中国东南沿海大(中)型浅成中低温热液矿床—斑岩型矿床评价的地质准则、成矿模式及其找矿意义

本文总结中国东南沿海高钾钙碱性—双峰式火山岩带中已勘查大中型矿床成矿环境的共性：矿床所处区域构造的部位、成岩与成矿时代、矿床与岩浆成因类型、火山构造及其基底构造控矿性、矿床与爆发角砾岩、矿床与矿化类型叠加与共生、矿化与蚀变的分带往、矿床定位深度与剥蚀深度。作者认为这八点可作为找寻与评价大（中）型矿床的地质准则。通过火山地质与矿床地质统一的研究提出本区晚中生代以火山为中心地热体系的成矿模式。并就三个方面作类比：①与现代火山地热体系成矿作用类比；②以紫金山高硫型浅成低温热液矿床与世界同类型矿床作比较；③与环太平洋其他火山岩带同类型矿床模式作类比．通过建立本区的模式与类比获得进一步找矿中值得重视的一些思路．     

与韧性剪切带有关的不同金矿化类型地质地球化学特征对比研究

与韧性剪切带有关的金矿化类型主要有蚀变糜棱岩型、构造蚀变岩型和石英脉型。不同金矿化类型具有不同的控矿构造类型 ,蚀变糜棱岩型金矿化受韧性变形带控制 ,构造蚀变岩型金矿化受脆性碎裂岩控制 ,石英脉型金矿化则受浅部裂隙带控制 ;未矿化糜棱岩变形越强 ,金元素含量就越低 ,超糜棱岩明显低于粗糜棱岩 ,但强烈变形的糜棱岩容易叠加后期的矿化蚀变 ;在时空关系上 ,同一成矿期内石英脉型金矿化稍晚于构造蚀变岩型和蚀变糜棱岩型金矿化 ,且石英脉型往往穿切蚀变糜棱岩型和构造蚀变岩型 ;在地球化学特征方面 ,与构造蚀变岩型和蚀变糜棱岩型相比 ,石英脉型的轻重稀土元素比值较大 ,更富集轻同位素 ;在成矿物理化学条件方面 ,与构造蚀变岩型和蚀变糜棱岩型相比 ,石英脉型的成矿温度低、压力小、成矿深度浅。从构造带成生演化的时空统一的角度分析可知 ,这三类金矿化都是在造山过程中韧性剪切带持续演化变形的条件下形成的 ,这种韧性剪切带持续演化变形是形成大型金矿床的重要条件之一。     

《环太平洋火山作用及成矿作用国际讨论会》筹备工作进展

地质矿产部及联合国亚太经社会(ESCAP)联合发起、资助,由中国地质科学院/南京地质矿产研究所和亚太经社会/区域矿产资源发展计划组织共同召开的《环太平洋火山作用及成矿作用国际讨论会》,正按计划进行各项筹备工作。 会议所确定的主题包括两部份: 第二部份:中—新生代火山作用、构造背景、火山构造和火山岩岩石学 1、区域火山作用,与不同构造背景有关的岩石系列和岩石组合; 2、火山构造—破火山口,火山—构造洼地等的演化,中生代古火山构造的重建; 3、火山—侵入杂岩的地球化学和岩浆演化; 4、熔结凝灰岩及其它类似的岩石,其成因模式和相模式; 5、次火山岩,爆发角砾岩和火山构造与金属成矿作用的关系。 第二部份:与中—新生代火山作用有关的金属矿床(Fe、Cu、Pb、Zn、Au、Ag、U等)勘查方法。这部分是本次讨论会的重点,有如下专题: 1、构造—岩浆带的成矿规律及成矿系列; 2、与一定火山构造和火山—侵入杂岩有关的成矿作用;     

喀麦隆东部省贝克铜多金属矿区地质特征和成矿作用分析

本文以海外风勘选区评价项目为基础,结合该地区已探明的多处铜矿床特征,贝克矿区铜矿赋存于台缘中-基性安山岩-玄武岩杂岩体中,产于安山熔岩上部的构造裂隙带中,伴随着矿化作用,产生围岩蚀变,形成脉型铜矿(化)体。区内铜多金属矿为火山作用与后期热液作用叠加成矿,矿区内安山熔岩裂隙带为高渗透带,既可作流体物质运移的通道,又可成为良好的成矿场所,为寻找分布于火山口内、火山颈下的次火山岩体中块状硫化物型铜矿脉,次火山岩型铜矿床指明远景区。     

运用火山地质学理论研究竹田头火山机构

系采用火山活动旋回-火山构造-火山地层-岩性、岩相一体化思路对浙东谷来地区的竹田头复活破火山机构进行地质填图的一些认识,主要有如下五点:1.采用火山旋回-火山构造-火山地层-岩性、岩相一体化思路在火山岩区进行地质填图,取得了很好的地质效果;2.区域火山地层层序的厘定,首先应在同一旋回的火山机构内,测制剖面,厘定火山地层层序,而后把不同旋回火山机构内的地层层序叠置,建立区域综合地层层序,在此基础上,确定岩石地层单位和填图单元;3.划分岩相,建立相序,是推演古火山演化历史,建立演化模式的有效途径;4.线形构造与环形火山构造组合形成的线-环构造格局,是火山岩区地质构造的重要特征;5.在火山岩区用火山地层组-段-岩性填制的地质图,实质上是一种实际材料图,只有以火山旋回-火山构造-火山地层-岩相为内容的火山岩相构造图,才能正确反映火山岩区的地质构造特点,揭示火山岩的成因,追溯古火山演化历史,恢复古火山面貌.     

宁蒗地区铜厂河铜矿控矿条件与热液成矿模式探讨

宁蒗地区铜厂河铜矿系喜山期隐伏斑岩体外接触带玄武岩系热液型铜矿床 ,其主要含矿、赋矿层位为上二叠统玄武岩组 (P2 β)与黑泥哨组 (P2h)玄武岩系 ,主干控矿构造为南北向断裂体系。矿区NWW向F1断裂为阻矿构造 ,铜矿化均产于其下盘 (南盘 ) ;NE向F2 、F3 断裂将本区分成三个不同矿化特征的矿段。通过对矿区铜矿的碳、氧、硫等稳定同位素和包裹体分析及成矿热液演化特征探讨 ,建立了铜厂河铜矿热液成矿模式     

安徽省霍山县东溪-南关岭金矿地质特征与成矿条件

东溪-南关岭金矿为北淮阳东段发现的第一个原生金矿,产于磨子潭-晓天中生代火山盆地边缘,容矿围岩为安山质-英安质火山岩,矿化和蚀变受桐柏-桐城深大断裂带的次级构造带控制。该金矿发育陡倾斜的脉状矿体和缓倾斜的似层状矿体,成因类型为冰长石-绢云母型浅成低温热液金矿。火山岩盆地之下的变质基底可能起到了初始矿源层作用,桐柏-桐城断裂带及其次级构造破碎带为重要的导岩导矿构造,早白垩世强烈的岩浆活动提供了热源、动力源和部分矿源。参照国内外类似金矿的特征,认为本区成矿地质条件良好,有可能隐伏着与石英正长岩体有关的细脉浸染型矿化,晓天火山盆地具有良好的找矿前景。     

巴布亚新几内亚浅成低温热液型金矿概述

巴布亚新几内亚大地构造位置上位于欧亚板块、印度-澳大利亚板块和太平洋板块三大板块结合部位,自白垩纪以来经历了复杂的构造演化过程,形成了特有的沟-弧-盆体系,使得区内广泛发育了岩浆弧有关的浅成低温热液型金矿。区内的浅成低温热液型金矿可分为低硫型和高硫型两种,而根据矿物组成、形成深度的不同,低硫型矿床又可分为石英-硫化物型、碳酸盐-贱金属型、浅成低温石英型和冰长石-绢云母型四个亚类型,低硫型金矿的不同的矿化亚类型常相互叠加,对于形成大型、超大型的金矿具有重要的意义。     

赣南W、Sn多金属成矿区划及找矿方向

赣南地区是南岭成矿区(带)中重要的W、Sn多金属矿产聚集地,已探明黑钨矿储量和产量均居世界第一。区内主要矿化元素为W、Sn、Pb、Zn、Ag、Au、Nb、Ta、Mn等。主要矿化类型为石英脉型、破碎蚀变岩型钨矿,斑岩型、层间隐爆裂隙带型锡矿,隐爆角砾岩型铜矿,形成了与燕山期岩浆活动有关的钨锡多金属成矿系列。新矿化类型是赣南中生代岩浆—火山岩区找矿的重要方向。     

火山矿床研究的新进展(1987—1990)

1987-1990年四年中我国火山矿床研究中取得下列诸方面的成就:(1)玢岩铁矿的形成决定于基性-中基性并具有高碱低硅岩浆的演化,结晶分异时低氧逸度条件;从世界范围看,构造背景与板块俯冲带或缝合带(包括板内古缝合带)直接或间接有关;实验研究解决了几种特殊矿物组合如“膏包辉”组合等的物理化学条件问题。(2)随着中生代火山岩区金矿床的不断发现,对含矿主岩、基底及矿床类型与分布规律有了进一步的认识。(3)斑岩型矿床分布广泛,除Cu,Mo外,涉及Pb-Zn,Ag,Au,W及Sn矿床,并发现与国外层火山中心地区可以对比的上部为脉状矿下部为斑岩型铜矿的实例;(4)火山岩中铀矿床多形成于晚白垩世之后,受火山盆地攻破火山口构造的明显控制;(5)西北与西南海相火山岩区的块状硫化物矿床中,明确了黑矿型钢及多金属矿床和独立的金矿床的存在,在分类上除了Cu-,Cu-Zn-,Zn-Cu-Pb-及Zn-Pb-型之外,Cu-Pb型在国外很少有报导。(6)从成因或构造角度进行了火山岩区矿床成矿规律成分布规律的探索,注意到基底性质与基底构造的关系,对分布规律挺出了岩浆活动中心迁移造成的分布格局上的超覆和地区的剥蚀深度问题;(7)区分出非金属矿床的两个系列:次生石英岩系列及玻璃岩系列。通过这些研究,在火山岩中发现了一些新的远景区和新的矿床。     

Toxic effects of acetochlor, methamidophos and their combination on nifH gene in soil

Toxic effects of two agrochemicals on nifH gene in agricultural black soil were investigated using denaturing gradient gel electrophoresis （DGGE） and sequencing approaches in a microcosm experiment. Changes of soil nifH gene diversity and composition were examined following the application of acetochlor, methamidophos and their combination. Acetochlor reduced the nifH gene diversity （both in gene richness and diversity index values） and caused changes in the nifH gene composition. The effects of acetochlor on nifH gene were strengthened as the concentration of acetochlor increased. Cluster analysis of DGGE banding patterns showed that nifH gene composition which had been affected by low concentration of acetochlor （50 mg/kg） recovered firstly. Methamidophos reduced nifH gene richness that except at 4 weeks. The medium concentration of methamidophos （150 mg/kg） caused the most apparent changes in nifH gene diversity at the first week while the high concentration of methamidophos （250 mg/kg） produced prominent effects on nifH gene diversity in the following weeks. Cluster analysis showed that minimal changes of nifH gene composition were found at 1 week and maximal changes at 4 weeks. Toxic effects of acetochlor and methamidophos combination on nifH gene were also apparent. Different nifH genes （bands） responded differently to the impact of agrochemicals： four individual bands were eliminated by the application of the agrochemicals, five bands became predominant by the stimulation of the agrochemicals, and four bands showed strong resistance to the influence of the agrochemicals. Fifteen prominent bands were partially sequenced, yielding 15 different nifH sequences, which were used for phylogenetic reconstructions. All sequences were affiliated with the alpha- and beta-proteobacteria, showing higher similarity to eight different diazotrophic genera.     

Arsenic uptake by arbuscular mycorrhizal maize （Zea mays L.） grown in an arsenic-contaminated soil with added phosphorus

The effects of arbuscular mycorrhizal (AM) fungus (Glomus mosseae) and phosphorus (P) addition (100 mg/kg soil) on arsenic (As) uptake by maize plants (Zea mays L.) from an As-contaminated soil were examined in a glasshouse experiment.Non-mycorrhizal and zero-P addition controls were included.Plant biomass and concentrations and uptake of As,P,and other nutrients,AM colonization,root lengths,and hyphal length densities were determined.The results indicated that addition of P significantly inhibited root colonization and development of extraradical mycelium.Root length and dry weight both increased markedly with mycorrhizal colonization under the zero-P treatments,but shoot and root biomass of AM plants was depressed by P application.AM fungal inoculation decreased shoot As concentrations when no P was added,and shoot and root As concentrations of AM plants increased 2.6 and 1.4 times with P addition,respectively.Shoot and root uptake of P,Mn,Cu,and Zn increased,but shoot Fe uptake decreased by 44.6%,with inoculation, when P was added.P addition reduced shoot P,Fe,Mn,Cu,and Zn uptake of AM plants,but increased root Fe and Mn uptake of the nonmycorrhizal ones.AM colonization therefore appeared to enhance plant tolerance to As in low P soil,and have some potential for the phytostabilization of As-contaminated soil,however,P application may introduce additional environmental risk by increasing soil As mobility.     

Degradation of metabolites accumulated of benzo[a]pyrene by coupling Penicillium Chrysogenum with KMnO4

Several main metabolites of benzo[a]pyrene （BaP） formed by Penicillium chrysogenum, Benzo[a]pyrene-1,6-quinone （BP 1,6- quinone）, trans-7,8-dihydroxy-7,8-dihydrobenzo[a]pyrene （BP 7,8-diol）, 3-hydroxybenzo[a]pyrene （3-OHBP）, were identified by high-performance liquid chromatography （HPLC）. The three metabolites were liable to be accumulated and were hardly further metabolized because of their toxicity to microorganisms. However, their further degradation was essential for the complete degradation of BaP. To enhance their degradation, two methods, degradation by coupling Penicillium chrysogenum with KMnO4 and degradation only by Penicillium chrysogenum, were compared; Meanwhile, the parameters of degradation in the superior method were optimized. The results showed that （1） the method of coupling Penicillium chrysogenum with KMnO4 was better and was the first method to be used in the degradation of BaP and its metabolites; （2） the metabolite, BP 1,6-quinone was the most liable to be accumulated in pure cultures; （3） the effect of degradation was the best when the concentration of KMnO4 in the cultures was 0.01% （w/v）, concentration of the three compounds was 5 mg/L and pH was 6.2. Based on the experimental results, a novel concept with regard to the bioremediation of BaP-contaminated environment was discussed, considering the influence on environmental toxicity of the accumulated metabolites.     

Impact of atrazine and nitrogen fertilizers on the sorption of chlorotoluron in soil and model sorbents

Sorption of chlorotoluron in ammonium sulfate, urea and atrazine multi-solutes system was investigated by batch experiments. The results showed application of nitrogen fertilizers to the soil could affect the behavior of chlorotoluron. At the same concentration of N, sorption of chlorotoluron decreased as the concentration of atrazine increased on the day 0 and 6 in soil, respectively. The sorption of chlorotoluron increased from 0 to 6 d when soils were preincubated with deionized water, ammonium sulfate and urea solution for 6 d. That indicated incubation time was one of the most important factors for the sorption of chlorotoluron in nitrogen fertilizers treatments. The individual sorption isotherms of chlorotoluron in rubbery polymer and silica were strictly linear in single solute system, but there were competition sorption between pesticides or between pesticides and nitrogen fertilizers. That indicated the sorption taken place by concurrent solid-phase dissolution mechanism and sorption on the interface of water-organic matter or water-mineral matter.     

Potential of plant polyphenol oxidases in the decolorization and removal of textile and non-textile dyes

In this study an effort has been made to use plant polyphenol oxidases; potato （Solanum tuberosum） and brinjal （Solanum melongena）, for the treatment of various important dyes used in textile and other industries. The ammonium sulphate fractionated enzyme preparations were used to treat a number of dyes under various experimental conditions. Majority of the treated dyes were maximally decolorized at pH 3.0. Some of the dyes were quickly decolorized whereas others were marginally decolorized. The initial first hour was sufficient for the maximum decolorization of dyes. The rate of decolorization was quite slow on long treatment of dyes. Enhancement in the dye decolorization was noticed on increasing the concentration of enzymes. The complex mixtures of dyes were treated with both preparations of polyphenol oxidases in the buffers of varying pH values. Potato polyphenol oxidase was significantly more effective in decolorizing the dyes to higher extent as compared to the enzyme obtained from brinjal polyphenol oxidase. Decolorization of dyes and their mixtures, followed by the formation of an insoluble precipitate, which could be easily removed simply by centrifugation.     

Removal of heavy metals from sewage sludge by low costing chemical method and recycling in agriculture

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Isolation and preliminary characterization of a 3-chlorobenzoate degrading bacteria

A study was conducted to compare the diversity of 2-, 3-, and 4-chlorobenzoate degraders in two pristine soils and one contaminated sewage sludge. These samples contained strikingly different populations of mono-chlorobenzoate degraders. Although fewer cultures were isolated in the uncontaminated soils than contaminated one, the ability of microbial populations to mineralize chlorobenzoate was widespread. The 3- and 4-chlorobenzoate degraders were more diverse than the 2-chlorobenzoate degraders. One of the strains isolated from the sewage sludge was obtained. Based on its phenotype, chemotaxonomic properties and 16S rRNA gene, the organism S-7 was classified as Rhodococcus erythropolis. The strain can grow at temperature from 4 to 37℃. It can utilize several （halo）aromatic compounds. Moreover, strain S-7 can grow and use 3-chlorobenzoate as sole carbon source in a temperatures range of 10-30℃ with stoichiometric release of chloride ions. The psychrotolerant ability was significant for bioremediation in low temperature regions. Catechol and chlorocatechol 1,2-dioxygenase activities were present in cell free extracts of the strain, but no （chloro）catechol 2,3- dioxygenase activities was detected. Spectral conversion assays with extracts from R. erythropolis S-7 showed accumulation of a compound with a similar UV spectrum as chloro-cis,cis-muconate from 3-chlorobenzoate. On the basis of these results, we proposed that S-7 degraded 3-chlorobenzoate through the modified ortho-cleave pathway.     

Single and joint effects of pesticides and mercury on soil urease

The influence of two pesticides including chlorimuron-ethyl and furadan and mercury （Hg） on urease activity in 4 soils （meadow burozem and phaeozem） was investigated. The soils were exposed to various concentrations of the two pesticides and Hg individually and simultaneously. Results showed that there was a close relationship between urease activity and organic matter content in soil. Chlorimuron-ethyl and furadan could both activate urease in the 4 soils. The maximum increment of urease activity by chlorimuronethyl was up to 14%-18%. There was almost an equal increase （up to 13%-21%） in the urease activity by furadan. On the contrary, Hg markedly inhibited soil urease activity. A logarithmic equation was used to describe the relationship （P〈0.05） between the concentration of Hg and the activity of soil urease in the 4 tested soils. Semi-effect dose （ED50） values by the stress of Hg based on the inhibition of soil urease in the 4 soils were 88, 5.5, 24 and 20 mg/kg, respectively, according to the calculation of the corresponding equations. The interactive effect of chlorimuron-ethyl or furadan with metal Hg on soil urease was mainly synergic at the highest tested concentrations.     

Organochlorine pesticides in soils under different land usage in the Taihu Lake region, China

A field study was conducted in the Taihu Lake region, China in 2004 to reveal the organochlorine pesticide concentrations in soils after the ban of these substances in the year 1983. Thirteen organochlorine pesticides (OCPs) were analyzed in soils from paddy field, tree land and fallow land. Total organochlorine pesticide residues were higher in agricultural soils than in uncultivated fallow land soils. Among all the pesticides, ΣDDX (DDD, DDE and DDT) had the highest concentration for all the soil samples, ranging from 3.10 ng/g to 166.55 ng/g with a mean value of 57.04 ng/g and followed by ΣHCH, ranging from 0.73 ng/g to 60.97 ng/g with a mean value of 24.06 ng/g. Dieldrin, endrin, HCB and α-endosulfan were also found in soils with less than 15 ng/g. Ratios of p,p'-(DDD DDE)/DDT in soils under three land usages were: paddy field ＞ tree land ＞ fallow land, indicating that land usage inlfuenced the degradation of DDT in soils. Ratios of p,p'-(DDD DDE)/DDT ＞1, showing aged residues of DDTs in soils of the Taihu Lake region. The results were discussed with data from a former study that showed very low actual concentrations of HCH and DDT in soils in the Taihu Lake region, but according to the chemical half-lives and their concentrations in soils in 1980s, the concentration of DDT in soils seemed to be underestimated. In any case our data show that the ban on the use of HCH and DDT resulted in a tremendous reduction of these pesticide residues in soils, but there are still high amounts of pesticide residues in soils, which need more remediation processes.     

Alterations of organ histopathology and metallolhionein mRNA expression in silver barb, Puntius gonionotus during subchronic cadmium exposure

Common silver barb,Puntius gonionotus,exposed to the nominal concentration of 0.06 mg/L Cd for 60 d,were assessed for histopathological alterations(gills,liver and kidney),metal accumulation,and metallothionein(MT)mRNA expression.Fish exhibited pathological symptoms such as hypertrophy and hyperplasia of primary and secondary gill lamellae,vacuolization in hepatocytes,and prominent tubular and glomerular damage in the kidney.In addition,kidney accumulated the highest content of cadmium,more than gills and liver.Expression of MT mRNA was increased in both liver and kidney of treated fish.Hepatic MT levels remained high after fish were removed to Cd-free water.In contrast,MT expression in kidney was peaked after 28 d of treatment and drastically dropped when fish were removed to Cd-free water.The high concentrations of Cd in hepatic tissues indicated an accumulation site or permanent damage on this tissue.