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1.
Leachates are generated as a result of water or other liquid passing through waste at a landfill site. These contaminated liquids originate from a number of sources, including the water produced during the decomposition of the waste as well as rain-fall which penetrates the waste and dissolves the material with which it comes into contact. The penetration of the rain-water depends on the nature of the landfill (e.g. surface characteristics, type and quantity of vegetation, gradient of layers, etc). The uncontrolled infiltration of leachate into the vadose (unsaturated) zone and finally into the saturated zone (groundwater) is considered to be the most serious environmental impact of a landfill. In the present paper the water flow and the pollutant transport characteristics of the Ano Liosia Landfill site in Athens (Greece) were simulated by creating a model of groundwater flows and contaminant transport. A methodology for the model is presented. The model was then integrated into the Ecosim system which is a prototype funded by the EU, (Directorate General XIII: Telematics and Environment). This is an integrated environmental monitoring and modeling system, which supports the management of environmental planning in urban areas.  相似文献   

2.
This study investigates the heavy metal pollution vulnerability of the groundwater in the coastal aquifers of Kalpakkam region in the state of Tamilnadu, India. Integrated-approach includes pollution evaluation indices, principal component analysis (PCA), and correlation matrix (CM) to evaluate the intensity and source of pollution in groundwater. The data have been used for the calculation of heavy metal pollution index (HPI) and degree of contamination (C d). The mean metal levels in groundwater followed a descending order as: Zn?>?Ba?>?Fe?>?Al?>?Se?>?Mn?>?Cu?>?Ni?>?Pb?>?Cr?>?Mo?>?As?>?Cd?>?Sb?>?Be. The concentrations of Fe, Cd, Zn, Se, Ba, Mn, Ni, Pb, and Al in some of the groundwater samples exceed the maximum admissible concentration (MAC). The HPI and C d yield different results despite significant correlations between them. The following elemental associations were obtained from PCA and CM: Fe?CMn?CNi?CCr?CPb?CCd?CZn?CBe?CAl, Cu?CAs, Sb?CAs, Al?CBa and Se?CMo, which could be linked to anthropogenic sources (i.e., processes of tannery and dying industries with some contribution from the landfill leachate and municipal sewage). GIS-based factor score maps suggest that the activities of tannery industries and landfill leachate are pervasive processes in the area. This study has provided the evidence that effluents discharged from the tannery and auxiliary industries and landfill leachate are the main sources of heavy metal pollution in the groundwater. The high metal concentrations observed in the groundwater may have serious public health and potential environmental hazard implications.  相似文献   

3.
Floodplain forests provide unique ecological structure and function, which are often degraded or lost when watershed hydrology is modified. Restoration of damaged ecosystems requires an understanding of surface water, groundwater, and vadose (unsaturated) zone hydrology in the floodplain. Soil moisture and porewater salinity are of particular importance for seed germination and seedling survival in systems affected by saltwater intrusion but are difficult to monitor and often overlooked. This study contributes to the understanding of floodplain hydrology in one of the last bald cypress [Taxodium distichum (L.) Rich.] floodplain swamps in southeast Florida. We investigated soil moisture and porewater salinity dynamics in the floodplain of the Loxahatchee River, where reduced freshwater flow has led to saltwater intrusion and a transition to salt-tolerant, mangrove-dominated communities. Twenty-four dielectric probes measuring soil moisture and porewater salinity every 30 min were installed along two transects-one in an upstream, freshwater location and one in a downstream tidal area. Complemented by surface water, groundwater, and meteorological data, these unique 4-yr datasets quantified the spatial variability and temporal dynamics of vadose zone hydrology. Results showed that soil moisture can be closely predicted based on river stage and topographic elevation (overall Nash-Sutcliffe coefficient of efficiency = 0.83). Porewater salinity rarely exceeded tolerance thresholds (0.3125 S m(-1)) for bald cypress upstream but did so in some downstream areas. This provided an explanation for observed vegetation changes that both surface water and groundwater salinity failed to explain. The results offer a methodological and analytical framework for floodplain monitoring in locations where restoration success depends on vadose zone hydrology and provide relationships for evaluating proposed restoration and management scenarios for the Loxahatchee River.  相似文献   

4.
D epth to water, net Recharge, Aquifer media, Soil media, Topography, Impact of the vadose zone, and Conductivity of the aquifer). Using such an approach allows one to investigate the potential for groundwater contamination on a regional, rather than site-specific, scale. Based upon data from variables such as soil permeability, depth to water, aquifer hydraulic conductivity, and topography, subjective numerical weightings have been assigned according to the variable's relative importance in regional groundwater quality. The weights for each variable comprise a GIS map layer. These map layers are combined to formulate the final groundwater pollution potential map. Using this method of investigation, the pollution potential map for the study area classifies 47% of the area as having low pollution potential, 26% as having moderate pollution potential, 22% as having high pollution potential, and 5% as having very high pollution potential.  相似文献   

5.
Diffuse Nitrogen (N) loss from agriculture is a major factor contributing to increased concentrations of nitrate in surface and groundwater, and of N2O and NH3 in the atmosphere. Different approaches to assess diffuse N losses from agriculture have been proposed, among other direct measurements of N loads in leachate and groundwater, and physically-based modelling. However, both these approaches have serious drawbacks and are awkward to use at a routine base. N loss indicators (NLIs) are environmental management tools for assessing the risk of diffuse N losses from agricultural fields. They range in complexity from simple proxy variables to elaborate systems of algebraic equations. Here we present an overview of NLIs developed in different parts of the world. NLIs can be categorized into source-based, transport-based, and composite approaches. Several issues demand more attention in future studies. (1) Is incorporation of leaching losses and gaseous losses into one single NLI warranted? (2) Is it sufficient to restrict the focus on the rooted soil zone without considering the vadose zone and aquifer? (3) Calibration and validation of NLIs using field data of N loss seems not sufficient. Comparisons of several different NLIs with each other needs more attention; however, the different scaling of NLIs impedes comparability. (4) Sensitivity of input parameters with regard to the final NLI output needs more attention in future studies. (5) For environmental management purposes, factors addressing management decision by farmers deserve more attention.  相似文献   

6.
Abstract: To reduce the risk of surface and ground water pollution from nitrate, and in so doing improve the quality of receiving waters, better management options for land application of wastewater must be explored. In order to determine proper and environmentally safe wastewater land application methods, different application scenarios were simulated in this study to determine the fate and transport of nitrogen in sand‐filled field lysimeters. The Leaching Estimation and CHemistry Model for Nutrients (LEACHN) model was used to assess alternative wastewater land application scenarios: applications of low‐, medium‐, or high‐N concentration wastewaters, at different rates (0.06, 0.19, 0.31, or 0.6 m3/m2/day), under continuous or intermittent application. In the simulations, the NO3?‐N levels decreased in the leachate with an increase in wastewater application rates, due to enhanced denitrification in the upper anoxic zone of the soil generated under high flow rates. With low‐N concentrated wastewater, under all tested flow rates, the NO3?‐N levels in the leachate were below the permissible limit. When medium‐N wastewater was applied, the NO3?‐N level in leachate from the highest flow rate was below the permissible limit. Therefore, wastewater with low‐N concentrations, about 10 and 0.5 mg/l NO3?‐N and NH4+‐N, may be continuously applied to soil at all tested flow rates, with minimal nitrate pollution problems. Medium and high‐N concentrated wastewaters increased nitrate levels in the leachate, as compared to their levels in the low‐N concentrated wastewater. It appears that while low‐N wastewater can be safely applied to land without much nitrate leaching problems, the application of medium and high‐N wastewater could pose nitrate pollution problems. The simulation with intermittent application of low‐, medium‐, and high‐N concentrated wastewater at different rates showed a 51‐89% greater reduction in NO3?‐N levels in the leachate, than for continuous application under all tested wastewater N‐levels and flow rates. Also, the levels of NO3?‐N in their leachates were below the permissible limit. Therefore, wastewater with high levels of nitrogenous compounds (up to 54 NO3‐N mg/l) could be treated through an intermittent application to land.  相似文献   

7.
垃圾填埋场建设项目的主要环境问题包括:渗沥液排放、地下水环境污染、大气环境污染、噪声污染、景观变化和环境安全。根据工作经验,建立了包括建设项目基本情况、生态环境影响、社会环境影响、生态环境保护措施四大类调查监测指标为核心的环保验收调查指标体系,提出了文件资料核实、现场勘查、遥感调查、公众意见调查、环境监测和摄影法为主的建设项目竣工环保验收调查技术方法。  相似文献   

8.
The weights of evidence (WofE) modeling technique has been used to analyze both natural and anthropogenic factors influencing the occurrence of high nitrate concentrations in groundwater resources located in the central part of the Po Plain (Northern Italy). The proposed methodology applied in the Lodi District combines measurements of nitrate concentrations, carried out by means of a monitoring net of 69 wells, with spatial data representing both categorical and numerical variables. These variables describe either potential sources of nitrate and the relative ease with which it may migrate towards groundwater. They include population density, nitrogen fertilizer loading, groundwater recharge, soil protective capacity, vadose zone permeability, groundwater depth, and saturated zone permeability. Once conditional dependence problems among factors have been solved and validation tests performed, the statistical approach has highlighted negative and positive correlations between geoenvironmental factors and nitrate concentration in groundwater. These results have been achieved analysing the calculated statistical parameters (weights, contrasts, normalized contrasts) of each class by which each factor has been previously subdivided. This has permitted to outline: the overall influence each factor has on the presence/absence of nitrate; the range of their values mostly influencing this presence/absence; the most and least critical combination of factor classes existing in each specific zone; areas where the influence of impacting factor classes is reduced by the presence of not impacting factor classes. This last aspect could represent an important support for a correct land use management to preserve groundwater quality.  相似文献   

9.
Based on the reality of (a) soil heterogeneity in the vadose zone, (b) enhanced desorption from soil and solubility in water of water insoluble contaminants in the presence of surfactants, and (c) wetting/drying cycles of groundwater recharge (a major cause of fractures formation), a coherent “short-cut” conceptual approach is advanced to account for enhanced groundwater contamination. This is an attempt to close the gap between theory, lab simulations and conventional modelling-based predictions, and observed higher concentrations and more rapid arrival times of contaminants reaching groundwater. Recent data concerning chloride ion and non-ionic surfactants concentrations in aquifers and groundwater wells, combined with previous results concerning the concentrations of tritium, chlorides, metals, organic hydrocarbons and surfactants in the unsaturated and saturated zones of Israel's aquifers, are accounted for in terms of the “short-cut” approach. The contradiction between predictions of groundwater contamination made with conventional, deterministic, homogeneous models and the actual observed behavior of contaminants in soils and aquifers is thus explaind. The “short cut” approach should not be perceived as a better type of model to guide modelling. Rather, it is a proposal for a conceptual change from the realistically invalid, but commonly accepted, conventional “buffer-protective soil/long-term groundwater contamination” to the “short cut” conceptual model to explain the enhanced groundwater contamination actually observed. Although the validity of the proposed approach is strongly supported by the data here presented for the case of Israel (serving as an illustrative case study), selected results and conclusions drawn from studies conducted worldwide suggest its general applicability and usefulness. A major conclusion evolved from the “short-cut” conceptual model is that contemporary groundwater management policies, based on the current perception of groundwater contamination processes and their modelling, may result in an irreversible detrimental effect on the environmental situation in the long run. In any case, prevention, rather than correction/remediation, is strongly recommended as the strategy of choice for rational long-term management of groundwater resources.  相似文献   

10.
Municipal solid waste landfill leachate must be removed and treated to maintain landfill cover integrity and to prevent contamination of surface and ground waters. From 2003 to 2007, we studied an onsite disposal system in Ottawa County, Michigan, where leachate was spray irrigated on the vegetated landfill cover. We established six 20-m-diameter circular experimental plots on the landfill; three were spray irrigated as part of the operational system, and three remained as untreated control plots. We quantified the effects of leachate application on soil properties, soil solution chemistry, vegetative growth, and estimated solute leaching. The leachate had high mean levels of electrical conductivity (0.6-0.7 S m(-1)), Cl (760-900 mg L(-1)), and NH(4)-N (290-390 mg L(-1)) but was low in metals and volatile organic compounds. High rates of leachate application in 2003 (32 cm) increased soil electrical conductivity and NO(3)-N leaching, so a sequential rotation of spray areas was implemented to limit total leachate application to <9.6 cm yr(-1) per spray area. Concentrations of NO(3)-N and leaching losses remained higher on irrigated plots in subsequent years but were substantially reduced by spray area rotation. Leachate irrigation increased plant biomass but did not significantly affect soil metal concentrations, and plant metal concentrations remained within normal ranges. Rotating spray areas and timing irrigation to conform to seasonal capacities for evapotranspiration reduced the localized impacts of leachate application observed in 2003. Careful monitoring of undiluted leachate applications is required to avoid adverse impacts to vegetation or soils and elevated solute leaching losses.  相似文献   

11.
The German insignificance thresholds (GFS) for groundwater, derived with an added risk approach, will soon be adopted as trigger values for percolation water entering groundwater. The physicochemical properties of the vadose zone differ considerably from those of groundwater, which may lead to difficulties in the applicability of groundwater-derived GFS to percolation water. To test the applicability of the GFS to percolation water regarding the concentration level and the field-scale variability, 46 sites in Northern Germany were sampled, including arable land, grassland, and forest, situated on three spatially dominant parent materials: sand, glacial loam, and loess. Concentrations of As, Ba, Cd, Co, Cr, Cu, Mo, Ni, Pb, Sb, Sn, V, Zn, and F were analyzed in percolation water from the transition between the unsaturated to the saturated zone. We compared median and 90th percentile values of the background concentrations with the GFS. In more than 10% of all samples, background concentrations of Cd, Co, Ni, V, or Zn exceeded the GFS. We evaluated the applicability of the GFS on field-scale medians of background concentrations taking field-scale interquartile distance and the bootstrap percentile confidence interval of the field scale median of trace element background concentrations into consideration. Statements about exceedance or nonexceedance of GFS values could only be made with acceptable statistical uncertainty (α ≤ 0.1) when operational median concentrations were about one third higher or lower than the corresponding GFS.  相似文献   

12.
In this study, two pilot-scale aerobic landfill reactors with (A1) and without (A2) leachate recirculation are used to obtain detailed information on the quantity and quality of leachate in aerobic landfills. The observed parameters of leachate quality are pH, chloride (Cl), chemical oxygen demand (COD), biological oxygen demand (BOD), total Kjeldahl nitrogen (TKN), ammonia nitrogen (NH3-N), and nitrate (NO3-N). pH values of the leachate increased to 7 after 50 days in reactor A1 and after 70 days in reactor A2. Cl concentrations increased rapidly to 6100 (A1) and 6900 (A2) mg/L after 80 days, from initial values of 3000 and 2800 mg/L, respectively. COD and BOD values decreased rapidly in the A1 landfill reactor, indicating the rapid oxidation of organic matter. The BOD/COD ratio indicates that leachate recirculation slightly increases the degradation of solid waste in aerobic landfills. NH3-N concentrations decreased as a result of the nitrification process. Denitrification occurred in parts of the reactors as a result of intermittent aeration; this process causes a decrease in NO3 concentrations. There is a marked difference between the A1 and A2 reactors in terms of leachate quantity. Recirculated leachate made up 53.3% of the leachate generated from the A1 reactor during the experiment, while leachate quantity decreased by 47.3% with recirculation when compared with the aerobic dry landfill reactor.  相似文献   

13.
ABSTRACT: Areas of low topographic relief have low water-table gradients and make the direction of movement of contaminants from land fills in the ground water difficult to predict from regional gradients alone. The landfill, nearby free-flowing ditches or canals, variations in hydraulic conductivity, and the influence of nearby pumping wells can all affect the direction of flow. In low-gradient areas the concepts of “upgradient” and “downgradient” are less useful in planning the location of monitoring wells than in areas of higher relief. Low-relief areas also may be affected by the discharge of mineralized water from deeper aquifers, naturally or through irrigation, which can mask geochemical surveys intended to detect landfill leachate. Examples of effects of low topographic relief are noted in southeast Florida where water-table gradients are 7×10?-4 to 5×10?-4 feet per foot. Water-table mounding beneath the landfill and the drainage effects of nearby ditches and well have created multiple leachate plumes in Stuart where one plume migrated in a direction opposite to the apparent regional gradient. In Coral Springs analysis suggests a bifurcating plume migrating along two narrow zones. In Fort Pierce it was difficult to detect leachate because of mineralized irrigation water and fertilizer runoff from an adjacent citrus grove.  相似文献   

14.
The 1991 EU Nitrate Directive was designed to reduce water pollution from agriculturally derived nitrates. England and Wales implemented this Directive by controlling agricultural activities within their most vulnerable areas termed Nitrate Vulnerable Zones. These were designated by identifying drinking water catchments (surface and groundwater), at risk from nitrate pollution. However, this method contravened the Nitrate Directive because it only protected drinking water and not all waters. In this paper, a GIS was used to identify all areas of groundwater vulnerable to nitrate pollution. This was achieved by constructing a model containing data on four characteristics: the quality of the water leaving the root zone of a piece of land; soil information; presence of low permeability superficial (drift) material; and aquifer properties. These were combined in a GIS and the various combinations converted into a measure of vulnerability using expert knowledge. Several model variants were produced using different estimates of the quality of the water leaving the root zone and contrasting methods of weighting the input data. When the final models were assessed all produced similar spatial patterns and, when verified by comparison with trend data derived from monitored nitrate concentrations, all the models were statistically significant predictors of groundwater nitrate concentrations. The best predictive model contained a model of nitrate leaching but no land use information, implying that changes in land use will not affect designations based upon this model. The relationship between nitrate levels and borehole intake depths was investigated since there was concern that the observed contrasts in nitrate levels between vulnerability categories might be reflecting differences in borehole intake depths and not actual vulnerability. However, this was not found to be statistically important. Our preferred model provides the basis for developing a new set of groundwater Nitrate Vulnerable Zones that should help England and Wales to comply with the EU Nitrate Directive.  相似文献   

15.
氧化法预处理垃圾渗滤液技术研究及应用   总被引:3,自引:0,他引:3  
叶胜辉 《环境技术》2005,24(3):33-34
由于垃圾渗滤液含有多种有毒有害的难降解的有机物,影响了生物处理效果。采用Fenton氧化法、湿式催化氧化法和电解氧化法预处理,可减少渗滤液的污染负荷,提高可生化性,在实际应用中取得良好的效果。  相似文献   

16.
The flux of dissolved organic carbon (DOC) in soil facilitates transport of nutrients and contaminants in soil. There is little information on DOC fluxes and the relationship between DOC concentration and water flux in agricultural soils. The DOC fluxes and concentrations were measured during 2.5 yr using 30 automatic equilibrium tension plate lysimeters (AETPLs) at 0.4 m and 30 AETPLs at 1.20-m depth in a bare luvisol, previously used as an arable soil. Average annual DOC fluxes of the 30 AETPLS were 4.9 g C m(-2) y(-1) at 0.4 m and 2.4 g C m(-2) y(-1) at 1.2 m depth. The average leachate DOC concentrations were 17 mg C L(-1) (0.4 m) and 9 mg C L(-1) (1.2 m). The DOC concentrations were unrelated to soil moisture content or average temperature and rarely dropped below 9 mg C L(-1) (0.4 m) and 5 mg C L(-1) (1.2 m). The variability in cumulative DOC fluxes among the plates was positively related to leachate volume and not to average DOC concentrations at both depths. This suggests that water fluxes are the main determinants of spatial variability in DOC fluxes. However, the largest DOC concentrations were inversely proportional to the mean water velocity between succeeding sampling periods, suggesting that the maximal net DOC mobilization rate in the topsoil is limited. Elevated DOC concentrations, up to 90 mg C L(-1), were only observed at low water velocities, reducing the risks of DOC-facilitated transport of contaminants to groundwater. The study emphasizes that water flux and velocity are important parameters for DOC fluxes and concentrations.  相似文献   

17.
渗滤液回灌在实际应用中应注意的问题   总被引:3,自引:0,他引:3  
李青松  金春姬  乔志香  向勇 《四川环境》2004,23(4):78-80,84
本文介绍了垃圾填埋场渗滤液回灌的机理、优缺点,“干填埋”与“湿填埋”之间的区别。渗滤液回灌可增加填埋废物的含水率,加快垃圾的降解速率,减少渗滤液的处理时间,提高填埋气中甲烷的含量,加速填埋场稳定化进程。鉴于以上这些优点,渗滤液回灌作为一种渗滤液处理方式将会有极大的应用前景。但在实际应用中回灌的渗滤液容易泄漏而导致地下水污染,这是影响渗滤液回灌广泛应用的主要原因。为了避免使地下水受污染,本文总结和分析了渗滤液回灌在实际应用中应注意的问题。  相似文献   

18.
In 1988, the Florida Institute of Phosphate Research (FIPR) funded project to develop an advanced hydrologic model for shallow water table systems. The FIPR hydrologic model (FHM) was developed to provide an improved predictive capability of the interactions of surface water and ground water using its component models, HSPF and MODFLOW. The Integrated Surface and Ground Water (ISGW) model was developed from an early version of FHM and the two models were developed relatively independently in the late 1990s. Hydrologic processes including precipitation, interception, evapotranspiration, runoff, recharge, streamflow, and base flow are explicitly accounted for in both models. Considerable review of FHM and ISGW and their applications occurred through a series of projects. One model evolved, known as the Integrated Hydrological Model IHM. This model more appropriately describes hydrologic processes, including evapotranspiration fluxes within small distributed land‐based discretization. There is a significant departure of many IHM algorithms from FHM and ISGW, especially for soil water and evapotranspiration (ET). In this paper, the ET concepts in FHM, ISGW, and IHM will be presented. The paper also identifies the advantages and data costs of the improved methods. In FHM and IHM, ground water ET algorithms of the MODFLOW ET package replace those of HSPF (ISGW used a different model for ground water ET). However, IHM builds on an improved understanding and characterization of ET partitioning between surface storages, vadose zone storage, and saturated ground water storage. The IHM considers evaporative flux from surface sources, proximity of the water table to land surface, relative moisture condition of the unsaturated zone, thickness of the capillary zone, thickness of the root zone, and relative plant cover density. The improvements provide a smooth transition to satisfy ET demand between the vadose zone and deeper saturated ground water. While the IHM approach provides a more sound representation of the actual soil profile than FHM, and has shown promise at reproducing soil moisture and water table fluctuations as well as field measured ET rates, more rigorous testing is necessary to understand the robustness and/or limitations of this methodology.  相似文献   

19.
ABSTRACT: Surface water, groundwater, and groundwater discharge quality surveys were conducted in Cherrystone Inlet, on Virginia's Eastern Shore. Shallow groundwater below agricultural fields had nitrate concentrations significantly higher than inlet surface waters and shallow groundwater underlying forested land. This elevated nitrate groundwater discharged to adjacent surface waters. Nearshore discharge rates of water across the sediment-water interface ranged from 0.02 to 3.69 liters·m?2·hr?1 during the surveys. The discharge was greatest nearshore at low tide periods, and decreased markedly with increasing distance offshore. Vertical hydraulic heads, Eh, and inorganic nitrogen flux in the sediments followed similar patterns. Nitrate was the predominant nitrogen species discharged nearshore adjacent to agricultural land use, changing to ammonium farther offshore. Sediment nitrogen fluxes were sufficient to cause observable impacts on surface water quality; nitrate concentrations were up to 20 times greater in areas of groundwater discharge than in the main stem inlet water. Based on DIN:DIP ratios, nitrogen contributions from direct groundwater discharge and tidal creek inputs appear to be of significant ecological importance. This groundwater discharge links land use activity and the quality of surface water, and therefore must be considered in selection of best management practices and water quality management strategies.  相似文献   

20.
Soil and plant characteristics of landfill sites near Merseyside,England   总被引:2,自引:0,他引:2  
An ecological survey of the plant and soil characteristics was carried out on three landfill sites near Merseyside, England. It was discovered that bare ground at two of the landfill areas had high levels of methane contained in the soil air (Sefton Meadows landfill: 6–8% at 35 cm and 16–35% at 65 cm below soil surface; Coalgate Lane landfill: 1–24% at 35 cm and 39–45% at 40 cm below soils surface), causing the appearance of dark grey reduced regions in the soil, a phenomenon similar to flooded soil. The wellvegetated areas at the two sites had lower levels of methane (under 7%).In areas relatively free of methane, the concentrations of mineralized N and NO3 had significant correlations with the dry weights of vegetation (r = 0.71 withp<0.01;r=0.61 withp<0.02 accordingly), indicating the necessity of applying available nitrogen fertilizer.  相似文献   

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