Treatment of MTBE‐Contaminated Waters with Fenton's Reagent

Methyl tertiary‐butyl ether (MTBE) is commonly used as a fuel additive because of its many favorable properties that allow it to improve fuel combustion and reduce resulting concentrations of carbon monoxide and unburnt hydrocarbons. Unfortunately, increased production and use have led to its introduction into the environment. Of particular concern is its introduction into drinking water supplies. Accordingly, research studies have been initiated to investigate the treatment of MTBE‐contaminated soil and groundwater. The summer 2000 issue of Remediation reported the results of an initial study conducted by the authors to evaluate the treatment of MTBE using Fenton's reagent. In this follow‐up study, experiments were conducted to further demonstrate the effectiveness of using Fenton's reagent (H₂O₂:Fe⁺²) to treat MTBE‐contaminated groundwater. The concentration of MTBE was reduced from an initial concentration of 1,300 μg/l (14.77 μ moles) to the regulatory level of 20 μg/l (0.23 μ moles) at a H₂O₂:Fe⁺² molar ratio of 1:1, with ten minutes of contact time and an optimum pH of 5. The by‐products, acetone and tertiary butyl alcohol, which are always present in MTBE in trace amounts, were not removed even after 60 minutes of reaction time. © 2002 Wiley Periodicals, Inc. *     

A chemox treatment for urea‐ and ammonium‐contaminated groundwater

In a pilot project performed at a fertilizer manufacturing facility, a one‐step chemical oxidation technique successfully treated urea‐ and ammonium‐contaminated groundwater. The oxidation reaction occurred in an 1,100‐gallon batch reactor. The contaminated inflow was buffered by the metered addition of sodium bicarbonate solution and subsequently treated with sodium hypochlorite in an 8:1 weight ratio of Cl₂:N. In an instantaneous reaction, the urea and ammo‐nium‐N were completely oxidized to nitrogen gas that was vented to the atmosphere during mixing. The pH of the reactor discharge was ?6.5. Sodium sulfite was used to reduce residual hypochlorite in the reactor effluent to chloride to provide process water with characteristics suitable for discharge. Oxidation rates were similar with different strengths of hypochlorite; however, a 5 to 6 percent sodium hypochlorite (as Cl₂) solution was the most stable. © 2005 Wiley Periodicals, Inc.     

Pilot‐scale evaluation of in situ cometabolic bioremediation of TCE in groundwater using PHOSter® technology

A study was conducted to evaluate the efficacy of PHOSter® technology for treating groundwater contaminated with trichloroethene (TCE) at Edwards Air Force Base, California. The technology consists of injecting a gaseous mixture of air, methane, and nutrients into groundwater with the objective of stimulating the growth of methanotrophs, a naturally occurring microbial group that is capable of catalyzing the aerobic degradation of chlorinated solvents into nontoxic products. Injection operations were performed at one well for a period of three months. Six monitoring wells were utilized for groundwater and wellhead vapor monitoring and for groundwater and microbial sampling. In the five monitoring wells located within 44 feet of the injection well, the following results were observed: dissolved oxygen concentrations increased to a range between 6 and 8 milligrams per liter (μg/L); the biomass of target microbial groups increased by one to five orders of magnitude; and TCE concentrations decreased by an average of 92 percent, and to below the California primary maximum contaminant level (MCL; 5 micrograms per liter [µg/L]) in the well closest to the injection well. © 2008 Wiley Periodicals, Inc. *

1 This article is a U.S. Government work and, as such, is in the public domain of the United States of America.

     

Pilot‐scale demonstration of in situ capping of PCB‐containing sediments in the lower Grasse River

A fish‐consumption advisory is currently in effect in a seven‐mile stretch of the Grasse River in Massena, New York, due to elevated levels of PCBs in fish tissue. One remedial approach that is being evaluated to reduce the PCB levels in fish from the river is in situ capping. An in‐river pilot study was conducted in the summer of 2001 to assess the feasibility of capping PCB‐containing sediments of the river. The study consisted of the construction of a subaqueous cap in a seven‐acre portion of the river using various combinations of capping materials and placement techniques. Optimal results were achieved with a 1:1 sand/topsoil mix released from a clamshell bucket either just above or several feet below the water surface. A longer‐term monitoring program of the capped area commenced in 2002. Results of this monitoring indicated: 1) the in‐place cap has remained intact since installation; 2) no evidence of PCB migration into and through the cap; 3) groundwater advection through the cap is not an important PCB transport mechanism; and 4) macroinvertebrate colonization of the in‐place cap is continuing. Additional follow‐up monitoring in the spring of 2003 indicated that a significant portion of the cap and, in some cases, the underlying sediments had been disturbed in the period following the conclusion of the 2002 monitoring work. An analysis of river conditions in the spring of 2003 indicated that a significant ice jam had formed in the river directly over the capping pilot study area, and that the resulting increase in river velocities and turbulence in the area resulted in the movement of both cap materials and the underlying sediments. The pilot cap was not designed to address ice jam–related forces on the cap, as the occurrence of ice jams in this section of the river had not been known prior to the observations conducted in the spring of 2003. These findings will preclude implementation of the longer‐term monitoring program that had been envisioned for the pilot study. The data collected immediately after cap construction in 2001 and through the first year of monitoring in 2002 serve as the basis for the conclusions presented in this article. It should be recognized that, based on the observation made in the spring of 2003, some of these conclusions are no longer valid for the pilot study area.The occurrence of ice jams in the lower Grasse River and their importance on sediments and PCBs within the system are currently under investigation. © 2003 Wiley Periodicals, Inc.     

Performance assessment of hanging funnel‐and‐gate structures designed by reverse particle tracking for capturing polluted groundwater

The objective of this study was to evaluate the capability of partially penetrating (hanging) funnel‐and‐gate structures, designed using reverse flow trajectories, for capturing plumes of contaminated groundwater. Linear capture structures, comprised of two slurry cutoff walls on either side of a permeable gate, were positioned perpendicular to regional groundwater flow in a hypothetical unconfined aquifer. A four‐step approach was used for each of two simulated settings: (1) a numerical mass transport model generated a contaminant plume originating from a source area; (2) a particle‐tracking model projected groundwater flow paths upstream from a treatment gate; (3) the structure was widened and deepened until bounding path lines contained the plume; and (4) mass transport simulation tested the ability of the structure to capture the plume. Results of this study suggest that designing funnel‐and‐gate structures using reverse particle tracking may result in too small a structure to capture a contaminant plume. This practice generally ignores effects of hydrodynamic dispersion, which may enlarge plumes such that contaminants move beneath or around a capture structure. This bypassing effect may be considerable even for low values of dispersivity. Particle‐tracking approaches may also underestimate the amount of time required to reduce contaminant concentrations to acceptable levels. © 2007 Wiley Periodicals, Inc.     

Laboratory validation study of new vapor‐phase‐based approach for groundwater monitoring

Recent improvements in field‐portable analytical equipment allow accurate on‐site measurement of VOCs present in air at concentrations of less than 0.1 parts per million volume (ppmv). The objective of this project is to determine if the use of these instruments for vapor‐phase measurements of headspace in a monitoring well can serve as a reliable and accurate method for monitoring volatile organic compound (VOC) concentrations in groundwater under equilibrium conditions. As part of a comprehensive research project investigating the utility of this proposed monitoring method, the authors have completed a laboratory validation study to identify instruments and sample‐collection methods that will provide accurate measurement of VOC concentrations in groundwater. This laboratory validation study identified two field‐portable instruments (a gas chromatograph and a photoionization detector) with sufficient sensitivity to measure VOCs in groundwater at concentrations below typical monitoring standards (i.e., 1 to 5 μg/L). The accuracy and precision of these field instruments was sufficient to satisfy typical data‐quality objectives for laboratory‐based analysis. In addition, two sample‐collection methods were identified that yield vapor‐phase samples in equilibrium with water: direct headspace sampling and passive diffusion samplers. These sample‐collection methods allow the field instruments (which measure VOC concentrations in vapor‐phase samples) to be used to measure VOC concentrations in water. After further validation of these sample‐collection methods in the field, this monitoring method will provide a simple way to obtain accurate real‐time measurements of VOC concentrations in groundwater using inexpensive field‐portable analytical instruments. © 2009 Wiley Periodicals, Inc.     

Microbial responses to in situ chemical oxidation,six‐phase heating,and steam injection remediation technologies in groundwater

The evaluation of microbial responses to three in situ source removal remedial technologies—permanganate‐based in situ chemical oxidation (ISCO), six‐phase heating (SPH), and steam injection (SI)—was performed at Cape Canaveral Air Station in Florida. The investigation stemmed from concerns that treatment processes could have a variety of effects on the indigenous biological activity, including reduced biodegradation rates and a long‐term disruption of community structure with respect to the stimulation of TCE (trichloroethylene) degraders. The investigation focused on the quantity of phospholipid fatty acids (PLFAs) and its distribution to determine the immediate effect of each remedial technology on microbial abundance and community structure, and to establish how rapidly the microbial communities recovered. Comprehensive spatial and temporal PLFA screening data suggested that the technology applications did not significantly alter the site's microbial community structure. The ISCO was the only technology found to stimulate microbial abundance; however, the biomass returned to predemonstration values shortly after treatment ended. In general, no significant change in the microbial community composition was observed in the SPH or SI treatment areas, and even small changes returned to near initial conditions after the demonstrations. © 2004 Wiley Periodicals, Inc.     

In situ chemical oxidation of residual LNAPL and dissolved‐phase fuel hydrocarbons and chlorinated alkenes in groundwater using activated persulfate

A treatablity study (TS) was conducted to evaluate the efficacy of in situ chemical oxidation (ISCO) using activated persulfate, alone and in combination with air sparging (AS), for treating a source area contaminated with residual light nonaqueous‐phase liquid (LNAPL), dissolved‐phase fuel hydrocarbons (HCs), and dissolved‐phase chlorinated alkenes at Edwards Air Force Base (AFB), California. The TS was implemented in two phases. Phase I included injecting a solution of sodium persulfate and sodium hydroxide (NaOH) into groundwater via an existing well where residual LNAPL and dissolved‐phase contaminants were present. Because the results of Phase I indicated a limited distribution of the activated persulfate, Phase II was performed to assess whether AS could enhance the distribution of the sodium persulfate. Each phase was followed by groundwater monitoring and sampling at the injection well and at three monitoring wells, located 20 to 44 feet from the injection well. Results from Phases I and II of the TS indicated that (1) alkaline‐activated persulfate was effective in promoting the dissolution of LNAPL and the degradation of dissolved‐phase contaminants, but only at the injection well; (2) the addition of AS was effective in enhancing the radius of persulfate distribution from less than 20 feet to greater than 44 feet, and (3) persulfate alone (i.e., not in an activated state) was effective in reducing the concentrations of dissolved‐phase fuel HC and chlorinated alkenes. © 2009 Wiley Periodicals, Inc.     

Life‐cycle assessment of in situ thermal remediation

A detailed cradle‐to‐grave life‐cycle assessment (LCA) of an in situ thermal treatment remedy for a chlorinated‐solvent‐contaminated site was performed using process LCA. The major materials and activities necessary to install, operate, monitor, and deconstruct the remedy were included in the analysis. The analysis was based on an actual site remedy design and implementation to determine the potential environmental impacts, pinpoint major contributors to impacts, and identify opportunities for improvements during future implementation. The Electro‐Thermal Dynamic Stripping Process (ET‐DSP?) in situ thermal technology coupled with a dual‐phase extraction and treatment system was evaluated for the remediation of 4,400 yd³ of tetrachloroethene‐ and trichloroethene‐impacted soil, groundwater, and bedrock. The analysis was based on an actual site with an estimated source mass of 2,200 lbs of chlorinated solvents. The remedy was separated into four stages: remedy installation, remedy operation, monitoring, and remedy deconstruction. Environmental impacts were assessed using Sima Pro software, the ecoinvent database, and the ReCiPe midpoint and endpoint methods. The operation stage of the remedy dominated the environmental impacts across all categories due to the large amount of electricity required by the thermal treatment technology. Alternate sources of electricity could significantly reduce the environmental impacts of the remedy across all impact categories. Other large impacts were observed in the installation stage resulting from the large amount of diesel fuel, steel, activated carbon, and asphalt materials required to implement the technology. These impacts suggest where opportunities for footprint reductions can be found through best management practices such as increased materials reuse, increased recycled‐content materials use, and clean fuels and emission control technologies. Smaller impacts were observed in the monitoring and deconstruction stages. Normalized results show the largest environmental burdens to fossil depletion, human toxicity, particulate matter formation, and climate‐change categories resulting from activities associated with mining of fossil fuels for use in electricity production. In situ thermal treatment can reliably remediate contaminated source areas with contaminants located in low‐permeability zones, providing complete destruction of contaminants in a short amount of time, quick return of the site to productive use, and minimized quantities of hazardous materials stored in landfills for future generations to remediate. However, this remediation strategy can also result in significant emissions over a short period of time. It is difficult to quantify the overall value of short‐term cleanups with intense treatment emissions against longer‐term cleanups with lower treatment emissions because of the environmental, social, and economic trade‐offs that need to be considered and understood. LCA is a robust, quantitative tool to help inform stakeholder discussions related to the remedy selection process, trade‐off considerations, and environmental footprint‐reduction opportunities, and to complement a broader toolbox for the evaluation of sustainable remediation strategies. © 2012 Wiley Periodicals, Inc.     

In situ soil stabilization for source control of a lithium and bromate groundwater plume

Historic mineral ore processing operations at the former Cyprus Foote Mineral Site located in East Whiteland Township, Pennsylvania, have resulted in the creation of an approximately 10,000‐foot‐long off‐site groundwater plume impacted with lithium and bromate. The plume emanating from the site is impacting the groundwater quality of downgradient private residences. As an early part of the remedial implementation, the private residences were provided with public water connections while the source control efforts were being designed and implemented. Bromate and lithium have recently emerged as groundwater contaminants subjected to increased regulatory scrutiny. This is evidenced in a recently lowered Federal Maximum Contaminant Level (MCL) for bromate of 0.010 milligrams per liter and a Medium‐Specific Concentration (MSC) of 0.005 mg/L for lithium recently proposed by the Pennsylvania Department of Environmental Protection (PADEP) for all groundwater within the Commonwealth. Elevated concentrations for bromate and lithium were detected above the Proposed Remediation Goals (PRGs) for the site, MCLs, and MSCs at a distance of 7,300 feet and 9,200 feet from the source area, respectively. To reduce the contaminant concentrations within the groundwater plume, which will ultimately result in a regressing plume, and to enable the Brownfield redevelopment of this Superfund site, auger‐based, in situ soil stabilization (ISS) with depths of up to 75 feet below ground surface (bgs) was selected as the remedy. The remedial implementation required the temporary removal and relocation of over 100,000 cubic yards of overburden to expose the lithium‐bearing tailings prior to treatment. Using customized 90‐foot‐long, 9‐foot‐diameter augers attached to cranes and drilling platforms, ancillary support excavators, and approximately 21,000 tons of reagent; 2,019 ISS columns were advanced to depths ranging from 10 to 74 feet bgs. This resulted in the creation of an in situ low‐permeablity 117,045‐yd³ “quasi‐monolith,” which encompasses a lateral extent of approximately three acres. The integration of a comprehensive ISS design with a comprehensive long‐term groundwater‐monitoring plan ensured the success of the ISS implementation and will enable a continued evaluation of the off‐site groundwater quality. © 2009 Wiley Periodicals, Inc.     

Re‐evaluation of treatment approach for a site contaminated with Freon‐113 and 1,1,1‐trichloroethane

This study demonstrates a remedial approach for completing the remediation of an aquifer contaminated with 1,1,2‐trichlorotrifluoroethane (Freon‐113) and 1,1,1‐trichloroethane (TCA). In 1987, approximately 13,000 pounds of Freon‐113 were spilled from a tank at an industrial facility located in the state of New York. The groundwater remediation program consisted of an extraction system coupled with airstripping followed by natural attenuation of residual contaminants. In the first phase, five recovery wells and an airstripping tower were operational from April 1993 to August 1999. During this time period over 10,000 pounds of CFC‐13 and 200 pounds of TCA were removed from the groundwater and the contaminant concentrations decreased by several orders of magnitude. However, the efficiency of the remediation system to recover residual Freon and/or TCA reduced significantly. This was evidenced by: (1) low levels (< 10 ppb) of Freon and TCA captured in the extraction wells and (2) a slight increase of Freon and/or TCA in off‐site monitoring wells. A detailed study was conducted to evaluate the alternative for the second‐phase remediation. Results of a two‐year groundwater monitoring program indicated the contaminant plume to be stable with no significant increase or decrease in contaminant concentrations. Monitored geochemical parameters suggest that biodegradation does not influence the fate and transport of these contaminants, but other mechanisms of natural attenuation (primarily sorption and dilution) appear to control the fate and transport of these contaminants. The contaminants appear to be bound to the soil matrix (silty and clay units) with limited desorption as indicated by the solid phase analyses of contaminant concentrations. Results of fate and transport modeling indicated that contaminant concentrations would not exceed the action levels in the wells that showed a slight increase in contaminant concentrations and in the downgradient wells (sentinel) during the modeled timeframe of 30 years. This feasibility study for natural attenuation led to the termination of the extraction system and a transaction of the property, resulting in a significant financial benefit for the original site owner. © 2003 Wiley Periodicals, Inc.     

Remediating TCE‐contaminated groundwater in low‐permeability media using hydraulic fracturing to emplace zero‐valent iron/organic carbon amendment

A field pilot test in which hydraulic fracturing was used to emplace granular remediation amendment (a mixture of zero‐valent iron [ZVI] and organic carbon) into fine‐grained sandstone to remediate dissolved trichloroethene (TCE)‐contaminated groundwater was performed at a former intercontinental ballistic missile site in Colorado. Hydraulic fracturing was used to enhance the permeability of the aquifer with concurrent emplacement of amendment that facilitates TCE degradation. Geophysical monitoring and inverse modeling show that the network of amendment‐filled fractures extends throughout the aquifer volume targeted in the pilot test zone. Two years of subsequent groundwater monitoring demonstrate that amendment addition resulted in development of geochemical conditions favorable to both abiotic and biological TCE degradation, that TCE concentrations were substantially reduced (i.e., greater than 90 percent reduction in TCE mass), and that the primary degradation processes are likely abiotic. The pilot‐test data aided in re‐evaluating the conceptual site model and in designing the full‐scale remedy to address a larger portion of the TCE‐contaminated groundwater plume. © 2012 Wiley Periodicals, Inc.     

Operation of a 27‐m3 biopile for the treatment of petroleum‐contaminated soil

Soil and groundwater contamination due to petroleum hydrocarbon spills is a frequent problem worldwide. In Mexico, even when programs oriented to the diminution of these undesirable events exist, in 2000, a total of 1,518 petroleum spills were reported. Exploration zones, refineries, and oil distribution and storage stations frequently are contaminated with total petroleum hydrocarbons (TPH); diesel fraction; gasoline fraction; benzene, toluene, ethyl benzene, and xylenes (BTEX); and polycyclic aromatic hydrocarbons (PAHs). Among the many methodologies available for the treatment of this kind of contaminated soil, bioremediation is the most favorable, because it is an efficient/low‐cost option that is environmentally friendly. This article discusses the capability of using a biopile to treat soils contaminated with about 40,000 mg/kg of TPH. Design and operation of a 27‐m³ biopile is described in this work, including microbiological and respirometric aspects. Parameters such as TPH, diesel fraction, BTEX, and PAHs considered by the U.S. Environmental Protection Agency were measured in biopile samples at 0, 2, 4, 6, 8, 10, and 22 weeks. A final average TPH concentration of 7,300 mg/kg was achieved in 22 weeks, a removal efficiency of 80 percent. © 2007 Wiley Periodicals, Inc.     

Continuous water‐level monitoring in the assessment of groundwater remediation and refinement of a conceptual site model

An Erratum has been published for this article in Remediation 16(1) 2005, 155–157. Water‐level data collection is a fundamental component of groundwater investigations and remediation. While the locations and depths of monitored wells are important, the frequency of data collection may have a large impact on conclusions made about site hydrogeology. Data‐logging water‐level probes may be programmed to record water levels at frequent intervals, providing site decision makers with abundant, detailed information on the response of an aquifer to both anticipated and unforeseen stresses. In this study, a network of movable probes has provided several years of hourly water‐ level data. The understanding of the site's phytoremediation system has been enhanced by the continuous data, but subsequent insights into an unexpected situation regarding the site's infrastructure have been the most valuable result of the monitoring program. © 2005 Wiley Periodicals, Inc.     

Remediation of chlorinated ethenes,ethanes, and methanes in groundwater using carbon‐ and iron‐based electron donor

Field‐scale pilot tests were performed to evaluate enhanced reductive dechlorination (ERD) of dissolved chlorinated solvents at a former manufacturing facility located in western North Carolina (the site). Results of the site assessment indicated the presence of two separate chlorinated solvent–contaminated groundwater plumes, located in the northern and southern portions of the site. The key chlorinated solvents found at the site include 1,1,2,2‐tetrachloroethane, trichloroethene, and chloroform. A special form of EHC^® manufactured by Adventus Americas was used as an electron donor at this site. In this case, EHC is a pH‐buffering electron donor containing controlled release carbon and ZV Iron MicroSphere 200, a micronscale zero‐valent iron (ZVI) manufactured by BASF. Approximately 3,000 pounds of EHC were injected in two Geoprobe^® boreholes in the saprolite zone (southern plume), and 3,500 pounds of EHC were injected at two locations in the partially weathered rock (PWR) zone (northern plume) using hydraulic fracturing techniques. Strong reducing conditions were established immediately after the EHC injection in nearby monitoring wells likely due to the reducing effects of ZV Microsphere 200. After approximately 26 months, the key chlorinated VOCs were reduced over 98 percent in one PWR well. Similarly, the key chlorinated solvent concentrations in the saprolite monitoring wells decreased 86 to 99 percent after initial increases in concentrations of the parent chlorinated solvents. The total organic carbon and metabolic acid concentrations indicated that the electron donor lasted over 26 months after injection in the saprolite aquifer. © 2009 Wiley Periodicals, Inc.     

Cyclodextrin‐enhanced remediation of organic and metal contaminants in porous media and groundwater

Heavy metals and toxic organic contaminants are found at numerous industrial and military sites. The generally poor performance of conventional pump‐and‐treat schemes has made the development of improved methods for contaminated site remediation a significant environmental priority. One such innovative method is cyclodextrin‐enhanced flushing of the contaminated porous media and groundwater. Cyclodextrin is a glucose‐based molecule that is produced on industrial scales by microorganisms. Over the last years, several cyclodextrin derivatives have received extensive research interest. It was shown that cyclodextrins can significantly enhance the solubility of toxic organics, and in some cases, heavy metals and radioactive isotopes. As a sugar, cyclodextrin is considered relatively non‐toxic to humans, plants, and soil microbes. Thus, there are minimal health‐related concerns associated with the injection of cyclodextrin into the subsurface, which is an inherent advantage for use of cyclodextrins as a remediation agent. This paper provides a review of the available literature concerning use of cyclodextrin for remediation of groundwater and soil.     

Field‐scale evaluation of a biobarrier for the treatment of a trichloroethene plume

In the 1960s, trichloroethene (TCE) was used at what is now designated as Installation Restoration Program Site 32 Cluster at Vandenberg Air Force Base to flush missile engines prior to launch and perhaps for other degreasing activities, resulting in releases of TCE to groundwater. The TCE plume extends approximately 1 kilometer from the previous launch facilities beyond the southwestern end of the site. To limit further migration of TCE and chlorinated degradation by‐products, an in situ, permeable, reactive bioremediation barrier (biobarrier) was designed as a cost‐effective treatment technology to address the TCE plume emanating from the source area. The biobarrier treatment would involve injecting carbon‐based substrate and microbes to achieve reductive dechlorination of volatile organic compounds, such as TCE. Under reducing conditions and in the presence of certain dechlorinating microorganisms, TCE degrades to nontoxic ethene in groundwater. To support the design of the full‐scale biobarrier, a pilot test was conducted to evaluate site conditions and collect pertinent design data. The pilot test results indicated possible substrate delivery difficulties and a smaller radius of influence than had been estimated, which would be used to determine the final biobarrier well spacing. Based on these results, the full‐scale biobarrier design was modified. In January 2010, the biobarrier was implemented at the toe of the source area by adding a fermentable substrate and a dechlorinating microbial culture to the subsurface via an injection well array that spanned the width of the TCE plume. After the injections, the groundwater pH in the injection wells continued to decrease to a level that could be detrimental to the population of Dehalococcoides in the SDC‐9^TM culture. In addition, 7 months postinjection, the injection wells could not be sampled due to fouling. Cleaning was required to restore their functions. Bioassay and polymerase chain reaction analyses were conducted, as well as titration tests, to assess the need for biobarrier amendments in response to the fouling issues and low pH. Additionally, slug tests were performed on three wells to evaluate possible localized differences in hydraulic conductivity within the biobarrier. Based on the test results, the biobarrier was amended with sodium carbonate and inoculated a second time with SDC‐9^TM. The aquifer pH was restored, and reductive dechlorination resumed in the treatment zone, evidenced by the reduction in TCE and the increase in degradation products, including ethene. © 2011 Wiley Periodicals, Inc.     

Effectiveness of Capture Zones Generated by Intermittent Pumping of a PV‐Powered Pump‐and‐Treat System Without Energy Storage

A common technology to remediate and/or contain contaminated groundwater is pump‐and‐treat remediation (P&T). Traditionally, P&T systems have been designed to operate continuously to achieve steady‐state capture zones, for which large amounts of energy are required. Green and sustainable remediation (GSR) is emerging as a viable method to minimize the adverse effects of remediation on the environment. One of the challenges associated with photovoltaic‐ (PV‐) powered P&T systems is the assessment of their performance given the intermittent nature of the power availability. This article characterizes the hydraulic containment effectiveness of a PV‐powered P&T system without energy storage using data collected at two different remediation sites, a Dry‐Cleaning Environmental Response Trust Fund site in Rolla, Missouri, and the Former Nebraska Ordnance Plant near Mead, Nebraska. Additionally, a method to estimate the effectiveness of the hydraulic containment as a function of the total volume of groundwater expected to be extracted is being proposed. Two transient and a continuously pumped capture zones were modeled using Visual MODFLOW^® 2012.1 along with MODPATH and compared. The study shows that smaller capture zones will be generated from intermittent pumping when compared to continuous pumping. © 2013 Wiley Periodicals, Inc.     

In situ biofilm barriers: Case study of a nitrate groundwater plume,Albuquerque, New Mexico

A new use for biofilm barriers was developed and successfully applied to treat nitrate‐contaminated groundwater down to drinking water standards. The barrier was created by stimulating indigenous bacteria with injections of molasses as the carbon donor and a combination of yeast extract and trimetaphosphate as nutrients. This injection of amendments results in bacterial growth in the aquifer, which attaches to the sand grains to create a reactive semipermeable biofilm. The biofilm barrier presented in this article reduced the migration of contaminants and provided an active zone for remediation. The cylindrical biobarrier was constructed using eight wells on the perimeter forming a 60‐foot‐diameter reactive biodenitrification region. Another well at the center was installed to continuously extract the treated water. The intent was to produce a continuous source of nitrate‐free water. The system operated for over one year, and during this period, the biobarrier was revived multiple times by reinjecting molasses in the perimeter wells. Nitrate concentrations of treated water decreased from 275 mg/L (as nitrogen) to < 1 mg/L. © 2005 Wiley Periodicals, Inc.     

Pilot scale testing composite swellable organosilica nanoscale zero‐valent iron—Iron‐Osorb®—for in situ remediation of trichloroethylene

Iron‐Osorb^® is a solid composite material of swellable organosilica with embedded nanoscale zero‐valent iron that was formulated to extract and dechlorinate solvents in groundwater. The unique feature of the highly porous organosilica is its strong affinity for chlorinated solvents, such as trichloroethylene (TCE), while being impervious to dissolved solids. The swellable matrix is able to release ethane after dechlorination and return to the initial state. Iron‐Osorb^® was determined to be highly effective in reducing TCE concentrations in bench‐scale experiments. The material was tested in a series of three pilot scale tests for in situ remediation of TCE in conjunction with the Ohio Environmental Protection Agency at a site in central Ohio. Results of these tests indicate that TCE levels were reduced for a period of time after injection, then leveled out or bounced back, presumably due to depletion of zero‐valent iron. Use of tracer materials and soil corings indicate that Iron‐Osorb^® traveled distances of at least 20 feet from the injection point during soil augmentation. The material appears to remain in place once the injection fluid is diluted into the surrounding groundwater. Overall, the technology is promising as a remediation method to treat dilute plumes or create diffuse permeable reactive barriers. Keys to future implementation include developing injection mechanisms that optimize soil distribution of the material and making the system long‐lasting to allow for continual treatment of contaminants emanating from the soil matrix. © 2011 Wiley Periodicals, Inc.