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1.
The ambient air concentrations and fluxes of various anionic species were sampled by MOUDI, TSP and dry deposition plates at a traffic sampling site in Taichung, central Taiwan. In the sampling period, from September to December 2000, the ambient air particle concentrations (PM1, PM2.5, PM10 and TSP) were lower in the September than in the other three months (October to December). The reason is that the northwest wind brought more particles (diameter less than 10 μm) and the higher wind speed caused higher dry deposition fluxes and TSP concentrations in the last three months. The anion species percentages of TSP were 0.24%, 13.7%, 0.52%, 12.0%, 18.9'% and 54.6% for F-, Cl-, Br-, NO2-, NO3- and SO42-, respectively. The results revealed that SO42-, NO3-, Cl- and NO2- were the dominant species at the traffic sampling site. The ion-size distributions of Cl-, NO2- and NO3- were unimodal, the main peak being between 3.2 and 5.6 μm. In contrast, the size distribution of SO42- was bimodal, with the main peaks in the particle size ranges 0.32.0.56 μm and 3.2.5.6 μm. The ambient average particle dry deposition flux was 6.28 μg/m2/s, and the dry deposition fluxes were 0.01, 94.6, 0.05, 34.7, 72.2 and 376.4 ng/m2/s for F-, Cl-, Br-, NO2-, NO3- and SO42-, respectively. The dry deposition velocities were 3.10, 0.03, 3.67, 0.05, 1.54, 2.03 and 3.67 cm/s for F-, Cl-, Br-, NO2-, NO3- and SO42-, respectively.  相似文献   

2.
Direct measurements of radionuclide tracers are useful tools for correcting proxy fluxes that are subject to post depositional changes. An analytical methodology was designed for the measurement of 210Pb and 7Be in rainwater. Atmospheric inputs of the radionuclides to Cumbria (UK) were recorded. Rainwater fluxes were then compared with measurements from soil cores. The annual deposition from April 1997 to March 1998 of 210Pb and 7Be was 165 ± 8 Bq m-2 and 3912 ± 120 Bq m-2, respectively, compared to an indirect 210Pb flux of 148 ± 7 Bq m-2 yr-1 calculated from soil core records.  相似文献   

3.
Atmospheric acid aerosols were sampled by two annular denuder systems (ADS) and a micro-orifice uniform deposit impactor (MOUDI) at a traffic site in central Taiwan. Theoretical analysis showed that the relative artifact for HNO3 gas sampling was about 0.53 when the initial HNO3 concentration was under 0.2 µg/m³ and should be considered carefully. The concentrations of gaseous acid at the traffic sampling site were higher than those in the other study. The size distributions of acid aerosols were unimodal for Cl-, NO2-, and NO3-, and bimodal for SO42-. The dominant acid ions in particles less than 18 µm were SO42-, NO3-, NO2- and Cl-.  相似文献   

4.
The spatial and temporal variations in the concentrations of nutrients (NH4+, NO2, PO43−, SiO4) and chlorophyll a were monitored simultaneously in a slow-flowing watercourse (Saricay Stream, Turkey), which runs in a rural–urban gradient. Chlorophyll a concentrations ranged between 0.044 μg l-1 and 206.15 μg l-1 and, in general, the higher concentrations of chlorophyll a and ammonium were measured downstream of the raw sewage outfalls. Nitrate was by far the most abundant form of inorganic nitrogen, and its concentration ranged between 411.71 μM and 87.25 μM. Silicates and phosphates were always potentially limiting to biomass relative to nitrogen. Agricultural run-off and point discharges from urban sources greatly affected the chemical composition of the water in the Saricay Stream and drove the system towards eutrophication.  相似文献   

5.
Integrated management of water resources is a major critical issue to be addressed in combating water stress in developing countries, such as Lebanon. At present, surface water is not properly used in Lebanon. This emphasises the importance of assessing surface water quality as a projected means to increase water availability. This study involves two different water bodies, the freely flowing Nahr-Ibrahin River and the Qaraaoun Reservoir, an impoundment of the Litani River. Water samples were collected from 16 chosen sites of each water body at four different dates during the dry season. Measured water parameters were temperature, pH, conductivity, BOD, HCO3-, Ca2+, Mg2+, Cl-, SO42-, PO43-, NO3-, NH3, Fe, Mn, Zn, Pb, and Cd. Statistical analysis of the data revealed significant differences in water quality. The differences could be attributed to the fact that whereas the Qaraaoun reservoir is receiving domestic waste discharges that lead to an increase in the CO2 content and a pH decrease, the Nahr-Ibrahim River is influenced by agricultural runoffs and industrial discharges that increase the pH values. Consequently, the water metal speciation of the two water bodies was different. The study indicated that the differential quality of the two water bodies could be attributed to the nature of the water resources and exposure to contaminants. This is crucial in recommending intervention studies to protect quality and promote the role of surface water use, as an integrated component of water management in Lebanon.  相似文献   

6.
Smokey Mountain Smelters in Knoxville, Tennessee USA is an abandoned aluminium smelter where smelter waste (slag) was dumped on site. ICP analyses indicated the highest slag metal concentrations were 223,000 mg kg−1 Al, 281 mg kg−1 As, 132 mg kg−1 Se, and 2910 mg kg−1 Cu. Metal uptake was quantified in plants growing on slag. Our data indicates that P. cretica accumulates Al in high concentrations, but not As, when grown in slag. Metal concentrations in vegetation grown on slag were lower than controls grown in uncontaminated soil, suggesting low metal availability or root exclusion mechanisms.  相似文献   

7.
In this study, Karadeniz Birlik Dogan Erdil vegetable oil factory, Elazig City, Turkey, was selected as representative of this sector. During the first part of the test programme, the quality of raw effluents was investigated. The removals of COD and oil-grease were above 85% at organic loadings between 1.62 and 7.83 kg COD m-3 d-1 at hydraulic retention times of 2.0 and 2.5 days. The conversion rates of the removed COD into methane gas were between 0.24 and 0.361 g CH4 (g COD)-1.  相似文献   

8.
Natural clinoptilolite-rich tuffs and natrolite from Iranian deposits and their different ion-exchanged forms were used for the adsorption of 99Mo as molybdate ion. The effect of pH, contact time, initial molybdate concentration, and some cationic and anionic interferences were also studied. To investigate the selectivity of zeolites and their exchanged forms, the isotherms of adsorption were constructed at room temperature. Desorption experiments were carried out to examine the ability of zeolite to retain adsorbed molybdate. It was concluded that molybdate could be considerably adsorbed by some of the exchanged forms of the zeolites (Ag+, Cd2+ and Pb2+ exchanged forms) whereas the uptake by the natural forms was negligible.  相似文献   

9.
The chemical compositions of precipitation show temporal and spatial variability. It is important to determine the temporal variation of the chemical composition of rainwater for estimating the impacts of pollutants on the forest. In this study, the 34 rainwater samples are collected using, for the first time, the specially designed collectors between November 1997 and March 1998 in Istanbul University, Faculty of Forestry at Bahcekoy, Istanbul in Belgrad Forest. The sequentially collected samples are analysed for major ions concentrations and pH estimations. The pH values for all samples vary from 5.1-7.6. In general, the concentration of all rainwater samples decrease with time. Furthermore, it is estimated that the average Ca2+) (1943.0 µeql-1) and SO42- (887.3 µeql-1) concentrations are extremely high during the first ten minutes of the precipitation event.  相似文献   

10.
Sixty-four surface soil samples taken in the vicinity of Al Ain landfill were analysed for cadmium, chromium, copper, nickel, lead and zinc by inductively coupled plasma spectroscopy. Extraction techniques were used to establish the association of the total concentrations of the six metals in the soil samples with their contents in the exchangeable, carbonate, iron/manganese oxides, and residual fractions. In the investigated soils, the recorded concentrations were as follows: 0.043 mg kg-1 for cadmium, 19.1 mg kg-1 for chromium, 53.3 mg kg-1 for copper, 60 mg kg-1 for nickel, 13.7 mg kg-1 for lead, and 117 mg kg-1 for zinc. Cadmium, chromium, nickel, lead and zinc concentrations in the investigated soil samples reflect the natural background values in shale, whereas copper is slightly enriched. I-geo (geoaccumulation index) values of the metals in the soils under study indicate that they are uncontaminated with cadmium, chromium, nickel, lead and zinc, but contaminated to moderately contaminated with copper. Heavy metal contents in the sediments were found to be significantly influenced by different physico-chemical parameters. The effect of these parameters can be arranged in the following order: clay fraction > carbonate fraction > silt fraction > organic matter fractions. A sequential extraction procedure showed that the total concentrations of the heavy metals are largely bound to the residual phase (retained 71.4% of cadmium, 77.8% of chromium, 75% of copper, 47% of nickel, 62.8% of lead, and 75.8% of zinc). A likely sequence of mobility in the investigated soils is as follows: chromium > lead > nickel > cadmium > zinc > copper.  相似文献   

11.
The concentrations of some naturally occurring radioisotopes in sediments of the Kufranja river basin in Jordan were determined by means of γ-ray spectrometry with precise calibration of energy and efficiency. The nuclides' concentrations were found by either direct measurement of their activities, as in the case of 226Ra and 40K, or through the measurements of the activities of their daughters with short half-lives, as in the case of 238U and 232Th. Furthermore, the hazard index, the radium equivalent activity and the absorbed dose rate for each of these nuclides had been calculated. It turned out that the concentrations of radioisotopes in sediments of the studied area were below the standard limits and the human effective dose equivalent ranged from 23.8 to 35.7 μSv/yr.  相似文献   

12.
Preliminary studies of the oxidation of arsenic(III) by potassium ferrate   总被引:1,自引:0,他引:1  
The Pollutant Standards Index (PSI) was developed in the USA to give the public an overall assessment of the air quality on a regular basis. Currently, the PSI does not include the synergistic effects of the major air pollutants. Synergism applies when the damage caused by two or more pollutants, either to human health or property, is greater than the effect or damage caused by each individual pollutant acting alone. The purpose of this work is to develop a methodology that would take into account the synergistic effects of the priority air pollutants, and therefore give us a better understanding of the severity of the damage caused by these pollutants. The equation suggested is D(P1,P2,P3,P4,P5) = C1A C2B C3C C4D C5E. If it is assumed that the weight constants A to E are equal to one (all pollutants contribute equally to the damage), the equation becomes D (P1,P2,P3,P4,P5) = K·C1·C2·C3·C4·C5 where the constant K represents a conversion factor between the PSI scale and the new Synergistic Theory scale. The value of K is to be determined experimentally by finding the threshold value in the synergistic scale and dividing the threshold value of the PSI scale (100) by this number K = 100/SSC1threshold where SSthreshold is the Synergistic Scale threshold value.  相似文献   

13.
The aim of this work is to define the most efficient parameterisation of the PBL (planetary boundary layer) by using the simulation with a simple Gaussian dispersion model of the plume type and comparing it with the improved OML model. A different type of σy and σz parameterisation in a Gaussian dispersion scheme was introduced. The old Pasquill–Gifford scheme and the new boundary layer parameterisation based on Monin–Obukhov length and other convective scaling parameters were compared, using a classical Gaussian model. For this comparison, the hourly average concentration and the long-term concentrations generated by these models, using same input data, were computed. These computed values and the field observations clearly show the importance of the parameterisations used by the models and the necessity of improving them. With this new parameterisation, we can easily add in new phenomena, such as dry and wet deposition, building effects and stack tip downwash penetration.  相似文献   

14.
The CMB8 model was applied for source apportionment of particulate matter in Bangkok area. The 24 h of ambient data were collected and analysed for elemental composition during December 1996 to January 1997 by high volume air samplers at a station in Bangkok, Thailand. Seven source profiles and the average mass concentrations of 42 ambient data were used to run the chemical mass balance (CMB8) model. The source apportionment by CMB8 gave similar results comparing with factor analysis – multiple regression (FA–MR) model of the same data. The results revealed that major sources of particulate matter in Bangkok were: soil (33%), road dust (33%) and automobile (15%). The minor source contributions were: sea salt (4.34%), refuse incineration and biomass burning (0.84%), steel mill (0.62%) and fuel oil combustion (0.35%). The lack of source profile for biomass or open burning in Bangkok resulted in much lower predicted contribution of this source when compared to that from FA–MR. When apply this CMB8 model with daily ambient data, the result revealed that one fourth of daily CMB8 source apportionment had high value of 2 (>4). These exceedance values of Chi2 also point out that one of the selected sources (biomass burning) may not be the true contributing sources. Presumably, accurate biomass burning source profile is needed to improve the CMB calculation of source contributions for particulate matter in Bangkok metropolitan area.  相似文献   

15.
Agricultural region wastewater near Dianchi Lake, China increases eutrophication of the lake. Thus nitrogen and phosphorus removal from the wastewater by Phragmites australis and Zizania caduciflora in two Constructed Wetlands (CWs) was studied. South CW and North CW have areas of 2800 and 4200 m², respectively. From January 2003 to December 2003, the input loads were 5.31 (2.89) and 0.68 (0.37) kg P ha−1 day−1 in SCW (NCW). The removal amounts of N and P via plant harvesting accounted for 32 (58) and 37 (51)% of the corresponding removal load in SCW (NCW).  相似文献   

16.
The deposition of atmospheric nitrogen (N) to surface waters of de la Plata River downwind of Buenos Aires city has been estimated using atmospheric dispersion-deposition models. The CALPUFF model has been applied to point source emissions and the DAUMOD-RD model has been developed to evaluate the area source emission contributions. Annual N dry deposition is 31,763 kg-N yr−1 (≈ 18 kg-N km−2 yr−1). Nitrogen dioxide contribution to this value is 54% and nitric acid contribution is 46%. The maximum monthly N dry deposition fluxes vary between 7 kg-N km−2 month−1 (in February) and 13 kg-N km−2 month−1 (in December).  相似文献   

17.
The treatability of anaerobic effluent from a molasses-based distillery was studied in a shaft-type hybrid bioreactor under purely suspended growth and hybrid system containing 5 mm tyre-tube beads. The Ks, k, Y and k found as 111.29 mg/l, 0.026/h, 0.4607 and 0.0040/h respectively. The maximum COD removal was 51.7% at a loading rate of 5.250 kg d−1 m−3. The overall removal rate was 0.0431, 0.0452, 0.0484 and 0.053/h under 0, 10, 20 and 30 g/l of beads respectively. When attached biomass increased, the cell synthesis part of oxygen utilisation coefficient gradually decreased and that for endogenous respiration increased.  相似文献   

18.
Mn in street dust and soil from selected roads was studied to assess the contribution of combustion of vehicular methylcyclopentadienyl manganese tricarbonyl (MMT) to Mn levels and distribution in Pretoria, South Africa. Total Mn concentrations ranged from (329.1-863.9 μg g−1) for dust and (215.8-450.6 μg g−1) for soil. These values were significantly higher than the mean value (278.9 μg g−1) found on soil from a rural environment in Pretoria. The lowest value for the dust sample (329.1 μg g−1) was close to the mean background level of 330 μg g−1 for Mn in soil. Mn distribution in the samples was most in the residual fraction (178.18-487.50 μg g−1) and (140.76-293.40 μg g−1) for dust and soil respectively. Mn in the other fractions were 56.45-202.60 μg g−1 oxides, 90.71-45.34 μg g−1 organic, 45.36-12.65 μg g−1 carbonates and 1.98-6.72 μg g−1 exchangeable for dust and 32.54–167.31 μg g−1 oxides, 34.23–70.45 μg g−1 organic, 10.98-30.45 μg g−1 carbonate and 1.0-4.87 μg g−1 exchangeable for soil. Major source of Mn determined was mainly from the combustion of vehicular MMT.  相似文献   

19.
Chemical ionisation mass spectrometry (CI-MS) was applied to study the benzene emission characteristics of a TWC-vehicle at a time resolution of one Hertz. Three important operating conditions with increased emissions were identified: at vehicle start; at extended stop-and-go situations; and whenever a catalyst-induced benzene formation occurs. The cold start influence was detectable for about 200 seconds of driving corresponding to a distance of 1.2 km. At hot engine/catalyst mean pre- and post-catalyst emission rates of 25–150 mg km-1 and 0.1–135 mg km-1 were determined. Catalyst conversion varied from 0.07 to >0.99. Even negative conversion efficiencies were observed at several occasions, indicating that benzene can be formed de novo in a TWC. It is of importance to lower benzene emissions at these critical operating conditions to further reduce ambient air levels in cities and with it the cancer risk for large proportions of our population.  相似文献   

20.
Nitrification of anaerobically digested sludge centrate was studied in bench-scale suspended growth and fixed film enhanced suspended growth systems at temperatures of 10.5-28.5°C and pH values of 6.0-9.1. Nitrification followed zero-order kinetics in both systems, and ammonia removals in excess of 99% were observed. The temperature dependency of the suspended growth nitrification rate observed under not fully acclimated biomass conditions at pH between 6.8 and 8.5, was expressed as kT = k20θT-20where k20 and θ were found to be 0.34 mg NH3-N/MLVSS-d and 1.033, respectively. The nitrification rate in the fixed film enhanced suspended growth system involving styrofoam pads ranged from 0.11 to 0.13 mg NH3-N/mg MLVSS-d at temperatures of 21.5-25°C and pH values of 7.8-8.6. The process contained suspended solids in the range of 10-20 mg/l.  相似文献   

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