Pyrolysis of plastic packaging waste: A comparison of plastic residuals from material recovery facilities with simulated plastic waste

Pyrolysis may be an alternative for the reclamation of rejected streams of waste from sorting plants where packing and packaging plastic waste is separated and classified. These rejected streams consist of many different materials (e.g., polyethylene (PE), polypropylene (PP), polystyrene (PS), polyvinyl chloride (PVC), polyethylene terephthalate (PET), acrylonitrile butadiene styrene (ABS), aluminum, tetra-brik, and film) for which an attempt at complete separation is not technically possible or economically viable, and they are typically sent to landfills or incinerators. For this study, a simulated plastic mixture and a real waste sample from a sorting plant were pyrolyzed using a non-stirred semi-batch reactor. Red mud, a byproduct of the aluminum industry, was used as a catalyst. Despite the fact that the samples had a similar volume of material, there were noteworthy differences in the pyrolysis yields. The real waste sample resulted, after pyrolysis, in higher gas and solid yields and consequently produced less liquid. There were also significant differences noted in the compositions of the compared pyrolysis products.     

Hydrothermal carbonization of food waste and associated packaging materials for energy source generation

Hydrothermal carbonization (HTC) is a thermal conversion technique that converts food wastes and associated packaging materials to a valuable, energy-rich resource. Food waste collected from local restaurants was carbonized over time at different temperatures (225, 250 and 275 °C) and solids concentrations to determine how process conditions influence carbonization product properties and composition. Experiments were also conducted to determine the influence of packaging material on food waste carbonization. Results indicate the majority of initial carbon remains integrated within the solid-phase at the solids concentrations and reaction temperatures evaluated. Initial solids concentration influences carbon distribution because of increased compound solubilization, while changes in reaction temperature imparted little change on carbon distribution. The presence of packaging materials significantly influences the energy content of the recovered solids. As the proportion of packaging materials increase, the energy content of recovered solids decreases because of the low energetic retention associated with the packaging materials. HTC results in net positive energy balances at all conditions, except at a 5% (dry wt.) solids concentration. Carbonization of food waste and associated packaging materials also results in net positive balances, but energy needs for solids post-processing are significant. Advantages associated with carbonization are not fully realized when only evaluating process energetics. A more detailed life cycle assessment is needed for a more complete comparison of processes.     

The applicability of different waste materials for the production of lightweight aggregates

The applicability of different waste materials for the production of lightweight aggregates has been studied. The following waste materials were investigated: silica sludge, superfluous clay in the quarry, waste glass, and residue from the polishing process of different types of stone. SiC and MnO₂ were selected as foaming agents. Feldspar containing minerals and scrap glass were added in order to lower the softening point of the waste materials. The granules were prepared by mixing together finely ground waste with one or both of the selected foaming agents. The granules were then fired at different temperatures above the softening point of the glassy phase within the temperature range from 1150 to 1220 °C, where the foaming agent degasses, and the resulting gasses remain trapped in the glassy structure. The foaming process was observed by hot-stage microscopy. The properties of the so-obtained granules, such as their apparent density and compressive strength, were determined, and their microstructures were evaluating using SEM and polarizing microscopy.With the addition to clay of polishing residue from granite-like rocks, after firing at 1220 °C homogeneously porous granules with a density down to 0.42 g/cm³ were obtained, whereas with the addition to waste silica sludge of polishing residue from granite-like rocks and waste glass with a foaming agent, after firing at 1220 °C densities from 0.57 to 0.82 g/cm³ were obtained.     

我国包装废物回收体系研究

包装废物作为再生资源的重要一类,其回收体系融入在整个再生资源回收体系之中,与再生资源回收体系难以割裂,没有完全独立的包装废物回收系统。总结了我国包装废物回收体系的发展阶段,从目前看,其回收体系仍处于调整和规范发展阶段,并且还将维持较长时间;从不同角度归纳出包装废物的各种回收模式及相应特点;阐述了目前我国各种包装废物回收体系存在的合理性,与现阶段我国国情相符合;最后分析了包装废物回收体系中存在的主要问题,并提出相应的解决对策。     

我国包装废物回收利用管理体系研究

目前我国已具备可适用于包装废物管理的法律法规和政策制度基础,但对包装废物回收利用的管理多依靠市场行为和再生资源管理体系,缺乏规范性和针对性。包装废物管理的法规、政策、管理主体及其责任等方面都存在不足,导致对包装废物的监管缺位等一系列问题。在现有的法规体系基础上,提出包装废物管理改进的主要方面和对策措施,将法规政策落到实处,需要有关部门加以重视。     

韩国包装废物管理制度

介绍了韩国固体废物的管理中针对包装废物的管理体制和制度。韩国固体废物的主要监管执行部门是环境资源公社。韩国固体废物管理制度按照循环经济3R原则,制订了生产者责任延伸制度、废物付费制度、押金返还制度、分类排放标识制度及事业场废物减量化制度,在控制韩国包装废物产量和提高回收中起到了很好的作用。     

The origins of municipal solid waste: The relations between residues from packaging materials and food

Data for the composition of municipal solid waste (MSW) from around the world are used to further examine a previously reported statistical correlation between the fraction of food residues and the fractions of paper and board, metal, glass and plastics residues in MSW. For data from many locations, these correlations are statistically significant; multiple linear regressions are computed. The fraction of food waste decreases as the fractions of waste from paper and board, metals and glass increase.The situation in the U.S.A. is examined further for just packaging waste. Similar correlations are established for the fraction of food residues and the fractions of paper and board and plastics packaging residues for predicted compositions for 1980 to 2000. Similar correlations for the U.K. are not statistically significant. Some reasons for this are postulated.The results of the statistical analyses predict that a strategy for decreasing the fraction of food waste in MSW is to increase the use of food packaging by some amount, especially plastics and metals, contrary to conventional wisdom.     

Fate of metals contained in waste electrical and electronic equipment in a municipal waste treatment process

In Japan, waste electrical and electronic equipment (WEEE) that is not covered by the recycling laws are treated as municipal solid waste. A part of common metals are recovered during the treatment; however, other metals are rarely recovered and their destinations are not clear. This study investigated the distribution ratios and substance flows of 55 metals contained in WEEE during municipal waste treatment using shredding and separation techniques at a Japanese municipal waste treatment plant. The results revealed that more than half of Cu and most of Al contained in WEEE end up in landfills or dissipate under the current municipal waste treatment system. Among the other metals contained in WEEE, at least 70% of the mass was distributed to the small-grain fraction through the shredding and separation and is to be landfilled. Most kinds of metals were concentrated several fold in the small-grain fraction through the process and therefore the small-grain fraction may be a next target for recovery of metals in terms of both metal content and amount. Separate collection and pre-sorting of small digital products can work as effective way for reducing precious metals and less common metals to be landfilled to some extent; however, much of the total masses of those metals would still end up in landfills and it is also important to consider how to recover and utilize metals contained in other WEEE such as audio/video equipment.     

英国包装废物管理、产生和回收经验

英国制定了包装管理法规,提出了国家回收目标和公司回收目标。英国包装废物的总体回收率和再生利用率逐年提高,通过良好的环保理念、宣传措施、经济措施和建立回收体系,实现提高全社会参与包装废物回收和利用的水平。     

Immobilisation of PAH in waste materials

This paper gives an overview of the results of a research project into the possibilities of immobilising polycyclic aromatic hydrocarbons (PAH), that are present in waste materials. The results show that with hydraulic binders the waste materials can be solidified. The PAH do still leach to a relatively high extent. However, this PAH leaching can be decreased by more than a factor 10 by means of the addition of a specific additive. The immobilisation product fulfils technological requirements for the use as a road base construction material, such as compressive strength.     

Recycling of plastic packaging waste in Bandung City,Indonesia

Economic growth, changing consumption and production patterns are resulting in rapid increase in the generation of plastic wastes, including plastic packaging waste (PPW). A variety of PPW is identified in the municipal solid waste (MSW) stream. In this paper, quantity and composition of PPW at generators (residential and nonresidential sectors) and at the informal sector of waste recycling were measured, and accordingly the flow of PPW within Bandung City, Indonesia was analyzed. Though the generation rate per capita is not so high (25.1 g per day), total PPW generated by 2.3 million inhabitants in Bandung becomes 58.4 tonnes per day (3.76 % of total MSW generated). Due to lack of integrated MSW management, most of PPW is neither collected properly nor disposed of in appropriate manner by the municipality. Collection of valuable wastes including PPW is done predominantly by the informal sector without regard to health and safety. It is predicted that total PPW recycled by various informal waste recycling players like scavengers, junkmen, intermediates, and dealers is 27.5 tonnes per day (64.6 % of total PPW generated). Interviews regarding the existing handling methods and incentives preferred by generators to increase the recycling rate are also presented.     

废纸包装材料的研究现状及发展趋势

介绍了废纸包装材料的研究、应用和进展,分析了现有废纸材料应用上的优势及不足,提出了废纸包装材料的发展趋势。     

An econometric analysis of regional differences in household waste collection: the case of plastic packaging waste in Sweden

The Swedish producer responsibility ordinance mandates producers to collect and recycle packaging materials. This paper investigates the main determinants of collection rates of household plastic packaging waste in Swedish municipalities. This is done by the use of a regression analysis based on cross-sectional data for 252 Swedish municipalities. The results suggest that local policies, geographic/demographic variables, socio-economic factors and environmental preferences all help explain inter-municipality collection rates. For instance, the collection rate appears to be positively affected by increases in the unemployment rate, the share of private houses, and the presence of immigrants (unless newly arrived) in the municipality. The impacts of distance to recycling industry, urbanization rate and population density on collection outcomes turn out, though, to be both statistically and economically insignificant. A reasonable explanation for this is that the monetary compensation from the material companies to the collection entrepreneurs vary depending on region and is typically higher in high-cost regions. This implies that the plastic packaging collection in Sweden may be cost ineffective. Finally, the analysis also shows that municipalities that employ weight-based waste management fees generally experience higher collection rates than those municipalities in which flat and/or volume-based fees are used.     

美国包装废物管理、回收体系及产生回收状况

包装废物既产生于工业生产过程,也产生于商业物质循环流过程,更产生于居民的日常生活,是一类广泛存在的废物和资源。通过大量的资料和数据全面分析了美国的包装废物管理、产生和回收体系的特点和发展趋势,其中的一些经验可以为我国包装废物的管理提供借鉴。     

我国玻璃包装废物产生特性和回收对策研究

目前,玻璃包装废物的市场价值较低,难以依靠以自发自愿为主的市场化回收体系很好地回收各类玻璃包装废物。从玻璃包装行业特点入手,通过大量文献资料和必要的实地调研,分析了我国玻璃包装废物的流向特征、环境特征和产生数量特征,分析了玻璃包装废物回收的有利因素,提出了回收玻璃包装废物的两个关键控制环节的对策措施。为进一步强化玻璃包装废物的环境管理和循环利用提供支持依据。     

Management of packaging waste in Poland--development agenda and accession to the EU.

In recent years the issue of the municipal waste in Poland has become increasingly topical, with a considerable rise in the waste generation, much of which can be attributed to a boom in product packaging (mainly plastic). The annual production of plastics packaging has been constantly increasing over the last 20 to 30 years, and now exceeds 3.7 million tons. Due to a lack of processing technologies and poorly developed selective segregation system, packaging waste is still treated as a part of the municipal solid waste (MSW) stream, most of which is landfilled. As a result of Poland's access to the European Union, previous legal regulations governing municipal waste management have been harmonized with those binding on the member countries. One of the main changes, the most revolutionary one, is to make entrepreneurs liable for environmental risks resulting from the introduction of packaging to the market, and for its recycling. In practice, all entrepreneurs are to ensure recovery, and recycling, of used packaging from products introduced to the market at the required level. In recent year, the required recycling levels were fulfilled for all types of materials but mainly by large institutions using grouped and transport packaging waste for that matter. Household packaging gathered in the selective segregation system at the municipalities was practically left alone. This paper is an attempt to describe the system and assess the first year of functioning of the new, revamped system of packaging waste management in Poland. Recommendations are made relating to those features that need to be included in packaging waste management systems in order to maximize their sustainability and harmonization with the EU legal system.     

Life cycle assessment of a packaging waste recycling system in Portugal

Life Cycle Assessment (LCA) has been used to assess the environmental impacts associated with an activity or product life cycle. It has also been applied to assess the environmental performance related to waste management activities. This study analyses the packaging waste management system of a local public authority in Portugal. The operations of selective and refuse collection, sorting, recycling, landfilling and incineration of packaging waste were considered. The packaging waste management system in operation in 2010, which we called “Baseline” scenario, was compared with two hypothetical scenarios where all the packaging waste that was selectively collected in 2010 would undergo the refuse collection system and would be sent directly to incineration (called “Incineration” scenario) or to landfill (“Landfill” scenario). Overall, the results show that the “Baseline” scenario is more environmentally sound than the hypothetical scenarios.