Ecosystem monitoring at global baseline sites

Integrated ecosystem and pollutant monitoring is being conducted at prototype global baseline sites in remote areas of the Noatak National Preserve, Alaska, the Wind River Mountains, Wyoming, and Torres del Paine National Park, Chile. A systems approach has been used in the design of these projects. This approach includes: (1) evaluation of source-receptor relationships, (2) multimedia (i.e., air, water, soil, biota) monitoring of key contaminant pathways within the environment, (3) the use of selected ecosystem parameters to detect anthropogenic influence, and (4) the application of a systems conceptual framework as a heuristic tool.Initial short-term studies of air quality (e.g. SO₂, NO₂) plus trace metal concentrations in mosses generally indicate pristine conditions at all three of the above sites as expected although trace metals in mosses were higher at the Wyoming site. Selected ecosystem parameters for both terrestrial (e.g. litter decomposition) and aquatic (e.g. shredders, a macroinvertebrate functional feeding group) habitats at the Wyoming site reflected baseline conditions when compared to other studies.Plans also are being made to use U.S. Department of Energy Research Parks for global change monitoring. This will involve cross-site analyses of existing ecological databases and the design of a future monitoring network based on a systems approach as outlined in this paper.     

Ensuring quality in long term environmental monitoring for chemical speciation

The awareness regarding quality assurance (QA) and quality control (QC) for environmental monitoring has considerably increased in the past few years, especially with respect to the determination of chemical species, since errors occurring at various levels may considerably affect the interpretation of results (e.g. studies of toxic impact, geochemical pathways, etc.). QA for environmental analysis covers a broad range of activities from sample collection to laboratory work and the approach for ensuring quality data should be considered in a global context. However, whereas great emphasis has been placed on QA within the laboratory, there have been few systematic attempts to evaluate risks of discrepancies related, for example, to field manipulations. The situation is even worse when monitoring is applied to relatively new fields such as chemical speciation. This paper outlines some of the main aspects of quality control of environmental analysis, including the validation of methods, sampling and sample handling, storage, etc., with special emphasis on the monitoring of chemical forms of elements (e.g. species of tin, mercury, lead and selenium).     

Population monitoring for genetic damage induced by environmental physical and chemical agents

The short-term tests performed in vitro on different systems, from phage to human cells, or in vivo, on laboratory animals, allow only a qualitative estimate of the action of mutagenic agents, and the extrapolation of such experimental results to man may encounter many difficulties.Direct biomonitoring of populations exposed to chemicals could represent a more realistic approach for an evaluation of the hazards to man. Certain methods are still under development. Nevertheless, other ones can already by used routinely, e.g. the cytogenetic observations on peripheral blood lymphocytes and the Ames test for mutagenic substances in urine, and can provide useful suggestions how to set threshold limits for chemical substances encountered in the working environment.     

The use of thermal desorption in monitoring for the chemical weapons demilitarization program

Under international treaty, the United States and Russia are disposing of their aging stockpile of chemical weapons. Incineration and chemical neutralization are options for sites in the United States, although Russia prefers the latter. The storage and disposal of bulk and chemical agents and weapons involve unique hazards of handling extremely toxic materials. There are three major areas of concern--the storage stockpile, the disposal area, and the discovery and destruction of "found" material not considered part of the stockpile. Methods have been developed to detect the presence of chemical agents in the air, and these are used to help assure worker protection and the safety of the local population. Exposure limits for all chemical agents are low, sometimes nanograms per cubic meter for worker control limits and picograms per cubic meter for general population limits. There are three types of monitoring used in the USA: alarm, confirmation, and historical. Alarm monitors are required to give relatively immediate real-time responses to agent leaks. They are simple to operate and rugged, and provide an alarm in near real-time (generally a few minutes). Alarm monitors for the demilitarization program are based on sorbent pre-concentration followed by thermal desorption and simple gas chromatography. Alarms may need to be confirmed by another method, such as sample tubes collocated with the alarm monitor and analyzed in a laboratory by more sophisticated chromatography. Sample tubes are also used for historical perimeter monitoring, with sample periods typically of 12 h. The most common detector is the flame photometric detector, in sulfur or phosphorous mode, although others, such as mass-selective detectors, also have been used. All agents have specific problems with collection, chromatography and detection. Monitoring is not made easier by interferences from pesticide spraying, busy roadways or military firing ranges. Exposure limits drive the requirements for analytical sensitivity. Lowering limits adds additional difficulties to the monitoring efforts. The various monitoring methods and the role they play in ensuring worker and general population safety are discussed.     

Assessing workplace chemical exposures: the role of exposure monitoring

Occupational exposure is the condition of being subjected through employment to a chemical, physical, or biological agent, or to a specific process, practice, behavior, or organization of work. Exposure to a chemical agent is typically the contact of that agent with the outer boundary of a subject, such as the respiratory system, skin, or digestive system. In occupational hygiene we are most concerned with exposure through the respiratory system, although, increasingly we are concerned with the results of dermal exposures, including those exposures to the skin that can be transferred to the mouth and digestive system. This presentation will detail methods available for assessing personal exposures to chemicals through monitoring. The results from monitoring can then be compared to established guidelines and regulations, although this is not the only rationale for making measurements. These monitoring methods are currently used around the world to establish the benchmark hazard from which risk to the worker can be predicted. The presentation will describe the general techniques for assessing exposures to the respiratory system from chemical gases and vapors, chemical dusts, and exposures to the skin from bulk chemicals or chemical contamination of surfaces. For respiratory exposures, direct-reading instruments are available for spot measurements, and for monitoring short-term fluctuations in concentration. However, most standards and regulations are based on time-integrated (time-weighted average) exposures, requiring longer-term integrative methods. Therefore, the specific focus of this review will be the methods available for full work-shift sampling. For gases and vapors this will include taking whole-air samples in canisters or polymer bags, or concentration of chemicals by absorption in liquids or adsorption on solid sorbents, with subsequent chemical analysis. Chemical concentration can take place by pumping air through the sorbing media, or by allowing molecules to diffuse to the sorbent surface. Transfer of the collected chemicals to the analytical instrumentation can be accomplished using solvent displacement and injection, or through the application of heat to bring the collected molecules back into the vapor phase. For particles, the particle size is important as this determines the site of deposition in the lungs, and so time-integrated sampling on filters using various types of size-selective samplers is preferred. Finally, some techniques that have been used to assess the potential for chemical contamination of the skin are presented. Biomonitoring is another tool that can be used to assess exposure, and the results are more relevant to dosimetric considerations than exposure. Biomonitoring is a complex subject worthy of a separate review, and will be considered only briefly here.     

Analysis of multi-temporal landsat satellite images for monitoring land surface temperature of municipal solid waste disposal sites

This studypresents a remote sensing application of using time series Landsat satellite images for monitoring the Trail Road and Nepean municipal solid waste (MSW) disposal sites in Ottawa, Ontario, Canada. Currently, the Trail Road landfill is in operation; however, during the 1960s and 1980s, the city relied heavily on the Nepean landfill. More than 400 Landsat satellite images were acquired from the US Geological Survey (USGS) data archive between 1984 and 2011. Atmospheric correction was conducted on the Landsat images in order to derive the landfill sites’ land surface temperature (LST). The findings unveil that the average LST of the landfill was always higher than the immediate surrounding vegetation and air temperature by 4 to 10 °C and 5 to 11.5 °C, respectively. During the summer, higher differences of LST between the landfill and its immediate surrounding vegetation were apparent, while minima were mostly found in fall. Furthermore, there was no significant temperature difference between the Nepean landfill (closed) and the Trail Road landfill (active) from 1984 to 2007. Nevertheless, the LST of the Trail Road landfill was much higher than the Nepean by 15 to 20 °C after 2007. This is mainly due to the construction and dumping activities (which were found to be active within the past few years) associated with the expansion of the Trail Road landfill. The study demonstrates that the use of the Landsat data archive can provide additional and viable information for the aid of MSW disposal site monitoring.     

Risk assessment near uncontrolled hazardous waste sites: Role of monitoring data

The traditional approach of coupling estimates of human exposures to individual chemicals with laboratory studies of the toxicity of the chemicals as the basis for quantitative assessments of risk is not adequate when considering problems near hazardous waste sites. For example, there are (a) too many chemicals and mixtures involved, (b) containment uncertainties, and (c) future exposure problems associated with groundwater and soil contamination. Among the items to be considered in expanding the dimensions of risk assessment methodologies of the past are (a) identification of chemical groups or of dominant toxic chemicals of principal concern and the likely man-made as well as natural pathways for environmental migration, (b) the role of biological monitoring in addition to traditional monitoring approaches, and (c) the coupling of monitoring data with past, current, and future population activity patterns and with epidemiological and other health data.Monitoring data is a key in risk assessments since there is little likelihood that materials balances or modelling will provide authoritative information concerning exposure levels. The use of monitoring data from control areas and from nationwide baseline surveys in developing comparative risk assessments is particularly important. Finally, recent experience provides us with a number of practical guidelines for designing and carrying out monitoring programs that will provide authoritative and useful data. *** DIRECT SUPPORT *** AZ802019 00002     

Dose-time-response functions for toxic chemicals

In many situations, the effect of a toxic chemical on a biological system depends on both the intensity and the duration of exposure. The dependence on the time dimension can be the expression of a range of processes including the physical accumulation of toxic chemicals or their metabolites and the functional accumulation of damage. Measures and functions that have been used to describe this dependence are reviewed.Some of these functions are compared through a case study of the neurotoxicity of methylmercury. Use is made of data that indicates a dependency between the blood concentration at which monkeys were exposed and the length of time before damage was detected. Several exposure functions are fitted to these data and their appropriateness is compared. Using the most appropriate function, an exposure-response relationship is developed using probit analysis. An alternative data analysis procedure is also investigated. The apparent threshold after a 100 day exposure is estimated to be greater by a factor of 3–5 compared to the threshold for chronic exposure. Applying this factor to man, the blood concentration threshold for chronic exposure is estimated to be 40–170 ppb, a finding consistent with recent reports of neurological damage in humans exposed below the generally accepted threshold.     

Biological and chemical monitoring of some major Calabrian (Italy) Rivers

To address the problem of whether hydrographic basins of southern Italian regions such as Calabria are exposed to "ecological stability pressures," we here provide the first results of four chemical and biological (macroinvertebrates) monitoring activities. The data accumulated within four hydrographic basins between May and November of 2002, November of 2005 and May of 2006 showed that about 1/3 of the macrobenthos sampled among a total of 14 rivers in the northern-central part of Calabria region provided optimal environmental quality values of Extended Biotic Index (E.B.I.), 1/3 denoted a slight impairment and the remaining samples exhibited very strong environmental alterations. It is interesting to note that E.B.I. is directly correlated with the taxonomic richness plus abundance, and inversely with the dominating taxon. This suggests that high environmental quality values are rather positively correlated with spatial heterogeneity and taxa eveness. In addition, the more compromised stations were located on plain segments where anthropization is reported to be at its highest level and there the macrobenthic communities seem to be made up of mostly potamon type of taxa with a high abundance of collector euriecious organisms while better quality stations, mostly located at high altitude, are characterized by a considerable presence of E.P.T. taxa. Chemical parameters did not result to be substantially altered underling that the hydrologic and geomorphological alterations may play a primary role in the control of macrobenthic communities and environmental quality. Overall the above results suggest that E.B.I. variations seem to be highly coherent with changes of main biodiversity parameters and their joined application is an efficient tool for detecting ecological state alterations of lotic environments.     

Prioritizing GM crop monitoring sites in the dynamics of cultivation systems and their environment

EU legislation stipulates that GM crops have to be monitored for potential adverse environmental effects. Monitoring preferably should take place in the most exposed areas-the cultivated fields and their neighbouring environment. Current monitoring designs do not give detailed consideration to the different exposure intensities in agricultural practice. At the same time, the selection of specific, more exposed sites is difficult considering the dynamic and diversity of crop cultivation and rotation systems and their environments. We developed an approach for prioritising the monitoring of on-farm and neighbouring sites based on differing exposure levels using a minimum dataset of cultivation and land use information. Applying a Bt-maize cultivation scenario to Brandenburg, Germany, where presently no GM crops are cultivated, we systemised and categorised areas with different spatio-temporal exposure intensities including 50 m, 200 m and 1000 m buffers. These categories correspond to different suitabilities to serve as monitoring sites. Sites are prioritised using a sequential scheme. This yields an improved and objective spatial monitoring design providing detailed exposure information. This methodology is flexible and transferable to any agricultural setting, therefore enabling superior statistical comparisons between locations and regions and thus enhancing monitoring data quality.     

Application of Microwave Plasma Atomic Emission Spectrometry (MP-AES) for environmental monitoring of industrially contaminated sites in Hyderabad City

Recently introduced microwave plasma-atomic emission spectroscopy (MP-AES) represents yet another and very important addition to the existing array of modern instrumental analytical techniques. In this study, an attempt is made to summarize the performance characteristics of MP-AES and its potential as an analytical tool for environmental studies with some practical examples from Patancheru and Uppal industrial sectors of Hyderabad city. A range of soil, sediment, water reference materials, particulate matter, and real-life samples were chosen to evaluate the performance of this new analytical technique. Analytical wavelengths were selected considering the interference effects of other concomitant elements present in different sample solutions. The detection limits for several elements were found to be in the range from 0.05 to 5 ng/g. The trace metals analyzed in both the sectors followed the topography with more pollution in the low-lying sites. The metal contents were found to be more in ground waters than surface waters. Since a decade, the pollutants are transfered from Patancheru industrial area to Musi River. After polluting Nakkavagu and turning huge tracts of agricultural lands barren besides making people residing along the rivulet impotent and sick, industrialists of Patancheru are shifting the effluents to downstream of Musi River through an 18-km pipeline from Patancheru. Since the effluent undergoes primary treatment at Common Effluent Treatment Plant (CETP) at Patanchru and travels through pipeline and mixes with sewage, the organic effluents will be diluted. But the inorganic pollutants such as heavy and toxic metals tend to accumulate in the environmental segments near and downstreams of Musi River. The data generated by MP-AES of toxic metals like Zn, Cu, and Cr in the ground and surface waters can only be attributed to pollution from Patancheru since no other sources are available to Musi River.     

Development of soil chemical and biological properties in the initial stages of post-mining deposition sites

The aim of this study was to assess the seasonal development of the physicochemical (pH, organic C, organic N, extractable P, Ca²⁺, Mg²⁺) and biological soil properties (microbial biomass, activities of urease, dehydrogenase and alkaline phosphatase) of the topsoil of mine deposition sites that differed based on the material used exclusively for their creation: (a) marlstones, (b) red-grey formations (RGF), and (c) fly ash (FA), during the first year after their creation. Our hypothesis was that all deposition sites, regardless the material they consist of, present equal opportunities for the establishment of spontaneous vegetation. All macronutrients concentrations (P, Ca²⁺, and Mg²⁺) remained constant with time and were found to be higher in the FA sites. Organic C, organic N, all enzyme activities, and microbial biomass were higher in the RGF and marl depositions, with marl sites presenting the highest values. All values of biological variables, with the exception of alkaline phosphatase, increased with time. The alkaline environment along with the slow improvement in soil biological properties of the FA sites seemed to present the most unfavorable conditions for spontaneous vegetation growth. On the contrary, the other two spoil materials presented significant improvement in the initial stages of soil formation in terms of soil functionality.     

Quality control and quality assurance for particle size distribution measurements at an urban monitoring station in Augsburg, Germany

Long-term observations of atmospheric constituents such as aerosol particles are increasingly needed to assess their impact on climate and human health. In contrast to particle mass concentration (MC), there are currently no standardized quality control (QC) and quality assurance (QA) procedures for the measurement of particle size distribution (PSD). This study describes some fundamental QC and QA procedures associated with the collection and evaluation of a 2 year dataset between 2005 and 2006 at an urban background monitoring site in Augsburg, Germany. The considered parametres include ambient PSD between 3 nm and 10 microm (merged from a twin differential mobility and an aerodynamic particle sizer, TDMPS and APS, respectively) as well as total particle number (TNC), length (LC) and MC determined by independent instruments. The hourly 1st and 0th moment of PSD showed good correlations with the independently measured LC (R(2) = 0.86) and TNC (R(2) = 0.79), respectively, the deviation for LC with 4% and for TNC with 22% being rather small. The volume concentration (3rd moment) of hourly measured PSD and the resultant MC (when assuming a realistic apparent density of 1.5 g cm(-3)) correlated well with the independently measured MC of PM(2.5) or PM(10) (R(2) > 0.86) and showed only small deviation from PM(2.5) (1%) or PM(10) (5%), respectively. The study demonstrates that the described QC and QA measures define both a high accuracy of the PSD measurements and their long-term comparability against data obtained in similar measurement programmes.     

Spatial variation of potentially toxic elements in different grain size fractions of marine sediments from Gulf of Mannar, India

Marine sediments of the Gulf of Mannar (GoM), India are contaminated by potential toxic elements (PTEs) due to anthropogenic activities posing a risk to the existing fragile coral ecosystem and human health. The current study aimed to assess the distribution of PTEs (arsenic—As; cobalt—Co; copper—Cu, molybdenum—Mo; lead—Pb; and zinc—Zn) in marine sediments of different grain size fractions, viz., medium sand (710 μm), fine sand (250 μm), and clay (<63 μm) among the different coastal regions of Pamban, Palk Bay, and Rameswaram coasts of GoM, using grain size as one of the key factor controlling their concentrations. The concentrations of PTEs were measured in the different size fractions of sediment using inductively coupled plasma mass spectrophotometer. The order of accumulation of all PTEs in the three fractions was ranked as Zn > Cu > Pb > As > Co > Mo and in the three locations as Rameswaram > Palk Bay > Pamban. The concentration of PTEs in Palk Bay and Rameswaram coast was significantly different (P?<?0.05), when compared to Pamban coast. Measured geoaccumulation index (I _geo) and contamination factor (CF) indicated significant enrichment of Co and Pb from Rameswaram coast when compared to other two coasts. Although the concentration of Co was low but the measured I _geo and CF values indicated significant enrichment of this PTE in Rameswaram coast. The increased input of PTEs in the coastal regions of GoM signifies the need to monitor the coast regularly using suitable monitoring tools such as sediments to prevent further damage to the marine ecosystem.     

苏州市区大气监测点位调整中的相关性和聚类分析

根据苏州市8个国控大气监测站点2013—2015年的PM_(10)、PM_(2.5)、O_3、SO_2监测数据,计算了各站点之间监测数据的相关系数;通过分析相关系数矩阵,发现苏州市大气国控点位的监测数据相关性均较高,点位设置存在一定的冗余,国控监测点位的优化调整十分必要。利用最长距离法对各站点的监测数据进行聚类分析,从而得出中心城区的点位调整方案。点位调整前后4种污染物监测数据四季平均值的相对误差均小于5%;正负偏差的二项检验结果表明,调整后未对监测结果产生显著的正/负影响。因此,经过优化的大气监测网络具有较好的客观性和代表性。     

Measurement instability and temporal bias in chemical soil monitoring: sources and control measures

Concern that human impacts on the environment may be harmful to natural resources such as soils as well as to living conditions is the major motivation for long-term environmental monitoring. However, the evidence that measurement bias is not constant through time affects time series as an artifact; this also holds true for chemical soil monitoring. Measurement instabilities occur along the whole measurement chain, from soil sampling to the expression of results. The first step in controlling measurement instability is to identify its relevant sources, and the second is to control it by stabilizing, minimizing, or quantifying measurement instability. For all five steps in the measurement process, from soil sampling to the expression of the analytical results, sources of measurement instability are identified and measures of control discussed, leading to the main conclusion concerning the requirement to continuously control the relevant environmental and measurement boundary conditions that may affect measurement instability. The innovative aspect of this paper consists in explicitly addressing measurement instability in chemical soil monitoring and tracking it along the whole measurement chain. The paper is also a plea for a change of paradigm in long-term environmental monitoring, namely to consider temporal measurements as unstable unless their degree of stability is traceably demonstrated, adequately quantified, and included in interpretation.     

Characterisation of weathered hydrocarbon wastes at contaminated sites by GC-simulated distillation and nitrous oxide chemical ionisation GC-MS, with implications for bioremediation

An extended analytical characterisation of weathered hydrocarbons isolated from historically contaminated sites in Alberta is presented. The characterisation of soil extracts, chromatographically separated into component classes, by GC-simulated distillation and nitrous oxide (N2O) chemical ionisation (CI) GC-MS provides new insights into the composition of the residual oil at these sites, the principal partition medium for risk critical components. The combined polar and asphaltene content of representative soil extracts ranged from 40% w/w to 70% w/w of the oils encountered. An abundance of C14-C22 2-4 ring alicyclics, alkylbenzenes and benzocycloparaffins is prevalent within the saturate fractions of site soils. Implications for the partitioning of risk critical compounds at sites with weathered hydrocarbons and the practical application of bioremediation technologies are discussed.     

Five-year monitoring study of chemical characteristics of Wet atmospheric precipitation in the southern region of Jordan

Wet atmospheric samples were collected from different locations in the southern region of Jordan during a 5-year period (October 2006 to May 2011). All samples were analyzed for pH, EC, major ions (Ca²⁺, Mg²⁺, Na⁺, K⁺, HCO₃ ^?, Cl^?, NO₃ ^?, and SO₄ ^2?), and trace metals (Fe²⁺, Al³⁺,Cu²⁺, Pb²⁺, and Zn²⁺). The highest ion concentrations were observed during the beginning of the rainfall events because large amounts of dust accumulated in the atmosphere during dry periods and were scavenged by rain. The rainwater in the study area is characterized by low salinity and neutral pH. The major ions found in rainwater followed the order of HCO₃?>?Cl^??>?SO₄ ^2? and Ca²⁺?>?Na⁺ > Mg²⁺ > NH₄ ⁺ > K⁺. Trace metals were identified to be of anthropogenic origin resulting from cement and phosphate mining activities located within the investigated area and from heating activities during the cold period of the year (January to April). The wet precipitation chemistry was analyzed using factor component analysis for possible sources of the measured species. Factor analysis (principal component analysis) was used to assess the relationships between the concentrations of the studied ions and their sources. Factor 1 represents the contribution of ions from local anthropogenic activities, factor 2 represents the contribution of ions from natural sources, and factor 3 suggests biomass burning and anthropogenic source. Overall, the results revealed that rainwater chemistry is strongly influenced by local anthropogenic sources rather than natural and marine sources, which is in a good agreement with the results obtained by other studies conducted in similar sites around the world.     

Effects of crude oil residuals on soil chemical properties in oil sites, Momoge Wetland, China

Crude oil exploration and production has been the largest anthropogenic factor contributing to the degradation of Momoge Wetland, China. To study the effects of crude oil on wetland soils, we examined the total petroleum hydrocarbon (TPH), total organic carbon (TOC), total nitrogen (TN), and total phosphorus (TP), as well as pH and electricity conductivity (EC) from oil sites and uncontaminated areas in the Momoge Wetland. All contaminated areas had significantly higher (p < 0.05) contents of TPH and TOC, but significantly lower (p < 0.05) TN contents than those of the uncontaminated areas. Contaminated sites also exhibited significantly higher (p < 0.05) pH values, C/N and C/P ratios. For TP contents and EC, no significant changes were detected. The level of soil contamination and impact of oil residuals on soil quality greatly depended on the length of time the oil well was in production. Oil residuals had caused some major changes in the soils’ chemical properties in the Momoge Wetland.