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1.
Rainy season is known to ease the transport of particulate matter whether they are microorganisms or inorganic compounds. Regardless of their origin, these particles have a great environmental importance through their influence on physical processes such as ice nucleation and cloud droplet formation. Pathogenic airborne microorganisms may also have public health consequences. In this paper, we analyse particles from rainwater which were collected in Teflon pipes and then filtered in 0.45-μm pore diameter cellulose filters from six environmental monitoring stations in the Metropolitan Zone of Toluca Valley, State of Mexico, Mexico, during June and September of 2009 rainy season. The particulate material was treated with nitric and hydrochloric acid in a microwave reactor to homogenise samples and to determine the polluting elements through inductively coupled plasma sector field mass spectrometry analyses. At the same time, blank filters were analysed by scanning electron microscopy followed by energy-dispersive X-ray spectroscopy to observe their morphology and to identify their chemical composition. The enrichment factor of the main metals was evaluated.  相似文献   

2.
Particulate organic carbon and nitrogen in sea water were measured in samples collected along a line 155°W; 50° N-15°S, during the cruise of R.V. “Hakuho-Maru” (KH-69-4). High concentrations of particulate matter were generally found at or near the sea surface; the concentrations decreased rapidly with depth. A consistent minimum was located in the depth range 150 to 250 m through the entire section sampled. The subsurface maximum layers roughly coincided with the chlorophyll maximum, but several irrregularities were noted. One of the most remarkable features of the vast stratum below 200 m depth was the presence of distinctively regional variation in concentration of particulate material through the entire section. In the section, we could define at least 6 large water parcels, vertically oriented, all with significantly different concentrations of both carbon and nitrogen. Variation in the deep water ranged from less than 5 μgC/l to more than 50 μgC/l. Correlation analysis between carbon concentration and apparent oxygen utilization (AOU) of ambient water for all samples showed that the carbon from particle-poor water parcels consistently decreased with increasing AOU, levelling to a practically constant low of around 5 to 10 μgC/l, whereas the carbon from particle-rich parcels was anomalously high (10 to 50 μgC/l) in the range of high AOU, and showed no consistent trend of convergence. The intergrated amount of particulate carbon in the total water column at each station was in the range 20 to 150 gC/m2. More than 90% of this total amount was in the water column below 200 m depth, and the correlation of total amount of particulate material between the surface layer (0 to 200 m) and the water column below 200 m depth was highly significant. These observations are considered to indicate that the downward transport of these materials may be much quicker than so far estimated, at least in some localized areas.  相似文献   

3.
In 2004, airborne particulate matter (PM) was collected for several aerosol episodes occurring in the southern region of Taiwan. The particulate samples were taken using both a MOUDI (Micro-orifice Uniform Deposit Impactor) and a nano-MOUDI sampler. These particulate samples were analyzed for major water-soluble ionic species with an emphasis to characterize the mass concentrations and distributions of these ions in the ambient ultrafine (PM0.1, diameter <0.1 μm) and nano mode (PMnano, diameter <0.056 μm) particles. Particles collected at the sampling site (the Da-Liao station) on the whole exhibited a typical tri-modal size distribution on mass concentration. The mass concentration ratios of PMnano/PM2.5, PM0.1/PM2.5, and PM1/PM2.5 on average were 1.8, 2.9, and 71.0%, respectively. The peak mass concentration appeared in the submicron particle mode (0.1 μm < diameter <1.0 μm). Mass fractions (percentages) of the three major water-soluble ions (nitrate, sulfate, and ammonium) as a group in PMnano, PM0.1, PM1, and PM2.5 were 18.4, 21.7, 50.0, and 50.7%, respectively. Overall, results from this study supported the notion that secondary aerosols played a significant role in the formation of ambient submicron particulates (PM0.1−1). Particles smaller than 0.1 μm were essentially basic, whereas those greater than 2.5 μm were neutral or slightly acidic. The neutralization ratio (NR) was close to unity for airborne particles with diameters ranging from 0.18 to 1 μm. The NRs of these airborne particles were found strongly correlated with their sizes, at least for samples taken during the aerosol episodes under study. Insofar as this study is exploratory in nature, as only a small number of particulate samples were used, there appears to be a need for further research into the chemical composition, source contribution, and formation of the nano and ultrafine mode airborne particulates.  相似文献   

4.
Lead contamination in the roadside soils of Slovenia   总被引:5,自引:0,他引:5  
The level of lead contamination along the roadway Ljubljana to Zagreb was established in 184 soil samples. The samples were taken from two depths (0–5cm and 15–20cm) and at different distances from the roadway. The influence of terrain morphology, prevailing winds, geological parent material and type of vegetation was estimated. Heavy traffic is confirmed as main source of lead contamination (average enrichment factor 17) in soils. The highest lead accumulation is localised in the top soil layer and within 10m from the roadside. Contamination with lead is more pronounced in soil samples from cuttings and slopes than in soils from plains and mounds. Soils derived from carbonate rocks contain higher lead concentration than those derived from other parent material.  相似文献   

5.
采集了上海市交通主干道金沙江路距路肩不同距离(近站位、远站位)近地表大气颗粒物样品24个,使用全谱直流电感耦合等离子光谱仪测定其As、Cr、Cu、Pb、Mn、N i等重金属元素浓度。结果表明,大气颗粒物的质量浓度及其重金属绝对浓度在每个采样点的近站位均高于远站位,而部分大气颗粒物的重金属相对浓度表现为远站位高于近站位;金沙江路沿线由外环到内环方向,大气颗粒物的质量浓度有明显降低的趋势,而大气颗粒物重金属含量具有明显的升高趋势,这与机动车的行驶速度是相关的。  相似文献   

6.
In this work, the airborne particulate matter with an aerodynamic diameter less than 10 µm (PM10) was fractionated in a six-stage high-volume cascade impactor to identify particulate size distribution in Tehran atmosphere. The study was conducted at 15 sites located in the north, south, east, west, and central parts of Tehran in 2005. Air samples were analyzed for 16 polycyclic aromatic hydrocarbons (PAHs) by HPLC. The daily PM10 concentrations at the peak of traffic in roadside areas were found to be 106–560 µg m?3. The cumulated concentration sum of PAHs, based on 16 species, was found to have an average concentration of 380 ng m?3. Furthermore, it was found that more than 60% of PAHs belonged to the small particulate size range, having sizes of less than 0.49 µm, some containing benzo(ghi)perylene and indeno(123cd)pyrene (high molecular weight) with average concentrations of 8 and 6 ng m?3 and fluorene, phenanthrene, and fluoranthene (low molecular weight) with average concentrations of 14, 13, and 19 ng m?3, respectively. In addition, the results revealed that the lighter three- and four-ring PAH compounds were the most abundant pollutants in the air collected at all the sampling sites.  相似文献   

7.
太湖流域水源地多氯联苯分布特征与污染水平   总被引:1,自引:0,他引:1  
为系统了解太湖流域主要水源地多氯联苯(PCBs)的污染现状,于2012年3月和6月分别采集水相、悬浮颗粒物和沉积物样品,并利用气相色谱-质谱联用仪(GC-MS)对PCBs的浓度进行了分析。结果表明,3月水相、悬浮颗粒物和沉积物中均未检测出PCBs类物质。6月水相中PCBs质量浓度在ND~1.04 ng·L~(-1)之间,平均值为0.57 ng·L~(-1),悬浮颗粒物和沉积物中PCBs质量浓度分别在0.96~2.72 ng·g-1和0.47~1.29 ng·g-1之间。Aroclor 1016和Aroclor 1260在3种介质中均有检出,且Aroclor1016浓度均为最高。与国内外研究相比较,太湖流域主要水源地PCBs污染水平较低。水相中PCBs浓度水平低于我国地表水环境质量标准;悬浮颗粒物和沉积物中PCBs浓度水平均低于加拿大保护水生环境沉积物化学品风险评价标准的LEL值,说明各样点PCBs对底栖动物无毒性影响。  相似文献   

8.
In vivo chlorophyll fluorescence is particularly interesting ot ecologists because of various concepts (biomass, productivity, physiological state) associated with it. Using a modified spectrophotofluorometer, we have studied the kinetics of fluorescence in unialgal cultures and in a natural population of marine phytoplankton. Our apparatus did not achieve satisfactory results with cell suspensions having a chlorophyll concentration less than 10 g l-1. We have also tested a method for estimating kinetics of diluted cultures and marine phytoplankton using cells collected on glass-fibre filters. For unialgal cultures in the exponential growth phase, the method proved satisfactory, and results obtained from both cell suspensions and filters were in good agreement. However, for aged cultures (principally diatoms) and natural marine phytoplankton the method proved unsuitable. The kinetics of fluorescence induction vary according to taxonomic position of the cells, light intensity of the measuring excitation beam and productiveness of the culture medium. The importance of the kinetics of fluorescence induction for characterization of phytoplankton activity is discussed.  相似文献   

9.
Estimates of the biomass of zooplankton, phytoplankton and particulate matter collected in the Celtic Sea during mixed-water conditions (on 8 and 9 April 1983) were compared to the concentration and diversity of sixteen dissolved free amino acids (DFAA) measured in seawater and in particles. During a day profile, variations of dissolved amino acids with depth reflected the feeding activity of copepods. The relationship was not apparent in a night profile and other processes, such as heterotrophic utilization of dissolved nitrogen by microorganisms, were thought to be involved. The ratios of total DFAA concentration (nM litre-1) in the particulate phase over the concentration in seawater ranged from 1 to 200 within the water column. Of the sixteen amino acids measured, ornithine, a decomposition product of arginine, was responsible for more than 70% of the total concentration of DFAA in seawater. In the particles, phenylalanine ranged from 30 to 88% of total DFAA. In seawater this amino acid occurred in the 20 to 40 m depths (1.3 to 9.9% of total DFAA) in the day profile and at 5 m (12.4%) and 80 m (6.4%) in the night profile. Previously it has only been found in very low concentrations (<5%) in seawater, and its presence is considered to be the result of zooplankton feeding.  相似文献   

10.
The increase in platinum (Pt) in the airborne particulate matter with size ≤2.5 µm (PM2.5) in urban environments may be interpreted as result of the abrasion and deterioration of automobile catalyst. Nowadays, about four million vehicles in Mexico City use catalytic converters, which means that their impact should be considered. In order to evaluate the contribution of Pt to environmental pollution of the metropolitan area of Mexico City (MAMC), airborne PM2.5 was collected at five different sites in the urban area (NW, NE, C, SW, SE) in 2011 during April (dry-warm season), August (rainy season) and December (dry-cold season). Analytical determinations were carried out using a ICP-MS with a collision cell and kinetic energy discrimination. The analytical and instrument performance was evaluated with standard road dust reference material (BCR-723). Median Pt concentration in the analyzed particulate was is 38.4 pg m?3 (minimal value 1 pg m?3 maximal value 79 pg m?3). Obtained Pt concentrations are higher than those reported for other urban areas. Spatial variation shows that SW had Pt concentration significantly higher than NW and C only. Seasonal variation shows that Pt median was higher in rainy season than in both dry seasons. A comparison of these results with previously reported data of PM10 from 1991 and 2003 in the same studied area shows a worrying increase in the concentration of Pt in the air environment of MAMC.  相似文献   

11.
The main purpose of this work was to develop a reliable method for the determination of vanadium (V) and molybdenum (Mo) in atmosphere particles or aerosols because they can not be readily measured using conventional techniques. For this research, 30 particulate samples were collected from five different stations located at Palermo, Italy. We used the catalytic adsorptive stripping voltammetry and differential pulsed voltammetry to measure V and Mo in atmospheric particulate, respectively. The represented method includes advantages of high sensitivity, high selectivity, simplicity, reproducibility, speed and low costs. The quantification limits for V and Mo are, respectively, 0.57 and 0.80 ng·m−3. The precision, expressed as relative standard deviation (RSD %), was about 2% for both metals. The mean recoveries of added V and Mo were about 99.5% and ranged from 97% to 101%. Vanadium concentrations in particulate samples collected in Palermo area ranged from 0.57 to 7.7 ng·m−3, while Mo concentrations were in the range 0.8–51 ng·m−3. In many cases the concentrations of two elements in the particulate samples fall below the detection limits. The mean concentrations for V and Mo in particulate samples, collected in Palermo area, were respectively 3.1 and 5.9 ng·m−3.  相似文献   

12.
Some experiments on phosphate assimilation by coastal marine plankton   总被引:2,自引:0,他引:2  
A study of phosphate assimilation by coastal marine plankton revealed that both phytoplankton and microheterotrophs incorporated radioactive phosphorus (33P). Size fractionation of the particulate matter (using 1 m pore diameter Nucleopore® membrane filters), antibiotic treatment (using garamycin), and independent estimaties of photoautotrophic (14CO2 uptake) and heterotrophic (3H-glucose uptake) activities were employed to separate phyto- and bacterioplankton phosphate uptake. Results indicated that phytoplankton 33P-uptake was best estimated by the fraction of particulate matter retained on the 1 m membrane filters. Usually, less than 10% of the phytoplankton (based on chlorophyll a measurements) passed the 1 m pore-diameter filters, whereas about 90% of the heterotrophic activity passed. At least 50% of the 33P-uptake was associated with the <1 m fraction. It may be possible to resolve the phytoplankton and bacterial contributions to 33P-uptake by comparing the percent of total 33P-uptake with the percent of total 3H-glucose uptake associated with the >1 m fraction.  相似文献   

13.
Arsenic is present in airborne particulate material released by coal-fired power plants and non-ferrous metal smelters. We have assessed whether the physico-chemical properties of arsenic in such particles play a role in its lung retention and uptake by the body. Female hamsters were given a single intratracheal instillation of fly ash or copper smelter dust suspensions (at doses of 50 or 100 g As kg–1) or identical amounts of soluble tri- and pentavalent arsenic, in the presence or absence of an inert dust material (tungsten carbide). The concentration of the element was measured in a 24 hour urine sample collected on the 1st, 2nd and 6th day after treatment and arsenic remaining in lung tissue was determined at the end of the same time periods. Both lung retention and urinary As excretion indicate a prolonged contact of the lung tissue with particulate As in contrast to soluble As salts. In addition to the effect of solubility described here, more research is needed to determine the effect of particle size and lung loading on retention, as well as the potential differences in the lung inflammatory response using arsenic-rich particulates from various sources.  相似文献   

14.
The food-concentrating filter within the house of Oikopleura vanhoeffeni Lohmann consists of three layers, upper and lower fine-mesh layers and an intermediate coarse-mesh layer. The filter is a natural analogue of man-made tangential, or cross-flow, filters that are used to concentrate fine particulate and colloidal material by the exclusion of water. Flow analysis using video microscopy of O. vanhoeffeni, collected in 1989 and 1990 at Logy Bay, insular Newfoundland, indicates concentration of particles of 74 to 1089 times that of ambient seawater ( ,n=23), for individuals 1.8 to 5.4 mm long. The smallest individuals had the highest concentration factors. Flow through the house is predominately affected by viscous forces and values of Reynolds numbers are 1. Flow rates through the house of O. vanhoeffeni indicate a maximum filtration capacity of ca. 1.4 to 26 liters d-1 and clearance rates (assuming ca. 50% of the time is spent not actively pumping) of 0.7 to 13 liters d-1, depending on body size. The estimated thickness of the boundary layer around individual fibers of the food-concentrating filter is 0.08 m, which is less than the pore width. The estimated concentration factors suggest that colloidal and fine particulate material may aggregate into larger particles within the food-concentrating filter and food tube during feeding.  相似文献   

15.
The ocean is a significant sink for increasing anthropogenic carbon dioxide emissions. The sea-surface microlayer (upper 50 m layer) serves as the primary point for exchange of materials, including carbon dioxide, between the atmosphere and hydrosphere. We determined microalgal standing stocks and activities in microlayer and subsurface water from areas with (S) and without (NS) visible natural surface slicks in Sequim Bay, Washington, USA, in July 1984. Enrichment ratios (microlayer concentration: subsurface bulkwater concentration) were: phytoneuston population abundance, 37 (NS) to 154 (S); total chlorophylls, 1.3 (NS) to 18 (S); particulate carbon fixation, 2 (NS) to 52 (S); and dissolved carbon excretion, 17 (NS) to 63 (S). Photoinhibition of 36 to 89% occurred in phytoneuston under natural summer light-intensities. Slick samples had greater standing stocks and rates of primary production than non-slick samples. The species composition of phytoneuston was distinctly different from that of phytoplankton. These results suggest that phytoneuston form a unique community. Although carbon fixation in summer was less per individual in phytoneuston than in phytoplankton, because of their overall abundance at the air-sea interface, phytoneuston may play an important role in the transfer of CO2 from the atmosphere into ocean surface-water.  相似文献   

16.
Cuttings of the marine phanerogam Posidonia oceanica (L.) Delile were collected and transplanted in January 1991 at four stations of different depths between 5 and 20 m in the underwater reserve at Monaco (1 ha in area). From January to July, samples of the transplants were collected to study the effect of depth on survival and on chlorophyll and carbohydrate concentrations. In the leaves, chlorophyll concentrations were significantly lower (1.00 mg g-1 dry wt) in cuttings taken from 5 m depth than in cuttings taken from 20 m (1.99 mg g-1). Transplantation of cuttings from 5 to 20 m or from 20 to 8 m did not significantly change the chlorophyll concentration in leaves for a period of 6 mo after transplantation. Cutting and transplantation result in stress, as indicated by a decrease in pigment concentration without change of depth. However, the carbohydrate concentration in rhizomes from 5 m (32 mg g-1 dry wt), is significantly higher than in material from 20 m (17 mg g-1). Cuttings transplanted from 5 to 20 m lost most of their carbohydrate reserves (reaching a minimum of 2.5 mg g-1 in May); cuttings transplanted from 20 to 8 m maintained higher reserves (with a minimum of 20 mg g-1 in June). This may explain why material transplanted from 5 to 20 m exhibited only 52% survival, while material transplanted from 20 to 8 m displayed 80 to 92% survival. Material taken from populations adapted to low light at 20 m is probably more resistant to transplantation stress, particularly when replanted at a higher light intensity in shallow water.  相似文献   

17.
The ‘scope for growth’ (SFG) tool was used to study the growth performance of cultivated populations of Mytilus galloprovincialis (Lmk., 1819) in an oligotrophic area of the Southern Mediterranean Sea. The study was carried out between 1993 and 1996 by using data from four seasonal oceanographic cruises and from growth experiments. Water samples were collected and analysed for total suspended matter (TSM), particulate organic carbon (POC) and nitrogen (PON), particulate lipids, proteins and carbohydrates and chloropigments. The sum of the carbon equivalents of carbohydrates, proteins and lipids is indicated as the total biopolymeric particulate organic carbon (BPC) and was converted into a unit of energy in order to calculate the SFG of a theoretical mussel of 5 cm length. In order to test the performance of mussel growth at two depths (5 and 15 m water depth), mussel body size [as ash free dry weight (AFDW)] and the actual concentrations of BPC were used to calculate the monthly SFG using the physiological energetic relationships suggested in the current literature. Data from the field cruises led us to characterise the study site as ultra-oligotrophic (annual average of chloropigment concentration approximately 0.5 μg L−1). SFG calculations allowed us to identify a site where mussels grown successively were found to reach a commercial size in approximately 12 months. The good agreement obtained between energetic response and subsequent production response suggests that the available energy from particulate food could be fully available for organic production for maintaining “proportionate” growth trajectories, even in a ultra-oligotrophic system.  相似文献   

18.
The ‘scope for growth’ (SFG) tool was used to study the growth performance of cultivated populations of Mytilus galloprovincialis (Lmk., 1819) in an oligotrophic area of the Southern Mediterranean Sea. The study was carried out between 1993 and 1996 by using data from four seasonal oceanographic cruises and from growth experiments. Water samples were collected and analysed for total suspended matter (TSM), particulate organic carbon (POC) and nitrogen (PON), particulate lipids, proteins and carbohydrates and chloropigments. The sum of the carbon equivalents of carbohydrates, proteins and lipids is indicated as the total biopolymeric particulate organic carbon (BPC) and was converted into a unit of energy in order to calculate the SFG of a theoretical mussel of 5 cm length. In order to test the performance of mussel growth at two depths (5 and 15 m water depth), mussel body size [as ash free dry weight (AFDW)] and the actual concentrations of BPC were used to calculate the monthly SFG using the physiological energetic relationships suggested in the current literature. Data from the field cruises led us to characterise the study site as ultra-oligotrophic (annual average of chloropigment concentration approximately 0.5 μg L−1). SFG calculations allowed us to identify a site where mussels grown successively were found to reach a commercial size in approximately 12 months. The good agreement obtained between energetic response and subsequent production response suggests that the available energy from particulate food could be fully available for organic production for maintaining “proportionate” growth trajectories, even in a ultra-oligotrophic system.  相似文献   

19.
We have studied carbohydrate metabolism in the marine environment by means of the isolation and characterization of carbohydrates of particulate matter from various depths. The present work is especially concerned with water-extractable carbohydrates of the particulate samples from 11 stations of the northwest Pacific Ocean. Water-extractable carbohydrate content in the particulate matter of the surface waters was measured; it ranged from 19.2 to 36.0% of the total particulate carbohydrate. These values decreased, ranging from 6.5 to 15.5% at 50 m depth. Such rapid vertical change of the concentration of the carbohydrate indicated that it was lost from the particulate matter much faster than the other particulate organic constituents such as protein and water-insoluble carbohydrate. This process left water-insoluble carbohydrate in the deep-water particulate matter as previously observed in the Sagami Nada, off eastern Honshu, Japan. Upon acid hydrolysis, water-extractable carbohydrate revealed glucose ranging from 67.0 to 84.2%. Rhamnose, fucose, ribose, arabinose, xylose, mannose and galactose were also identified as components of the carbohydrate fraction. Carbohydrate studies on the laboratory cultured diatoms clearly indicated that the water-extractable carbohydrates were food reserve materials of the diatoms. In view of this fact, the metabolism of the water-extractable carbohydrate in the euphotic zone and its underlying layer is discussed.  相似文献   

20.
Recently, the problem of indoor particulate matter pollution has received much attention. An increasing number of epidemiological studies show that the concentration of atmospheric particulate matter has a significant effect on human health, even at very low concentrations. Most of these investigations have relied upon outdoor particle concentrations as surrogates of human exposures. However, considering that the concentration distribution of the indoor particulate matter is largely dependent on the extent to which these particles penetrate the building and on the degree of suspension in the indoor air, human exposures to particles of outdoor origin may not be equal to outdoor particle concentration levels. Therefore, it is critical to understand the relationship between the particle concentrations found outdoors and those found in indoor micro-environments. In this study, experiments were conducted using a naturally ventilated office located in Qingdao, China. The indoor and outdoor particle concentrations were measured at the same time using an optical counter with four size ranges. The particle size distribution ranged from 0.3 to 2.5 μm, and the experimental period was from April to September, 2016. Based on the experimental data, the dynamic and mass balance model based on time was used to estimate the penetration rate and deposition rate at air exchange rates of 0.03–0.25 h?1. The values of the penetration rate and deposition velocity of indoor particles were determined to range from 0.45 to 0.82 h?1 and 1.71 to 2.82 m/h, respectively. In addition, the particulate pollution exposure in the indoor environment was analyzed to estimate the exposure hazard from indoor particulate matter pollution, which is important for human exposure to particles and associated health effects. The conclusions from this study can serve to provide a better understanding the dynamics and behaviors of airborne particle entering into buildings. And they will also highlight effective methods to reduce exposure to particles in office buildings.  相似文献   

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