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1.
The stabilities in water and dry storage of two solid-state disinfectants (3-chloro-4, 4-dimethyl-2-oxazolidinone, agent I, and calcium hypochlorite) have been compared under a variety of conditions. Variables in the study included pH, temperature, and water quality. Agent I is considerably more stable in dry storage and in water, especially at pH 4.5 and 7.0, than is calcium hypochlorite. This is true for solutions of the two compounds in sterile, distilled, deionized, demandfree water or in a synthetic water containing heavy organic load. Prior work in these laboratories concerning use of agent I as a disinfectant for lake water in a laboratory-scale treatment plant had suggested that agent I has considerable potential for use as an alternative to cholorine gas for water disinfection. The present work suggests that agent I is of sufficient stability to be of use as a solid-state disinfectant for swimming pools and for potable water for remote areas. 相似文献
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S. D. Worley W. B. Wheatley H. H. Kohl J. A. Van Hoose H. D. Burkett N. Bodor 《Journal of the American Water Resources Association》1983,19(1):97-100
ABSTRACT: The stability in water of a novel new chloramine agent, 3-chloro-4, 4-dimethyl-2-oxazolidinone (agent I), which is an excellent water disinfectant, has been compared to the stabilities of several other water disinfectants. The agents tested in addition to agent I included N-chlorosuccinimide, 2, 4-dichloro-5, 5-dimethylhydantoin, tichloroisocyanuric acid, calcium hypochlorite, commercial grade HTH, and household bleach. The total chlorine content of a water solution of agent I in a demand free environment remains constant over a period of at least eight weeks, while that for all of the other agents declines markedly over that time period. An explanation for these observations will be offered. Prior work in these laboratories concerning use of agent I as a disinfectant for lake water in a laboratory scale treatment plant had shown that agent I has considerable potential for use as an alternative to chlorine gas for water disinfection. 相似文献
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赵剑文 《环境保护与循环经济》2021,41(2):37-39
次氯酸钠药剂在水务行业应用广泛,常被用作消毒剂,对于保障水质具有重要的作用。介绍了近6年来次氯酸钠消毒剂在水务行业的应用情况,以期为不同性质水厂的运行提供参考。 相似文献
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G. Sun T Y Chen M. S. Habercom W. B. Wheatley S. D. Worley 《Journal of the American Water Resources Association》1996,32(4):793-797
ABSTRACT: A new insoluble N-halamine polymeric disinfectant material has been tested in a water filter application to determine (1) its tendencies to leach undesirable decomposition products, (2) its range of potential applicability, and (3) its regenerability. In flowing water tests, poly-1,3-dichloro-5-methyl-5-(4‘-vinylphenyl)hydantoin (Poly-I) leached only small amounts of total organic carbon, free and total chlorine, anions, and volatile organics such as trihalomethanes. Furthermore, Poly-I provided bactericidal efficacy over the pH range 4.5 to 9.5 and at temperatures as high as 37°C. Poly-I is deactivated by reducing agents such as sodium thiosulfate and by ethanol; following deactivation, it can be regenerated by exposure to flowing aqueous free chlorine. Poly-I appears suitable for use as a biocidal filter for small potable and recreational waters, for it is effective over a wide pH and temperature range and is readily regenerable. It would not be useful, however, for disinfection of large bodies of water such as in city treatment plants because of its cost and the large amount of the material that would be necessary. 相似文献
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F. Boukhoubza A. Jail F. Korchi L. Loukili Idrissi H. Hannache J.C. Duarte L. Hassani A. Nejmeddine 《Journal of environmental management》2009,91(1):124-132
The application of hypochlorite for the removal of soluble COD, phenolic and polyphenolic like compounds, and other organic compounds responsible for the olive mill wastewater (OOWW) colour has been experimentally studied. After the OOWW filtration on a sand column, the effluent was subjected to a fast liming under optimal conditions. Lime application reduced polyphenols, COD and SS contents to half of their initial values but an important blackening of the treated OOWW was observed, especially when adding high concentrations of lime (10% (W/V) and 15% (W/V)).A second stage of treatment was applied using calcium hypochlorite. In this stage, removal of the studied compounds reached as much as 95% at higher concentrations, and particularly the colouring of OOWW which is generally difficult to eliminate was greatly reduced. The OOWW hypochloration acted through coagulation–flocculation and a rapid oxidation of the organic matter proceeded from the first 5 min. The kinetic study of the degradation of the waste polluting compounds from liming showed that Ca(ClO)2 reacts similarly in the elimination of organic compounds, polyphenols, SS and colouration. The analysis of the organochloride compounds generated by the reaction between hypochlorite and the organic compounds showed that DDD, DDT and the heptachlor contents exceeded the values recommended by the International and European drinking water standards. 相似文献
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H. D. Burkett J. H. Faison H. H. Kohl W. B. Wheatley S. D. Worley N. Bodor 《Journal of the American Water Resources Association》1981,17(5):874-876
A new chloramine agent, 3-chloio-4, 4-dimethyl-2-oxazolidinone, has been tested in a laboratory scale water treatment plant as to its efficacy in water disinfection. The agent seems to be equally effective as compared to chlorine gas in this application. The results of preliminary toxicity studies on the agent are very encouraging. The agent has a long shelf life both in water solution and in the solid state. Being a solid, the agent is clearly less hazardous to handle than chlorine gas. The agent appears to inhibit oxidative corrosion of metals as well. The agent is less likely to produce toxic halocarbons (e.g., chloroform) in water than is chlorine gas. Possibly most important from the standpoint of water disinfection, the agent is a “slow release” one for its positive chlorine, which provides prolonged bactericidal activity. 相似文献
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采出水经处理后通常需作为地层回注水使用,由于油气生产的特殊性,常用的H2S脱除方法在使用中受到限制,探索适合于油气田生产的水处理方法十分必要。文章探讨了通常可用于油田采出水中H2S脱除的各种方法,对比了各类方法的优缺点,提出以NaClO为主要脱硫剂的水处理方法,通过对模拟采出水的室内实验,证明次氯酸法可以快速有效地去除采出水中的H2S,使H2S残留量低于1 mg/L。实验表明:经处理后的水质可以达到SY/T 5329-2012《碎屑岩油藏注水水质指标及分析方法》要求,处理成本较低。 相似文献
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Alan R. Collins Scott Steinback 《Journal of the American Water Resources Association》1993,29(2):199-209
ABSTRACT: About one-third of all West Virginians obtain domestic water from private water wells. In this research, mail and telephone surveys were used to investigate household responses to bacteria, mineral, and organic chemical contamination of domestic water supplies. Of households who were informed of contamination and acknowledged the problem, over 85 percent took action to avoid exposure to water contamination problems. The most common action was to clean and/or repair the water system (55.9 percent of valid surveys). Approximately 45 percent of households made investments of either a water treatment system, a new water source, or correction of contamination source. The average, annual economic cost of rural household actions was $320 for bacteria, $357 for minerals, and $1,090 for organic contamination. These economic costs represent a lower bound estimate for rural household willingness-to-pay (WTP) for a reduction in domestic water contamination from government action. On average, investment actions had lower annual economic costs than noninvestment actions of boiling and hauling water so that households who undertook investment actions in response to water contamination would have a lower WTP for government action to reduce water contamination. When effectiveness of water treatment systems was evaluated, treatment systems which require minimal household maintenance were found to reduce exposure to water contamination to safe levels as households intended when they installed the system. Treatment systems which were commonly ineffective included those which required continual maintenance (e.g., chiorinators) or were not designed to solve the contaminant problem for which they were purchased (e.g., filter systems for bacteria). 相似文献
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James L. Robinson Celeste A. Journey 《Journal of the American Water Resources Association》2004,40(4):851-861
ABSTRACT: Ground water samples were collected from 30 wells located in, or directly down gradient from, recharge areas of the Eutaw aquifer in Montgomery, Alabama. The major ion content of the water evolves from calcium‐sodium‐chloride‐dominated type in the recharge area to calcium‐bicarbonate‐dominated type in the confined portion of the aquifer. Ground water in the recharge area was under saturated with respect to aluminosilicate and carbonate minerals. Ground water in the confined portion of the aquifer was at equilibrium levels for calcite and potassium feldspar. Dissolved oxygen and nitrite‐plus‐nitrate concentrations decreased as ground water age increased; pH, iron, and sulfate concentrations increased as ground water age increased. Aluminum, copper, and zinc concentrations decreased as ground water age and pH increased. These relations indicate that nitrate, aluminum, copper, and zinc are removed from solution as water moves from recharge areas to the confined areas of the Eutaw aquifer. The natural evolution of ground water quality, which typically increases the pH and decreases the dissolved oxygen content, may be an important limiting factor to the migration of nitrogen based compounds and metals. 相似文献
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John C. Clausen Kenneth N. Brooks 《Journal of the American Water Resources Association》1983,19(5):763-767
ABSTRACT The likelihood of expanded use of Minnesota's 3 million hectares of peatlands prompted the state to initiate a hydrologic study to characterize these groundwater-linked systems. Determining the quality of streamflow from these peatlands was an integral part of the study. Peatlands could be differentiated either on the basis of streamflow quality or on soil-vegetation characteristics. The quality of streamflow from 45 undisturbed peatlands was characterized by collecting samples five times in 1979-80 and analyzing them for 27 water quality characteristics. Runoff pH, specific conductance, alkalinity, calcium, and magnesium were used to classify the peatlands as bog, transition, or fen. Bog runoff was lower (α= 0.05) in pH, calcium, sodium, manganese, and ammonia nitrogen than fen runoff, but was higher in acidity, color, aluminum, humic and fulvic acid, and chemical oxygen demand than fen runoff. Bogs had more fibric peat of a lower pH than fens; fens exhibited tall woody shrubs which were virtually absent on bogs. 相似文献
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井下作业废水处理的试验研究 总被引:13,自引:5,他引:8
油田开发过程中,井下作业工艺尤为复杂,施工类型繁多,容易发生各种污染。针对压裂施工排出井管返出液的特点,重点提出利用絮凝-隔油法,之后再用次氯酸钠结合紫外光对废水进行深度处理,可氧化分解难处理的部分高分子有机化合物的污染。结果表明:在适宜的处理条件下,该法可有效去除水中CODCr 和Oil ,去除率分别为98.9%、98.3%。 相似文献
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Harry I. Nightingale 《Journal of the American Water Resources Association》1987,23(2):197-205
ABSTRACT: The chemical impact of urban runoff water on water quality beneath five retention/recharge basins was investigated as part of the US EPA's Nationwide Urban Runoff Program in Fresno, California. Soil water percolating through alluvium soils and the ground water at the top of the water table were sampled with ceramic/Teflon vacuum water extractors at depths up to 26 m during the two-year investigation. Inorganic and organic pollutants are present in the runoff water delivered to the basins. No significant contamination of percolating soil water or ground water underlying any of the five retention/recharge basins has occurred for constituents monitored in the study. The oldest basins was constructed in 1962. The concentration of selected trace elements in the ground water samples was similar to the levels reported in the regional ground water. None of the pesticides or other organic priority pollutants, for which water samples were analyzed, was s̊ detected except diazinon which was found in trace amounts (0.3 μg/L or less) in only three soil water samples. These results are important to the continued conservation of storm water and the development of a best management practice for storm-water management using retention/recharge basins in a semi-arid climate. 相似文献
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Richard Lowrance Randall G. Williams Shreeram P Inamdar David D. Bosch Joseph M. Sheridan 《Journal of the American Water Resources Association》2001,37(6):1445-1455
ABSTRACT: Riparian buffers are increasingly important as watershed management tools and are cost‐shared by programs such as Conservation Reserve that are part of the USDA Conservation Buffer Initiative. Riparian buffers as narrow as 4.6m (15ft) are eligible for cost‐share by USDA. The Riparian Ecosystem Management Model (REMM) provides a tool to judge water quality improvement by buffers and to set design criteria for nutrient and sediment load reduction. REMM was used for a Coastal Plain site to simulate 14 different buffers ranging from 4.6 m to 51.8 m (15 to 170 ft) with three different types of vegetation (hardwood trees, pine trees, and perennial grass) with two water and nutrient loads. The load cases were low sediment/low nutrient‐typical of a well managed agricultural field and low sediment/high nutrient‐typical of liquid manure application to perennial forage crops. Simulations showed that the minimum width buffer (4.6 m) was inadequate for control of nutrients under either load case. The minimum width buffer that is eligible for cost share assistance on a field with known water quality problems (10.7 m, 35 ft) was projected to achieve at least 50 percent reduction of N, P, and sediment in the load cases simulated. 相似文献
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Alan M. Stueber Robert E. Criss 《Journal of the American Water Resources Association》2005,41(2):267-290
ABSTRACT: An extensive base of water quality information emphasizing the effects of land use and hydrology was obtained in the karstified Fountain Creek watershed of southwestern Illinois to help resolve local water quality issues. Agrichemicals dominate the loads of most water quality constituents in the streams and shallow karstic ground water. Only calcium (Ca), magnesium (Mg), Aluminum (A1), and sulfate (SO4) ions are predominantly derived from bedrock or soils, while agrichemicals contribute most of the sodium (Na), potassium (K), chlorine (Cl), nitrate (NO3), fluorine (F), phosphorus (P), and atrazine. Concentrations of individual ions correlate with discharge variations in karst springs and surface streams; highly soluble ions supplied by diffuse ground water are diluted by high flows, while less soluble ions increase with flow as they are mobilized from fields to karst conduits under storm conditions. Treated wastewater containing detergent residues dominates the boron load of streams and provides important subordinate loads of several other constituents, including atrazine derived from the Mississippi River via the public water supply. Average surface water concentrations at the watershed outlet closely approximate a 92:8 mixture of karst ground water and treated wastewater, demonstrating the dominance of ground water contributions to streams. Therefore the karst aquifer and watershed streams form a single water quality system that is also affected by wastewater effluent. 相似文献
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Predicting Sustainable Ground Water to Constructed Riparian Wetlands: Shaker Trace,Ohio, USA 总被引:1,自引:0,他引:1
Water isotopy is introduced as a tool to design, locate, and select storm water best management practices for the prediction of sustained ground water inflows to prospective constructed wetlands. A primer and application of the stable isotopes, 18O and 2H, are discussed for riparian wetland restoration areas among an agricultural landscape in southwestern Ohio. Conventional piezometric measurements were ambiguous in identifying groundwater mounding across a transect which includes numerous agricultural tile drains. Instead evaporative potential data represented by δ18O values indicated a well delineated zone for prospective constructed wetlands. All successful constructed wetland areas thus far at Shaker Trace are represented by ground water with depleted δ18O values below −9.0‰ VSMOW. Such areas of sustainable ground water inflow could either be due to perched units at depth or simply the result of an increased flow gradient. 相似文献