铜渣催化H2O2氧化处理棉浆黑液

采用铜渣催化H2O2类Fenton氧化反应处理棉浆黑液,研究了酸析pH、H2O2投加量、铜渣投加量对棉浆黑液COD和TOC去除率及溶出Fe2+质量浓度的影响,考察了铜渣重复使用性能,讨论了铜渣催化作用机制.结果表明:在酸析pH为2、H2O2投加量为25 mmol/L、铜渣投加量为2.5 g/L条件下,反应180 min...     

铜渣资源化利用技术研究现状

铜渣是工业上冶炼铜产生的固体废弃物.时至今日,大量铜渣的产生和堆积,使得大片"渣山"成为工况企业下游难以解决的问题.为了解决"渣山",国内外许多专家学者耗费大量的时间和精力,开展了相关的理论研究和实践研究.通过文献查阅,总结了目前国内外铜渣的主要组成、资源化方向,归纳了几种通过改善铜渣性质来增强其利用率或回收率的工艺技...     

钢渣净化水中磷素的研究进展

在对国内外钢渣除磷研究现状进行总结的基础上,介绍了铜渣的组成及其物理、化学性质,并进一步阐述了其在除磷过程中涉及到的反应机理,提出了钢渣应用于含磷废水处理时存在的问题及今后的研究发展方向。     

锡铜铅铁多元合金的氯化分离

含有锡铜铅锌的鼓风炉水淬渣经矿热电炉还原熔炼产出锡铜铅铁多元合金.用氯气浸出该合金,以硫酸铅的形式分离出铅,合金粉还原铜产出海绵铜,中和水解分离锡和铁,进而实现锡铜铅铁多元合金的有效分离.     

钙镁磷肥水淬水密闭循环自净化处理

1.概况我厂在钙镁磷肥生产过程中,排放水淬含氟废水1.5万米~3/天,其中含氟40毫克/升左右。过去废水长期外排,不仅严重污染环境,并使半成品磷肥流失。为此,我们进行了该废水密闭循环自净化试验,并在试验的基础上设计、建造了一套密闭循环自净化处理装置,1980年8月第     

燃煤发电清洁工艺又结硕果

1994年8月26日锦西市召开了新闻发布会，宣布：锦化旋风炉液态法制岩棉生产线成功了，这是一项在世界领先的清洁发电工艺。立式旋风炉增钙液态排渣友电较之于传统的煤粉护发电，可削减约90％除尘量;由于在煤中加石灰石可脱硫，可节约90％的输灰水；不设每万吨粉煤灰占用2亩地的贮灰场，节省占地，不受处理粉煤灰的困扰。增钙液态渣经过水淬即似高炉酸性水渣，可广泛用于制水泥、墙体材料、保温材料，代砂、筑路以及环境工程等。目前全国已有铜陵、武昌、沈阳等20余个这种清洁工艺电厂。为了提高液态渣的效能，为基本建设提供优质轻质保温材…     

长三角地区农村生活污水处理设施水污染物排放标准比较研究

随着全国各地农村人居环境整治工作的推进,农村生活污水处理设施的覆盖率稳步提升,各地区根据当地农村的生活污水水质现状、经济基础、管理水平,制定了符合各地区实际情况的农村生活污水处理设施水污染物排放标准。从适用范围、分级情况、控制指标、标准限值4方面,对长三角地区(江浙沪皖)已经发布实施的农村生活污水处理设施水污染物排放标准进行比较研究,为因地制定各地农村生活污水处理设施水污染物排放标准提供经验参考。     

湿式除尘冲灰水再循环系统的水质特征,水质预测及结垢判断

在湿式除尘冲灰水闭路循环系统工业性试验的基础上,通过现泉观察、理论分析及计算,揭示了湿式除尘冲灰水再循环系统灰水的水质特征,给出了水质预测及结垢判断的方法和标准,为类似系统的水质预测及稳定性判别提供了可靠依据。     

催化臭氧氧化—生物活性炭吸附组合工艺处理反渗透浓水

采用催化臭氧氧化—生物活性炭吸附组合工艺处理反渗透(RO)浓水,比较了4种催化剂催化臭氧氧化的性能,优化了初始RO浓水pH、臭氧氧化时间、生物活性炭柱空床停留时间(EBRT)等工艺条件。实验结果表明:以WP-01为催化剂催化臭氧氧化RO浓水时无需调节废水pH;臭氧氧化反应5 min时RO浓水的BOD5/COD达0.28,可生化性得到显著改善;WP-01催化剂重复使用30次其催化活性没有明显下降;生物活性炭吸附单元的EBRT控制在30 min左右,可确保出水COD稳定在50 mg/L以下,符合GB 18918—2002《城镇污水处理厂污染物排放标准》的一级A标准;催化臭氧单元处理每吨RO浓水的电费约为1.22元。     

压裂返排液的超声强化臭氧氧化处理

采用超声强化臭氧氧化技术处理经絮凝、沉降脱固、过滤预处理的页岩气压裂返排液,通过实验室实验优化工艺参数,并在自行研制的超声强化臭氧氧化装置上进行了中试验证。实验结果表明,在反应时间为30min、废水pH为10、废水臭氧质量浓度为40 mg/L、超声波功率为200 W时,COD去除率可达55.2%,处理后水质可满足GB 8978—1996《污水综合排放标准》一级标准的要求。中试试验结果表明,研制的臭氧超声氧化处理装置可形成臭氧氧化、超声空化、水力空化的协同作用,处理后出水COD为90 mg/L,具有一定的推广价值。     

Porous materials produced from incineration ash using thermal plasma technology

This study presents a novel thermal plasma melting technique for neutralizing and recycling municipal solid waste incinerator (MSWI) ash residues. MSWI ash residues were converted into water-quenched vitrified slag using plasma vitrification, which is environmentally benign. Slag is adopted as a raw material in producing porous materials for architectural and decorative applications, eliminating the problem of its disposal. Porous materials are produced using water-quenched vitrified slag with Portland cement and foaming agent. The true density, bulk density, porosity and water absorption ratio of the foamed specimens are studied here by varying the size of the slag particles, the water-to-solid ratio, and the ratio of the weights of the core materials, including the water-quenched vitrified slag and cement. The thermal conductivity and flexural strength of porous panels are also determined. The experimental results show the bulk density and the porosity of the porous materials are 0.9–1.2 g cm^?3 and 50–60%, respectively, and the pore structure has a closed form. The thermal conductivity of the porous material is 0.1946 W m^?1 K^?1. Therefore, the slag composite materials are lightweight and thermal insulators having considerable potential for building applications.     

Technological behaviour and leaching tests in ceramic tile bodies obtained by recycling of copper slag and MSW fly ash wastes

Journal of Material Cycles and Waste Management - The substitution of standard clays to residues, in this case copper smelter slag and fly ashes coming from the incineration process of MSW in...     

未知含铜物料固体废物属性鉴别研究

以某未知样品为研究对象,综合样品外观及物理、化学等特性,分析得出样品具有和铜冶炼渣一致的特征,含有特征物相——铁橄榄石,成分与铜精炼炉渣类似,而且其碳含量较高,含有少许金属铜,可以判断样品为铜;台炼渣。经过破碎、研磨、浮选得篓Ⅱ精炼渣（铜精矿）,可作为炼铜原料投入生产。     

Production of brown and black pigments by using flotation waste from copper slag.

One of the major problems in copper-producing countries is the treatment of the large amount of copper slag or copper flotation waste generated from copper slag which contains significant amounts of heavy metals such as Cu, Zn, Pb and Co. Dumping or disposal of such large quantities of flotation waste from copper slag causes environmental and space problems. In this study, the treatment of flotation waste from copper slag by a thermal method and its use as an iron source in the production of inorganic brown and black pigments that are used in the ceramic industry were investigated. The pigments were produced by calcining different amounts of flotation waste and chromite, Cr2O3, ZnO and CoO mixtures. The pigments obtained were added to transparent ceramic glazes and porcelainized tile bodies. Their colours were defined by L*a*b* measurements with a spectrophotometer. The results showed that flotation waste from copper slag could be used as an iron source to produce brown and black pigments in both ceramic body and glazes.     

Assessment of the use of spent copper slag for land reclamation.

The shortage of waste landfill space for waste disposal and the high demand for fill materials for land reclamation projects in Singapore have prompted a study on the feasibility of using spent copper slag as fill material in land reclamation. The physical and geotechnical properties of the spent copper slag were first assessed by laboratory tests, including hydraulic conductivity and shear strength tests. The physical and geotechnical properties were compared with those of conventional fill materials such as sands. The potential environmental impacts associated with the use of the spent copper slag for land reclamation were also evaluated by conducting laboratory tests including pH and Eh measurements, batch-leaching tests, acid neutralization capacity determination, and monitoring of long-term dissolution of the material. The spent copper slag was slightly alkaline, with pH 8.4 at a solid : water ratio of 1 : 1. The batch-leaching test results show that the concentrations of the regulated heavy metals leached from the material at pH 5.0 were significantly lower than the maximum concentrations for their toxicity limits referred by US EPA's Toxicity Characteristic Leaching Procedure (TCLP). It was also found that the material is unlikely to cause significant change in the redox condition of the subsurface environment over a long-term period. In terms of physical and geotechnical properties, the spent copper slag is a good fill material. In general, the spent copper slag is suitable to be used as a fill material for land reclamation.     

Processing of copper converter slag for metal reclamation. Part I: Extraction and recovery of copper and cobalt.

Clean processing of copper converter slag to reclaim cobalt and copper could be a challenge. An innovative and environmentally sound approach for recovering valuable metals from such a slag has been developed in the present study. Curing the slag with strong sulphuric acid, without re-smelting or roasting as practiced currently in the industry, render it accessible to leaching, and more than 95% of cobalt and up to 90% of copper was extracted together with iron by water leaching, leaving silica behind in a residue. The copper in the leach liquor was recovered by cementation with iron and the dissolved iron crystallized as ferrous sulphate monohydrate. The cobalt in the mother-liquor rich in iron was recovered by either cementation or sulphide precipitation. Operation variables in the new process were also investigated and optimized.     

Recovery of copper and cobalt from ancient slag.

About 2.5 million tonnes of copper smelter slag are available in Küre, northern part of Turkey. This slag contains large amounts of metallic values such as copper and cobalt. A representative slag sample containing 0.98% Cu, 0.49% Co and 51.47% Fe was used in the experimental studies. Two different methods, direct acid leaching and acid baking followed by hot water leaching were used for recovering Cu and Co from the slag. The effects of leaching time, temperature and acid concentration on Cu- and Co-dissolving efficiencies were investigated in the direct acid leaching tests. The optimum leaching conditions were found to be a leaching time of 2 h, acid concentration of 120 g L(-1), and temperature of 60 degrees C. Under these conditions, 78% Cu and 90% Co were extracted. In the acid baking + hot water leaching tests, 74% Co was dissolved after 1 h of roasting at 200 degrees C using a 3:1 acid:slag ratio, whereas the Cu-dissolving efficiency was 79% and the total slag weight loss was approximately 50%.     

Immobilization of copper flotation waste using red mud and clinoptilolite

The flash smelting process has been used in the copper industry for a number of years and has replaced most of the reverberatory applications, known as conventional copper smelting processes. Copper smelters produce large amounts of copper slag or copper flotation waste and the dumping of these quantities of copper slag causes economic, environmental and space problems. The aim of this study was to perform a laboratory investigation to assess the feasibility of immobilizing the heavy metals contained in copper flotation waste. For this purpose, samples of copper flotation waste were immobilized with relatively small proportions of red mud and large proportions of clinoptilolite. The results of laboratory leaching demonstrate that addition of red mud and clinoptilolite to the copper flotation waste drastically reduced the heavy metal content in the effluent and the red mud performed better than clinoptilolite. This study also compared the leaching behaviour of metals in copper flotation waste by short-time extraction tests such as the toxicity characteristic leaching procedure (TCLP), deionized water (DI) and field leach test (FLT). The results of leach tests showed that the results of the FLT and DI methods were close and generally lower than those of the TCLP methods.     

Processing of copper converter slag for metals reclamation: Part II: mineralogical study.

Chemical and mineralogical characterizations of a copper converter slag, and its products obtained by curing with strong sulphuric acid and leaching with hot water, were carried out using ore microscopy, scanning electronic microscopy with energy dispersive spectrometry, wave-length dispersive X-ray fluorescence spectrometry, X-ray diffractometry and chemical phase analysis, which provided necessary information to develop a new process for treating such slag and further understanding of the chemical and mineralogical changes in the process.     

干式还原法处理铬渣的机理及应用

采用干式还原法处理铬渣。在多级还原焙烧炉中于高温条件下,将过量的煤粉和铬渣混合后与O₂反应,经冷却、擦磨、磁分离后可得到铁精砂和处理后铬渣。介绍了干式还原法处理铬渣的机理和工艺参数。以3种铬渣试样进行应用试验,经多级还原焙烧—磁分离后,铬渣中的Cr（Ⅵ）质量浓度为0.05~0.18 mg/L,低于HJ/T301—2007标准中的要求（0.50 mg/L）,可作为建材原料加以利用。磁分离得到的铁精砂产品中铁的质量分数大于50%,铁回收率大于70%。目前设计的多级还原焙烧炉单炉处理铬渣能力为150 kt/a,标煤消耗为35 kg/t,处理成本约为60元/t。