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1.
    
ABSTRACT: A study of stream base flow and NO3‐N concentration was conducted simultaneously in 51 subwatersheds within the 116‐square‐kilometer watershed of East Mahantango Creek near Klingerstown, Pennsylvania. The study was designed to test whether measurable results of processes and observations within the smaller watersheds were similar to or transferable to a larger scale. Ancillary data on land use were available for the small and large watersheds. Although the source of land‐use data was different for the small and large watersheds, comparisons showed that the differences in the two land‐use data sources were minimal. A land use‐based water‐quality model developed for the small‐scale 7.3‐square‐kilometer watershed for a previous study accurately predicted NO3‐N concentrations from sampling in the same watershed. The water‐quality model was modified and, using the imagery‐based land use, was found to accurately predict NO3‐N concentrations in the subwatersheds of the large‐scale 116‐square‐kilometer watershed as well. Because the model accurately predicts NO3‐N concentrations at small and large scales, it is likely that in second‐order streams and higher, discharge of water and NO3‐N is dominated by flow from smaller first‐order streams, and the contribution of ground‐water discharge to higher order streams is minimal at the large scale.  相似文献   

2.
    
ABSTRACT: CREAMS was applied to a field-sized watershed planted to cotton in the Limestone Valley region of northern Alabama. The field was cultivated for three years with conventional tillage (CvT) followed by three years of conservation tillage (CsT). CREAMS is composed of three components: hydrology, erosion, and chemistry. Surface runoff and losses of sediment, N and P were simulated and results were compared with the observed data from the watershed. Curve numbers recommended in the CREAMS user's guide were not adequate for the watershed conditions. The hydrology submodel improved runoff simulation from CvT and CsT when field-data based curve numbers were used. The erosion submodel demonstrated that CsT reduced sediment loss more than CvT, even though CsT had higher runoff than CvT. The nutrient submodel based on the simulated runoff and sediment underpredicted N loss for both CvT and CsT. This submodel, however, accurately predicted P loss for CvT, but underpredicted for CsT (50 percent lower than the observed). The results of CREAMS simulation generally matched the observed order of magnitude for higher runoff, lower sediment, and higher N and P losses from CsT than from CvT.  相似文献   

3.
ABSTRACT: A model for urban stormwater quality was developed in this study. The basis for the model is the process by which pollutants build up on the watershed surface. For the wet climate of the study site, it was assumed that there exists an interval of time over which the pollutant buildup equals the pollutant washoff (no accumulation of pollutant). The buildup model was represented by a linear function of the antecedent dry time. The buildup function was then linked with a pollutant washoff model represented by a power function of the storm runoff volume. Various time intervals for no net accumulation were tested to calibrate the model. The model was calibrated to observed data for two small urban basins in Baton Rouge, Louisiana, and model results were used to analyze the behavior of phosphorus concentrations in storm runoff from these basins over a long period of time.  相似文献   

4.
    
Data from seven Management Systems Evaluation Areas (MSEA) were used to test the sensitivity of a leaching model, Pesticide Root Zone Model-2, to a variety of hydrologic settings in the Midwest. Atrazine leaching was simulated because it was prevalent in the MSEA studies and is frequently detected in the region's groundwater. Short-term simulations used site specific soil and chemical parameters. Generalized simulations used data avail. able from regional soil databases and standardized variables. Accurate short-term simulations were precluded by lack of antecedent atrazine concentrations in the soil profile and water, suggesting that simulations using data for less than five years underestimate atrazine leaching. The seven sites were ranked in order of atrazine detection frequency (concentration > 0.2 μg L-1) in soil water at 2 m depth in simulations. The rank order of the sites based on long-term simulations were similar to the ranks of sites based on atrazine detection frequency from groundwater monitoring. Simulations with Map Unit Use File (MUUF) soils data were more highly correlated with ranks of observed atrazine detection frequencies than were short-term simulations using site-specific soil data. Simulations using the MIJUIF data for soil parameters were sufficiently similarity to observed atrazine detection to allow the credible use of regional soils data for simulating leaching with PRZM-2 in a variety of Midwest soil and hydrologic conditions. This is encouraging for regional modeling efforts because soil parameters are among the most critical for operating PRZM-2 and many other leaching models.  相似文献   

5.
    
ABSTRACT: Agricultural and urban activities in the West Wellfield Interim Protection Area (WWIPA), located in West Dade County in South Florida, have the potential to impact both the environmentally sensitive Everglades and the Biscayne Aquifer. The Hydrological Simulation Program-FORTRAN (HSPF) is used to simulate surface runoff, ground water recharge, and transport of sediments, nutrients, and pesticides in the WWIPA, as a basis to quantify impacts and evaluate alternatives. Presented are four model test runs that consider current conditions, the effect of future urbanization of the agricultural land, as well as two preventive actions to minimize pollution levels. Preventive actions include application of minimum required rates of fertilizers and replacement of fertilizers by sewage sludge. Model results show that under current practices, sediments, nutrients, and pesticides are present in surface runoff and nutrients enter the ground water, and that both urbanization and preventive actions result in pollutant reductions.  相似文献   

6.
    
ABSTRACT: Although the curve number method of the Natural Resources Conservation Service has been used as the foundation of the hydrology algorithms in many nonpoint source water quality models, there are significant problematic issues with the way it has been implemented and interpreted that are not generally recognized. This usage is based on misconceptions about the meaning of the runoff value that the method computes, which is a likely fundamental cause of uncertainty in subsequent erosion and pollutant loading predictions dependent on this value. As a result, there are some major limitations on the conclusions and decisions about the effects of management practices on water quality that can be supported with current nonpoint source water quality models. They also cannot supply the detailed quantitative and spatial information needed to address emerging issues. A key prerequisite for improving model predictions is to improve the hydrologic algorithms contained within them. The use of the curve number method is still appropriate for flood hydrograph engineering applications, but more physically based algorithms that simulate all streamflow generating processes are needed for nonpoint source water quality modeling. Spatially distributed hydrologic modeling has tremendous potential in achieving this goal.  相似文献   

7.
ABSTRACT: Confined production of poultry results in significant volumes of waste material which are typically disposed of by land application. Concerns over the potential environmental impacts of poultry waste disposal have resulted in ongoing efforts to develop management practices which maintain high quality of water downstream of disposal areas. The timing of application to minimize waste constituent losses is a management practice with the potential to ensure high quality of streams, rivers, and lakes downstream of receiving areas. This paper describes the development and application of a method to identify which time of year is best, from the standpoint of surface water quality, for land application of poultry waste. The procedure consists of using a mathematical simulation model to estimate average nitrogen and phosphorus losses resulting from different application timings, and then identifying the timings which minimize losses of these nutrients. The procedure was applied to three locations in Arkansas, and three different criteria for optimality of application timing were investigated. One criterion was oriented strictly to water quality, one was oriented only to crop production, and the last was a combination. The criteria resulted in different windows of time being identified as optimal. Optimal windows also varied with location of the receiving area. The results indicate that it is possible to land-apply poultry waste at times which both minimize nutrient losses and maximize crop yield.  相似文献   

8.
    
ABSTRACT: An extensive base of water quality information emphasizing the effects of land use and hydrology was obtained in the karstified Fountain Creek watershed of southwestern Illinois to help resolve local water quality issues. Agrichemicals dominate the loads of most water quality constituents in the streams and shallow karstic ground water. Only calcium (Ca), magnesium (Mg), Aluminum (A1), and sulfate (SO4) ions are predominantly derived from bedrock or soils, while agrichemicals contribute most of the sodium (Na), potassium (K), chlorine (Cl), nitrate (NO3), fluorine (F), phosphorus (P), and atrazine. Concentrations of individual ions correlate with discharge variations in karst springs and surface streams; highly soluble ions supplied by diffuse ground water are diluted by high flows, while less soluble ions increase with flow as they are mobilized from fields to karst conduits under storm conditions. Treated wastewater containing detergent residues dominates the boron load of streams and provides important subordinate loads of several other constituents, including atrazine derived from the Mississippi River via the public water supply. Average surface water concentrations at the watershed outlet closely approximate a 92:8 mixture of karst ground water and treated wastewater, demonstrating the dominance of ground water contributions to streams. Therefore the karst aquifer and watershed streams form a single water quality system that is also affected by wastewater effluent.  相似文献   

9.
ABSTRACT: The impact on water quality by agricultural activity in karst terrain is an important consideration for resource management within the Appalachian Region. Karst areas comprise about 18 percent of the Region's land area. An estimated one-third of the Region's farms, cattle, and agricultural market value are located on karst terrain. Nitrate concentrations were measured in several karst springs in Southeastern West Virginia in order to determine the impact of animal agriculture on nitrate pollution of the karst ground water system. Karst basins with 79, 51, 16, and 0 percent agriculture had mean nitrate concentrations of 15.8, 12.2, 2.7, and 0.4 mg/l, respectively. A strong linear relationship between nitrate concentration and percent agricultural land was shown. Median nitrate concentration increased about 0.19 mg l-1 per percent increase in agricultural land. Weather patterns were also found to significantly affect the median nitrate concentrations and the temporal variability of those concentrations. Lower nitrate concentrations and lower temporal variability were observed during a severe drought period. It was concluded that agriculture was significantly affecting nitrate concentrations in the karst aquifer. Best management practices may be one way to protect the ground water resource.  相似文献   

10.
    
ABSTRACT: The impact on water quality by agricultural activity in karst terrain is an important consideration for resource management within the Appalachian Region. Karst areas comprise about 18 percent of the Region's land area. An estimated one-third of the Region's farms, cattle, and agricultural market value are on karst terrain. Nitrate concentrations were measured in cave streams draining two primary land management areas. The first area was pasture serving a beef cow-calf operation. The second area was a dairy. Nitrate-N concentrations were highest in cave streams draining the dairy and a cave stream draining an area of pasture where cattle congregate for shade and water. The dairy contributed about 60 to 70 percent of the nitrogen load increase in the study section of the cave system. It was concluded that agriculture was significantly affecting nitrate concentrations in the karst aquifer. Best management practices may be one way to protect the ground water resource.  相似文献   

11.
    
ABSTRACT: A synoptic sampling of five surface-water sites in central Nebraska was conducted by the U.S. Geological Survey as part of its National Water-Quality Assessment Program during storm runoff in May 1992 to relate transport, yields, and concentrations of atrazine to environmental setting. Atrazine was the most extensively applied pesticide in the study unit. Atrazine transport was related to the size of contributing drainage area, quantity of atrazine applied, amount of precipitation, and volume of stream-flow. Estimated yields and mean concentrations of atrazine were related to the percentage of cropland in a drainage area. The largest estimated yields and mean concentrations of atrazine in surface water were associated from drainage areas with the highest percentage of cropland, and the smallest was associated with the smallest amount of cropland. Atrazine concentrations increased as streamflow increased but decreased at or near the time of peak streamflows, perhaps due to dilution. Atrazine concentrations then increased and remained elevated far into the stream recession. Atrazine is a regulated contaminant in finished public-water supplies. Large concentrations of atrazine could affect the management of public-water supplies because atrazine remains in solution in contrast to many other pesticides that are more easily removed.  相似文献   

12.
ABSTRACT: Areas of low topographic relief have low water-table gradients and make the direction of movement of contaminants from land fills in the ground water difficult to predict from regional gradients alone. The landfill, nearby free-flowing ditches or canals, variations in hydraulic conductivity, and the influence of nearby pumping wells can all affect the direction of flow. In low-gradient areas the concepts of “upgradient” and “downgradient” are less useful in planning the location of monitoring wells than in areas of higher relief. Low-relief areas also may be affected by the discharge of mineralized water from deeper aquifers, naturally or through irrigation, which can mask geochemical surveys intended to detect landfill leachate. Examples of effects of low topographic relief are noted in southeast Florida where water-table gradients are 7×10?-4 to 5×10?-4 feet per foot. Water-table mounding beneath the landfill and the drainage effects of nearby ditches and well have created multiple leachate plumes in Stuart where one plume migrated in a direction opposite to the apparent regional gradient. In Coral Springs analysis suggests a bifurcating plume migrating along two narrow zones. In Fort Pierce it was difficult to detect leachate because of mineralized irrigation water and fertilizer runoff from an adjacent citrus grove.  相似文献   

13.
    
ABSTRACT: Twenty‐three stream sites representing a range of forested, agricultural, and urban land uses were sampled in the South Platte River Basin of Colorado from July through September 2002 to characterize water quality during drought conditions. With a few exceptions, dissolved ammonia, Kjeldahl nitrogen, total phosphorus, and dissolved orthophosphate concentrations were similar to seasonal historical levels in all land use areas during the drought. At some agricultural sites, decreased dilution of irrigation return flow may have contributed to higher concentrations of some nutrient species, increased primary productivity, and higher dissolved oxygen concentrations. At some urban sites, decreased dilution of base flow and wastewater treatment plant effluent may have contributed to higher dissolved nitrite‐plus‐nitrate concentrations, increased primary productivity, and higher dissolved oxygen concentrations. Total pesticide concentrations in urban and agricultural areas were not consistently higher or lower during the drought. At most forested sites, decreased dilution of ground water‐derived calcium bicarbonate type base flow likely led to elevated pH and specific‐conductance values. Water temperatures at many of the forested sites also were higher, contributing to lower dissolved oxygen concentrations during the drought.  相似文献   

14.
    
Abstract: Measured atrazine concentrations in Nebraska surface water have been shown to exceed water‐quality standards, posing risks to humans and to the ecosystem. To assess this risk, atrazine runoff was simulated at the field‐scale in Nebraska based on the pesticide component of the AGNPS model. This project’s objective was to determine the frequency that the atrazine concentration at the field outlet exceeded three different atrazine water‐quality criteria. The simulation was conducted for different farm management practices, soil moisture conditions, and five Nebraska topographic regions. If the criteria were exceeded, a risk to the drinking water consumer or freshwater aquatic life was hypothesized to exist. Three pesticide fate and transport processes were simulated with the model. Degradation was simulated using first‐order kinetics. Adsorption/desorption was modeled assuming a linear soil‐water partitioning coefficient. Advection (runoff) was based primarily on the USDA‐NRCS curve number method. Daily rainfall from the National Weather Service was used to compute the soil moisture conditions for the 1985‐2000 growing seasons. After each runoff event, the pesticide runoff concentration was compared with each of the three atrazine water‐quality criteria. The results show that environmental receptors (i.e., freshwater aquatic species) are exposed to unacceptable atrazine runoff concentrations in 20‐50% of the runoff events.  相似文献   

15.
    
ABSTRACT: Pesticides in stormwater runoff, within the Sacramento River Basin, California, were assessed during a storm that occurred in January 1994. Two organophosphate insecticides (diazinon and methidathion), two carbamate pesticides (molinate and carbofuran), and one triazine herbicide (simazine) were detected. Organophosphate pesticide concentrations increased with the rising stage of the hydrographs; peak concentrations were measured near peak discharge. Diazinon oxon, a toxic degradation product of diazinon, made up approximately 1 to 3 percent of the diazinon load. The Feather River was the principal source of organophosphate pesticides to the Sacramento River during this storm. The concentrations of molinate and carbofuran, pesticides applied to rice fields during May and June, were relatively constant during and after the storm. Their presence in surface water was attributed to the flooding and subsequent drainage, as a management practice to degrade rice stubble prior to the next planting. A photo-degradation product of molinate, 4-keto molinate, was in all samples where molinate was detected and made up approximately 50 percent of the total molinate load. Simazine, a herbicide used in orchards and to control weeds along the roadways, was detected in the storm runoff, but it was not possible to differentiate the two sources of that pesticide to the Sacramento River.  相似文献   

16.
    
ABSTRACT: ArcView Nonpoint Source Pollution Modeling (AVNPSM), an interface between ArcView GIS and AGNPS (Agricultural Nonpoint Source Pollution Model) is developed in support of agricultural watershed analysis and nonpoint source pollution management. The interface is PC‐based and operates in a Windows environment. It consists of seven modules: AGNPS utility, parameter generator, input file processor, model executor, output visualizer, statistical analyzer, and land use simulator. Basic input data to the interface include: soil, digital elevation model, land use/cover, water features, climate, and information on management practices. Application of the AVNPSM to a sample watershed indicates that it is user friendly, flexible, and robust, and it significantly improves the efficiency of the nonpoint source pollution modeling process.  相似文献   

17.
    
ABSTRACT: Phosphorus (P) in runoff from long term animal waste application fields can contribute to accelerated eutrophication of surface waters. Manure when applied at nitrogen (N) agronomic rates generally increases soil P concentrations, which can increase runoff of soluble P. Along the North Bosque River in central Texas, dairy waste application fields are identified as the most controllable nonpoint source of soluble P in a total maximum daily load. To evaluate P reduction practices for fields high in soil extractable P, edge‐of‐field runoff was measured from paired plots of Coastal bermudagrass (Cynodon dactylon) and sorghum (Sorghum bicolor)/ winter wheat (Triticum spp.). Plots (about 0.4 ha) received manure at P agronomic rates following Texas permit guidelines and commercial N during the pretreatment period. During the post‐treatment period, control plots continued to receive manure at P agronomic rates and commercial N. Treatment plots received only commercial N during the post‐treatment period. Use of only commercial N on soils with high extractable P levels significantly decreased P loadings in edge‐of‐field runoff by at least 40 percent, but runoff concentrations sometimes increased. No notable changes in extractable soil P concentrations were observed after five years of monitoring due to drought conditions limiting forage uptake and removal.  相似文献   

18.
    
Traditionally in the application of hydrologic/water quality (H/WQ) models, rainfall is assumed to be spatially homogeneous and is considered not to contribute to output uncertainty. The objective of this study was to assess the uncertainty induced in model outputs solely due to rainfall spatial variability. The study was conducted using the AGNPS model and the rainfall pattern captured by a network of 17 rain gauges. For each rainfall event, the model was run using the rainfall captured by each rain gauge, one at a time, under the assumption of rainfall spatial homogeneity. A large uncertainty in the modeled outputs resulted from the rainfall spatial variability. The uncertainty in the modeled outputs exceeded the input rainfall uncertainty. Results of this study indicate that spatial variability of rainfall should be captured and used in H/WQ models in order to accurately assess the release and transport of pollutants. A large uncertainty in the model outputs can be expected if this rainfall property is not taken into account.  相似文献   

19.
    
ABSTRACT: Since 1991, the U.S. Geological Survey has been conducting the National Water Quality Assessment (NAWQA) Program to determine the quality of the Nation's water resources. In an effort to obtain a better understanding of why pesticides are found in shallow ground water on a national scale, a set of factors likely to affect the fate and transport of two herbicides in the subsurface were examined. Atrazine and metolachlor were selected for this discussion because they were among the most frequently detected pesticides in ground water during the first phase of the NAWQA Program (1993 to 1995), and each was the most frequently detected compound in its chemical class (triazines and acetanilides, respectively). The factors that most strongly correlated with the frequencies of atrazine detection in shallow ground‐water networks were those that provided either: (1) an indication of the potential susceptibility of ground water to atrazine contamination, or (2) an indication of relative ground‐water age. The factors most closely related to the frequencies of metolachlor detection in ground water, however, were those that estimated or indicated the intensity of the agricultural use of metolachlor. This difference is probably the result of detailed use estimates for these compounds being available only for agricultural settings. While atrazine use is relatively extensive in nonagricultural settings, in addition to its widespread agricultural use, metolachlor is used almost exclusively for agricultural purposes. As a result, estimates of agricultural applications provide a less reliable indication of total chemical use for atrazine than for metolachlor. A multivariate analysis demonstrated that the factors of interest explained about 50 percent of the variance in atrazine and metolachlor detection frequencies among the NAWQA land‐use studies examined. The inclusion of other factors related to pesticide fate and transport in ground water, or improvements in the quality and accuracy of the data employed for the factors examined, may help explain more of the remaining variance in the frequencies of atrazine and metolachlor detection.  相似文献   

20.
    
n integrated approach coupling water quality computer simulation modeling with a geographic information system (GIS) was used to delineate critical areas of nonpoint source (NPS) pollution at the watershed level. Two simplified pollutant export models were integrated with the Virginia Geographic Information System (VirGIS) to estimate soil erosion, sediment yield, and phosphorus (P) loading from the Nomini Creek watershed located in Westmoreland County, Virginia. On the basis of selected criteria for soil erosion rate, sediment yield, and P loading, model outputs were used to identily watershed areas which exhibit three categories (low, medium, high) of non-point source pollution potentials. The percentage of the watershed area in each category, and the land area with critical pollution problems were also identified. For the 1505-ha Nomini Creek watershed, about 15, 16, and 21 percent of the watershed area were delineated as sources of critical soil erosion, sediment, and phosphorus pollution problems, respectively. In general, the study demonstrated the usefulness of integrating GIS with simulation modeling for nonpoint source pollution control and planning. Such techniques can facilitate making priorities and targeting nonpoint source pollution control programs.  相似文献   

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