浅谈低浓度有机废气治理技术的选择

文章介绍了4种常见低浓度有机废气治理技术的原理、优缺点,对比分析了低浓度有机废气治理技术的环保性能、运维费用和安全性能。沸石转轮吸附浓缩催化氧化技术在净化效率、运行费用、安全性方面明显优于其他有机废气治理技术。建议对于常规低浓度有机废气治理优先选择沸石转轮吸附浓缩催化氧化技术。     

有机废气治理技术的研究进展

有机废气治理问题是当前废气处理的难点问题之一。本文首先介绍了几类传统有机废气处理技术的发展现状,包括吸附法、吸收法、催化氧化法、生物处理法等。对这几类有机废气治理技术的应用机理、适用范围以及现存问题进行了综合地比较与分析。最后,对于近年来出现的几类新型有机废气处理技术,如膜分离法、光催化氧化法、综合处理法的发展前景进行了一定的展望并列举了几类新技术的工程应用实例。     

丙烯腈废气净化技术及其应用

文章分析了干法腈纶丙烯腈废气的污染因子及治理难点,提出了吸收与吸附相结合的废气联合净化治理技术,并对影响丙烯腈 (AN) 废气吸收的因素、工艺参数进行了总结,对提高废气治理技术有一定的指导作用.实践运行表明:丙烯腈废气经治理后可以直接排放,去除率达99.9%,达标率100%.     

RCO工艺在海工废气治理中的应用分析

针对某海洋工程公司喷漆车间产生的有机废气浓度波动范围大的特点,废气治理工程应用了沸石分子筛转轮吸附浓缩+蓄热式催化氧化工艺。通过设置完善的检测功能、制定不同工况下程序的自控切换功能,设置异常联锁处置安全程序,使有机废气治理设备可以在废气浓度波动范围大的工况条件下稳定运行,净化后废气达到国家及地方相关环保法规排放标准。     

吸附-冷凝回收技术探索

吸附法是一项广泛应用于治理大风量、中低浓度有机废气的浓缩净化技术,具有操作简单、净化效率高的优点。冷凝法是回收高浓度废气极为有效的手段。将吸附浓缩技术与冷凝回收技术进行有效结合,可高效回收中低浓度废气中具有再利用价值的有机溶剂等,实现有机溶剂的资源化回收利用。通过对吸附-冷凝工艺的详细介绍和分析,包括吸附剂和冷媒的选择、结构的优化、工业应用情况等,以期达到回收效率、设备成本及安全性等综合性能的最优化。     

长江经济带工业废气污染治理效率的时空演变及其影响因素研究

本文选取1998—2015年30个省份数据,采用超效率SBM模型测算全国、长江经济带工业废气污染治理效率;采用门槛效应模型研判长江经济带工业废气污染治理效率的影响因素.研究发现:1998—2015年长江经济带工业废气污染治理效率大于全国工业废气污染治理效率;长江经济带工业废气污染治理效率与全国工业废气污染治理效率的演变轨迹相似;长江经济带工业废气污染治理效率空间格局从"两极分化型"向"过渡型"演变;长江经济带沿线11省份工业废气污染治理效率与重工业占比呈负相关;当人均GDP较小时,长江经济带工业废气污染治理效率与工业化率、地方法规颁布件数、环境污染与破坏总次数呈负相关,与群众因污染来信数呈正相关;当人均GDP跨过门槛阈值拐点后,相关关系反之.为进一步推动长江经济带高质量发展,应加强中央与地方政府合作共促工业污染防控治理,推动重化工业绿色发展,加强媒体对废气污染的长期有效监督,推动建立科学有效的"三方共治"体系.     

化学实验室通风及废气治理工程设计

目前化学实验室的废气绝大多数都是直接排放,基本上未作废气处理.集中直接排放虽在某种程度上改善了操作人员的工作环境,但直接对大气造成了污染,严重地影响了周边地区的环境.本文介绍了一种高效率、低成本的将通风设计与实验室废气治理技术有机结合的方法.     

浅谈污水处理过程中曝气对大气环境的影响

在强化污水治理力度、大力建设污水处理厂的同时,污水处理过程中产生的废气对大气环境的污染应受到关注;作者分析了污水处理曝气过程产生的废气和排放量,以及废气含有的污染物对大气环境的影响;提出了应对污水处理废气进行研究及治理的新论点。     

硫醚类嗅味物质的检测和去除技术研究进展

硫醚类物质引起我国饮用水嗅味问题的典型嗅味物质。介绍了硫醚类物质的气味特征和产生来源;介绍了感官分析法、仪器分析法和感官气相色谱分析法3个主要的硫醚类物质检测技术的研究进展,简要阐述了各检测方法的优缺点和适用范围;论述了氧化技术、吸附技术、组合工艺对硫醚类物质的去除效果,阐明了去除技术适应情况及其主要问题。     

碳纤维吸附技术在双氧水氧化废气治理中的应用

介绍了活性碳纤维吸附技术在己内酰胺生产双氧水装置氧化废气治理中的应用,以及在应用过程中存在的误区和注意事项。     

废水资源化是实施可持续水资源管理的必然要求

介绍了可持续水资源管理的概念，阐述了实施可持续水资源管理的必要性。介绍了废水资源化的概念、意义及其发展历史与现状，论述了废水资源化是可持续水资源管理的必然要求。认为废水资源化管理必须充分考虑到其自身的特点。比较了废水资源化管理与普通的水资源管理的异同。     

低温捕集/热解吸气相色谱法分析废气中挥发性硫化物

采用低温捕集/热解吸/火焰光度检测填充柱气相色谱法可分析废气中挥发性硫化物。标准气浓度为2.80g/L～38.10g/L时,硫化氢、甲硫醇、乙硫醇、甲硫醚和二甲二硫的平均回收率及相对标准偏差分别为92.1%～106.8%及0.5%～6.0%,采样体积为1.0L时,上述挥发性硫化物的最低检出浓度为0.08ng/L～0.65ng/L。该分析测定了炼油厂某些污染源和催化燃烧脱硫中试装置废气中挥发性硫化物组成,验证了方法的适用性。     

Applicability of a continuous-flow system inner-coated with S-doped titania for the photocatalysis of dimethyl sulfide at low concentrations

The present study investigated the photocatalytic activity of an S-doped TiO₂ photocatalyst with regards to dimethyl sulfide degradation under visible-light irradiation, along with its deactivation and reactivation. The dimethyl sulfide conversion was between 85% and 93% for the lowest relative humidity range (10–20%) and close to 100% for the two higher relative humidity ranges (45–55% and 80–90%). The conversion was also close to 100% for the two lowest input concentrations (0.039 and 0.195 ppm), while it was between 91% and 96% at 3.9 ppm and between 85% and 90% at 7.9 ppm. In contrast to the input concentration dependences on conversion, the calculated degradation rates increased as input concentrations increased. The dimethyl sulfide conversion at low concentrations (≤0.39 ppm), which are associated with non-occupational inn occurring. However, catalyst deactivations were observed during the photocatalytic process whdoor air quality issues, was up to nearly 100% for long time periods (at least 603 h), without any significant catalyst deactivatioen higher concentrations (3.9 and 7.8 ppm) were used. The photocatalyst, reactivated by using two types of air (dried and humidified) under visible-light irradiation, did not regain all of its initial activities. Sulfate groups were qualitatively identified as the reaction products on the photocatalyst surface. In addition, gaseous byproducts, quantitatively determined, included dimethyl disulfide, methanol, and SO₂. It is noteworthy that the peak concentration of dimethyl disulfide (0.79 ppm = 790 ppb), generated over the photocatalytic process with the highest dimethyl sulfide input concentration, exceeded the odor threshold value of 0.1–3.6 ppb for dimethyl disulfide.     

Assessing determinants of industrial waste reuse: The case of coal ash in the United States

Devising effective strategies to facilitate waste reuse depends on the solid understanding of reuse behaviors. However, previous studies of reuse behavior have been limited in scope, focusing mostly on household recycling behaviors or very limited types of industrial wastes. To gain a better understanding of the business reuse behaviors, this study examined the impact of various factors in technical, economic, regulatory, and behavioral categories in the case of coal ash generated in the United States. The results of fixed effect models for fly ash and bottom ash particularly showed the significance role of the behavioral factor. In both models, a proxy variable, which represents knowledge sharing among the power plants or the utility's decision-making, turned out to be statistically significant and had the largest coefficient estimates among a group of variables. This finding may imply that the characteristics of waste reuse behavior are determined more by business decision-making behaviors than by market or institutional factors. However, the role of the behavioral variable was stronger in the bottom ash models than in the fly ash models. While the reuse of bottom ash was determined primarily by the behavioral variable, fly ash reuse was determined by more diverse factors including economic and regulatory variables. This could be explained by material characteristics in relation to competing resources and the nature of reuse applications.     

MULTIDISCIPLINARY PLANNING AND MANAGING OF WATER REUSE1

ABSTRACT: This paper examines a rapidly expanding area of water supplies, specifically water reclamation and reuse, and provides a comprehensive planning methodology for developing and evaluating water reuse alternatives. The methodology uses five phases: goal setting, identification of reuse opportunities, development and evaluation of planning alternatives, assessment of water reuse linkages, and making decisions and recommendations. A tool called “input-output modeling” is used in the third phase to present numerical data and choices. The methodology seeks to integrate the hydrologic and socio-economic aspects of water resources planning in the area of study. Water reuse may satisfy some of the increasing demands for water in the world, but water quality, economics, public attitudes, and legal and institutional constraints may impose limits on the extent to which it can be employed. The challenge in planning systems is to maximize the utilization of water reuse in the fact of these constraints. The importance of multidisciplinary collaboration cannot be overemphasized. This paper assesses the potential for water reclamation and reuse in developing countries by considering the relationships among the pertinent technical, social, economic, and environmental parameters. Generally, the planning process for water reuse has focused on specific technological processes, but in order to ensure the efficient transfer of waste water reuse technology into the society, the methodology seeks to provide a conceptual model which integrates the hydrologic and socioeconomic aspects of water resources planning and water reuse within the study area. (KEY WORDS: water reuse; water reclamation; planning; methodology; model; reuse technology; socio-hydrologic systems; socioeconomic systems.)     

Emergy evaluation of an integrated livestock wastewater treatment system

Wastewater treatment practices should pay more attention to their environmental performances due to their resources consumption and emissions’ impact. While reclaimed water reuse seems to have become a promising practice, is it always feasible in any condition? To address this issue, this study carried out an extended emergy evaluation of a holistic wastewater treatment system. On one hand, this method was extended to include the emissions’ impact. On the other hand, this study integrated a wastewater treatment plant, its excess sludge disposal system and treated water disposal system into an integrated wastewater treatment system (IWTS), so as to evaluate its performances more completely. And then several indicators, including cost per unit pollutant eliminated (CUPE), ratio of positive output (RPO), environmental load ratio (ELR), and sustainability index (SI), were proposed for evaluating the performances of an IWTS. Two scenarios (scenario A: wastewater treatment + sludge landfilling + treated water discharges; scenario B: wastewater treatment + sludge landfilling + reclaimed water reuse) for a livestock wastewater treatment plant in Sichuan Agricultural University located in Ya’an City in Southwest China, as cases, were researched. The results show that scenario B has lower positive output efficiency and greater environmental load than scenario A. Meanwhile, the reclaimed water reuse raises cost per unit pollutant eliminated compared with the treated water being discharged directly; emissions’ impact enhances the environmental load of the two scenarios to different degree; emissions’ impact has decisive effect on the sustainability of the two scenarios. These results mean that the reclaimed water reuse should not be advocated in this case. This study provides some policy implications: (1) wastewater treatment process should be comprehensively evaluated from its resources consumption and impact of emissions; (2) reclaimed water reuse should be carefully evaluated from its pros and cons simultaneously; (3) the local conditions should be considered when implementing reclaimed water reuse, such as local water body conditions, market demands, the related laws and regulations, corporations’ economic conditions, etc.     

中国城市污水集中处理的现状与对策研究

随着我国城市的迅速发展，城市普遍面临着水资源缺乏和水环境恶化的问题，已影响到城市的可持续发展。城市污水集中处理是解决城市水危机的有效方法，也是保护城市水环境的重要防线。分析了当前我国城市污水处理业的现状以及存在的问题，提出了加快污水处理厂技术革新，建设城市污水管网，加快城市污水回用产业化和完善污水处理厂的运营模式等解决办法，以保证我国城市实现可持续发展。     

Emergy-based fuzzy optimization approach for water reuse in an eco-industrial park

The establishment of an eco-industrial park (EIP) provides opportunity for individual plants to cooperate with each other in order to utilize resources efficiently and thus reduce waste. The goal of an EIP is to “close the loop” through recycling and reuse of material and energy streams. Studies show with current freshwater consumption trends there would be water stress aggravated by global warming in the near future. This paper presents a model to design an EIP water reuse network that considers overall system sustainability as measured with emergy, as well as cost saving desired by individual plants. Case studies from literature are then solved to illustrate the advantage of this method in decision making. The illustrative examples show how the model achieves a compromise among the potentially conflicting fuzzy goals of the various EIP stakeholders.     

Industrial symbiosis and waste recovery in an Indian industrial area

Recovery, reuse and recycling of industrial residuals, often dismissed as wastes, are common in India and other industrializing countries largely due to lower associated costs. Some wastes are reused within the facility where they are generated, others are reused directly by nearby industrial facilities, and some are recycled via the formal and informal recycling markets. Direct inter-firm reuse is the cornerstone of the phenomenon termed industrial symbiosis, where firms cooperate in the exchange of material and energy resources. This study applies material flow analysis to an economically diverse industrial area in South India to characterize the recovery, reuse and recycling of industrial residuals. It quantifies the generation of waste materials from 42 companies as well as the materials that are directly traded across facilities and those that are recycled or disposed. This study encompasses a business cluster in Mysore in the State of Karnataka, and is the first in India to thoroughly quantify material flows to identify existing symbiotic connections in an industrial area. Examined industries in this industrial area generate 897,210 metric tons of waste residuals annually, and recovered 99.5% of these, 81% with reused by the companies that generated them, with one company, a sugar refinery, processing most of this amount. Geographic data show that operations within 20 km of the industrial area receive over 90% of residuals exiting facility gates. Two-thirds of this amount goes directly to other economic actors for reuse. This study makes key contributions to the literature in distinguishing how particular types of materials are reused in different ways, the geographic extent of symbiotic activities and the important role of the informal sector in industrial waste management in industrializing regions.     

Grey water reclamation by decentralized MBR prototype

Grey water treatment and reuse for non-drinking water requirements has become of great interest in arid and semi-arid zones where water resources are becoming both quantitatively and qualitatively scarce. In this study a decentralized and automatic MBR prototype has been designed and installed in the REMOSA facilities for treatment of low-load grey water to be recycled in flushing-toilet application. The recycling treatment of grey water comprises four stages: screening, biological oxidation, filtration and a final disinfection by chlorination. The influent and effluent were monitored in order to determine the treatment efficiency and assessment of the quality potential of treated grey water. The results obtained indicate that recycling of grey water allows an effluent of excellent quality with organic, surfactants and microbial parameters under the limits defined by Spanish legislation for urban water reuse. The disinfection of treated grey water is required to ensure compliance with microbial standards and to avoid the health risk in storage and application of recycled water.