sediment and nutrient runoff export from watersheds maintained under an annual row crop production system have been studied at a long-term research site in central Iowa. Data from 2007 to 2011 indicate that the contour prairie strips utilized within row crop-dominated landscapes have greater than proportionate and positive effects on the functioning of biophysical systems. Crop producers and land management agencies require comprehensive information about the Best Management Practices with regard to performance efficacy, operational/management parameters, and the full range of financial parameters. Here, a farm-level financial model assesses the establishment, management, and opportunity costs of contour prairie strips within cropped fields. Annualized, depending on variable opportunity costs the 15-year present value cost of utilizing contour prairie strips ranges from $590 to $865 ha^?1 year^?1 ($240–$350 ac^?1 year^?1). Expressed in the context of “treatment area” (e.g., in this study 1 ha of prairie treats 10 ha of crops), the costs of contour prairie strips can also be viewed as $59 to about $87 per treated hectare ($24–$35 ac^?1). If prairie strips were under a 15-year CRP contract, total per acre cost to farmers would be reduced by over 85 %. Based on sediment, phosphorus, and nitrogen export data from the related field studies and across low, medium, and high land rent scenarios, a megagram (Mg) of soil retained within the watershed costs between $7.79 and $11.46 mg^?1, phosphorus retained costs between $6.97 and $10.25 kg^?1, and nitrogen retained costs between $1.59 and $2.34 kg^?1. Based on overall project results, contour prairie strips may well become one of the key conservation practices used to sustain US Corn Belt agriculture in the decades to come.     

Phosphorus concentrations in soil and subsurface water: a field study among cropland and riparian buffers

Riparian buffers can be effective at removing phosphorus (P) in overland flow, but their influence on subsurface P loading is not well known. Phosphorus concentrations in the soil, soil solution, and shallow ground water of 16 paired cropland-buffer plots were characterized during 2004 and 2005. The sites were located at two private dairy farms in Central New York on silt and gravelly silt loams (Aeric Endoaqualfs, Fluvaquentic Endoaquepts, Fluvaquentic Eutrudepts, Glossaquic Hapludalfs, and Glossic Hapludalfs). It was hypothesized that P availability (sodium acetate extractable-P) and soil-landscape variability would affect P release to the soil solution and shallow ground water. Results showed that P availability tended to be greater in crop fields relative to paired buffer plots. Soil P was a good indicator of soil solution dissolved (<0.45 microm) molybdate-reactive P (DRP) concentrations among plots, but was not independently effective at predicting ground water DRP concentrations. Mean ground water DRP in corn fields ranged from < or =20 to 80 microg L(-1), with lower concentrations in hay and buffer plots. More imperfectly drained crop fields and buffers tended to have greater average DRP, particulate (> or =0.45 microm) reactive P (PRP), and dissolved unreactive P (DUP) concentrations in ground water. Soil organic matter and 50-cm depth soil solution DRP in buffers jointly explained 75% of the average buffer ground water DRP variability. Results suggest that buffers were relatively effective at reducing soil solution and shallow ground water DRP concentrations, but their impact on particulate and organic P in ground water was less clear.     

Nitrogen and carbon leaching in agroecosystems and their role in denitrification potential

The drainage of water and leaching of dissolved constituents represent major components of agroecosystem mass budgets that have been exceedingly difficult to measure. Equilibrium-tension lysimeters (ETLs) were used to monitor drainage, nitrogen (N), and carbon (C) leaching through Plano silt loam (fine-silty, mixed, superactive, mesic Typic Argiudoll) for a 4-yr period in a restored prairie and N-fertilized no-tillage and chisel-plowed maize (Zea mays L.) agroecosystems. Mean drainage recorded during 4 yr for the prairie, no-tillage, and chisel-plowed ecosystems totaled 461, 1,116, and 1,575 mm and represented 16, 33, and 47% of precipitation plus melting of drifted snow received, respectively. Total inorganic N leaching losses during the 4-yr period for the prairie, no-tillage, and chisel-plowed ecosystems were 0.6, 201, and 179 kg N ha(-1), respectively. Inorganic N leaching represented 26 and 24% of applied fertilizer N additions to the no-tillage and chisel-plowed agroecosystems. Total dissolved C leaching losses were 119, 435, and 502 kg C ha(-1) for the prairie, no-tillage, and chisel-plowed ecosystems, respectively. Sufficient dissolved organic carbon (DOC) and nitrate N (NO3- -N) existed in the prairie and agroecosystems to support subsoil denitrification. Potential denitrification, however, was limited by insufficient lengths of saturated soil conditions in all three ecosystems, the supply of DOC in the agroecosystems, and the supply of nitrate N in the prairie. Based on available DOC and nitrate N, the maximum contribution of denitrification below the root zone in the agroecosystems was less than 25% of the total amount of leached nitrate N and the probable contribution of denitrification was much less.     

Biosolid colloid-mediated transport of copper, zinc, and lead in waste-amended soils

Increasing land applications of biosolid wastes as soil amendments have raised concerns about potential toxic effects of associated metals on the environment. This study investigated the ability of biosolid colloids to transport metals associated with organic waste amendments through subsurface soil environments with leaching experiments involving undisturbed soil monoliths. Biosolid colloids were fractionated from a lime-stabilized, an aerobically digested, and a poultry manure organic waste and applied onto the monoliths at a rate of 0.7 cm/h. Eluents were monitored for Cu, Zn, Pb, and colloid concentrations over 16 to 24 pore volumes of leaching. Mass-balance calculations indicated significantly higher (up to 77 times) metal elutions in association with the biosolid colloids in both total and soluble fractions over the control treatments. Eluted metal loads varied with metal, colloid, and soil type, following the sequences Zn = Cu > Pb, and ADB > PMB > LSB colloids. Colloid and metal elution was enhanced by decreasing pH and colloid size, and increasing soil macroporosity and organic matter content. Breakthrough curves were mostly irregular, showing several maxima and minima as a result of preferential macropore flow and multiple clogging and flushing cycles. Soil- and colloid-metal sorption affinities were not reliable predictors of metal attenuation/elution loads, underscoring the dynamic nature of transport processes. The findings demonstrate the important role of biosolid colloids as contaminant carriers and the significant risk they pose, if unaccounted, for soil and ground water contamination in areas receiving heavy applications of biosolid waste amendments.     

Developing risk models of Cryptosporidium transport in soils from vegetated, tilted soilbox experiments

Transport of Cryptosporidium parvum through macroporous soils is poorly understood yet critical for assessing the risk of groundwater contamination. We developed a conceptual model of the physics of flow and transport in packed, tilted, and vegetated soilboxes during and immediately after a simulated rainfall event and applied it to 54 experiments implemented with different soils, slopes, and rainfall rates. Using a parsimonious inverse modeling procedure, we show that a significant amount of subsurface outflow from the soilboxes is due to macropore flow. The effective hydraulic properties of the macropore space were obtained by calibration of a simple two-domain flow and transport model that accounts for coupled flow in the matrix and in the macropores of the soils. Using linear mixed-effects analysis, macropore hydraulic properties and oocyst attenuation were shown to be associated with soil bulk density and rainfall rate. Macropore flow was shown to be responsible for bromide and C. parvum transport through the soil into the underlying pore space observed during the 4-h experiments. We confirmed this finding by conducting a pair of saturated soil column studies under homogeneously repacked conditions with no macropores in which no C. parvum transport was observed in the effluent. The linear mixed-effects and logistic regression models developed from the soilbox experiments provide a basis for estimating macropore hydraulic properties and the risk of C. parvum transport through shallow soils from bulk density, precipitation, and total shallow subsurface flow rate. The risk assessment is consistent with the reported occurrence of oocysts in springs or groundwater from fractured or karstic rocks protected only by shallow overlying soils.     

Enzyme activities and arylsulfatase protein content of dust and the soil source: biochemical fingerprints?

Little is known about the potential of enzyme activities, which are sensitive to soil properties and management, for the characterization of dust properties. Enzyme activities may be among the dust properties key to identifying the soil source of dust. We generated dust (27 and 7 microm) under controlled laboratory conditions from agricultural soils (0-5 cm) with history of continuous cotton (Gossypium hirsutum L.) or cotton rotated with peanut (Arachis hypogaea L.), sorghum [Sorghum bicolor (L.) Moench], rye (Secale cereale L.), or wheat (Triticum aestivum L.) under different water management (irrigated or dryland) and tillage (conservation or conventional) systems. The 27- and 7-microm dust samples showed activities of beta-glucosidase, alkaline phosphatase, and arylsulfatase, which are related to cellulose degradation and phosphorus and sulfur mineralization in soil, respectively. Dust samples generated from a loam and sandy clay loam showed higher enzyme activities compared with dust samples from a fine sandy loam. Enzyme activities of dust samples were significantly correlated to the activities of the soil source with r > 0.74 (P < 0.01). The arylsulfatase proteins contents of the soils (0.04-0.65 mg protein kg(-1) soil) were lower than values reported for soils from other regions, but still dust contained arylsulfatase protein. The three enzyme activities studied, as a group, separated the dust samples due to the crop rotation or tillage practice history of the soil source. The results indicated that the enzyme activities of dust will aid in providing better characterization of dust properties and expanding our understanding of soil and air quality impacts related to wind erosion.