Improvements in dioxin abatement strategies at a municipal waste management plant in Barcelona

This study presents the results of a dioxin abatement programme undertaken in the municipal waste incineration plant of Montcada i Reixac (Barcelona, Spain) after the replacement of an obsolete air cleaning device by a new flue gas treatment system. A number of sampling campaigns were conducted with the aim of characterising stack gas emission levels of polychlorinated dibenzo-p-dioxins (PCDDs)/polychlorinated dibenzofurans (PCDFs) and to evaluate initial specifications of dioxin stack gas emission values below 0.1 ng I-TEQ/Nm(3). Preliminary results revealed levels between 44 and 111 ng I-TEQ/Nm(3) when the gas-cleaning system consisted only of an old electrostatic precipitator (ESP). Decreased levels around 15 ng I-TEQ/Nm(3) were observed when the semi-dry scrubber began to operate and the ESP was switched off. Again, remarkable dioxin removal was observed after the installation of the fabric filter and levels around 0.3-0.4 ng I-TEQ/Nm(3) were soon achieved. Nevertheless, the limit of 0.1 ng I-TEQ/Nm(3) was reached by additional injection of activated carbon which helped to lower PCDD/PCDF levels to around 0.036 ng I-TEQ/Nm(3). The results also demonstrated a significant change in the dioxin distribution present in combustion-derived materials (stack gas emission, bottom ash and solid waste from gas treatment). The major dioxin fraction was found in gaseous matrices before the flue gas control system was upgraded. After this step, the major dioxin fraction content was observed in solid waste from gas treatment.     

Curbing dioxin emissions from municipal solid waste incineration in China: Re-thinking about management policies and practices

As one of the countries with large amounts of dioxin releases, the control of dioxins is a major challenge for China. Municipal solid waste (MSW) incineration should be considered a high priority source of dioxin emissions because it is playing an increasingly more important role in waste management. MSW incineration in China has much higher emission rates of dioxins than in the developed countries, partially resulting from the gaps in the technologies of incineration and flue gas cleaning. Moreover, the current management policies and practices also contribute significantly to the problem. We recommend lowering dioxin emission standard, strengthening fly ash management, and improving regulation enforcement to reduce dioxin releases into the environment from MSW incineration. We also propose that alternative strategies should be considered on dioxin control and call for an expansion of economic instruments in waste management to reduce waste generation and thus the need for incineration.     

A life-cycle inventory model of municipal solid waste combustion

Evaluation of alternate strategies for municipal solid waste (MSW) management requires models to calculate environmental emissions as a function of both waste quantity and composition. A methodology to calculate waste component-specific emissions associated with MSW combustion is presented here. The methodology considers emissions at a combustion facility as well as those avoided at an electrical energy facility because of energy recovered from waste combustion. Emission factors, in units of kg pollutant per metric ton MSW entering the combustion facility, are calculated for CO2-biomass, CO2-fossil, SOx, HCl, NOx, dioxins/furans, PM, CO, and 11 metals. Water emissions associated with electrical energy offsets are also considered. Reductions in environmental emissions for a 500-metric-ton-per-day combustion facility that recovers energy are calculated.     

Memory effect on the dioxin emissions from municipal waste incinerator in Taiwan

Evaluation of the dioxin removal efficiency of the air pollution control device (APCD) at an existing municipal waste incinerator (MWI) located in Taiwan is conducted via stack sampling and analysis. The MWI investigated is equipped with cyclones, dry lime scrubbing systems and fabric filters as APCDs. Results indicate that the patterns of dioxin isomers at APCDs' inlet and stack are similar. During the first year of carbon injection, the concentrations of emitted dioxin decreased greatly. The dioxin removal efficiency increased from 26.9% to 96.6% after injecting 115 kg/day activated carbon (AC). At the second year, the dioxin removal efficiency reaches 98.7% after injecting the same rate of AC continuously. The lower efficiency achieved with activated carbon injection (ACI) during the first year can be attributed to the memory effect, i.e. the dioxin or precursor desorbs slowly to the flue gas and increases the dioxin concentration at stack, resulting in a lower dioxin removal efficiency than expected.     

广州市城市生活垃圾管理系统规划

运用最小费用规划模型,选取运输费用以及各处理设施（包括垃圾焚烧、制肥、回收利用、 填埋和中转处理）的处理费用为因子,同时把经济收入作为负的费用从中扣除,对选取的三个规划方案进行了计算,得出了广州市市区城市生活垃圾管理系统处理的最低费用,并给出了市属8个区的垃圾量相应的处理设置。     

Online measurements of low-volatile organic chlorine for dioxin monitoring at municipal waste incinerators

In this study, an automatic sampling device and an analysis device have been developed for the measurement of low-volatile organic chlorine (LVOCl) in flue gas. The concentrations of dioxins (polychlorinated dibenzo-p-dioxins, polychlorinated dibenzofurans, and dioxin-like polychlorinated biphenyls) have been estimated by online measurements of LVOCl at a municipal solid waste incinerator (MSWI) using these devices. The LVOCl concentration at the outlet of the selective catalyst reactor (SCR) of the MSWI increased momentarily up to 95 μg Cl m⁻³ during the startup period of the MSWI; subsequently, it gradually decreased to less than 1.0 μg Cl m⁻³ after 50 h from the start of waste feeding. The concentration of toxic equivalent quantity (TEQ)-Dioxins at the SCR outlet had a linear positive relationship with the LVOCl concentrations. Moreover, the level of TEQ-Dioxins concentration can be estimated by using this relationship with LVOCl. From our results, since the LVOCl concentrations in a flue gas can thus be automatically analyzed every hour by online measurements, the operators of an MSWI would be able to monitor approximate TEQ-Dioxin emissions on a daily basis.     

The European dioxin air emission inventory project--final results

Main results of the second stage of the so-called "European Dioxin Emission Inventory" are presented. They cover emission testing data gained from various facilities in the EU (among these the first emission measurements reported from Portugal and Greece) and some central European countries. Further, updated dioxin emission estimates for the most important emission sources in the 17 western European countries and an evaluation of the emission time trend from 1985 to 2005 are presented. The major conclusions are, that at present, iron ore sintering is likely to be the most important emission source type followed by the former "No. 1", municipal waste incineration; measurement data from a considerable number of installations are still missing, in particular from the metal industries in Spain and Italy; there still exist an unknown number of health care waste incinerators with flue gas PCDD/F concentrations above 100 ng I-TEQ/m3 which must be considered as important local sources; in general, considerable emission reduction has been achieved with respect to the industrial emission sources, whereas emissions from non-industrial sources hardly decreased; hence, in the near future the emissions from non-industrial sources are likely to exceed those from industrial installations; the goal of 90% emission reduction set in the 5th EU Action Programme will be achieved for some source types only.     

Factors influencing regional municipal solid waste management strategies

Although regionalization policies have been proven as good strategies for municipal solid waste (MSW) management in previous studies, the optimal allocation of the waste stream is significantly affected by several influential factors, thus further investigation of the impacts of these factors on regional MSW management strategies is necessary. This study demonstrated the impacts of waste-to-electricity transformation coefficient (WETC) of incinerators and the fluctuation of unit tipping fees on the regional MSW flow/allocation of the Taipei metropolitan area from practical and economic perspectives. Real-world data and linear programming were used to obtain the least-cost alternatives under different scenarios. Analytical results indicated some treatment facilities had geographic superiority and their priorities changed when actual WETCs of incinerators were considered. Treatment facilities located at weighted centers were identified. The allocation of MSW among incinerators and landfills is affected by fluctuation of unit tipping fees within a certain range. Treatment facilities sensitive to the changes in unit tipping fees were also identified. Regression equations were also established that can estimate the cost items of MSW management scenarios with different unit tipping fees. The results of this study are very useful for daily basis regulation of MSW administration.     

Health risk assessment of dioxin emissions from municipal waste incinerators: the Neerlandquarter (Wilrijk, Belgium)

Two municipal waste incinerators in the vicinity of a residential area close to the city of Antwerp caused concern to local habitants. Risk assessment was performed combining chemical, toxicological measurements and model calculations. As the first step in risk assessment an inventory was made of historic emissions from both incinerators with emphasis on dioxins. The operational atmospheric transport and deposition model for priority substances (OPS) was used to calculate the deposition of dioxins in the vicinity of incinerators. The observed soil contamination pattern did not correspond to the calculated deposition pattern, indicating that other sources may contribute at least partly to the local PCDD/PCDF contamination of the area. Dioxin exposure of people in the Neerlandquarter as a function of the food consumption behavior was calculated using a mathematical model (VLIER-HUMAAN) combined with transfer factors. According to the results of these calculations, just residing in the impact area does not result in a meaningful risk. Only if locally produced food was consumed (milk, meat and vegetables), exposure in the Neerlandquarter was enhanced compared to the average dioxin exposure estimated for the Flemish population. Exposure in 1997 was below the exposure in 1980. As a consequence of different eating habits and lower bodyweight, children are subjected to significantly higher exposure than adults. Adverse health outcomes from dioxin exposure in the past cannot be excluded. There was no evidence for enhanced exposure to genotoxicants based on a comparison of chromosomal damage to blood cells of children from the study area to those from a control group.     

Remedial strategies for municipal solid waste management in China

The purpose of this investigation is to evaluate the current status and to identify the problems of municipal solid waste (MSW) management in China to determine appropriate remedial strategies. This is the second of two papers proposed on this topic. Major problems or difficulties identified in MSW management in China include MSW land, air, and water pollution, commingled collection, poor administration, shortage of funds, lack of facilities, and problems of training and public awareness. In order to solve these problems and to improve MSW management in China, remedial strategies in three areas are recommended: institutional reform, technology development, and legislation and administrative improvement. The primary principle involved in institutional reform is unifying legislative responsibilities into one body and developing a market mechanism for handling MSW. Composting, landfills, and incineration should be equally developed in accordance with China's needs. The feasibility of developing technology to handle MSW in China is discussed. Also recommended is the establishment of sound regulatory systems, including a service fee system, a source separation system, and a training program. China is presently undergoing economic and institutional reform at the national and local levels. Results of this study will provide useful information on MSW management in China.     

中国二噁英管理策略研究

通过研究美国、日本、欧盟二噁英管理方式,构建中国二噁英全过程管理体系,建立、完善二噁英削减和控制长效机制,进而实现中国二噁英管理.全过程管理体系包括源头控制、过程控制和末端控制,即通过严格把关环境准入、实施"三同时"制度进行源头控制,鼓励企业实施清洁生产审核和ISO 14001环境管理认证进行过程控制,实施二噁英排污许可和排放申报制度进行末端控制.建立二噁英削减和控制长效机制,即通过建设法律、标准和技术规范体系,实施经济刺激,加强行政管理来保证二噁英削减和控制工作的稳步进行.     

Using stochastic risk assessment in setting information priorities for managing dioxin impact from a municipal waste incinerator

The objectives of this study were to assess site-specific carcinogenic risk of incinerator-emitted dioxins in a manner reflecting pollutant transfer across multimedia and multi-pathways. The study used site-specific environmental and exposure information and combined the Monte Carlo method with multimedia modeling to produce probability distributions of risk estimates. The risk estimates were further categorized by contaminated environmental media and exposure pathways that are experienced by human receptors in order to pinpoint significant sources of risk. Rank correlation coefficients were also calculated along with the Monte Carlo sampling to identify key factors that influenced estimation of risk. The results showed that ingestion accounted for more than 90% of the total risk and that risk control on ingestion of eggs, aboveground vegetables, and poultry should receive priority. It was also found that variation of parameters with variability accounted for around 35% of the total risk variance, while uncertainty contributed to the remaining 65%. Intake rates of aboveground vegetables, eggs, and poultry were the key parameters with the largest contribution to variance. In addition, sufficient sampling and analysis of dioxin contents in eggs, aboveground vegetables, poultry, soil, and fruit should be performed to improve risk estimation because the variation in concentrations in these media accounted for the largest overall risk variance. Finally, focus should be placed on reduction of uncertainty associated with the risk estimation through ingestion of aboveground vegetables, eggs, poultry, fruit, and soil because the risk estimates associated with these exposure pathways had the largest variance.     

Economic evaluation of a landfill system with gas recovery for municipal solid waste management: a case study

Economic activity uses resources, which leads to waste generation. With rapid industrialisation and urbanisation, per capita solid waste generation has increased considerably. Solid waste generation data for last two decades shows an alarming increase. Owing to its improper and untimely collection, the transport and disposal of municipal solid waste poses a severe threat to various components of the environment and also to public health. This paper describes the merits and demerits of various technological aspects of solid waste management. Landfill technology, as it is the most widely employed and is regarded as the most suitable and simple mechanism, especially for tropical countries such as India, is emphasised. All possible costs and benefits and externalities are examined. A cost-benefit analysis of a landfill system with gas recovery (LFSGR) has been carried out for Mumbai city's solid waste, accounting for certain external costs and benefits, and found that it could make a huge difference of savings of about Rs. 6.366 billion (approx. $0.l40 billion) per annum with reference to the existing system of waste disposal.     

Economic insight into municipal solid waste management in Mumbai: a critical analysis

Mumbai generates 6256 tonnes of waste every day, of which 17.20% is recyclable, but only a fraction of this is retrieved by rag-pickers. The economic value of the retrieved material is not considered by the Municipal Corporation of Greater Mumbai in valuing the waste management system as there is no retrieval mechanism except the informal rag-picking activity. Moreover, the cost of land used for the dumping of waste is also not accounted for. In the present paper, a comprehensive cost-benefit analysis for the present system of municipal solid waste management in Mumbai is carried out, with due consideration for implicit or hidden costs and benefits. Accounting for the implicit costs and benefits showed a difference of $6 per every tonne of waste disposal. This could show a considerable difference in policy development at the municipality level. Demand supply analysis proved that the present system of waste management would not yield a feasible market solution without private sector participation. With the increasing demand for improved waste management, private sector participation is essential and a Pigouvian tax is a necessary tool to make the private sector participation in solid waste management a success.     

Minimax regret analysis for municipal solid waste management: an interval-stochastic programming approach

In this study, an interval minimax regret programming (IMMRP) method is developed for the planning of municipal solid waste (MSW) management under uncertainty. It improves on the existing interval programming and minimax regret analysis methods by allowing uncertainties presented as both intervals and random variables to be effectively communicated into the optimization process. The IMMRP can account for economic consequences under all possible scenarios without any assumption on their probabilities. The developed method is applied to a case study of long-term MSW management planning under uncertainty. Multiple scenarios associated with different cost and risk levels are analyzed. Reasonable solutions are generated, demonstrating complex tradeoffs among system cost, regret level, and system-failure risk. The method can also facilitate examination of the difference between the cost incurred with identified strategy and the least cost under an ideal condition. The results can help determine desired plans and policies for waste management under a variety of uncertainties.     

COVID-19 and municipal solid waste (MSW) management: a review

Environmental Science and Pollution Research - Municipal solid waste (MSW) represents an inevitable by-product of human activity and a major crisis for communities across the globe. In recent...     

Cemetery waste as a substream of municipal waste: research and structure of the selective waste collection in Poland

Environmental Science and Pollution Research - Cemetery waste (CW) constitutes one of the streams of municipal waste (MW). Based on the available data, it can be said that it accounts for about 1%...     

An assessment of dioxin contamination from the intermittent operation of a municipal waste incinerator in Japan and associated remediation

Significant dioxin (polychlorinated dibenzo-para-dioxins (PCDDs)/polychlorinated dibenzo-furans (PCDFs)) pollution from a municipal solid waste incinerator was discovered in 1997 in Osaka prefecture/Japan. The cause and mechanism of pollution was identified by a detailed assessment of the environment and incinerator plant. The primary sources of PCDD/PCDF pollution were high dioxin releases from an intermittently operated waste incinerator with PCDD/PCDF emissions of 150 ng-TEQ/Nm³. PCDD/PCDF also accumulated in the wet scrubber system (3,000 μg TEQ/L) by adsorption and water recirculation in the incinerator. Scrubber water was air-cooled with a cooling tower located on the roof of the incinerator. High concentrations of dioxins in the cooling water were released as aerosols into the surrounding and caused heavy soil pollution in the area near the plant. These emissions were considered as the major contamination pathway from the plant. Decontamination and soil remediation in and around the incinerator plant were conducted using a variety of destruction technologies (including incineration, photochemical degradation and GeoMelt technology). Although the soil remediation process was successfully finished in December 2006 about 3 % of the waste still remains. The case demonstrates that releases from incinerators which do not use best available technology or which are not operated according to best environmental practices can contaminate their operators and surrounding land. This significant pollution had a large impact on the Japanese government’s approach toward controlling dioxin pollution. Since this incident, a ministerial conference on dioxins has successfully strengthened control measures.     

Simple and rapid yeast reporter bioassay for dioxin screening: evaluation of the dioxin-like compounds in industrial and municipal waste incineration plants

The CROMIS AhR kit, a simple and rapid yeast bioassay kit, was developed and used to detect dioxins and dioxin-like compounds in 20 gas and solid samples collected from refuse incineration plants in Japan. The World Health Organization toxic equivalent (WHO-TEQ) values of the samples were also calculated using high-resolution gas chromatography/high--resolution mass spectrometry. The WHO-TEQ values of the samples varied greatly, ranging from 0.0021–6.3 ng/g to 0.00013–16 ng/m³N (normal cubic meter) in the solid and gas samples, respectively. 2,3,4,7,8-Pentachlorodibenzofuran (23478-PeCDF) and 1,2,3,7,8-pentachlorodibenzo-p-dioxin (12378-PeCDD) were the major contributors to the samples’ WHO-TEQ values. The yeast in the bioassay responded to these congeners, and the EC₅₀ values of 2,3,7,8-tetrachlorodibenzo-p-dioxin (2378-TeCDD), 12378-PeCDD, and 2,3,4,7,8-PeCDF were 490, 560, and 590 nM, respectively. The incinerator samples were subjected to the bioassay to obtain 2378-TeCDD equivalent values (CROMIS-TEQ values). The CROMIS-TEQ values of the solid and gas samples ranged from 0.0019 to 5.64 ng/g and from 0.14 to 20 ng/m³N, respectively. The CROMIS-TEQ and WHO-TEQ values displayed good correlations (r ²?=?0.94 and 0.95 in the solid and gas samples, respectively), except for those of the samples with low dioxin concentrations (below the Japanese emission standards). Therefore, the CROMIS AhR kit is a useful tool for the initial screening of samples containing dioxin-like compounds.     

台北市生活垃圾管理经验及启示

台北市生活垃圾管理效果显著,人均生活垃圾日清运量年均减量7.3%、资源回收率年均增长28.3%并带动资源回收产业发展、居民负担仅为1998年的22.0%、社会成本较1998年减少30.7%。主要经验包括:明确的生活垃圾减量与资源回收目标;系统的管理模式设计,包括政府(环保局、地方清洁队、资源回收管理基金)、生产商、回收商、处理商、居民、垃圾焚烧厂和填埋场以及第三方等主要干系人。采取的主要政策手段包括强制源头分类、随袋征收垃圾处理费、建立资源回收管理基金、对资源回收行业的政策扶持以及信息公开与公众参与等。台北市先进的生活垃圾管理经验对中国大陆城市开展垃圾分类与资源化管理具有重要的参考价值。