7Be to 210Pb concentration ratio in ground level air in Belgrade area

7Be to 210Pb concentration ratios in ground level air on two monitoring stations (MS1 and MS2) in Belgrade area were determined from 1996 to 2001. The average monthly concentrations of 7Be in ground level air were in the range of 0.6-18.3 mBq/m3 and exhibited one or two summer/early fall maxims and one minimum in winter. The maximum concentrations for 210Pb were generally observed in the fall, with the average concentrations in the range of 1.09 x 10(-4) to 30.9 x 10(-4) Bq/m3. The 7Be/210Pb ratios were in the range of 1.7-12.7 (MS1) and 1.8-11.3 (MS2), with summer maxims and late fall/winter minimums. The mean Radionuclides Loading Indices values approach zero except for 1996/1997 (MS1) and 2001 (MS2) due to higher concentrations of 7Be and 210Pb. The mean monthly concentrations of both radionuclides exhibited lognormal distributions. There is significant correlation between the 7Be/210Pb activities ratio and the air stability classes A + B + C for both monitoring stations (correlation coefficients 0.61-0.65), and no correlation with D class and E + F classes. Correlation was found between the activity of 7Be and air stability classes A + B + C (0.46-0.68), and E + F (0.38 for MS1), while for 210Pb, a moderate correlation (0.38-0.40) was found with the E + F air stability classes.     

Chlorine-39 in rainfall at a temperate latitude (40 degrees N)

Rainwater samples were collected and measured for the radioactivity to confirm the presence of Chlorine-39 (T1/2=56.2 min) formed by the interaction of cosmic-ray slow negative muons, mu- with Argon-40 in the lower atmosphere. The presence of 39Cl was confirmed by estimating the half-life of a radionuclide present in the rainwater ranging from 58 to 63 min and averaging 60.4 min. The disintegration rate of this radionuclide varied from 2.1 to 2.7 Bq L(-1) (125-160 dpm/L) of rainwater and averaged 2.3 Bq L(-1) (140 dpm/L) of rainwater in Thessaloniki (40 degrees 38'N, 22 degrees 58'E), Northern Greece. This concentration is indicative of mid or temperate latitudes. This is clearly less than that reported in the literature, 1.7 Bq L(-1) (100 dpm/L) of rainwater, for a southern latitude 31 degrees 54'N, 34 degrees 49'E (Rehovot, Israel), due to the latitudinal effect of cosmic radiation.     

Wet and dry deposition of 129I in Seville (Spain) measured by accelerator mass spectrometry.

Iodine-129 (T1/2 = 1.57 x 10(7) yr) concentrations have been determined by accelerator mass spectrometry in rainwater samples taken at Seville (southwestern Spain) in 1996 and 1997. This technique allows a reduction in the detection limits for this radionuclide in comparison to radiometric counting and other mass spectrometric methods such as ICP-MS. Typical 129I concentrations range from 4.7 x 10(7) 129I atoms/l (19.2%) to 4.97 x 10(9) 129I atoms/l (5.9%), while 129I depositions are normally in the order of 10(8)-10(10) atoms/m2d. These values agree well with other results obtained for recent rainwater samples collected in Europe. Apart from these, the relationship between 129I deposition and some atmospheric factors has been analyzed, showing the importance of the precipitation rate and the concentration of suspended matter in it.     

Determination of radionuclide levels in rainwater using ion exchange resin and γ-spectrometry

The evaluation of radioactivity accidentally released into the atmosphere involves determining the radioactivity levels of rainwater samples. Rainwater scavenges atmospheric airborne radioactivity in such a way that surface contamination can be deduced from rainfall rate and rainwater radioactivity content. For this purpose, rainwater is usually collected in large surface collectors and then measured by γ-spectrometry after such treatments as evaporation or iron hydroxide precipitation. We found that collectors can be adapted to accept large surface (diameter 47 mm) cartridges containing a strongly acidic resin (Dowex AG 88) which is able to quantitatively extract radioactivity from rainwater, even during heavy rainfall. The resin can then be measured by γ-spectrometry. The detection limit is 0.1 Bq per sample of resin (80 g) for ¹³⁷Cs. Natural ⁷Be and ²¹⁰Pb can also be measured and the activity ratio of both radionuclides is comparable with those obtained through iron hydroxide precipitation and air filter measurements. Occasionally ²²Na has also been measured above the detection limit. A comparison between the evaporation method and the resin method demonstrated that 2/3 of ⁷Be can be lost during the evaporation process. The resin method is simple and highly efficient at extracting radioactivity. Because of these great advantages, we anticipate it could replace former rainwater determination methods. Moreover, it does not necessitate the transportation of large rainwater volumes to the laboratory.     

Measurements of major ion concentration in settled coarse particles and aerosols at a semiarid rural site in India

Deposition rates and deposition velocities of water-soluble ions (F, Cl, NO3, SO4, NH4, Ca, Mg, Na and K) were measured at a rural site (Gopalpura, Agra). Dry deposition samples were collected throughout the year from December 1995 to August 1997, while the aerosol samples were collected only during the winter season of 1996. Surrogate technique was used to collect the dry deposition samples, while aerosol samples were collected on PTFE membrane filter. Deposition velocities (Vd) of SO4 and NO3 are < or = 0.01 m s(-1) while Ca, Mg, Na, K, NH4, F and Cl exhibit greater than 0.01 m s(-1) Equivalent concentration ratios of K/Na, Ca/Na and Mg/Na conform with the corresponding ratios of local soil, indicating the dominant contribution of local sources. Deposition rates are maximum in winter, followed by summer and monsoon. No significant differences are found in dry deposition rates of all ions or in atmospheric concentrations of soil-derived elements with respect to wind direction. However, in aerosols, concentrations of F, Cl, NO3 and SO4 are higher with winds from southwesterly and westerly directions corresponding to pollution sources located in these directions. Deposition data have been used to calculate the critical load of S and N for soil with respect to Triticum vulgaris. The critical load of actual acidity was found to be 622.4 eq ha(-1) year(-1) within the range of 500-1,000 eq ha(-1) year(-1) as assessed by the RAINS-Asia model for this region. The present load of S and N (77.4 and 86.4 eq ha(-1) year(-1)) was much lower than the critical load of S and N (622.4 and 2,000 eq ha(-1) year(-1)), indicating that at present there is no harmful effect on ecosystem structure and function.     

Short-term seasonal variability in Be wet deposition in a semiarid ecosystem of central Argentina

The ⁷Be wet deposition has been intensively investigated in a semiarid region at San Luis Province, Argentina. From November 2006 to May 2008, the ⁷Be content in rainwater was determined in 58 individual rain events, randomly comprising more than 50% of all individual precipitations at the sampling period. ⁷Be activity concentration in rainwater ranged from 0.7 ± 0.3 Bq l⁻¹ to 3.2 ± 0.7 Bq l⁻¹, with a mean value of 1.7 Bq l⁻¹ (sd = 0.53 Bq l⁻¹). No relationship was found between ⁷Be content in rainwater and (a) rainfall amount, (b) precipitation intensity and (c) elapsed time between events. ⁷Be ground deposition was found to be well correlated with rainfall amount (R = 0.92). For the precipitation events considered, the ⁷Be depositional fluxes ranged from 1.1 to 120 Bq m⁻², with a mean value of 32.7 Bq m⁻² (sd = 29.9 Bq m⁻²). The annual depositional flux was estimated at 1140 ± 120 Bq m⁻² y⁻¹. Assuming the same monthly deposition pattern and that the ⁷Be content in soil decreases only through radioactive decay, the seasonal variation of ⁷Be areal activity density in soil was estimated. Results of this investigation may contribute to a valuable characterization of ⁷Be input in the explored semiarid ecosystem and its potential use as tracer of environmental processes.     

Precipitation scavenging of 7Be and 137Cs radionuclides in air

Atmospheric depositional fluxes of the naturally occurring 7Be of cosmogenic origin and 137Cs from fallout of the Chernobyl accident were measured over a 6-year period (January 1987-December 1992) at Thessaloniki, Greece (40 degrees 38'N, 22 degrees 58'E). Total precipitation accumulation during 1987-1992 varied between 33.7 cm and 65.2 cm, reflecting a relatively dry (precipitation-free) climate. The activity concentrations of 7Be and 137Cs in rainwater depended on the precipitation rate, being higher for low precipitation rates and lesser for high precipitation rates. 137Cs was removed by rain and snow more efficiently than 7Be. Snowfall was more efficient than rainfall in removing the radionuclides from the atmosphere. The annual bulk depositional fluxes of 7Be varied between 477 and 1133 Bq m(-2) y(-1) and this variability was attributed to the amount of precipitation and the variations of the atmospheric concentrations of 7Be. The annual bulk depositional fluxes of 137Cs showed a significant decrease over time from 1987 to 1992, resulting in a removal half-life of 1.33 years. The presence of 137Cs in air, and therefore in rainwater and snow, long after the Chernobyl accident (26 April 1986) was mainly due to the resuspension process. The normalized depositional fluxes of both radionuclides showed maximal values during the spring season where the maximum amount of precipitation occurred. The relatively high positive correlation between 7Be and 137Cs normalized depositional fluxes indicates that the scavenging process of local precipitation controlled the fluxes of both radionuclides. The dry depositional flux of 7Be was less than 9.37% of total (wet and dry) depositional flux. The fraction of dry-to-total depositional flux of 137Cs was much higher than that of 7Be, due to the resuspended soil.     

90Sr, 137Cs and (239,240)Pu concentration surface water time series in the Pacific and Indian Oceans--WOMARS results

Under an IAEA's Co-ordinated Research Project "Worldwide Marine Radioactivity Studies (WOMARS)" 90Sr, 137Cs and (239,240)Pu concentration surface water time series in the Pacific and Indian Oceans have been investigated. The Pacific and Indian Oceans were divided into 17 latitudinal boxes according to ocean circulation, global fallout patterns and the location of nuclear weapons test sites. The present levels and time trends in radionuclide concentrations in surface water for each box were studied and the corresponding effective half-lives were estimated. For the year 2000, the estimated average 90Sr, 137Cs and (239,240)Pu concentrations in surface waters of the Pacific and Indian Oceans varied from 0.1 to 1.5 mBq/L, 0.1 to 2.8 mBq/L, and 0.1 to 5.2 microBq/L, respectively. The mean effective half-lives for 90Sr and 137Cs in surface water were 12+/-1 years for the North, 20+/-1 years for the South and 21+/-2 years for the Equatorial Pacific. For (239,240)Pu the corresponding mean effective half-lives were 7+/-1 years for the North, 12+/-4 years for the South and 10+/-2 years for the Equatorial Pacific. For the Indian Ocean the mean effective half-lives of 137Cs and (239,240)Pu were 21+/-2 years and 9+/-1 years, respectively. There is evidence that fallout removal rates before 1970 were faster than those observed during recent decades. The estimated surface water concentrations of 90Sr, 137Cs and (239,240)Pu in latitudinal belts of the Pacific and Indian Oceans for the year 2000 may be used as the average levels so that any new contribution from nuclear facilities, nuclear weapons test sites, radioactive waste dumping sites and from possible nuclear accidents can be identified.     

Seasonal and inter-annual variation of Beryllium-7 deposition in birch-tree leaves and grass in the northeast upland area of the Czech Republic

The activity concentrations of Beryllium-7 (⁷Be), a naturally occurring radioisotope produced in the atmosphere, were measured in leaves of birch-trees, above-ground parts of grass, soil and rainwater in the mountain massive Kralicky Sneznik (the northeast of the Czech Republic, altitude about 750 m) in the years of 2005, 2006 and 2007. Dried and ground samples of the plants and soils, and water samples from wet deposition were used to determine the ⁷Be content using a semiconductor gamma spectrometer. The ⁷Be values ranged from 147.0 to 279.6 Bq kg⁻¹, from 48.7 to 740.8 Bq kg⁻¹, from 2.1 to 8.7 Bq kg⁻¹, and from 0.6 to 1.9 Bq kg⁻¹ in birch-tree leaves, grass samples, soils, and rainwater, respectively. Insignificant inter-annual variations but significant increase in the ⁷Be activity concentrations during the spring and summer months were observed in birch-tree leaves and grass samples. The seasonal variation of the ⁷Be concentrations in grass samples correlated (R² = 0.4663 and 0.6489) with precipitation. No similar correlation was found for ⁷Be in birch-tree leaves. Beryllium-7 content in birch-tree leaves and in aerial parts of grass was mainly caused by direct transport of ⁷Be from wet deposition into aerial parts of the observed plants.     

Sorption behaviour of Am on marl groundwater colloids.

The sorption of americium on marl colloids is studied in a comprehensive way. In Na-HCO3 groundwater conditions, americium in the concentration range 3 x 10(-11)-3 x 10(10) M sorbs onto groundwater colloids. In these tests, the colloid concentration is rather high, i.e. Ccoll 1.7+/-1.3 mg l(-1) for sizes 505000 nm or Ncoll (1.7+/-0.1) x 10(11) l(-1) for sizes larger than 100 nm. These colloids are mainly chlorite and smectite/illite with an average size smaller than 500 nm. For the groundwater (pH 8.6, [Na+]-[HCO3]-2 x 10(-2) M), Kd values in the range 1-3 x 10(6)mlg(-1) are measured. These values are compared with experimental and modelled values reported earlier in the literature.     

The relationship of climatic and hydrological parameters to surface water quality in the lower Mekong River

The relationship between climatic, hydrological and water quality parameters of the lower Mekong River flowing through four different countries (Thailand, Cambodia, Lao PDR and Vietnam) was studied. The Mekong River Commission (MRC) secondary data of climatic and hydrological parameters included precipitation, evaporation, average air temperatures, mean water level and discharge flow. Water quality parameters consisted of TSS, NO(3)(-), PO(4)(3-), DO, pH, conductivity, Ca, Mg, Na, K, alkalinity, Cl, SO(4)(2-), Fe, TP, Si and COD. Pearson's correlation was used to determine their relationship. The results reveal that the correlations of climatic, hydrological and water quality parameters in those four countries located along the lower Mekong River had the same trend. Precipitation had fair positive correlations with mean water level (ranging 0.375-0.661), discharge flow (ranging 0.526-0.659) and mean air temperature (ranging 0.515-0.621), however had weak negative correlation with evaporation (ranging 0.169-0.468). Concerning relationship with water quality, the results show that TSS, NO(3)(-), PO(4)(3-), TP and COD had weak to fair positive correlations with precipitation, mean water level, discharge flow. However, DO, pH, conductivity, Ca, Mg, Na, K, alkalinity, Cl, SO(4)(2-) and Si had fair to strong negative correlations with all hydrological parameters. Finally, TSS, alkalinity and conductivity were proposed as sensitive water quality parameters for monitoring impacts of changing climate in the lower Mekong River.     

World crop residues production and implications of its use as a biofuel

Reducing and off-setting anthropogenic emissions of CO(2) and other greenhouse gases (GHGs) are important strategies of mitigating the greenhouse effect. Thus, the need for developing carbon (C) neutral and renewable sources of energy is more than ever before. Use of crop residue as a possible source of feedstock for bioenergy production must be critically and objectively assessed because of its positive impact on soil C sequestration, soil quality maintenance and ecosystem functions. The amount of crop residue produced in the US is estimated at 367x10(6) Mg/year for 9 cereal crops, 450x10(6) Mg/year for 14 cereals and legumes, and 488x10(6) Mg/year for 21 crops. The amount of crop residue produced in the world is estimated at 2802x10(6) Mg/year for cereal crops, 3107x10(6) Mg/year for 17 cereals and legumes, and 3758x10(6) Mg/year for 27 food crops. The fuel value of the total annual residue produced is estimated at 1.5x10(15) kcal, about 1 billion barrels (bbl) of diesel equivalent, or about 8 quads for the US; and 11.3x10(15) kcal, about 7.5 billion bbl of diesel or 60 quads for the world. However, even a partial removal (30-40%) of crop residue from land can exacerbate soil erosion hazard, deplete the SOC pool, accentuate emission of CO(2) and other GHGs from soil to the atmosphere, and exacerbate the risks of global climate change. Therefore, establishing bioenergy plantations of site-specific species with potential of producing 10-15 Mg biomass/year is an option that needs to be considered. This option will require 40-60 million hectares of land in the US and about 250 million hectares worldwide to establish bioenergy plantations.     

Concentration measurements of 7Be at ground level air at Palermo, Italy-comparison with solar activity over a period of 21 years

Air activity concentrations of (7)Be in Palermo determined for the period January 1995-December 2002 by gamma-ray spectrometric analysis of particulate samples collected on paper filter by a high-volume sampler (approximately 900 m(3) h(-1)) are reported. The temporal behaviour of (7)Be concentration presents the same characteristics already observed in the measurements carried out over the previous 13-year (1982-1994) investigated period. The mean value of 5.06 mBq m(-3) obtained from the analysis of the 4636 particulate samples collected from 1982 to 2002 can be considered a representative value of (7)Be air concentration at ground level in our geographical zone. The comparison of long-term variation in the (7)Be concentrations with the cyclic solar activity-extended to the whole period of 21 years-confirms the inverse correlation between the two quantities.     

Seasonal and spatial variation of atmospheric 210Pb and 7Be deposition: features of the Japan Sea side of Japan

Monthly depositional fluxes of (210)Pb and (7)Be at Tatsunokuchi, Japan which faces the Japan Sea were studied over a 12-year period from 1991 to 2002. The data were compared with the spatial variability of these fluxes at Taejon in Korea and at 11 other sites in Japan from Ishigaki of the southern islands of Okinawa to Wakkanai of the northern end of Hokkaido over a 2-year period from 2000 to 2001. The monthly depositions of both (210)Pb and (7)Be at Tatsunokuchi revealed very similar seasonal variations with a single peak; both depositions were high in winter and low in summer. This phenomenon was found to be not transient but stationary. The deposition of these nuclides was much greater on the Japan Sea side of Japan than on the Pacific Ocean side. The cause for high deposition of (210)Pb and (7)Be in winter might be explained by a combination of a series of the following processes: blowing out of air masses with a high (210)Pb concentration near the surface layer over the continent by strong winter monsoons, additional flow of cold air masses with high (7)Be concentration at high latitude, well-mixing with generation of ascending current and convection clouds over the Japan Sea, and heavy snowfalls accompanying them.     

Resuspension and redistribution of radionuclides during grassland and forest fires in the Chernobyl exclusion zone: part I. Fire experiments

Controlled burning of experimental plots of forest or grassland in the Chernobyl exclusion zone has been carried out in order to estimate the parameters of radionuclide resuspension, transport and deposition during forest and grassland fires and to evaluate the working conditions of firemen. An increase of several orders of magnitude of the airborne radionuclide concentration was observed in the territory near the fire area. The resuspension factor for (137)Cs and (90)Sr was determined to range from 10(-6) to 10(-5) m(-1), and for the plutonium radionuclides from 10(-7) to 10(-6) m(-1) (related to the nuclides in the combustible biomass). These values are 2 orders of magnitude lower if they are calculated relatively to the total contamination density (including the nuclides in the soil). The radionuclide fallout along the plume axis is negligible in comparison to the existing contamination. However, the additional inhalation dose for firemen exposed in the affected area can reach the level of the additional external irradiation in the period of their mission. The plutonium nuclides constitute the dominating contribution to the inhalation dose.     

Activities of 210Po and 210Pb in the water column at Kuala Selangor, Malaysia

Natural radionuclides, such as (210)Po and (210)Pb were measured in the water samples collected from six stations at Kuala Selangor, Malaysia. Results for (210)Po and (210)Pb in dissolved and particulate phases have showed the difference in distribution and chemical behavior. The fluctuation activities of (210)Po and (210)Pb depend on wave action, geology and degree of fresh water input occurring at study areas and probably due to different sampling dates. The distribution coefficient, K(d), values of (210)Po and (210)Pb ranged from 2.0 x 10(3)lg(-1) to 265.15 x 10(5)lg(-1), and from 3.0 x 10(3)lg(-1) to 558.16 x 10(5)lg(-1), respectively. High K(d) values of (210)Po and (210)Pb indicated that a strong adsorption of (210)Po and (210)Pb onto suspended particles, and the sinking of both nuclides on the seabed at study locations were controlled by the characteristics of suspended particles.     

A study of the vertical diffusion of the cosmogenic radionuclides, 7Be and 22Na in the atmosphere

The study of the mean vertical concentration profile of cosmogenic radionuclides provides information on the vertical transport in the troposphere and stratosphere. This paper is based on the results of accurate measurements of the mean monthly activity concentrations of (7)Be and (22)Na in ground-level air, data of the production rate of cosmogenic radionuclides in the atmosphere and a one-dimensional steady-state diffusion equation numerically solving the finite difference approximation.     

三峡水库“水华”成因初探

2004年3月、5月、7月、8月、10月和2005年5月对长江干流29个站点进行了5次调查。2004年3月（旱季）在三峡库区坝前（秭归）发现藻类“水华”，藻类密度达2.73×106 cells/L，优势种类为拟多甲藻。2004年8月（雨季）和2005年4月（旱季）沿香溪河下游及河口区以及香溪河口到三峡大坝干流江段进行了2次6个断面分层调查，两次调查中在香溪河下游以及香溪河口区发现了严重的藻类“水华”，藻类密度高达1.87×107 cells/L 和1.67×107 cells/L，优势种分别为蓝隐藻（1.84×107 cells/L）和美丽星杆藻 (1.34×107 cells/L)。相关分析结果表明：三峡库区干流藻类数量和生物量与水库的出水流量有着显著的负相关(Spearman，r=-1.000, r=-0.900, p<0.05)，而与可溶性营养盐（NO3 N, PO4 P, SiO3 Si）的浓度无显著的相关性；在2004年7~8月（雨季）香溪河下游及河口区浮游植物生物量与主要营养盐（NO3 N, PO4 P,SiO3 Si）的浓度呈显著负相关（Spearman,p<0.01, p<0.05,p<0.01, n=21）；在2005年4月（旱季）该河段藻类密度与主要营养盐（NO3 N N,SiO3 Si）呈显著负相关 (Spearman, p<0.05，p<0.01,n=28)，但与PO4 P无显著的相关性。香溪河口到秭归的坝前库区河段藻类数量与主要营养盐（NO3 N, PO4 P,SiO3 Si）没有显著相关性(Spearman, │r│<0.2, n=20)。然而香溪河下游及河口区主要营养盐（NO3 N, PO4 P, SiO3 Si）浓度却低于长江干流。可以推断三峡库区蓄水后干流和支流发生“水华”的最主要原因是筑坝后库区内水动力条件的改变而非营养盐浓度较高。随着三峡工程的全面完工，库区内水体滞留时间的进一步延长，三峡库区水体富营养化趋势将会进一步加剧。     

A preliminary study on the use of (10)Be in forensic radioecology of nuclear explosion sites

Cosmogenic (10)Be, known for use in dating studies, unexpectedly is also produced in nuclear explosions with an atom yield almost comparable to (e.g.) (137)Cs. There are major production routes via (13)C(n, alpha)(10)Be, from carbon dioxide in the air and the organic explosives, possibly from other bomb components and to a minor extent from the direct fission reaction. Although the detailed bomb components are speculative, carbon was certainly present in the explosives and an order of magnitude calculation is possible. The (n, alpha) cross-section was determined by irradiating graphite in a nuclear reactor, and the resulting (10)Be estimated by Accelerator Mass Spectrometry (AMS) giving a cross-section of 34.5+/-0.7mb (6-9.3MeV), within error of previous work. (10)Be should have applications in forensic radioecology. Historical environmental samples from Hiroshima, and Semipalatinsk (Kazakhstan) showed two to threefold (10)Be excesses compared with the background cosmogenic levels. A sample from Lake Chagan (a Soviet nuclear cratering experiment) contained more (10)Be than previously reported soils. (10)Be may be useful for measuring the fast neutron dose near the Hiroshima bomb hypocenter at neutron energies double those previously available.     

Atmospheric versus lithogenic contribution to the composition of first- and second-order stream waters in Seoul and its vicinity

The spatial variations in the chemistry of first- and second-order stream waters (N = 65) were investigated in the easterly bound of Seoul in order to assess the effects of urban air pollution on surface water chemistry. The sulfate (SO4(2-)) was high (range 3.9-17.8 mg l(-1), mean 11.8 mg l(-1)) within 30 km away from the center of Seoul, compared to the levels (range 1.1-7.7 mg l(-1), mean 4.3 mg l(-1)) observed in remote areas (30-70 km away). Both graphical examination and statistical evaluation (variogram) of sulfate concentration data consistently showed the decrease of sulfate concentration with increasing distance. The results of mass balance modeling also indicate that the concentrations of SO4(2-), Cl- and Na+ may be affected mainly by dry/wet deposition. However, the spatial variations of major cations such as Ca2+ and Na+ are well explained by the reaction of rainwater with diverse rocks in the watercourse. The water type was found to change from Ca(-Na)-SO4) type to Ca(-a)-HCO3 type with the increasing distance. It is thus inferred that the pollutants like SO2 emitted from strong man-made source areas of Seoul are transported to the considerable distance (at least 30 km away) by westerlies and that such mechanism may lead to the changes of the anion composition in surface water. In the remote area (> 30 km away from Seoul), the stream water chemistry appears to be influenced more effectively by the weathering of rock-forming minerals.