WATER QUALITY OF AN INTENSWE AGRICULTURAL WATERSHED IN QUEBEC1

ABSTRACT: . Under a watershed based approach being examined by the Quebec Ministry of Agriculture to accelerate the adoption of conservation practices, a study on the impacts of agricultural practices on the St. Esprit watershed was initiated in the fall of 1993. The water quality of this 26 km² intensive agricultural watershed was studied over an 18 month period. Water samples taken at the outlet of the watershed were analyzed for nitrate, phosphate, suspended sediment, and atrazine. Water quality data were analyzed to establish seasonal trends in pollutant concentration and load in the watercourse. Spring snowmelt was identified as a significant period of pollutant material export. All pollutant materials displayed seasonal variability in the export process. Peak pollutant concentrations were associated with high flow events. Mean observed pollutant concentrations did not exceed drinking water quality standards.     

A MODELING APPROACH FOR STORM WATER QUANTITY AND QUALITY CONTROL VIA DETENTION BASINS1

ABSTRACT: Storm water detention basins have historically been employed for quantity (i.e., flooding) control only. However, recently it has been suggested that these basins may also provide a practical means of storm water quality control. This paper presents the formulation of a mathematical modeling approach which may be used by professionals to simultaneously design detention basins for the dual purpose of storm water quantity and quality control. Model simulations demonstrate that for a given basin, pollutant removal increases as storm frequency increases. The importance of particle size distribution and settling velocity for net pollutant removal is illustrated, The design procedure is demonstrated, and pollutant loading diagrams for estimating pollutant removal as a function of storm size are developed.     

CURVE NUMBER HYDROLOGY IN WATER QUALITY MODELING: USES,ABUSES, AND FUTURE DIRECTIONS1

ABSTRACT: Although the curve number method of the Natural Resources Conservation Service has been used as the foundation of the hydrology algorithms in many nonpoint source water quality models, there are significant problematic issues with the way it has been implemented and interpreted that are not generally recognized. This usage is based on misconceptions about the meaning of the runoff value that the method computes, which is a likely fundamental cause of uncertainty in subsequent erosion and pollutant loading predictions dependent on this value. As a result, there are some major limitations on the conclusions and decisions about the effects of management practices on water quality that can be supported with current nonpoint source water quality models. They also cannot supply the detailed quantitative and spatial information needed to address emerging issues. A key prerequisite for improving model predictions is to improve the hydrologic algorithms contained within them. The use of the curve number method is still appropriate for flood hydrograph engineering applications, but more physically based algorithms that simulate all streamflow generating processes are needed for nonpoint source water quality modeling. Spatially distributed hydrologic modeling has tremendous potential in achieving this goal.     

A FRAMEWORK FOR PHOSPHORUS TRANSPORT MODELING IN THE LAKE OKEECHOBEE WATERSHED1

ABSTRACT: A modeling framework was developed to determine phosphorus loadings to Lake Okeechobee from watersheds located north of the lake. This framework consists of the land-based model CREAMS-WT, the in-stream transport model QUAL2E, and an interface procedure to format the land-based model output for use by the in-stream model. QUAL2E hydraulics and water quality routines were modified to account for flow routing and phosphorus retention in both wetlands and stream channels. Phosphorus loadings obtained from previous applications of CREAMS-WT were used by QUAL2E, and calibration and verification showed that QUAL2E accurately simulated seasonal and annual phosphorus loadings from a watershed. Sensitivity and uncertainty analyses indicated that the accuracy of monthly loadings can be improved by using better estimates of in-stream phosphorus decay rates, ground water phosphorus concentrations, and runoff phosphorus concentrations as input to QUAL2E.     

SIMULATION OF SEDIMENT AND PLANT NUTRIENT LOSSES BY THE CREAMS WATER QUALITY MODEL1

ABSTRACT: CREAMS was applied to a field-sized watershed planted to cotton in the Limestone Valley region of northern Alabama. The field was cultivated for three years with conventional tillage (CvT) followed by three years of conservation tillage (CsT). CREAMS is composed of three components: hydrology, erosion, and chemistry. Surface runoff and losses of sediment, N and P were simulated and results were compared with the observed data from the watershed. Curve numbers recommended in the CREAMS user's guide were not adequate for the watershed conditions. The hydrology submodel improved runoff simulation from CvT and CsT when field-data based curve numbers were used. The erosion submodel demonstrated that CsT reduced sediment loss more than CvT, even though CsT had higher runoff than CvT. The nutrient submodel based on the simulated runoff and sediment underpredicted N loss for both CvT and CsT. This submodel, however, accurately predicted P loss for CvT, but underpredicted for CsT (50 percent lower than the observed). The results of CREAMS simulation generally matched the observed order of magnitude for higher runoff, lower sediment, and higher N and P losses from CsT than from CvT.     

IDENTIFICATION OF CRITICAL NONPOINT POLLUTION SOURCE AREAS USING GEOGRAPHIC INFORMATION SYSTEMS AND WATER QUALITY MODELING1

n integrated approach coupling water quality computer simulation modeling with a geographic information system (GIS) was used to delineate critical areas of nonpoint source (NPS) pollution at the watershed level. Two simplified pollutant export models were integrated with the Virginia Geographic Information System (VirGIS) to estimate soil erosion, sediment yield, and phosphorus (P) loading from the Nomini Creek watershed located in Westmoreland County, Virginia. On the basis of selected criteria for soil erosion rate, sediment yield, and P loading, model outputs were used to identily watershed areas which exhibit three categories (low, medium, high) of non-point source pollution potentials. The percentage of the watershed area in each category, and the land area with critical pollution problems were also identified. For the 1505-ha Nomini Creek watershed, about 15, 16, and 21 percent of the watershed area were delineated as sources of critical soil erosion, sediment, and phosphorus pollution problems, respectively. In general, the study demonstrated the usefulness of integrating GIS with simulation modeling for nonpoint source pollution control and planning. Such techniques can facilitate making priorities and targeting nonpoint source pollution control programs.     

CHANGES IN LAND USE/MANAGEMENT AND WATER QUALITY IN THE LONG CREEK WATERSHED1

ABSTRACT: Surface water in the Long Creek watershed, located in western Piedmont region of North Carolina, was monitored from 1993 to 2001. The 8,190 ha watershed has undergone considerable land use and management changes during this period. Land use surveys have documented a 60 percent decrease in cropland area and a more than 200 percent increase in areas being developed into new homes. In addition, more than 200 conservation practices have been applied to the cropland and other agricultural land that remains in production. The water quality of Long Creek was monitored by collecting grab samples at four sites along Long Creek and continuously monitoring discharge at one site. The monitoring has documented a 70 percent reduction in median total phosphorus (TP) concentrations, with little reductions in nitrate and total Kjel‐dahl nitrogen, or suspended sediment levels. Fecal coliform (FC) and streptococci (FS) levels declined significantly downstream as compared to upstream during the last four years of monitoring. This decrease was attributed to the implementation of waste management practices and livestock exclusion fencing on three dairy operations in the watershed. Annual rainfall and discharge increased steadily until peaking in the third year of the monitoring period and varied while generally decreasing during the last four years of the project. An array of observation, pollutant concentration, and hydrologic data provide considerable evidence to suggest that the implementation of BMPs in the watershed have significantly reduced phosphorus and bacteria levels in Long Creek.     

DETERMINATION OF BEST TIMING FOR POULTRY WASTE DISPOSAL: A MODELING APPROACH1

ABSTRACT: Confined production of poultry results in significant volumes of waste material which are typically disposed of by land application. Concerns over the potential environmental impacts of poultry waste disposal have resulted in ongoing efforts to develop management practices which maintain high quality of water downstream of disposal areas. The timing of application to minimize waste constituent losses is a management practice with the potential to ensure high quality of streams, rivers, and lakes downstream of receiving areas. This paper describes the development and application of a method to identify which time of year is best, from the standpoint of surface water quality, for land application of poultry waste. The procedure consists of using a mathematical simulation model to estimate average nitrogen and phosphorus losses resulting from different application timings, and then identifying the timings which minimize losses of these nutrients. The procedure was applied to three locations in Arkansas, and three different criteria for optimality of application timing were investigated. One criterion was oriented strictly to water quality, one was oriented only to crop production, and the last was a combination. The criteria resulted in different windows of time being identified as optimal. Optimal windows also varied with location of the receiving area. The results indicate that it is possible to land-apply poultry waste at times which both minimize nutrient losses and maximize crop yield.     

WATERSHED SCALING EFFECT ON BASE FLOW NITRATE,VALLEY AND RIDGE PHYSIOGRAPHIC PROVINCE1

ABSTRACT: A study of stream base flow and NO₃‐N concentration was conducted simultaneously in 51 subwatersheds within the 116‐square‐kilometer watershed of East Mahantango Creek near Klingerstown, Pennsylvania. The study was designed to test whether measurable results of processes and observations within the smaller watersheds were similar to or transferable to a larger scale. Ancillary data on land use were available for the small and large watersheds. Although the source of land‐use data was different for the small and large watersheds, comparisons showed that the differences in the two land‐use data sources were minimal. A land use‐based water‐quality model developed for the small‐scale 7.3‐square‐kilometer watershed for a previous study accurately predicted NO₃‐N concentrations from sampling in the same watershed. The water‐quality model was modified and, using the imagery‐based land use, was found to accurately predict NO₃‐N concentrations in the subwatersheds of the large‐scale 116‐square‐kilometer watershed as well. Because the model accurately predicts NO₃‐N concentrations at small and large scales, it is likely that in second‐order streams and higher, discharge of water and NO₃‐N is dominated by flow from smaller first‐order streams, and the contribution of ground‐water discharge to higher order streams is minimal at the large scale.     

SIMULATING HYDROLOGIC AND WATER QUALITY IMPACTS IN AN URBANIZING WATERSHED1

ABSTRACT: The Hydrologic Simulation Program‐Fortran (HSPF) was calibrated and used to assess the future effects of various land development scenarios on water quality in the Polecat Creek watershed in Caroline County, Virginia. Model parameters related to hydrology and water quality were calibrated and validated using observed stream flow and water quality data collected at the watershed outlet and the outlets of two sub water sheds. Using the county's Comprehensive Plan, land use scenarios were developed by taking into account the trends and spatial distributions of future development. The simulation results for the various land use scenarios indicate that runoff volume and peak rate increased as urban areas increased. Urbanization also increased sediment loads mainly due to increases in channel erosion. Constituent loads of total Kjeldal nitrogen, orthophosphorus, and total phosphorous for Polecat Creek watershed slightly decreased under future development scenarios. These reductions are due to increases in urban areas that typically contribute smaller quantities of nitrogen and phosphorous, as compared to agricultural areas. However, nitrate loads increased for the future land use scenarios, as compared to the existing land use. The increases in nitrate loads may result from increases in residential land and associated fertilizer use and concurrent decreases in forested land. The procedures used in this paper could assist local, state, and regional policy makers in developing land management strategies that minimize environmental impacts while allowing for future development.     

PATTERNS OF WATERSHED URBANIZATION AND IMPACTS ON WATER QUALITY1

ABSTRACT: Urban runoff contributes to nonpoint source pollution, but there is little understanding of the way that pattern and extent of urbanization contributes to this problem. Indicators of type and density of urbanization and access to municipal services were examined in six urban watersheds in Durham, North Carolina. Principal components analysis (PCA) was used to identify patterns in the distribution of these variables across the urban landscape. While spatial variation in urban environments is not perfectly captured by any one variable, the results suggest that most of the variation can be explained using several variables related to the extent and distribution of urban development. Multiple linear regression models were fit to relate these urbanization indicators to total phosphorus, total kjeldahl nitrogen, total suspended solids, and fecal coliforms. Development density was correlated to decreased water quality in each of the models. Indicators of urbanization type such as the house age, amount of contiguous impervious surface, and stormwater connectivity explained additional variation. In the nutrient models, access to city services was also an important factor. The results indicate that while urbanization density is important in predicting water quality, indicators of urbanization type and access to city services help explain additional variation in the models.     

LARGE AREA HYDROLOGIC MODELING AND ASSESSMENT PART I: MODEL DEVELOPMENT1

ABSTRACT: A conceptual, continuous time model called SWAT (Soil and Water Assessment Tool) was developed to assist water resource managers in assessing the impact of management on water supplies and nonpoint source pollution in watersheds and large river basins. The model is currently being utilized in several large area projects by EPA, NOAA, NRCS and others to estimate the off-site impacts of climate and management on water use, non-point source loadings, and pesticide contamination. Model development, operation, limitations, and assumptions are discussed and components of the model are described. In Part II, a GIS input/output interface is presented along with model validation on three basins within the Upper Trinity basin in Texas.     

CHALLENGES IN MODELING HYDROLOGIC AND WATER QUALITY PROCESSES IN RIPARIAN ZONES1

This paper presents key challenges in modeling water quality processes of riparian ecosystems: How can the spatial and temporal extent of water and solute mixing in the riparian zone be modeled? What level of model complexity is justified? How can processes at the riparian scale be quantified? How can the impact of riparian ecosystems be determined at the watershed scale? Flexible models need to be introduced that can simulate varying levels of hillslope‐riparian mixing dictated by topography, upland and riparian depths, and moisture conditions. Model simulations need to account for storm event peak flow conditions when upland solute loadings may either bypass or overwhelm the riparian zone. Model complexity should be dictated by the level of detail in measured data. Model algorithms need to be developed using new macro‐scale and meso‐scale experiments that capture process dynamics at the hillslope or landscape scales. Monte Carlo simulations should be an integral part of model simulations and rigorous tests that go beyond simple time series, and point‐output comparisons need to be introduced. The impact of riparian zones on watershed‐scale water quality can be assessed by performing simulations for representative hillsloperiparian scenarios.     

MODELING THE BUILDUP AND WASHOFF OF POLLUTANTS ON URBAN WATERSHEDS1

ABSTRACT: A model for urban stormwater quality was developed in this study. The basis for the model is the process by which pollutants build up on the watershed surface. For the wet climate of the study site, it was assumed that there exists an interval of time over which the pollutant buildup equals the pollutant washoff (no accumulation of pollutant). The buildup model was represented by a linear function of the antecedent dry time. The buildup function was then linked with a pollutant washoff model represented by a power function of the storm runoff volume. Various time intervals for no net accumulation were tested to calibrate the model. The model was calibrated to observed data for two small urban basins in Baton Rouge, Louisiana, and model results were used to analyze the behavior of phosphorus concentrations in storm runoff from these basins over a long period of time.     

MODELING SEDIMENT AND PHOSPHORUS LOSSES IN AN AGRICULTURAL WATERSHED TO MEET TMDLs1

ABSTRACT: This paper studies the effectiveness of alternative farm management strategies at improving water quality to meet Total Maximum Daily Loads (TMDLs) in agricultural watersheds. A spatial process model was calibrated using monthly flow, sediment, and phosphorus (P) losses (1994 to 1996) from Sand Creek watershed in south‐central Minnesota. Statistical evaluation of predicted and observed data gave r² coefficients of 0.75, 0.69, and 0.49 for flow (average 4.1 m³/s), sediment load (average 0.44 ton/ha), and phosphorus load (average 0.97 kg/ha), respectively. The calibrated model was used to evaluate the effects of conservation tillage, conversion of crop land to pasture, and changes in phosphorus fertilizer application rate on pollutant loads. TMDLs were developed for sediment and P losses based on existing water quality standards and guidelines. Observed annual sediment and P losses exceeded these TMDLs by 59 percent and 83 percent, respectively. A combination of increased conservation tillage, reduced application rates of phosphorus fertilizer, and conversion of crop land to pasture could reduce sediment and phosphorus loads by 23 percent and 20 percent of existing loads, respectively. These reductions are much less than needed to meet TMDLs, suggesting that control of sediment using buffer strips and control of point sources of phosphorus are needed for the remaining reductions.     

ORIGIN AND TRANSPORT OF DISSOLVED CHEMICALS IN A KARST WATERSHED,SOUTHWESTERN ILLINOIS1

ABSTRACT: An extensive base of water quality information emphasizing the effects of land use and hydrology was obtained in the karstified Fountain Creek watershed of southwestern Illinois to help resolve local water quality issues. Agrichemicals dominate the loads of most water quality constituents in the streams and shallow karstic ground water. Only calcium (Ca), magnesium (Mg), Aluminum (A1), and sulfate (SO₄) ions are predominantly derived from bedrock or soils, while agrichemicals contribute most of the sodium (Na), potassium (K), chlorine (Cl), nitrate (NO₃), fluorine (F), phosphorus (P), and atrazine. Concentrations of individual ions correlate with discharge variations in karst springs and surface streams; highly soluble ions supplied by diffuse ground water are diluted by high flows, while less soluble ions increase with flow as they are mobilized from fields to karst conduits under storm conditions. Treated wastewater containing detergent residues dominates the boron load of streams and provides important subordinate loads of several other constituents, including atrazine derived from the Mississippi River via the public water supply. Average surface water concentrations at the watershed outlet closely approximate a 92:8 mixture of karst ground water and treated wastewater, demonstrating the dominance of ground water contributions to streams. Therefore the karst aquifer and watershed streams form a single water quality system that is also affected by wastewater effluent.     

DROUGHT EFFECTS ON WATER QUALITY IN THE SOUTH PLATTE RIVER BASIN,COLORADO1

ABSTRACT: Twenty‐three stream sites representing a range of forested, agricultural, and urban land uses were sampled in the South Platte River Basin of Colorado from July through September 2002 to characterize water quality during drought conditions. With a few exceptions, dissolved ammonia, Kjeldahl nitrogen, total phosphorus, and dissolved orthophosphate concentrations were similar to seasonal historical levels in all land use areas during the drought. At some agricultural sites, decreased dilution of irrigation return flow may have contributed to higher concentrations of some nutrient species, increased primary productivity, and higher dissolved oxygen concentrations. At some urban sites, decreased dilution of base flow and wastewater treatment plant effluent may have contributed to higher dissolved nitrite‐plus‐nitrate concentrations, increased primary productivity, and higher dissolved oxygen concentrations. Total pesticide concentrations in urban and agricultural areas were not consistently higher or lower during the drought. At most forested sites, decreased dilution of ground water‐derived calcium bicarbonate type base flow likely led to elevated pH and specific‐conductance values. Water temperatures at many of the forested sites also were higher, contributing to lower dissolved oxygen concentrations during the drought.     

WATER QUALITY TRAP EFFICIENCY OF STORM WATER MANAGEMENT BASINS1

ABSTRACT: While the quality of rivers has received much attention, the degradation of small streams in upland areas of watersheds has only recently been recognized as a major problem. A major cause of the problem is increases in nonpoint source pollution that accompany urban expansion. A case study is used to examine the potential for storm water detention as a means of controlling water quality in streams of small watersheds. The storm water management basin, which is frequently used to control increases in discharge rates, can also be used to reduce the level of pollutants in inflow to receiving streams. Data collected on a 148-acre site in Maryland shows that a detention basin can trap as much as 98 percent of the pollutant in the inflow. For the 11 water quality parameters, most showed reductions of at least 60 percent, depending on storm characteristics.     

WALNUT CREEK WATERSHED MONITORING PROJECT,IOWA MONITORING WATER QUALITY IN RESPONSE TO PRAIRIE RESTORATION1

ABSTRACT: Land use and surface water data for nitrogen and pesticides (1995 to 1997) are reported for the Walnut Creek Watershed Monitoring Project, Jasper County Iowa. The Walnut Creek project was established in 1995 as a nonpoint source monitoring program in relation to watershed habitat restoration and agricultural management changes implemented at the Neal Smith National Wildlife Refuge by the U.S. Fish and Wildlife Service. The monitoring project utilizes a paired‐watershed approach (Walnut and Squaw creeks) as well as upstream/downstream comparisons on Walnut for analysis and tracking of trends. From 1992 to 1997, 13.4 percent of the watershed was converted from row crop to native prairie in the Walnut Creek watershed. Including another 6 percent of watershed farmed on a cash‐rent basis, land use changes have been implemented on 19.4 percent of the watershed by the USFWS. Nitrogen and pesticide applications were reduced an estimated 18 percent and 28 percent in the watershed from land use changes. Atrazine was detected most often in surface water with frequencies of detection ranging from 76–86 percent. No significant differences were noted in atrazine concentrations between Walnut and Squaw Creek. Nitrate‐N concentrations measured in both watersheds were similar; both basins showed a similar pattern of detection and an overall reduction in nitrate‐N concentrations from upstream to downstream monitoring sites. Water quality improvements are suggested by nitrate‐N and chloride ratios less than one in the Walnut Creek watershed and low nitrate‐N concentrations measured in the subbasin of Walnut Creek containing the greatest amount of land use changes. Atrazine and nitrate‐N concentrations from the lower portion of the Walnut Creek watershed (including the prairie restoration area) may be decreasing in relation to the upstream untreated component of the watershed. The frequencies of pesticide detections and mean nitrate‐N concentrations appear related to the percentage of row crop in the basins and subbasins. Although some results are encouraging, definitive water quality improvements have not been observed during the first three years of monitoring. Possible reasons include: (1) more time is needed to adequately detect changes; (2) the size of the watershed is too large to detect improvements; (3) land use changes are not located in the area of the watershed where they would have greatest effect; or (4) water quality improvements have occurred but have been missed by the project monitoring design. Longer‐term monitoring will allow better evaluation of the impact of restoration activities on water quality.     

HYDROLOGICAL MODELING OF THE IROQUOIS RIVER WATERSHED USING HSPF AND SWAT1

ABSTRACT: The performance of two popular watershed scale simulation models — HSPF and SWAT — were evaluated for simulating the hydrology of the 5,568 km² Iroquois River watershed in Illinois and Indiana. This large, tile drained agricultural watershed provides distinctly different conditions for model comparison in contrast to previous studies. Both models were calibrated for a nine‐year period (1987 through 1995) and verified using an independent 15‐year period (1972 through 1986) by comparing simulated and observed daily, monthly, and annual streamflow. The characteristics of simulated flows from both models are mostly similar to each other and to observed flows, particularly for the calibration results. SWAT predicts flows slightly better than HSPF for the verification period, with the primary advantage being better simulation of low flows. A noticeable difference in the models' hydrologic simulation relates to the estimation of potential evapotranspiration (PET). Comparatively low PET values provided as input to HSPF from the BASINS 3.0 database may be a factor in HSPF's overestimation of low flows. Another factor affecting baseflow simulation is the presence of tile drains in the watershed. HSPF parameters can be adjusted to indirectly account for the faster subsurface flow associated with tile drains, but there is no specific tile drainage component in HSPF as there is in SWAT. Continued comparative studies such as this, under a variety of hydrologic conditions and watershed scales, provide needed guidance to potential users in model selection and application.