Energy and environmental applications of carbon nanotubes

Energy and environment are major global issues inducing environmental pollution problems. Energy generation from conventional fossil fuels has been identified as the main culprit of environmental quality degradation and environmental pollution. In order to address these issues, nanotechnology plays an essential role in revolutionizing the device applications for energy conversion and storage, environmental monitoring, as well as green engineering of environmental friendly materials. Carbon nanotubes and their hybrid nanocomposites have received immense research attention for their potential applications in various fields due to their unique structural, electronic and mechanical properties. Here, we review the applications of carbon nanotubes (1) in energy conversion and storage such as in solar cells, fuel cells, hydrogen storage, lithium ion batteries and electrochemical supercapacitors, (2) in environmental monitoring and wastewater treatment for the detection and removal of gas pollutants, pathogens, dyes, heavy metals and pesticides and (3) in green nanocomposite design. Integration of carbon nanotubes in solar and fuel cells has increased the energy conversion efficiency of these energy conversion applications, which serve as the future sustainable energy sources. Carbon nanotubes doped with metal hydrides show high hydrogen storage capacity of around 6?wt% as a potential hydrogen storage medium. Carbon nanotubes nanocomposites have exhibited high energy capacity in lithium ion batteries and high specific capacitance in electrochemical supercapacitors, in addition to excellent cycle stability. High sensitivity and selectivity towards the detection of environmental pollutants are demonstrated by carbon nanotubes based sensors, as well as the anticipated potentials of carbon nanotubes as adsorbent to remove environmental pollutants, which show high adsorption capacity and good regeneration capability. Carbon nanotubes are employed as reinforcement material in green nanocomposites, which is advantageous in supplying the desired properties, in addition to the biodegradability. This article presents an overview of the advantages imparted by carbon nanotubes in electrochemical devices of energy applications and green nanocomposites, as well as nanosensor and adsorbent for environmental protection.     

对苏南地区城市化过程中环境问题的思考

对苏南地区城市化的特征和城市化过程中出现的环境问题进行了分析，指出城市化发展的必由之路是实行可持续发展，提出了该地区为实现可持续发展必须做到５个协调     

Higher education level teaching of (master’s) programmes in sustainable development: analysis of views on prerequisites and practices based on a worldwide survey

The concept of sustainable development (SD) has highly been debated since it was presented 25 years ago, with ‘hard science’ approaches on one side and more process-oriented approaches on the other side. Academic teaching in SD has emerged in response to this in very different contexts, partly mirroring this academic debate. Some master’s programmes in SD take a strong science approach, while other programmes focus on the process of implementing sustainability projects, sometimes connected with forms of action research and teaching. In this article, we identify diverse views on the concept of SD as well as views on most relevant modes of teaching. We discuss core competencies required for sustainability professionals in their working practices and we organise them in three main clusters: Know, Interact and Be (KIB). The article presents the results of a worldwide survey, which addresses these visions on the concept of SD, the capabilities needed for ‘sustainable development professionals’ and the teaching approach needed. The analysis is based on the responses of 54 lecturers and 287 students active in 34 SD master’s programmes on all continents. The results of this worldwide survey are discussed. We observe in practice some gaps between preferences and practice. Looking at what both lecturers and students see as essential topics to address, some topics get relatively less attention (like the population issue). The identified core competencies (KIB) are supported and all addressed in practice, while the ‘Be’ competencies receive relatively less attention. Suggested consequences for academic teaching include a further matching of programmes with perceived needs and bridging the gap between the experienced teaching approaches in practice with such identified needs.     

Redox-active ligands in artificial photosynthesis: a review

Environmental Chemistry Letters - Given the rising socioeconomic issues of fossil fuels, efficient artificial photosynthesis would be an important milestone toward a sustainable world. A key step...     

From teleconnection to telecoupling: taking stock of an emerging framework in land system science

Land use change is influenced by a complexity of drivers that transcend spatial, institutional and temporal scales. The analytical framework of telecoupling has recently been proposed in land system science to address this complexity, particularly the increasing importance of distal connections, flows and feedbacks characterising change in land systems. This framework holds important potential for advancing the analysis of land system change. In this article, we review the state of the art of the telecoupling framework in the land system science literature. The article traces the development of the framework from teleconnection to telecoupling and presents two approaches to telecoupling analysis currently proposed in the literature. Subsequently, we discuss a number of analytical challenges related to categorisation of systems, system boundaries, hierarchy and scale. Finally, we propose approaches to address these challenges by looking beyond land system science to theoretical perspectives from economic geography, social metabolism studies, political ecology and cultural anthropology.     

Transforming conservation science and practice for a postnormal world

We examine issues to consider when reframing conservation science and practice in the context of global change. New framings of the links between ecosystems and society are emerging that are changing peoples’ values and expectations of nature, resulting in plural perspectives on conservation. Reframing conservation for global change can thus be regarded as a stage in the evolving relationship between people and nature rather than some recent trend. New models of how conservation links with transformative adaptation include how decision contexts for conservation can be reframed and integrated with an adaptation pathways approach to create new options for global‐change‐ready conservation. New relationships for conservation science and governance include coproduction of knowledge that supports social learning. New processes for implementing adaptation for conservation outcomes include deliberate practices used to develop new strategies, shift world views, work with conflict, address power and intergenerational equity in decisions, and build consciousness and creativity that empower agents to act. We argue that reframing conservation for global change requires scientists and practitioners to implement approaches unconstrained by discipline and sectoral boundaries, geopolitical polarities, or technical problematization. We consider a stronger focus on inclusive creation of knowledge and the interaction of this knowledge with societal values and rules is likely to result in conservation science and practice that meets the challenges of a postnormal world.     

Nanomaterials for biofuel production using lignocellulosic waste

Production of biofuels using second-generation, non-food, lignocellulosic waste biomass is a sustainable approach that solve the economic issues of fossil fuels and environmental pollution. The major issues of biofuel production are biomass complexity, pretreatment, enzyme denaturation and cost. This article reviews the application of nanomaterials for biofuel production from various lignocellulosic wastes.     

Conversion of plant materials into hydroxymethylfurfural using ionic liquids

The use of fossil fuels now induces two major issues. First, fossil fuel burning is increasing atmospheric carbon dioxide (CO₂) concentrations and, in turn, global warming. Second, fossil fuel resources are limited and will thus decrease in the long run. As a potential solution, there is a need for ecological manufacturing processes that convert raw plant materials into chemical products. For instance, raw plants can be directly converted into hydroxymethylfurfural, which is a versatile intermediate for the synthesis of valuable biofuels such as dimethylfuran and 5-ethoxymethyl-2-furfural. This technology has two benefits for chemical sustainability. First, the pretreatment step is eliminated, thus contributing to reduction of CO₂ emissions. Second, plants are sustainable resources versus fossil fuels, which are limited. Here, we review current sustainable technologies for the production of biobased products and hydroxymethylfurfural from plants, using in particular ionic liquids. Plant sources include poplar, switchgrass, miscanthus, weed plants, and agave species.     

Building Dialogue on Complex Conservation Issues in a Conference Setting

Dialogue about complex science and society issues is important for contemporary conservation agendas. Conferences provide an appropriate space for such dialogue, but despite its recognized worth, best practices for facilitating active dialogue are still being explored. Face‐to‐face (FTF) and computer‐mediated communication (CMC) are two approaches to facilitating dialogue that have different strengths. We assessed the use of these approaches to create dialogue on cultural perspectives of conservation and biodiversity at a national ecology conference. In particular, we aimed to evaluate their potential to enhance dialogue through their integrated application. We used an interactive blog to generate CMC on participant‐sourced issues and to prime subsequent discussion in an FTF conference workshop. The quantity and quality of both CMC and FTF discussion indicated that both approaches were effective in building dialogue. Prior to the conference the blog averaged 126 views per day, and 44 different authors contributed a total of 127 comments. Twenty‐five participants subsequently participated in active FTF discussion during a 3‐h workshop. Postconference surveys confirmed that CMC had developed participants’ thinking and deepened FTF dialogue; 88% indicated specifically that CMC helped facilitate the FTF discussion. A further 83% of respondents concluded that preliminary blog discussion would be useful for facilitating dialogue at future conferences. Construcción del Diálogo sobre Problemas Complejos de Conservación en un Escenario de Conferencia     

Conversion of biomass into hydrogen by supercritical water gasification: a review

Environmental Chemistry Letters - The rising issues of global warming due to the rapid use of fossil fuels are calling for sustainable energies such as dihydrogen, thereafter named...     

生态承载力的概念及其研究方法

生态承载力研究是可持续发展科学领域关注的热点问题,是判定可持续发展的重要分析手段,对生态承载力的概念和评价方法的研究有利于可持续发展科学的发展与完善。对国内外相关研究中的生态承载力概念进行了总结,并深入探讨了不同学者对于生态承载力概念达成的共识及存在的分歧,在此基础上提出了生态承载力概念的内涵。依据生态承载力评价的思路,将国内外生态承载力评价方法分为3类,第1类是指标体系评价法,第2类是以能量、物质流为基础的产品周期评价,第3类是综合性评价。上述评价方法在处理复杂系统问题上都有各自的优缺点,需要评价者根据评价目的采用互补的方式对方法进行集成,加强综合集成的方法在生态承载力评价中的应用。最后,结合生态承载力研究的发展趋势,分析了目前生态承载力研究的不足,提出了生态承载力中主动因子与被动因子、生态承载力预测及其与区域规划的结合、经济发展和科技进步对生态承载力的影响、生态承载力方法改进等亟待开展的研究内容。     

Facilitating sustainable development in Chile: a survey of suitable energy technologies

Sustainable development in developing countries is the main aim of the Kyoto Protocol's Clean Development Mechanism (CDM). However, in the present context, uncertainty prevails as to whether the CDM is actually achieving its aims in terms of achieving sustainable development and to what extent. Chile has several renewable energy and energy efficiency options with significant greenhouse gas (GHG) emissions abatement potential that are not yet financially and economically competitive. In order to be able to identify potential CDM projects and to formulate a series of possible investment strategies with a sustainable development component, it is crucial to establish a clear understanding of the host country's needs and priorities and the suitable sustainable energy technologies to meet these needs. The main scope of this paper is to present results obtained from an elaborated stakeholder assessment on Chile's high priority energy needs and sustainable energy technologies fulfilling these needs in order to assist Chile in finding ways of encouraging technology transfer that would contribute to low-carbon sustainable energy development.     

Methodological integration for sustainable natural resource management beyond field/farm level: lessons from the ecoregional initiative for the humid and sub-humid tropics of Asia

SUMMARY

Integrated natural resources management (INRM) has to address both the livelihood goals of farmers and the ecological sustainability of agroecosystems and natural resources. Under the Ecoregional Initiative for the Humid and Sub-Humid Tropics of Asia — Ecor(1)Asia — one major set of activities has been the development of approaches, methodologies, and tools to meet the challenges of INRM research for sustainable agricultural development. Examples provided illustrate the role of these methodologies in the three main phases of knowledge development for improving INRM impact: knowledge generation, knowledge capitalization, and knowledge mobilization. The methodologies are designed for better integration across disciplines, spatial scales, and hierarchical levels of social organization. Attempts are made to quantify trade-offs between biophysical sustainability and socio-economic considerations. The case is made for using these methodologies in a more complementary manner to help bridge the topdown and bottom-up approaches in INRM. Inherent in the developing and implementing of these methodologies is the forging of partnerships and fostering linkages with multiple stakeholders, as well as using the knowledge base and integrative tools as communication platforms.     

AIC model selection and multimodel inference in behavioral ecology: some background,observations, and comparisons

We briefly outline the information-theoretic (I-T) approaches to valid inference including a review of some simple methods for making formal inference from all the hypotheses in the model set (multimodel inference). The I-T approaches can replace the usual t tests and ANOVA tables that are so inferentially limited, but still commonly used. The I-T methods are easy to compute and understand and provide formal measures of the strength of evidence for both the null and alternative hypotheses, given the data. We give an example to highlight the importance of deriving alternative hypotheses and representing these as probability models. Fifteen technical issues are addressed to clarify various points that have appeared incorrectly in the recent literature. We offer several remarks regarding the future of empirical science and data analysis under an I-T framework.     

Bioleaching metal-bearing wastes and by-products for resource recovery: a review

The global transition to a circular economy calls for research and development on technologies facilitating sustainable resource recovery from wastes and by-products. Metal-bearing materials, including electronic wastes, tailings, and metallurgical by-products, are increasingly viewed as valuable resources, with some possessing comparable or superior quality to natural ores. Bioleaching, an eco-friendly and cost-effective alternative to conventional hydrometallurgical and pyrometallurgical methods, uses microorganisms and their metabolites to extract metals from unwanted metal-bearing materials. The performance of bioleaching is influenced by pH, solid concentration, energy source, agitation rate, irrigation rate, aeration rate, and inoculum concentration. Optimizing these parameters improves yields and encourages the wider application of bioleaching. Here, we review the microbial diversity and specific mechanisms of bioleaching for metal recovery. We describe the current operations and approaches of bioleaching at various scales and summarise the influence of a broad range of operational parameters. Finally, we address the primary challenges in scaling up bioleaching applications and propose an optimisation strategy for future bioleaching research.

     

Biological hydrogen production from organic wastewater by dark fermentation in China: Overview and prospects

Biological hydrogen production by dark fermentation is an important part of biological hydrogen production technologies. China is a typical developing country that heavily relies on fossil fuels; thus, new, clean, and sustainable energy development turns quite urgent. It is delightful that Chinese government has already drawn up several H₂ development policies since 1990s and provided financial aid to launch some H₂ development projects. In this paper, the research status on dark fermentative hydrogen production in China was summarized and analyzed. Subsequently, several new findings and achievements, with some of which transformed into scale-up tests, were highlighted. Moreover, some prospecting coupling processes with dark fermentation of hydrogen production were also proposed to attract more research interests in the future.     

Measurement of sustainability performance in Brazilian organizations

In recent years, sustainability issues are gaining greater prominence among organizations and their stakeholders around the world. This paper aims to verify the sustainability performance of Brazilian organizations in performance measures and to propose sustainable guidelines with the intention of directing future efforts to the transition to sustainable development. The research utilized a triangulated approach by collecting qualitative and quantitative data acquired through multiple collection methods of a theoretical literature review, documentary analysis of corporate reports, questionnaire survey and semi-structured interviews with industry professionals and academic researchers. The results show that internal organizational factors are the main inductors of the sustainable environment in organizations, and sustainability must be tied to strategic planning, starting from upper management to lower levels. It is essential to use sustainable performance measurement systems in order to respond to external and internal levers and serve as benchmarking for future corporate operations and strategies. In addition, it is the responsibility of organizations to focus their efforts on environmental protection, reduction of energy, corporate reputation, quality management, customer satisfaction and investor relations, as they are considered to be more important and have a relationship of dependence on organizational sustainability. The findings will be of value to professionals and academics who want to start measuring and for continuously improving the sustainability performance of their organizations according to the technical, economic, environmental, social and governance dimensions. This research work also helps to understand the perceptions and expectations of stakeholders.     

Ethics and governance for internet-based conservation science research

Internet-based research is increasingly important for conservation science and has wide-ranging applications and contexts, including culturomics, illegal wildlife trade, and citizen science. However, online research methods pose a range of ethical and legal challenges. Online data may be protected by copyright, database rights, or contract law. Privacy rights may also restrict the use and access of data, as well as ethical requirements from institutions. Online data have real-world meaning, and the ethical treatment of individuals and communities must not be marginalized when conducting internet-based research. As ethics frameworks originally developed for biomedical applications are inadequate for these methods, we propose that research activities involving the analysis of preexisting online data be treated analogous to offline social science methods, in particular, nondeceptive covert observation. By treating internet users and their data with respect and due consideration, conservationists can uphold the public trust needed to effectively address real-world issues.     

Exploring relationships between conservation and poverty reduction in wetland ecosystems: lessons from 10 integrated wetland conservation and poverty reduction initiatives

It is well known that whilst wetlands deliver a wide range of services vital for human well-being, they are being rapidly degraded and lost. Losses tend to be higher where human populations are increasing most and demands for economic development are greatest. Multidisciplinary management approaches that integrate conservation and development objectives in wetlands are therefore urgently requested for by the Ramsar Convention on Wetlands. This paper describes the evaluation of 10 wetland management case studies from Asia, Africa and South America that adopted such an integrated approach. The evaluation assessed the outcomes of these integrated initiatives to identify conditions and processes for linking conservation and poverty reduction objectives in wetlands. The findings are also compared with other assessments of integrated approaches, particularly in terms of their effectiveness in optimizing conservation and poverty reduction outcomes. The results from our studies suggest an ongoing evolution of such integrated interventions, which also implies cycles of learning from past mistakes. Overall, our results highlight the significant variation between wetlands in types and quantities of services they provide and emphasize the need to view many ecological issues as social challenges for equitable solutions to both wetlands and people. The analysis further shows that the positive on-ground results owe much to the interdisciplinary problem analysis, whereby interventions can move from treating symptoms to addressing root causes. while no blueprint emerged on how to successfully integrate conservation and poverty reduction in wetlands, important lessons for future interventions were drawn.