Evaluation of seasonal scale first flush pollutant loading and implications for urban runoff management

This study investigated how the occurrence and magnitude of first flush events in stormwater may influence the effective management of urban runoff pollution. To facilitate the understanding of the first flush phenomenon on a seasonal scale, the City of San Jose, CA carried out an investigation between May 1997 and April 2000 to characterize concentrations of pollutants in local waterbodies during eight storm events. The purpose of the investigation was twofold: (1) To determine if concentrations of specific constituents in stormwater runoff are elevated during the first substantial storm of the wet season, and (2) To identify the physical and environmental conditions surrounding such events. Concentration data for total and dissolved metals, pesticides, polyaromatic hydrocarbons, anions, total suspended solids, total organic carbon, conductivity, gasoline and diesel, and volatile and semi-volatile organics were collected at over 25 sites. Monitoring data analysis focused on identifying physical and environmental conditions yielding increased levels of pollutants during the first substantial storms of the rainy season compared to other storm events. Quantitative analysis focused on metals and anions because most observations for other constituents were below detectable levels. The results suggest that first flush phenomena did not occur consistently throughout most of the stations investigated. The results further suggest that there are specific combinations of site and storm conditions that result in a first flush effect with respect to dissolved metals. Based on the results of this and related investigations, implications for urban runoff management are discussed. For example, if dissolved metals are of principal concern, it may be worthwhile to optimize existing control strategies to minimize pollutant loading from storms that are preceded by an extended dry period.     

Variation of Nitrogen Concentrations in Stormpipe Discharge in a Residential Watershed1

Abstract: Use of lawn chemicals in residential areas may contribute nonpoint source (NPS) pollutants, such as nutrients, pesticides, and herbicides to streams. We conducted a 2‐year screening study of discharge in stormwater pipes in the Wissahickon Valley Watershed (suburban Philadelphia) using nitrogen as an indicator of lawn chemical use. Stormwater samples representing first flush and composite runoff were collected approximately twice a month using automatic samplers triggered by rise in water level during storms. The runoff collected by the stormpipes was from neighborhoods with 15‐100 residences, and from 2 to 18 ha (5‐45 acres). Several factors were examined to evaluate the effects on nitrate concentration. These factors included time of sampling (season), number of homes, total area, size of the storm, and time since last storm. Nitrate levels were generally less than 5 mg/l, but still above background in typical undeveloped areas. Concentrations were slightly higher in the first summer than during a drought in the second year, but the difference was not statistically significant. There was a positive correlation between size of the neighborhood (capture area) and peak concentration of nitrate. Storm characteristics (size of storm and time since last storm) did not correlate with nitrate concentrations. The variation in both space and time suggests that a more local control may be a factor. Although individual lawn chemical applications were not monitored, they may influence the timing of increased loading. Furthermore, the variability indicates that quarterly monitoring will not capture discharge characteristics of storm basins.     

Management of Urban Road Runoff Containing PAHs: Probabilistic Modeling and Its Application in Beijing,China1

Abstract: Pollutant loading from storm runoff is considered to be an important component of nonpoint source pollution in urban areas. In developing countries, because of the accelerated urbanization and motorization, storm runoff pollution has become a challenge for improving aquatic environmental quality. An effective storm runoff management plan needs to be developed, and questions concerning how much and which proportion of a storm should be treated need to be answered. In this study, a model is developed to determine the fraction of storm runoff that needs to be treated to meet the discharge standard within a given probability. The model considers that the pollutants can be mobilized during the early stage of a storm. The model is applied to a field study of polycyclic aromatic hydrocarbons (PAHs) in road runoff in Beijing, China. In this case, the probability that the PAH load will be mobilized with suspended sediments by the earlier portion of the flush is 73%. Given the high PAH loading in the study area and the referenced discharge standard, the probability that the entire runoff should be captured and treated is 94%. Thus, urban planners need to consider treatment systems for the majority of the storms in this area, whether the PAH load is in the first flush or not. This methodology can be applied to other regions where PAH loads may result in different management outcomes.     

Temporal variability in physical speciation of metals during a winter rain-on-snow event

Particulate matter in urban rivers transports a significant fraction of pollutants, changes rapidly during storm events, and is difficult to characterize. In this study, the physical speciation of trace metals and organic C in an urban river and upstream headwaters site in Torrington, CT, were measured during a winter rain-on-snow event. In addition, a selective fractionation scheme, using membrane and tangential-flow ultrafiltration methods to separate suspended particulate matter into sand, silt, clay, and colloid fractions, was evaluated based on the appropriateness of the chosen size categories. During peak runoff at the urban river site, total-recoverable concentrations of the metals Cu and Pb increased 6- and 13-fold to 16.9 and 9.5 microg L(-1), respectively, compared with baseflow concentrations. Concentrations of Cu and Pb reached only 0.9 and 0.86 microg L(-1) at the headwaters site. For the measured storm event, the majority of metals were transported by the urban river in association with coarse silt (20-80 microm particle diam.) during peak runoff. During peak runoff at the urban site, organic C associated with the large colloid fraction (0.1-1.0 microm) increased from 5% (at baseflow) to 54% of the total C in transport, whereas dissolved organic C and that associated with smaller colloids decreased from 91.5% (at baseflow) to 41% of the total. Other elements that were monitored as part of the study were Na, K, Ca, Mg, Fe, Mn, Al, Cd, Cl-, NO3(-), and SO4(2-). The chosen fractionation scheme was useful to characterize pollutant transport during this event, but further testing should be undertaken to determine the most appropriate size range categories, and to ensure that the sizes measured are comparable to those used in other studies.     

RUNOFF POLLUTION FROM MULTIPLE FAMILY HOUSING1

ABSTRACT: Increasingly, residential development in urbanizing areas is accomplished by large housing projects, composed of clusters of townhouses or garden partments. It is hypothesized that the runoff from such developments should carry more pollution than that from the same number of housing units on separate plots, because the runoff is conveyed directly to drainage channels rather than being drained across lawns and gardens, which may absorb part of the pollutants. In order to evaluate this effect, storm event data were obtained from a planned unit development near Hightstown, N. J., using samples taken every 10 minutes throughout the storm at two different storm sewers. Results show heavy metals pollution about what had been anticipated, in accordance with the hypothesis given above, and BOD ammonia and phosphates higher than predicted. The results are significant for areawide water quality planning in metropolitan areas, where projections of future pollution loadings depends upon the land use.     

DESIGN OF A DIVERSION SYSTEM TO MANAGE THE FIRST FLUSH1

ABSTRACT: To manage the first flush of storm runoff in urbanized areas, a diversion box and detention basin system has been proposed for a new storm sewer system or for retrofitting an existing system. A software package for a personal computer has been developed to facilitate the analysis and design of the system. Hydrographs and pollutographs are generated at the inlet and outlet of the diversion box and the detention basin. The peak outflow and peak pollutant concentrations are compared with the allowable outflow and pollutant concentration for urban stormwater quantity and quality management. The model is developed for both analysis and design purposes.     

Wastewater Effluent,Combined Sewer Overflows,and Other Sources of Organic Compounds to Lake Champlain1

Abstract: Some sources of organic wastewater compounds (OWCs) to streams, lakes, and estuaries, including wastewater‐treatment‐plant effluent, have been well documented, but other sources, particularly wet‐weather discharges from combined‐sewer‐overflow (CSO) and urban runoff, may also be major sources of OWCs. Samples of wastewater‐treatment‐plant (WWTP) effluent, CSO effluent, urban streams, large rivers, a reference (undeveloped) stream, and Lake Champlain were collected from March to August 2006. The highest concentrations of many OWCs associated with wastewater were in WWTP‐effluent samples, but high concentrations of some OWCs in samples of CSO effluent and storm runoff from urban streams subject to leaky sewer pipes or CSOs were also detected. Total concentrations and numbers of compounds detected differed substantially among sampling sites. The highest total OWC concentrations (10‐100 μg/l) were in samples of WWTP and CSO effluent. Total OWC concentrations in samples from urban streams ranged from 0.1 to 10 μg/l, and urban stream‐stormflow samples had higher concentrations than baseflow samples because of contributions of OWCs from CSOs and leaking sewer pipes. The relations between OWC concentrations in WWTP‐effluent and those in CSO effluent and urban streams varied with the degree to which the compound is removed through normal wastewater treatment. Concentrations of compounds that are highly removed during normal wastewater treatment [including caffeine, Tris(2‐butoxyethyl)phosphate, and cholesterol] were generally similar to or higher in CSO effluent than in WWTP effluent (and ranged from around 1 to over 10 μg/l) because CSO effluent is untreated, and were higher in urban‐stream stormflow samples than in baseflow samples as a result of CSO discharge and leakage from near‐surface sources during storms. Concentrations of compounds that are poorly removed during treatment, by contrast, are higher in WWTP effluent than in CSO, due to dilution. Results indicate that CSO effluent and urban stormwaters can be a significant major source of OWCs entering large water bodies such as Burlington Bay.     

Improving the accuracy of sediment-associated constituent concentrations in whole storm water samples by wet-sieving

Sand-sized particles (>63 microm) in whole storm water samples collected from urban runoff have the potential to produce data with substantial bias and/or poor precision both during sample splitting and laboratory analysis. New techniques were evaluated in an effort to overcome some of the limitations associated with sample splitting and analyzing whole storm water samples containing sand-sized particles. Wet-sieving separates sand-sized particles from a whole storm water sample. Once separated, both the sieved solids and the remaining aqueous (water suspension of particles less than 63 microm) samples were analyzed for total recoverable metals using a modification of USEPA Method 200.7. The modified version digests the entire sample, rather than an aliquot, of the sample. Using a total recoverable acid digestion on the entire contents of the sieved solid and aqueous samples improved the accuracy of the derived sediment-associated constituent concentrations. Concentration values of sieved solid and aqueous samples can later be summed to determine an event mean concentration.     

WATER QUALITY BENEATH URBAN RUNOFF WATER MANAGEMENT BASINS1

ABSTRACT: The chemical impact of urban runoff water on water quality beneath five retention/recharge basins was investigated as part of the US EPA's Nationwide Urban Runoff Program in Fresno, California. Soil water percolating through alluvium soils and the ground water at the top of the water table were sampled with ceramic/Teflon vacuum water extractors at depths up to 26 m during the two-year investigation. Inorganic and organic pollutants are present in the runoff water delivered to the basins. No significant contamination of percolating soil water or ground water underlying any of the five retention/recharge basins has occurred for constituents monitored in the study. The oldest basins was constructed in 1962. The concentration of selected trace elements in the ground water samples was similar to the levels reported in the regional ground water. None of the pesticides or other organic priority pollutants, for which water samples were analyzed, was s̊ detected except diazinon which was found in trace amounts (0.3 μg/L or less) in only three soil water samples. These results are important to the continued conservation of storm water and the development of a best management practice for storm-water management using retention/recharge basins in a semi-arid climate.     

Farmyards, an overlooked source for highly contaminated runoff

Summer sampling of storm runoff generated from areas of roofs and hardstanding situated on four dairy/beef farms has provided novel information regarding its microbiological and chemical quality. All farm hardstandings generated runoff that was contaminated with respect to those pollutants (faecal coliforms, FC, and faecal streptococci, FS, major nutrients, organic carbon) that are ubiquitously associated with faecal matter and urine. The separate analysis of roof runoff indicated that these can contribute significant concentrations of FS, phosphorus (P) and potentially toxic elements such as zinc (Zn), and suggests a level of 'background' contamination originating from wash-off of bird droppings and in the case of Zn galvanised surfaces. On average hardstanding runoff showed enhanced concentrations of >4 orders of magnitude for FC and 2-3 for major nutrients and carbon relative to roof runoff. Organic forms of nitrogen (N) and P contributed significantly (averaging >40%) to the total dissolved fraction in both roof and hardstanding runoff. Part of the substantial variability in composition of runoff samples could be attributed to differences between farms as well as the timing of sample collection during individual storms. Where situations allowed, a comparison of water upstream and downstream of the farmyard demonstrated they acted as a source of multiple contaminants not only during hydrologically active storm events but also during dry periods. Contamination pathways included a combination of both point (e.g., septic overflows) and non-point (e.g., seepage from livestock housing) sources. Farmyards situated within intensive livestock farming areas such as SW Scotland, would be expected to have significant local and accumulated downstream impacts on the aquatic environment. Localised impacts would be particularly important for headwaters and low order streams.     

A COMPARISON OF RUNOFF QUALITY EFFECTS OF ORGANIC AND INORGANIC FERTILIZERS APPLIED TO FESCUEGRASS PLOTS1

ABSTRACT: Application of fertilizer can degrade quality of runoff, particularly during the first post-application, runoff-producing storm. This experiment assessed and compared runoff quality impacts of organic and inorganic fertilizer application for a single simulated storm occurring seven days following application. The organic fertilizers used were poultry (Gallus gallus domesticus) litter, poultry manure, and swine (Sus scrofa domesticus) manure. All fertilizers were applied at an application rate of 217.6 kg N/ha. Simulated rainfall was applied at 50 mm/h for an average duration of 0.8 h. Runoff samples were collected, composited, and analyzed for nitrate N (NO₃-N), ammonia N (NH₃-N), total Kjeldahl N (TKN), ortho-P (PO₄-P), total P (TP), chemical oxygen demand (COD), total suspended solids (TSS), fecal coliforms (FC), and fecal streptococci (FS). Application of the fertilizers did not alter the hydrologic characteristics of the receiving plots relative to the control plots. Concentrations of fertilizer constituents were almost always greater from treated than from control plots and were usually much greater. Flow-weighted mean concentrations of NH₃-N, PO₄-P, and TP were highest for the inorganic fertilizer treatment (42.0, 26.6, and 27.9 mg/L, respectively). Runoff COD and TSS concentrations were greatest for the poultry litter treatment. Concentrations of FC and FS were greater for fertilized than for control plots with no differences among fertilized plots, but FC concentrations for all treatments were in excess of Arkansas' primary and secondary contact standards. Mass losses of fertilizer constituents were low (≤ 3 kg/ha) and were small proportions (≤ 3 percent) of amounts applied.     

WATER QUALITY CHARACTERISTICS OF STORM WATER FROM MAJOR LAND USES IN SOUTH FLORIDA1

ABSTRACT: Starting in 1998, a study was conducted to characterize storm water quality from predominant land use types in a coastal watershed along the south central coast of Florida, namely citrus, pasture, urban, natural wetland, row crop, dairy, and golf courses. Sixty‐three sampling sites were located at strategic points on drainage conveyances for each of seven specific land use areas. Runoff samples were collected following storm events that met defined rainfall criteria for a period of 30 months. Nitrogen (N), phosphorus (P), heavy metals, pesticides, and other water quality parameters were determined, and the results were analyzed to compare and characterize land uses as relative sources for these constituents in runoff. Results showed that runoff from most land use types had low dissolved oxygen concentration and that sediment and nutrient concentrations were closely related to land use, particularly to the amount of fertilizer applied in each land use. Among the eight heavy metals tested, copper was the most frequently detected and was mostly associated with runoff from citrus and golf course land uses. High levels of arsenic were also detected in golf course runoff. The most frequently detected pesticide was simazine from citrus. The information and methodologies presented may facilitate pollution source characterization and ecological restoration efforts.     

USING INFILTRATION ENHANCEMENT AND SOIL WATER MANAGEMENT TO REDUCE DIAZINON IN RUNOFF1

ABSTRACT: Pesticide runoff from dormant sprayed orchards is a major water quality problem in California's Central Valley. During the past several years, diazinon levels in the Sacramento and San Joaquin Rivers have exceeded water quality criteria for aquatic organisms. Orchard water management, via post‐application irrigation, and infiltration enhancement, through the use of a vegetative ground cover, are management practices that are believed to reduce pesticide loading to surface waters. Field experiments were conducted in Davis, California, to measure the effectiveness of these management practices in reducing the toxicity of storm water runoff. Treatments using a vegetative ground cover significantly reduced peak concentrations and cumulative pesticide mass in runoff for first flush experiments compared with bare soil treatments. Post‐application irrigation was found to be an effective means of reducing peak concentrations and cumulative mass in runoff from bare soil treatments, but showed no significant effect on vegetated treatments.     

PRELIMINARY OBSERVATIONS ON WATER QUALITY OF STORM RUNOFF FROM FOUR SELECTED RESIDENTIAL ROOFS1

ABSTRACT: Storm runoff from four characteristic types of residential roofs and incident rainwater were monitored for 47 storm events over a six-month period at Nacogdoches, Texas, to study water quality conditions for 20 element and four chemical variables. The total element concentration in storm runoff from each roof type was greater than that of rainwater in the open. Differences in element concentrations in storm runoff among the four roof types were statistically significant (α≤ 0.05) with the differences for the wood shingle roof being the greatest and that for terra cotta clay roof being the least. The median concentrations of four element variables exceeded the Texas surface water quality standards, while 12 variables exceeded the standards at least one time in all samples collected. Zinc concentrations violated the Standard ranging from 85.7 percent of the samples for the wood shingle roof to 66.0 percent for the composite shingle, the greatest exceedances of all 24 variables studied. Storm characteristics and gutter maintenance level had some effects on these water quality conditions. The study suggested that roof types can be important to water pollution management programs. More detailed studies on roof water quality in major municipalities are required.     

Dry Weather Water Quality Loadings in Arid,Urban Watersheds of the Los Angeles Basin,California, USA1

Abstract: Dry weather runoff in arid, urban watersheds may consist entirely of treated wastewater effluent and/or urban nonpoint source runoff, which can be a source of bacteria, nutrients, and metals to receiving waters. Most studies of urban runoff focus on stormwater, and few have evaluated the relative contribution and sources of dry weather pollutant loading for a range of constituents across multiple watersheds. This study assessed dry weather loading of nutrients, metals, and bacteria in six urban watersheds in the Los Angeles region of southern California to estimate relative sources of each constituent class and the proportion of total annual load that can be attributed to dry weather discharge. In each watershed, flow and water quality were sampled from storm drain and treated wastewater inputs, as well as from in‐stream locations during at least two time periods. Data were used to calculate mean concentrations and loads for various sources. Dry weather loads were compared with modeled wet weather loads under a range of annual rainfall volumes to estimate the relative contribution of dry weather load. Mean storm drain flows were comparable between all watersheds, and in all cases, approximately 20% of the flowing storm drains accounted for 80% of the daily volume. Wastewater reclamation plants (WRP) were the main source of nutrients, storm drains accounted for almost all the bacteria, and metals sources varied by constituent. In‐stream concentrations reflected major sources, for example nutrient concentrations were highest downstream of WRP discharges, while in‐stream metals concentrations were highest downstream of the storm drains with high metals loads. Comparison of wet vs. dry weather loading indicates that dry weather loading can be a significant source of metals, ranging from less than 20% during wet years to greater than 50% during dry years.     

Seasonal Flushing of Pollutant Concentrations and Loads in Urban Stormwater1

Schiff, Kenneth C. and Liesl L. Tiefenthaler, 2011. Seasonal Flushing of Pollutant Concentrations and Loads in Urban Stormwater. Journal of the American Water Resources Association (JAWRA) 47(1):136‐142. DOI: 10.1111/j.1752‐1688.2010.00497.x Abstract: Despite broad observations of first flush within storms, the scientific understanding of seasonal flushing remains incomplete. Seasonal flushing occurs when initial storms of the season have greater concentrations or loads than storms later in the season. The goal of this study was to census stormwater concentrations and loads from an arid, urban watershed to quantify seasonal flushing. Samples were collected every 15 min during the 1997‐1998 wet season from the Santa Ana River and analyzed for total suspended solids. Initial storms of the season generated event mean concentrations 3‐10 times the event mean concentration of storms later in the season. Cumulative flow‐weighted mean concentrations were calculated as the season progressed. Early season storms discharged only 6% of the annual volume, but influenced flow‐weighted mean concentrations well past the midpoint of the wet season. Mass‐based estimates also indicated a disproportionate load in the early portion of the year; over 52% of the annual load was discharged in the first 30% of the annual volume from the highly urbanized lower watershed. Other stormwater pollutants, including six trace metals (Cd, Cr, Cu, Pb, Ni, Zn), were highly correlated with total suspended solids and also exhibited a significant seasonal flush.     

Monitoring of Seasonal Variation in the Water Quality of Ubu River in Ekwusigo and Nnewi Local Government Areas of Anambra State,Nigeria

Investigation of the water quality of the Ubu river has been carried out. The upstream course of the river is slightly acidic (pH 5.45 ± 0.23), and the acidity decreases along the lower courses of the river. Turbidity, surfactant, and iron content parameters of the river increased during the wet season, and these changes have been attributed to inputs from flood, leachates of soil erosion, and storm water runoff discharged into the river in increased quantities during the season. Concentrations of some metals were found to increase during the dry season because of absence of dilution of the river by storm water runoff. Most water quality parameters are within World Health Organization acceptable limits set for potable water, and they include most of the cationic and anionic constituents. Although there is no hydrocarbon or metal ion pollution, potability is reduced along the mid to downstream courses of the river by unacceptable levels of turbidity, surfactant concentration, and iron content, particularly during the wet season.     

Farm factors associated with reducing Cryptosporidium loading in storm runoff from dairies

A systems approach was used to evaluate environmental loading of Cryptosporidium oocysts on five coastal dairies in California. One aspect of the study was to determine Cryptosporidium oocyst concentrations and loads for 350 storm runoff samples from dairy high use areas collected over two storm seasons. Selected farm factors and beneficial management practices (BMPs) associated with reducing the Cryptosporidium load in storm runoff were assessed. Using immunomagnetic separation (IMS) with direct fluorescent antibody (DFA) analysis, Cryptosporidium oocysts were detected on four of the five farms and in 21% of storm runoff samples overall. Oocysts were detected in 59% of runoff samples collected near cattle less than 2 mo old, while 10% of runoff samples collected near cattle over 6 mo old were positive. Factors associated with environmental loading of Cryptosporidium oocysts included cattle age class, 24 h precipitation, and cumulative seasonal precipitation, but not percent slope, lot acreage, cattle stocking number, or cattle density. Vegetated buffer strips and straw mulch application significantly reduced the protozoal concentrations and loads in storm runoff, while cattle exclusion and removal of manure did not. The study findings suggest that BMPs such as vegetated buffer strips and straw mulch application, especially when placed near calf areas, will reduce environmental loading of fecal protozoa and improve stormwater quality. These findings are assisting working dairies in their efforts to improve farm and ecosystem health along the California coast.     

事故状态下污染物排放对水环境影响的预测研究

对辽河油田欢喜岭采油厂在事故状态下污染物排放对大凌河水域环境的影响进行预测研究。计算了洪水淹没、油罐冒顶泄漏、油井井喷泄漏、联合站泄漏、管道泄漏、暴雨径流带走落地油等16种情景下对该河流水质的影响情况,并建立数学模型,进行情景模拟。研究结果表明,事故状态下对大凌河水质影响的次序由大到小依次为:洪水淹没、油罐冒顶泄漏、油井井喷泄漏、联合站泄漏、管道泄漏、暴雨径流。