Role and impact of CO2–rock interactions during CO2 storage in sedimentary rocks

Before implementing CO₂ storage on a large scale its viability regarding injectivity, containment and long-term safety for both humans and environment is crucial. Assessing CO₂–rock interactions is an important part of that as these potentially affect physical properties through highly coupled processes. Increased understanding of the physical impact of injected CO₂ during recent years including buoyancy driven two-phase flow and convective mixing elucidated potential CO₂ pathways and indicated where and when CO₂–rock interactions are potentially occurring. Several areas of interactions can be defined: (1) interactions during the injection phase and in the near well environment, (2) long-term reservoir and cap rock interactions, (3) CO₂–rock interactions along leakage pathways (well, cap rock and fault), (4) CO₂–rock interactions causing potable aquifer contamination as a consequence of leakage, (5) water–rock interactions caused by aquifer contamination through the CO₂ induced displacement of brines and finally engineered CO₂–rock interactions (6). The driving processes of CO₂–rock interactions are discussed as well as their potential impact in terms of changing physical parameters. This includes dissolution of CO₂ in brines, acid induced reactions, reactions due to brine concentration, clay desiccation, pure CO₂–rock interactions and reactions induced by other gases than CO₂. Based on each interaction environment the main aspects that are possibly affecting the safety and/or feasibility of the CO₂ storage scheme are reviewed and identified. Then the methodologies for assessing CO₂–rock interactions are discussed. High priority research topics include the impact of other gaseous compounds in the CO₂ stream on rock and cement materials, the reactivity of dry CO₂ in the absence of water, how CO₂ induced precipitation reactions affect the pore space evolution and thus the physical properties and the need for the development of coupled flow, geochemical and geomechanical models.     

The role of parental behaviour for the development of behaviour specific environmental norms – The example of recycling and re-use behaviour

Based on the norm activation theory we developed assumptions about how parents may influence specific pro-environmental behaviours (i.e. re-use of paper and recycling) of their children (age 8–10). A sample of 206 parent-child-dyads were investigated using questionnaires recording norm activation model variables for children (i.e. awareness of need, awareness of consequences, personal norm, subjective norm, pro-environmental behaviour), as well as communication behaviour and actual behaviour of parents. For both behaviours (re-use and recycling) two separate structural equation models were tested (N = 206 and N = 194). Model fit statistics indicate a good fit of empirical data and model structure for both behaviours, supporting our assumption that the norm activation model can be applied to pro-environmental behaviour of young children. Communication behaviour of parents had a different influence on the two respective behaviours. While parents seemed to influence their children's recycling behaviour via sanctions and their own behaviour, re-use of paper was mainly influenced via communication of problem knowledge.     

Updraft gasification of juniper wood biomass using CO2–O2 and Air (N2–O2)

Biomass gasification is being considered as one of the most promising technologies for converting low-quality solid biomass fuel into gaseous fuel. Redberry juniper (Juniperus pinchotii), one of the woody species that dominate uncultivated lands in the southern great plains, USA, may have a great potential for bioenergy utilization. In this study, the results of gasification of juniper are presented. Juniper wood chips were gasified in an adiabatic fixed bed updraft gasifier using air and the mixture gas of carbon dioxide and oxygen (CO₂:O₂) as gasification medium. The effect of gasification parameters such as moisture contents, gasification mediums, and gasification temperature on produced gas properties and the tar yield were investigated. It was observed that oxy fuel gasification (the reaction of woody fuels with carbon dioxide) of juniper resulted in the increase of production of carbon monoxide, especially at higher peak gasification temperatures. As a result, the CO₂ gasification resulted in producing higher heating value gas (6264 kJ/nm³ with dilution of CO₂ and 19,750 kJ/nm³ inert free) compared to air gasification. For air gasification, it was observed that the updraft gasification produced large amount of the tar in the product gas (more than 100 g/nm³) for the fuels with moisture content between 6% and 11%. Generally, the tar yield increased with the increase of equivalence ratio (er) and moisture content. However, when the fuel moisture content reached 23.5%, the tar yield reduced significantly due low gasification temperature which reduced the less tar cracking.     

Are mere instructions enough? Evaluation of four types of messaging on community depot recycling

Curbside recycling efforts have made an important contribution to waste containment, but many communities have specific limitations on what products can be recycled within their community bins (e.g., no cartons, styrofoam, soft plastics) and must rely on depots for recycling these other items. These specialty depots typically take the form of local community or large central municipal sites. The purpose of this randomized trial was to examine messages targeting (1) awareness/instructions, (2) utility, (3) affect, and (4) planning upon community and central depot recycling across eight weeks. One hundred and seventy-six community-dwelling residents between the ages of 18–65 years who self-identified as having the potential to improve their depot recycling activities completed baseline recycling measures and then were randomly assigned to one of the four messaging conditions. One hundred and forty-four of these participants subsequently answered follow-up recycling behavior measures four and eight weeks later. Intention to treat analyses showed that depot recycling increased significantly from baseline to four weeks. The effect waned for community recycling while holding for municipal depot recycling at eight weeks. Distance to recycling depot (closer proximity resulted in greater community recycling), access to a car (low access resulted in greater community recycling), and baseline recycling behavior (no prior recycling resulted in greater behavior change) all acted as significant moderators of the effect. There was no time by group interaction among conditions. The findings support the use of basic instructions – as a minimum – for promoting depot recycling efforts and provide evidence that local community depots, in conjunction with municipal depots, are important to increasing recycling behavior.     

The Great Recession or progressive energy policies? Explaining the decline in US greenhouse gas emissions forecasts

This paper evaluates the causes of the 23% decline in 2030 US greenhouse gas emissions forecasts between 2007 and 2011. Dynamic regression modeling predicts that the Great Recession contributed to about 67% of the 2008–2009 emissions decline, but then fell to about an 18% share for the 2030 emissions forecast. An analysis of electricity generation forecasts show that switching from coal to gas contributed only 6% to the total 2030 decline. In contrast, regulatory impact assessments and policy analysis showed that state and federal policies were responsible for 46% of the 2030 decline in emissions.     

The drivers of greenhouse gas emissions: What do we learn from local case studies?

Abstract

What can local case studies contribute to our understanding of the processes underlying the growth in greenhouse gas emissions? Since much abatement and mitigation are local in character, it is important that policy makers identify the mix of local, national and international processes that contribute to changes in greenhouse gas emissions. Drawing upon the results of case studies in Kansas, North Carolina and Ohio, how patterns of emissions in local areas can be connected analytically to the driving forces of environmental change is demonstrated. Emissions at the local level are empirically associated with the same set of trends found at national and international scale, namely, changes in population, affluence‐consumption and technology.     

The use of ionic liquids based on choline chloride for metal deposition: A green alternative?

Ionic liquids are studied intensively for different applications. They tend to be denoted as “green solvents”, largely because of their low vapour pressure. In recent years toxicity and biotoxicity of ionic liquids have also been investigated, which proved that not all of these are “green”. In this paper the use of ionic liquids based on choline chloride and ethylene glycol in electrochemistry is discussed in the context of their use as green solvents. Due to their low toxicity and ready biodegradability, these deep eutectic solvents are promising for the electrodeposition of metals. The influence of the use of these liquids as metal deposition baths on the waste water is investigated. Drag-out was found to be the most influencing parameter on the environmental impact of the process, as it is three times higher compared to classical solutions due to the higher viscosity of the ionic liquid. There are no major changes needed in the rinsing configuration of classic electroplating plants, and ion exchange to remove the metal out of the waste water was not hindered by the presence of the ionic liquid. The formation of by-products during the deposition of metals has to be further investigated and evaluated in consideration of the environmental impact.     

“By and for local people”: assessing the connection between local energy plans and community energy

ABSTRACT

“Community energy” (CE) is argued to be an opportunity to transition to low-carbon energy systems while creating additional benefits for local communities. CE is defined as energy initiatives that place a high degree of emphasis on participation of local community members through ownership and control, where through doing so, benefits are created for the community. The trend has seen considerable growth in many countries over the last decade. Occurring simultaneously is a trend for local communities (e.g. municipalities) to create their own Local Energy Plans (LEPs) – a planning process that articulates energy-related actions (i.e. expected outcomes). While CE and LEPs both address energy activities in a local context, any further connection between these trends remains unclear.

This research develops a framework, based on CE and LEP literature, to assess LEPs for their relevance to CE. The research analyses 77 LEPs from across Canada for the ways in which they address the three components that define CE: community participation, community ownership, and community capacity. The main findings are that LEPs have emerged as a process that is both relevant to CE and capable of strategically addressing its components. Despite this, LEPs do not appear to reveal a radically different approach to the “closed and institutional” models of traditional community involvement practices. The investigation suggests that for CE advocates, LEPs may be considered to be an important avenue to pursue CE ambitions. LEPs could increase their relevance to CE by improving the processes and actions related to all three CE components.     

Effects of aircraft noise and speech on prose memory: What role for working memory capacity?

Previous research indicates that aircraft noise and meaningful background speech are particularly detrimental to school adolescents' ability to remember what they read, but until now the effects from aircraft noise and speech have never been compared directly in an experiment. Furthermore, individual differences in susceptibility to these effects are not well understood. The present investigation addressed these two issues. Adolescents attending upper secondary school were recruited as participants and the data collection was made in their ordinary classrooms. The results from two experiments revealed that speech is more detrimental to prose memory than is aircraft noise, and individual differences in working memory capacity contributes more to individual differences in susceptibility to the effects of aircraft noise on prose memory than to the effects of speech. Some applied implications of those findings to noise abatement interventions are suggested.     

Gender,age and subject matter: impact on teachers’ ecological values

By means of environmental education, teachers are supposed to intervene in pupils’ awareness and concern of environmental issues. Teachers’ environmental attitudes, however, have rarely been studied. We analysed 367 German pre- and in-service teachers’ environmental attitudes for their structure and socio-economic correlates within the frame of a European project. Thus, we retrieved for adults the two-dimensional model of ecological values (2-MEV) presented for adolescents by Bogner and Wiseman (Sci Educ Int 15(1):27–48, 2004). For the two domains, Preservation and Utilisation, the psychometric structure was confirmed and discriminative correlations with age, gender and teaching subject were unveiled. Further research is needed to deduce the implications for teaching practice.     

Consuming for the Sake of Others: Whose Interests Count on a Market for Animal-Friendly Products?

Many Europeans are concerned about the living conditions of farm animals because they view animals as beings that possess interests of their own. Against this background the introduction of an animal welfare label is being intensively discussed in Europe. In choosing a market-based instrument to take these concerns into account, normative judgments are made about the formation of preferences, the value system that is implicitly assumed, and the distribution of property rights. From the perspective of classical institutional economics it can be shown that the introduction of a label as an institutional change does not redefine institutions in a way that allows them to consider the interests of animals for their own sake. Rather, the label only redefines the property rights that humans have over animals. The market segregation into privileged and normal animals conflicts with the idea of equality between sentient animals. Within the group of humans only the interests of those who act on markets count. The commodification of their moral concerns assumes that people always decide based on their own interests, which can be traded off. The lexicographical ordering of preferences, which occurs when humans view animals as entities with rights, is not compatible with the normative assumptions of markets. Furthermore, interpreting animal suffering as market failure that can be corrected by labeling impedes a reasoned dialog within the society about the values and beliefs that serve as a basis for preference formation. Thus, an animal welfare label cannot replace a fundamental societal debate about legal standards on animal well-being.     

Investigations on CO2 storage capacity in saline aquifers—Part 2: Estimation of storage capacity coefficients

Many studies on geological carbon dioxide (CO₂) storage capacity neglect the influence of complex coupled processes which occur during and after the injection of CO₂. Storage capacity is often overestimated since parts of the reservoirs cannot be reached by the CO₂ plume due to gravity segregation and are thus not accessible for storage. This work investigates the effect of reservoir parameters like depth, temperature, absolute and relative permeability, and capillary pressure on the processes during CO₂ injection and thus on estimates of effective storage capacity. The applied statistical characteristics of parameters are based on a large reservoir parameter database. Different measured relative permeability relations are considered. The methodology of estimating storage capacity is discussed. Using numerical 1D and 3D experiments, detailed time-dependent storage capacity estimates are derived. With respect to the concept developed in this work, it is possible to estimate effective CO₂ storage capacity in saline aquifers. It is shown that effective CO₂ mass stored in the reservoir varies by a factor of 20 for the reservoir setups considered. A high influence of the relative permeability relation on storage capacity is shown.     

International and European Law on Protected Areas and Climate Change: Need for Adaptation or Implementation?

The protection and management of protected areas must be adapted to the effects of climate change. An important question is if the law on protected areas is capable of dealing with the required changes. In general, both international nature conventions and European Union nature conservation law do not contain any specific provisions on climate change and protected areas. Attention has been paid to this link in non-binding decisions and policy documents. In order to adapt the law to increased dynamics from climate change, more flexibility is needed. This flexibility should not be understood as “legal” flexibility, in the sense of the weakening nature conservation provisions. Scientific uncertainties on the effects of climate change might conflict with the need for legal certainties. In order to adapt to the effects of climate change, the two crucial elements are the strengthening of core protected areas and connectivity between the core areas. At the international level, both elements can be found in non-binding documents. International law enables the required adaptation; however, it often lacks concrete obligations. A stronger legal framework can be found at the level of the European Union. The Birds and Habitats Directives contain sufficient tools to deal with the effects of climate change. The Directives have been insufficiently implemented so far. Especially the central goals of reaching a favorable conservation status and connectivity measures need to be addressed much more in the future.     

Potential CO2 emission reduction for BF–BOF steelmaking based on optimised use of ferrous burden materials

Currently, the blast furnace (BF) to basic oxygen furnace (BOF) is the dominant steel production route in the steel industry. The direct CO₂ emission in this process system exceeds 1 t of CO₂/t of crude steel produced. Different ferrous burden materials, for instance iron ore and scrap, can be used in various proportions in this steelmaking route. This paper analyses how energy use, conversion costs, and CO₂ emissions can be influenced by the use of different ferrous burden materials when producing crude steel. An optimisation mixed integer linear programming (MILP) model has been applied for analysis. By the use of the optimisation model, it is possible to highlight some issues of special importance, such as best practices to increase production at low conversion cost, or best practices to increase production at low CO₂ emission. It is found out that more benefits will be gained when using the system-oriented analysis to the steelmaking process. Furthermore, a comprehensive view of the trade-offs between the objectives of Cost and CO₂ can provide useful information for decision makers to generate strategies under the future emission trading.     

Well-being for all? The social distribution of benefits gained from woodlands and forests in Britain

Well-being is a positive physical, mental and social state and has increasingly become an area of interest to researchers and policy-makers internationally. This paper presents results from research that analyses the well-being benefits gained by different sections of society through viewing, engaging with, and accessing woodlands and forests in Britain. We draw on 31 studies undertaken since 2001 and present a meta-analysis of quantitative data and a meta-synthesis of qualitative data to explore the range of benefits and associated activities in woodlands, and their social distribution. We also present a state-of-the-art typology of well-being benefits for woodlands in Britain. The findings illustrate the wide range of well-being benefits gained by different social groups through various forms of engagement with and activities undertaken in woodlands. We illustrate the wide range of meanings and values attached to trees and woodlands across different social groups. The evidence also illustrates how carefully designed and targeted interventions can be particularly effective in enabling and encouraging people to visit woodland sites, to participate or get involved in new activities and, therefore, to realise a range of well-being benefits.     

Greenery on residential buildings: Does it affect preferences and perceptions of beauty?

Recently there has been a surge in the number of green roofs and façades (vegetation on the roofs & walls of a building) installed in the UK, with advocation of their use by policy-makers and claims that they are aesthetically pleasing and promote restoration. But these claims rely on generalisations from different landscapes, raising concerns about validity. The present study examined whether houses with vegetation would be more preferred than those without, be perceived as more beautiful and restorative, and have a more positive affective quality. Differences between types of building-integrated vegetation were also examined. Two studies were conducted: an online survey in which participants (N = 188) rated photographs of houses with and without vegetation on each of these measures, and interviews (N = 8) which examined preference and installation concerns. Results showed that houses with (some types of) building-integrated vegetation were significantly more preferred, beautiful, restorative, and had a more positive affective quality than those without. The ivy façade and meadow roof rated highest on each. These findings are consistent with other areas of landscape research and the claims of those in the industry, and suggest that building-integrated vegetation would be a valuable addition to the urban environment.