Dry deposition (downward, upward) concentration study of particulates and heavy metals during daytime, nighttime period at the traffic sampling site of Sha-Lu, Taiwan

Downward, upward dry deposition fluxes and total suspended particulate of particulate heavy metals (Fe, Pb, Zn, Cu, Mg and Mn) were measured in daytime and nighttime period in Sha-Lu, a small city in the central Taiwan during summer period of 2003. The results showed that the total suspended particulate concentrations of particulate mass in the daytime period (averaged 996.2 g/m3) were higher than in nighttime period (averaged 560.7 g/m3). And the downward dry deposition fluxes (averaged 54.07 g/m2s) were about two times as that of upward dry deposition fluxes (averaged 26.48 g/m2s) in the daytime period. Furthermore, the average downward dry deposition fluxes (averaged 26.22 g/m2s) were also about two times as that of upward dry deposition fluxes (averaged 12.11 g/m2s) in the nighttime period. In addition, the average downward dry deposition fluxes are greater than the upward dry deposition fluxes for all the heavy metals in either daytime or nighttime period. The proposed reasons are that the wind speed and concentration difference for daytime and nighttime period lead to these results at the traffic sampling site of central Taiwan. In addition, the deposition velocity for mass, heavy metals (Fe, Pb, Zn, Cu, Mg and Mn) during daytime and nighttime period were also calculated. The average daytime dry deposition velocity for downward particulate mass, upward particulate mass, Fe, Pb, Zn, Cu, Mg and Mn were 5.56, 2.66, 1.71, 0.18, 1.06, 0.24, 0.47 and 0.11 (cm/s), respectively. And the average nighttime dry deposition velocity for downward particulate mass, upward particulate mass, Fe, Pb, Zn, Cu, Mg and Mn were 4.70, 2.11, 1.66, 0.18, 0.86, 0.23, 0.32 and 0.07 (cm/s), respectively at traffic sampling site of central Taiwan.     

Particulates and Metallic Elements Monitoring at Two Sampling Sites (Harbor,Airport) in Taiwan

This study characterized the dry deposition flux and dry deposition velocity (Vd) of metallic elements attached on particulate matter. Specifically, large particles (>10 μm), coarse particles (10 μm～2.5 μm), and fine particles (<2.5 μm) were studied at the Gong Ming Junior High School (Taichung Airport) and Taichung Harbor sampling sites in central Taiwan. Ambient air samples were collected to determine total suspended particulate matter (TSP), dry deposition plate (DDP), Vd, coarse particulate matter (PM_2.5–10) and fine particulate matter (PM_2.5), and metallic elements concentrations at the Airport and Taichung Harbor sites between June 17, 2013, and November 14, 2013. The results revealed that the average TSP, DDP, Vd, PM_2.5–10, and PM_2.5 particulate at the Airport were 54.55 (μg/m³), 902.25 (μg/m²-min), 17.11 (m/sec), 0.003 (μg/m³), and 0.010 (μg/m³), respectively; while these values at Taichung Harbor were 63.66 (μg/m³), 539.69 (μg/m²-min), 9.94 (m/sec), 0.003 (μg/m³), and 0.014 (μg/m³), respectively. In addition, the results showed that the average Cu and Pb concentrations were higher than Cr, Ni, and Cd for both the airport and harbor sampling sites. Furthermore, Cr, N, Cu, Cd, and Pb had the highest average concentrations versus those reported for other study areas, with one exception: The results obtained in Kacanik, Kosovo, during 2005. The average metallic elements concentrations order was Cu > Pb > Cr > Ni > Cd.     

Comparisons of ambient air particulates concentrations (TSP,PM2.5) and dry depositions during smog and non-smog periods at Luliao,Shalu District sampling site

The concentrations of ambient total suspended particulates (TSP) and PM_2.5, and the dry depositions at a sample site at Luliao Junior High School (Luliao) in central Taiwan were measured during smog and non-smog days between December 2017 and July 2018. The results are compared to those obtained during non-smog periods in the years 2015–2017. The mean TSP and PM_2.5 concentrations and dry deposition flux were 72.41?±?26.40, 41.88?±?23.51?μg/m³, and 797.57?±?731.46?μg/m² min, respectively, on the smog days. The mean TSP and PM_2.5 concentrations and dry deposition flux on the non-smog days were 56.39?±?18.08, 34.81?±?12.59?μg/m³ and 468.93?±?600.57?μg/m² min, respectively. The mean TSP concentration in the smog period was 28% greater than that in the non-smog period, and the mean PM_2.5 concentration was 20% higher. The mean dry deposition flux in the smog period was 70% higher than that in the non-smog period at Luliao. The PM_2.5 concentrations exceeded the standards set by the Taiwan EPA (35?μg/m³ daily, and 15?μg/m³ annually). Therefore, the TSP and PM_2.5 concentrations and dry deposition must be reduced in central Taiwan on smog days. In addition, atmospheric TSP and PM_2.5 concentrations at various sampling sites were compared, and those herein were not higher than those measured in other countries. Finally, apart from the local traffic emissions, during smog periods, the other pollution source originated from the transportation process of traffic pollutants emitted in the northwest side of Taiwan.     

Characterization of atmospheric particulate and metallic elements at Taichung Harbor near Taiwan Strait during 2004-2005

Air aerosol samples for TSP (total suspended particulate), coarse particulate (particle matter with aerodynamical diameter 2.5–10 μm, PM_2.5–10), fine particulate (particle matter with aerodynamical diameter <2.5 μm, PM_2.5) and metallic elements were collected during March 2004 to January 2005 at TH (Taichung Harbor) in central Taiwan. The seasonal variation average concentration of TSP (total suspended particulate), coarse particulate (particle matter with aerodynamical diameter 2.5–10 μm, PM_2.5–10) and fine particulate (particle matter with aerodynamical diameter <2.5 μm, PM_2.5) were in the range 132–171.1 μg m⁻³ and 43–49.5 μg m⁻³, respectively. Seasonal variation of metallic elements Cu, Mn, Zn and Fe in the TSP (total suspended particulate) shows that higher concentration was observed during spring. Seasonal variation of metallic elements Pb, Cr and Mg in the TSP (total suspended particulate) shows that higher concentration was observed during winter. The average metallic element TSP (total suspended particulate) concentration order was Fe > Zn > Mg > Cu > Cr > Mn > Pb in spring. In addition, at the TH sampling site, the average concentration variation of TSP (total suspended particulate) displayed the following order: spring > winter > autumn > summer. However, the average concentration variation of coarse particulate (particle matter with aerodynamical diameter 2.5–10 μm, PM_2.5–10) displayed the following order: spring > winter > summer > autumn. Finally, the average concentration variations of fine particulate (particle matter with aerodynamical diameter <2.5 μm, PM_2.5) were in the following order: winter > spring > summer > autumn at the TH sample site.     

Characteristic study of particulates and metallic elements at an urban sampling site in Taichung, central Taiwan

Atmospheric total suspended particulate concentrations and metallic element concentrations were measured at three locations, characteristic of urban, suburban and rural sites. The sampling period was from July 2000 to August 2000. The results indicated that the urban sampling site had the highest total suspended particulate concentrations (average 108.61μ1m3), followed by the suburban site (average 60.11μ1m3) and the rural site (average 53.31μ1m3). The average PM_2.5 concentrations (24.11μ1m3) were higher than the PM_2.5-10 concentrations (12.81μ1m3) at the urban site. The average distributed ratios for PM_2.5/PM_2.5-10 were about 1.29, 1.53, 0.12, 1.12 and 2.31 for Pb, Zn, Fe, Ni and Cr, respectively. The average total suspended particulate mass ratios for daytime and nighttime were about 1.72. As for the elements Cu, Pb, Zn, Fe, Ni and Cr, these ratios were about 0.63, 0.97, 0.54, 1.66, 0.53 and 1.12, respectively. The total suspended particulate daytime concentrations of Pb and Zn were positively correlated (R = 0.925) at the urban sampling site. The elements Ni and Cr were positively correlated both during the daytime (R = 0.648) and the nighttime (R = 0.511), revealing that they came from the same emission source during daytime and nighttime, at the urban sampling site.     

Factors contributing to seasonal variations in wet deposition fluxes of trace elements at sites along Japan Sea coast

In this study, we measured the wet deposition fluxes of ten trace elements (As, Cd, Cr, Cu, Mn, Ni, Pb, Sb, V and Zn) from December 2002 to March 2006 at three sites along the Japan Sea coast, which have been strongly affected by the long-range transport of air pollutants from the Asian continent. Also, factors, contributing to their seasonal variations were investigated. At the northern and central sites, the monthly wet deposition fluxes of all or most trace elements greatly increased during the cold season (typically, November–April), along with their monthly average (volume-weighted) concentrations in the precipitation. The cold/warm season ratios for the average concentrations of trace elements in precipitation were within the range of 2.7–5.1 at the northern site and 1.8–5.9 at the central site, which were similar to the average scavenging ratios (= concentration in precipitation/concentration in air) at each site. However, there were small differences (0.47–1.2 at the northern site and 0.73–1.7 at the central site) in the ratios of average concentrations in air between the two seasons. These suggest that the increase in the wet deposition fluxes of trace elements during the cold season is due to increases in their scavenging ratios. On the other hand, the result for the southern site was different from those at the other sites. The number of days when the daily maximum wind speed exceeded 10 m s^?1 at the meteorological observatories near the study sites increased markedly during the cold season at the northern and central sites, showing that strong winds usually blow during the cold season at those sites, but not at the southern site. Higher wind speed transports larger amounts of constituents into the cloud system, which can result in their increased concentrations in precipitation. Thus, high scavenging ratios of trace elements during the cold season may be caused by the increase in their amounts of discharge into the cloud system owing to high wind speed, suggesting that wind speed is an important factor in the seasonal variations in the wet deposition fluxes.     

Characteristics and impacts of trace elements in atmospheric deposition at a high-elevation site,southern China

To investigate the regional background trace element (TE) level in atmospheric deposition (dry and wet), TEs (Fe, Al, V, Cr, Mn, Ni, Cu, Zn, As, Se, Mo, Cd, Ba, and Pb) in 52 rainwater samples and 73 total suspended particles (TSP) samples collected in Mt. Lushan, Southern China, were analyzed using inductively coupled plasma-mass spectrometry (ICP-MS). The results showed that TEs in wet and dry deposition of the target area were significantly elevated compared within and outside China and the volume weight mean pH of rainwater was 4.43. The relative contributions of wet and dry depositions of TEs vary significantly among elements. The wet deposition fluxes of V, As, Cr, Se, Zn, and Cd exceeded considerably their dry deposition fluxes while dry deposition dominated the removal of pollution elements such as Mo, Cu, Ni, Mn, and Al. The summed dry deposition flux was four times higher than the summed wet deposition flux. Prediction results based on a simple accumulation model found that the content of seven toxic elements (Cr, Ni, Cu, Zn, As, Cd, and Pb) in soils could increase rapidly due to the impact of annual atmospheric deposition, and the increasing amounts of them reached 0.063, 0.012, 0.026, 0.459, 0.076, 0.004, and 0.145 mg kg^?1, respectively. In addition, the annual increasing rates ranged from 0.05% (Cr and Ni) to 2.08% (Cd). It was also predicted that atmospheric deposition induced the accumulation of Cr and Cd in surface soils. Cd was the critical element with the greatest potential ecological risk among all the elements in atmospheric deposition.     

The study of TSP, PM(2.5-10) and PM2.5 during Taiwan Chi-Chi Earthquake in the traffic site of central Taiwan, Taichung

Ambient particle concentration was taken on the traffic sampling site over the Chung-Chi Road over bridge (CCROB) in front of Hungkuang Institute of Technology (HKIT). The sampling time was from August 1999 to December 1999. During the sampling period, Taiwan's biggest earthquake in more than a century registered 7.3 on the Richter scale (Taiwan Chi-Chi Earthquake). Besides, there were more than 20,000 aftershocks that followed the Taiwan Chi-Chi Earthquake within three months. Thus, the PM2.5, PM(2.5-10) particle concentrations were also collected then and compared with total suspended particle (TSP) in this study. The average PM(2.5-10), PM2.5 and TSP concentrations are 24.6, 58.0 and 106 microg/m3, respectively, after the Taiwan Chi-Chi Earthquake. The average TSP concentrations before and after Taiwan Chi-Chi Earthquake were 70 and 127 microg/m3, respectively. It is clearly shown that the average concentration of TSP after Taiwan Chi-Chi Earthquake was about 1.8 times as that of TSP concentration before Taiwan Chi-Chi Earthquake in the traffic site of central Taiwan. And the ratios of PM2.5/PM(2.5-10), PM2.5/PM10 and PM2.5/TSP are 2.2%, 67.2%, 38.9%, respectively. The results also indicated about Chi-Chi fine particle concentration (PM25) and the TSP increases in the traffic site of central Taiwan after Taiwan Chi-Chi Earthquake.     

Dry deposition, ionic species measured and source interpretation during seasonal cycle at offshore areas near Taiwan Strait

The characterization for water-soluble species of total suspended particulate (TSP), dry deposition flux, and dry deposition velocity (V(d)) were studied at Taichung Harbor (TH) and Wuchi traffic sampling sites at offshore sampling site near Taiwan Strait of central Taiwan during March 2004-January 2005. The average concentrations of TSP and dry deposition flux at the TH sampling site were higher than at the WT sampling site during the sampling period. The samples collected were analyzed by a ion chromatography (DIONEX-100) for the ionic species (Cl(-), SO(4)(2-), NO(3)(-), NH(4)(+), Na(+), Ca(2+), and Mg(2+)) analysis. The dominant ionic species for TSP are SO(4)(2-), NO(3)(-), and NH(4)(+) of the total mass of the inorganic ions at both sampling sites. In addition, the results indicated that the NH(4)(+), NO(3)(-) and SO(4)(2-) showed higher concentrations in winter and lower in summer for both TH and Wuchi sampling sites. Statistical methods such as correlation coefficient and principal component analysis were also used to identify the possible pollutant source.     

Trace elements in size-segregated urban aerosol in relation to the anthropogenic emission sources and the resuspension

Size segregated particulate samples of atmospheric aerosols in urban site of continental part of Balkans were collected during 6 months in 2008. Six stages impactor in the size ranges: Dp?≤?0.49 μm, 0.49?2?≈?30 %) followed by traffic (PC2, σ²?≈?20 %) that are together contributing around 50 % of elements in the investigated urban aerosol. The EF model shows that major origin of Cd, K, V, Ni, Cu, Pb, Zn, and As in the fine mode is from the anthropogenic sources while increase of their contents in the coarse particles indicates their deposition from the atmosphere and soil contamination. This approach is useful for the assessment of the local resuspension influence on element’s contents in the aerosol and also for the evaluation of the historical pollution of soil caused by deposition of metals from the atmosphere.     

Atmospheric dry deposition fluxes of trace elements measured in Bursa, Turkey

Trace element dry deposition fluxes were measured using a smooth, greased, knife-edge surrogate surface (KSS) holding greased Mylar strips in Bursa, Turkey. Sampling program was conducted between October 2002 and June 2003 and 46 dry deposition samples were collected. The average fluxes of crustal metals (Mg, Ca, and Fe) were one to four orders of magnitude higher than the fluxes of anthropogenic metals. Trace element fluxes ranged from 3 (Cd) to 24,230 (Ca) microg m(-2) d(-1). The average trace element dry deposition fluxes measured in this study were similar to those measured in other urban areas. In addition, ambient air samples were also collected simultaneously with flux samples and concentrations of trace elements, collected with a TSP sampler, were between 0.7 and 4900 ng m(-3) for Cd and Ca, respectively. The overall trace element dry deposition velocities, calculated by dividing the fluxes to the particle phase concentrations ranged from 2.3+/-1.7 cm s(-1) (Pb) to 11.1+/-6.4 cm s(-1) (Ni). These values are in good agreement with the values calculated using similar techniques. The anthropogenic and crustal contributions were estimated by employing enrichment factors (EFs) calculated relative to the average crustal composition. Low EFs for dry deposition samples were calculated. This is probably due to contamination of local dust and its important contribution to the collected samples.     

Metallic elements in particulates released during incense-burning at Tzu Yun Yen temple, Taichung, Taiwan

Concentrations of ambient suspended particulates were measured at Tzu Yun Yen temple (120°, 34′ 10”E; 24°, 16′, 12”N), using a Universal sampler and dry deposition plates. The temple is a characteristic incense-burning and semi-open sampling site. PM_2.5 concentrations for Period 1 (average 901μg/m3) were higher than those for Period 2 (average 701μg/m3). Results for average PM_2.5-10concentrations showed equal distributions in Period 1 and Period 2. Average ratios of PM_2.5/ PM₁₀ were higher in Period 1 (74%) than Period 2 (71%). In addition, the suspended particulate (PM₁₀) elements concentrations during Zhong Yuan Jie, and the first and 15th days of nong li for each month (Chinese lunar calendar) were all higher than during non-Zhong Yuan Jie and non-first and non-15th days. Furthermore, the dry deposition velocities of manganese in fine particulates (PM_2.5) and suspended particulates (PM₁₀) were 1.43 and 0.751cm/s, respectively, and the dry deposition velocities of cadmium in fine particulates (PM_2.5) and suspended particulates (PM₁₀) were 1.86 and 0.991cm/s, respectively.     

Source characterization for atmospheric trace metals over Kiel Bight

Atmospheric concentrations of Na, Al, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, As, Se, Rb, Sr, Ba and Pb are reported for 59 weekly air filter samples collected over the Kiel Bight. The contributions of sea salt, mineral dust and anthropogenic emissions to each of these elements were assumed to be represented by the concentrations of indicator elements, which were Na, Al and Zn, respectively. Based on this assumption a multiple regression analysis was applied to the concentration data. The results showed that atmospheric sea salt contributed significantly only to Sr and, of course, Na. Considerable portions of Al, K, Ca, Ti, Cr, Mn, Fe, Rb, Sr and Ba were derived from mineral dust. Anthropogenic sources were responsible for total V, Ni, Cu, Zn, As and Pb, and there was an anthropogenic component for most of the other elements.Moreover, the anthropogenic contribution was characterized by a nearly constant composition with respect to Ca, Ti, Cr, Mn, Fe, Cu, Zn, As, Rb, Sr, Ba and Pb, indicating that trace metals over the Kiel Bight are mainly derived from one source area. This conclusion was confirmed by correlating anthropogenic trace metal concentrations with the wind direction. A 40° wind sector directed to the south of the sampling site was identified as the major pathway for the transport of anthropogenic trace metals to the Kiel Bight.     

Effect of wind speed on the atmospheric levels of particles produced by traditional and non traditional sources on the island of curacao

The TSP, SO₄⁼ and Pb levels observed downwind of a large refinery and in the city of Willemstad in Curaçao are presented. The results show that wiht increasing wind speed TSP and SO₄⁼ levels increase while Pb levels decrease. On the other hand, at relatively constant wind speeds a good correlation between TSP and Pb was observed.The correlation observed between TSP, SO₄⁼ and Pb and the wind speed, the effect of rain on the atmospheric levels observed during the sampling period, the lack of secondary pollutants (e.g. ozone, NO₃^?) and the composition of the island background air, allow us to conclude that the SO₄⁼ measured at the monitoring sites is mainly produced as a primary pollutant in the refinery, the high atmospheric TSP levels are due to refinery emissions (traditional source) and the recirculation of street dust particles (non traditional source) produced by traffic and the predominantly high wind velocity.The implication on air quality and control measures are discussed.     

Dry deposition and foliar leaching of mercury and selected trace elements in deciduous forest throughfall

The estimated annual throughfall deposition flux of Hg in a northern mixed-hardwood forest in the Lake Huron Watershed was 10.5±1.0 μg m⁻² compared to an annual precipitation Hg flux of 8.7±0.5 μg m⁻² (June 1996–June 1997). The source of this additional Hg in throughfall is often attributed to wash-off of dry deposition, but foliar leaching of Hg may also be important. To determine the influence of both dry deposition and foliar leaching of Hg and other elements in throughfall, we measured a suite of trace elements (Hg, Al, Mg, V, Mn, Cu, Zn, As, Rb, Sr, Cd, Ba, La, Ce, and Pb) in throughfall, precipitation, and ambient air samples from a northern mixed-hardwood forest. Based on a multiple linear regression model, dry deposition had the most important influence on Hg, Al, La, Ce, V, As, Cu, Zn, Cd, and Pb fluxes while foliar leaching strongly influenced Mg, Mn, Rb, Sr, and Ba fluxes in net throughfall. The Hg dry deposition flux was estimated using gaseous and aerosol Hg measurements and modeled deposition velocities. The calculated dry deposition flux (∼12–14 μg m⁻²) of Hg to the canopy indicated that atmospheric deposition of Hg could easily account for all of the Hg deposited in net throughfall (1.9±0.1 μg m⁻²). Although there is a large uncertainty associated with these techniques, the modeling estimates indicate that atmospheric Hg may account for all of the Hg deposited in litterfall (11.4±2.8 μg m⁻²).     

Overall dry deposition velocities of trace elements measured at harbor and traffic site in central Taiwan

For reasonable and convenient assessments of the characteristics of the dry deposition velocities between Taichung harbor site and Wuchi town site in central Taiwan, the overall dry deposition velocities of several metallic elements were calculated as the particulate diameter (D(p)) distributions of large particles (D(p) > 10 microm), coarse particles (10 microm < D(p) < 2.5 microm), and fine particles (D(p) < 2.5 microm) based on the ambient measurements during March-December of 2004. In this work, the dry deposition fluxes showed the higher correlation with coarse particle concentrations than large particle concentrations; however, the least well correlation was observed between the dry deposition fluxes and the fine particle concentrations. The calculated best-fit overall dry deposition velocities obtained using coarse particle concentrations varied from approximately 0.2 cm s(-1) for Cr to 1.5 cm s(-1) for Pb and 0.2 cm s(-1) for Fe to 2.6 cm s(-1) for Pb at Taichung harbor and Wuchi town site, respectively. In general, the crustal elements had higher deposition velocities than anthropogenic elements. In addition, overall dry deposition velocities for crustal elements were higher in Wuchi town site than in Taichung harbor site. The results identified the dry deposition flux was mainly contributed from large and coarse particles due to their high deposition velocities. The results also indicated that the best approach to estimate overall dry deposition was by depending on the characteristics of particles with diameters larger than 2.5 microm.     

Concentration,size, and density of total suspended particulates at the air exhaust of concentrated animal feeding operations

Total suspended particulate (TSP) samples were seasonally collected at the air exhaust of 15 commercial concentrated animal feeding operations (CAFOs; including swine finishing, swine farrowing, swine gestation, laying hen, and tom turkey) in the U.S. Midwest. The measured TSP concentrations ranged from 0.38 ± 0.04 mg m^?3 (swine gestation in summer) to 10.9 ± 3.9 mg m^?3 (tom turkey in winter) and were significantly affected by animal species, housing facility type, feeder type (dry or wet), and season. The average particle size of collected TSP samples in terms of mass median equivalent spherical diameter ranged from 14.8 ± 0.5 µm (swine finishing in winter) to 30.5 ± 2.0 µm (tom turkey in summer) and showed a significant seasonal effect. This finding affirmed that particulate matter (PM) released from CAFOs contains a significant portion of large particles. The measured particle size distribution (PSD) and the density of deposited particles (on average 1.65 ± 0.13 g cm^?3) were used to estimate the mass fractions of PM₁₀ and PM_2.5 (PM ≤10 and ≤2.5 μm, respectively) in the collected TSP. The results showed that the PM₁₀ fractions ranged from 12.7 ± 5.1% (tom turkey) to 21.1 ± 3.2% (swine finishing), whereas the PM_2.5 fractions ranged from 3.4 ± 1.9% (tom turkey) to 5.7 ± 3.2% (swine finishing) and were smaller than 9.0% at all visited CAFOs. This study applied a filter-based method for PSD measurement and deposited particles as a surrogate to estimate the TSP’s particle density. The limitations, along with the assumptions adopted during the calculation of PM mass fractions, must be recognized when comparing the findings to other studies.

Implications: The concentration, size, and density of TSP samples varied greatly with animal species, housing facility type, feeder type, and season, suggesting that PM emission data derived from limited measurements may not be readily applied to estimate the overall emission from concentrated animal feeding operations (CAFOs). This study also affirmed that particles released from CAFOs is of relatively high density (~1.65 g cm^?3) and with diameter mostly larger than 10 µm, indicating that regular PM abatement devices, such as cyclones, fabric filters, or even a simple downward-facing exhaust duct, may be employed to mitigate the TSP emission with acceptable efficiency.     

Contents and Leachability of Heavy Metals (Pb,Cu, Sb,Zn, As) in Soil at the Pantex Firing Range,Amarillo, Texas

ABSTRACT

Pantex firing range soil samples were analyzed for Pb, Cu, Sb, Zn, and As. One hundred ninety-seven samples were collected from the firing range and vicinity area. There was a lack of knowledge about the distribution of Pb in the firing range, so a random sampling with proportional allocation was chosen. Concentration levels of Pb and Cu in the firing range were found to be in the range of 11-4675 and 13-359 mg/kg, respectively. Concentration levels of Sb were found to be in the range of 1-517 mg/kg. However, the Zn and As concentration levels were close to average soil background levels. The Sn concentration level was expected to be higher in the Pantex firing range soil samples. However, it was found to be below the neutron activation analysis (NAA) detection limit of 75 mg/kg.

Enrichment factor analysis showed that Pb and Sb were highly enriched in the firing range with average magnitudes of 55 and 90, respectively. Cu was enriched ~6 times more than the usual soil concentration levels. Tox-icity characteristic leaching procedure (TCLP) was carried out on size-fractionated homogeneous soil samples. The concentration levels of Pb in leachates were found to be ~12 times higher than the U.S. Environmental Protection Agency (EPA) regulatory concentration level of 5 mg/L. Sequential extraction (SE) was also performed to characterize Pb and other trace elements into five different fractions. The highest Pb fraction was found with organic matter in the soil.     

Elemental and organic carbon in urban canyon and background environments in Budapest,Hungary

As part of an international research project, aerosol samples were collected by several filter-based devices on Nuclepore polycarbonate membrane, Teflon membrane and quartz fibre filters over separate daylight periods and nights, and on-line aerosol measurements were performed by TEOM and aethalometer within an urban canyon (kerbside) and at a near-city background site in Budapest, Hungary from 23 April–5 May 2002. Aerosol masses in PM2.0, PM10–2.0, PM2.5, PM10 size fractions and of TSP were determined gravimetrically; atmospheric concentrations of organic (OC) and elemental carbon (EC) for PM2.5 (or PM2.0), PM10 fractions and for TSP were measured by thermal–optical transmission method. Repeatability of the mass determination by Nuclepore filters seems to be 5–6%. Collections on Teflon filters yielded smaller mass on average by 8(±12)% than that for the Nuclepore filters. Quartz filters overestimated the PM10 mass in comparison with the Nuclepore filters due primarily to sampling artefacts on average by 10(±16)% at the kerbside. Tandem filter set-ups were utilised for correcting the sampling artefacts for OC by subtraction method. At the kerbside, the aerosol mass was made up on average of 35(±4)% of organic matter (OM) in the PM10 fraction, while the contribution of OM to the PM2.5 mass was 43(±9)%. At the background, OM also accounted for 43(±13)% of the PM2.0 mass. On average, EC made up 14(±6)%, 7(±2)% and 4.5(±1.1)% of the mass in the PM2.5, PM10 fractions and TSP, respectively, at the kerbside; while its contribution was only 2.1(±0.5)% in the PM2.0 fraction in the near-city background. Temporal variability for PM mass, OC and EC concentrations was related to road traffic, local meteorology and long-range transport of air masses. It was concluded that a direct coupling between the atmospheric concentration levels and vehicle circulation can be identified within the urban canyon, nevertheless, the local meteorology in particular and long-range transport of air masses have much more influence on the air quality than changes in the source intensity of road traffic. Concentration ratios of OC/EC were evaluated, and the amount of secondary organic aerosol (SOA) was estimated by using EC as tracer for the primary OC emissions. Mean contribution and standard deviation of the SOA to the OM in the PM2.5 size fraction at the kerbside over daylight periods and nights were of 37(±18) and 46(±16)%, respectively.