Biosorption of Cu and Zn from aqueous solutions by dried marine green macroalga Chaetomorpha linum

The biosorption of the heavy metals Cu²⁺ and Zn²⁺ by dried marine green macroalga (Chaetomorpha linum) was investigated. The biosorption capacities of the dried alga for copper and zinc were studied at different solution pH values (2–6), different algal particle sizes (100–800 μm) and different initial metal solution concentrations (0.5–10 mM). An optimum pH value of 5 was found suitable for both metal ions biosorption for both metal ions. At the optimum particle size (100–315 μm), biosorbent dosage (20 g/l) and initial solution pH (pH 5), the dried alga produced maximum copper and zinc uptakes values (q_max) of 1.46 and 1.97 mmol/g respectively (according to the Langmuir model). The kinetic data obtained at different initial metal concentrations indicated that the biosorption rate was fast and most of the process was completed within 120 min. This study illustrated an alternative technique for the management of unwanted biological materials using processed algal material. C. linum is one of the fast-growing marine algae in the lake of Tunis and could be utilized as a biosorbent for the treatment of Cu²⁺ and Zn²⁺ contaminated wastewater streams.     

STREAM WATER CHEMISTRY IN WATERSHEDS RECEIVING DIFFERENT ATMOSPHERIC INPUTS OF H+, NH4, NO3−, AND SO42−1

ABSTRACT: Weekly precipitation and stream water samples were collected from small watersheds in Denali National Park, Alaska, the Fraser Experimental Forest, Colorado, Isle Royale National Park, Michigan, and the Calumet watershed on the south shore of Lake Superior, Michigan. The objective was to determine if stream water chemistry at the mouth and upstream stations reflected precipitation chemistry across a range of atmospheric inputs of H⁺, NH₄⁺, NO₃^?_?, and SO₄^2?. Volume-weighted precipitation H⁺, NH₄⁺, NO₃^?_?, and SO₄^2? concentrations varied 4 to 8 fold with concentrations highest at Calumet and lowest in Denali. Stream water chemistry varied among sites, but did not reflect precipitation chemistry. The Denali watershed, Rock Creek, had the lowest precipitation NO₃^?_? and SO₄^2? concentrations, but the highest stream water NO₃^?and SO₄^2? concentrations. Among sites, the ratio of mean monthly upstream NO₃^?_? concentration to precipitation NO₃^?_- concentration declined (p < 0.001, R²= 0.47) as precipitation NO₃^?_? concentration increased. The ratio of mean monthly upstream to precipitation SO₄^2? concentration showed no significant relationship to change in precipitation SO₄^2? concentration. Watersheds showed strong retention of inorganic N (> 90 percent inputs) across inputs ranging from 0.12 to > 6 kg N ha^?1 y^?1. Factors possibly accounting for the weak or non-existent signal between stream water and precipitation ion concentrations include rapid modification of meltwater and precipitation chemistry by soil processes, and the presence of unfrozen soils which permits winter mineralization and nitrification to occur.     

Study on the hydrolysis/precipitation behavior of Keggin Al13 and Al30 polymers in polyaluminum solutions

The hydrolysis/precipitation behaviors of Al³⁺, Al₁₃ and Al₃₀ under conditions typical for flocculation in water treatment were investigated by studying the particulates' size development, charge characteristics, chemical species and speciation transformation of coagulant hydrolysis precipitates. The optimal pH conditions for hydrolysis precipitates formation for AlCl₃, PAC_Al13 and PAC_Al30 were 6.5–7.5, 8.5–9.5, and 7.5–9.5, respectively. The precipitates' formation rate increased with the increase in dosage, and the relative rates were AlCl₃ ? PAC_Al30 > PAC_Al13. The precipitates' size increased when the dosage increased from 50 μM to 200 μM, but it decreased when the dosage increased to 800 μM. The Zeta potential of coagulant hydrolysis precipitates decreased with the increase in pH for the three coagulants. The iso-electric points of the freshly formed precipitates for AlCl₃, PAC_Al13 and PAC_Al30 were 7.3, 9.6 and 9.2, respectively. The Zeta potentials of AlCl₃ hydrolysis precipitates were lower than those of PAC_Al13 and PAC_Al30 when pH > 5.0. The Zeta potential of PAC_Al30 hydrolysis precipitates was higher than that of PAC_Al13 at the acidic side, but lower at the alkaline side. The dosage had no obvious effect on the Zeta potential of hydrolysis precipitates under fixed pH conditions. The increase in Zeta potential with the increase in dosage under uncontrolled pH conditions was due to the pH depression caused by coagulant addition. Al–Ferron research indicated that the hydrolysis precipitates of AlCl₃ were composed of amorphous Al(OH)₃ precipitates, but those of PAC_Al13 and PAC_Al30 were composed of aggregates of Al₁₃ and Al₃₀, respectively. Al³⁺ was the most un-stable species in coagulants, and its hydrolysis was remarkably influenced by solution pH. Al₁₃ and Al₃₀ species were very stable, and solution pH and aging had little effect on the chemical species of their hydrolysis products. The research method involving coagulant hydrolysis precipitates based on Al–Ferron reaction kinetics was studied in detail. The Al species classification based on complex reaction kinetic of hydrolysis precipitates and Ferron reagent was different from that measured in a conventional coagulant assay using the Al–Ferron method. The chemical composition of Al_a, Al_b and Al_c depended on coagulant and solution pH. The Al_b measured in the current case was different from Keggin Al₁₃, and the high Al_b content in the AlCl₃ hydrolysis precipitates could not used as testimony that most of the Al³⁺ was converted to highly charged Al₁₃ species during AlCl₃ coagulation.     

Production of Fe2O3 from FeSO4·xH2O formed in galvanizing works

FeSO₄·xH₂O is generated in large amounts in galvanizing workshops. It can be reutilized by conversion to Fe₂O₃. In this study, the recovery of Fe₂O₃ from FeSO₄·xH₂O formed in the galvanizing process has been examined. The experimental work was carried out at various temperatures and times in the oxidizing medium. The reaction temperatures and times were selected as 450, 500, 550, 600, 650, 700, 800 and 900°C, and 15, 30, 45, 60, 90 and 120 minutes, respectively. In order to determine the amount of Fe₂O₃, a titrimetric method was applied. The reaction products were characterized by means of IR and XRD techniques.The extent of conversion is low at temperatures below 650°C. Almost all of the iron (II) sulfate in the original sample was converted to iron(III) oxide at 650°C (120 min), 700°C (90 min), 800°C (60 min) and 900°C (45 min).     

Utilization of waste product (tamarind seeds) for the removal of Cr(VI) from aqueous solutions: Equilibrium, kinetics, and regeneration studies

In the present study, an adsorbent was prepared from tamarind seeds and used after activation for the removal of Cr(VI) from aqueous solutions. The tamarind seeds were activated by treating them with concentrated sulfuric acid (98% w/w) at a temperature of 150 °C. The adsorption of Cr(VI) was found to be maximum at low values of initial pH in the range of 1–3. The adsorption process of Cr(VI) was tested with Langmuir, Freundlich, Redlich–Peterson, Koble–Corrigan, Tempkin, Dubinin–Radushkevich and Generalized isotherm models. Application of the Langmuir isotherm to the system yielded a maximum adsorption capacity of 29.7 mg/g at an equilibrium pH value ranging from 1.12 to 1.46. The adsorption process followed second-order kinetics and the corresponding rate constants obtained were 2.605 × 10⁻³, 0.818 × 10⁻³, 0.557 × 10⁻³ and 0.811 × 10⁻³ g/mg min⁻¹ for 50, 200, 300 and 400 mg/L of initial Cr(VI) concentration, respectively. The regenerated activated tamarind seeds showed more than 95% Cr(VI) removal of that obtained using the fresh activated tamarind seeds. A feasible solution is proposed for the disposal of the contaminants (acid and base solutions) containing high concentrations of Cr(VI) obtained during the regeneration (desorption) process.     

Batch and continuous biosorption of Cu by immobilized biomass of Arthrobacter sp.

The ability of free and polysulphone immobilized biomass of Arthrobacter sp. to remove Cu²⁺ ions from aqueous solution was studied in batch and continuous systems. The Langmuir and Freundlich isotherm models were applied to the data. The Langmuir isotherm model was found to fit the sorption data indicating that sorption was monolayer and uptake capacity (Q^o) was 175.87 and 158.7 mg/g for free and immobilized biomass respectively at pH 5.0 and 30 °C temperature, which was also confirmed by a high correlation coefficient, a low RMSE and a low Chi-square value. A kinetic study was carried out with pseudo-first-order reaction and pseudo-second-order reaction equations and it was found that the Cu²⁺ uptake process followed the pseudo-second-order rate expression. The diffusivity of Cu²⁺ on immobilized beads increased (0.402 × 10⁻⁴ to 0.435 × 10⁻⁴ cm²/s) with increasing concentration from 50 to 150 mg/L. The maximum percentage Cu²⁺ removal (89.56%) and uptake (32.64 mg/g) were found at 3.5 mL/min and 20 cm bed height. In addition to this the Bed Depth Service Time (BDST) model was in good agreement with the experimental data with a high correlation coefficient (>0.995). Furthermore, sorption and desorption studies were also carried out which showed that polysulphone immobilized biomass could be reused for up to six sorption–desorption cycles.     

Model prediction on the rise of pCO2 in uniform flows by leakage of CO2 purposefully stored under the seabed

A numerical study was conducted to predict pCO₂ change in the ocean on a continental shelf by the leakage of CO₂, which is originally stored in the aquifer under the seabed, in the case that a large fault connects the CO₂ reservoir and the seabed by an earthquake or other diastrophism. The leakage rate was set to be 6.025 × 10⁻⁴ kg/m²/sec from 2 m × 100 m fault band, which corresponds to 3800 t-CO₂/year, referring to the monitored seepage rate from an existing EOR field. The target space in this study was limited to the ocean above the seabed, the depth of which was 200 or 500 m. The computational domain was idealistically rectangular with the seabed fault-band perpendicular to the uniform flow. The CO₂ takes a form of bubbles or droplets, depending on the depth of water, and their behaviour and dissolution were numerically simulated during their rise in seawater flow. The advection–diffusion of dissolved CO₂ was also simulated. As a result, it was suggested that the leaked CO₂ droplets/bubbles all dissolve in the seawater before spouting up to the atmosphere, and that the increase in pCO₂ in the seawater was smaller than 500 μ atm.     

Acid-forming emissions in Alberta,Canada

The sulphur dioxide and nitrogen oxides emissions from all sources in Alberta, Canada, during 1982 amounted to 488,297 and 353,511 tonnes, respectively. During this year deposition of wet sulphate from all stations in the province, 8 kg ha^–1 yr^–1, compares well with the five-year average (1978–1982) value of 10 kg ha^–1 yr^–1. These measurements are about one-half of the wet sulphate deposition criteria of 20 kg ha^–1 yr^–1 established for protecting the moderately sensitive aquatic ecosystem in eastern Canada. Due to dry, cold, continental climate conditions of Alberta, dry sulphate or sulphur deposition is equally or more important than wet deposition. No effects of the long-range transport of atmospheric pollutants (LRTAP) on the ecosystems in Alberta have been observed to date. Atmospheric deposition target loadings of SO₄ ^–2, NO₃ ^–, and H⁺ for Alberta and western Canadian environmental conditions should be developed to protect the highly sensitive ecosystems. Some future research and monitoring priorities for Alberta and western Canada are outlined.     

Operation strategy of a sequencing batch reactor for simultaneous removal of wastewater organic matter and nutrients

The Sequencing Batch Reactor (SBR) system employing activated sludge process is an alternative wastewater treatment technology. A cycle of the conventional SBR system generally consists of five periods, with complete aeration during the React period to oxidize the organic matter and nitrify the ammonium-nitrogen of wastewater. Laboratory-scale reactors were used to evaluate the feasibility of incorporating alternative aerobic-anoxic-aerobic stages within the React period for simultaneous removal of organic matter, N and P. Two cycles of SBR process per day were maintained.Under the operation strategy of 0.75-h fill, 8-h react (with continuous aeration), 3.25-h settle, draw and idle periods, the treatment performance became consistent after running the system for two to four cycles (1–2 days). The percentages of both BOD₅ and COD removal were around 94% from Cycle 2 onwards, the BOD₅ content dropped from initial 251 mg L⁻¹ to less than 14 mg L⁻¹ in the final effluent. A steady nitrification (about 97%) was obtained from Cycle 4 onwards, with 1 mg NH₄⁺-N L⁻¹ and 25 mg NO₃⁻-N L⁻¹ present in the final effluent. This suggested that the time required for SBR system to acclimate and reach an equilibrium state was relatively short when compared with the time needed for continuous flow activated sludge system. The findings also show that 4-h aeration during the react period was long enough to achieve more than 90% nitrification. With the incorporation of a 3-h anoxic stage after the initial 4-h aeration of the react period, a satisfactory denitrification process was observed, with nitrate level dropped from 27 to around 8 mg L⁻¹ within 3 h. The second aeration stage did not cause significant change in wastewater nitrogen content. The wastewater phosphate content declined rapidly during the initial 4-h aeration and P-release was not observed during the anoxic stage. A slight reduction of P was found in the second aeration stage suggesting that more P-uptake occurred in this stage. A 12-h cyclic SBR system with the incorporation of 4-h aerobic, 3-h anoxic and final 1-h aerobic stages into the 8-h react period was demonstrated to be able to remove C, N and P simultaneously.     

Revegetation of serpentine substrates: Response to phosphate application

Revegetation was studied on stockpiled serpentine substrate. The native vegetation surrounding the revegetation site is annual grassland. The seed mixture applied to both subsoil and topsoil plots was largely ineffective for revegetation. No growth occurred in the subsoil plots and most of the growth in the topsoil plots was from indigenous seed. Phosphate application (100 kg P ha^–1 as NaH₂PO₄ · H₂O) to the topsoil plots resulted in a significant increase in total above-ground productivity. Annual legumes (mostlyLotus subpinnatus Lag.) and, to a lesser degree,Plantago erecta Morris responded to the added phosphate with an increased above-ground productivity. Other annual forbs and annual grasses showed no significant response. The legumes also increased in abundance. Mycorrhizal root colonization forPlantago was not significantly affected by phosphate application, but was lower in this disturbed serpentine site compared to other undisturbed serpentine annual grassland sites nearby.     

Responses of herbaceous mimosa (Mimosa strigillosa), a new reclamation species, to soil pH

Growth responses of herbaceous mimosa (Mimosa strigillosa Torr. and Gray), a potential new reclamation species in the SE USA and Mexico, to nine soil pH scales were studied under a controlled environment at Nacogdoches, TX, USA. Twenty seeds were planted in each of 40 (nine scales plus one control in four replicates) 20.3-cm pots filled with Tonkawa sandy soil. These pots were treated with H₂SO₄ or Ca(OH)₂ to adjust each pot to its designated pH level. After 15 days of seeding, the emergence rate was at best about 50–70% for pH 4.7–6.6. The plant can survive and grow at soil pH as low as 4.7, but the optimum growth seems to be on soils with pH ranging from 6.2 to 7.1. At this pH range, the plant exhibits higher values of green and dry biomass, longer shoot growth and lower root/shoot weight and length ratios. The survival rate was greater than 90% for all treatments, except for pH 4.1. There were no nutrient deficiencies in plant tissues on soil pH 4.7 or higher. The plant allocated more growth to the shoot under optimum conditions, but more growth to the roots under environmental stress. It is not suitable for herbaceous mimosa to grow on soils with pH 4.1 or less.     

Removal and recycling of copper from aqueous solutions using treated Indian barks

Removal of copper from aqueous solutions containing 100–1000 ppm, using different Indian bark species, was performed on laboratory scale. The percentage removal of metal ions depends on the solution pH, bark species and time. The efficiency of copper removal by the used raw barks increases with a rise of solution pH and reaches a maximum of about 65–78% around pH 4–5. However, the decontaminated aqueous solutions were colored due to the dissolution of soluble organic compounds contained in the raw bark. This increases the biological and chemical oxygen demand (BOD and COD) of the solutions as well as the total organic carbon content (TOC). For this reason, raw bark should be treated either by chemical or biological means. Such treatment will allow the extraction of the soluble organic compounds and increase the chelating capacity and efficiency of the treated bark. Depending on the pH value, the chelating efficiency of treated barks is about 1.2–2.2 times that of the raw ones. Moreover, the retention capacity of the Indian treated bark varies from about 42–51 mg/g of dry bark. It is equal to or higher than that of common European species. About 1.8 mols of H₃O⁺ are released, by the treated barks, for every mol of chelated copper ions. Moreover, scanning electron microscopy (SEM) observations show uniform distribution of metal ions throughout the copper saturated bark. Infra red (IR) spectra suggest that the copper ions are chelated to hydroxyl and/or carboxyl functional groups of organic compounds contained in the treated bark. It seems that the interaction of the copper ions with the bark follows a cation exchange mechanism. This hypothesis is supported by elution experiments that allow recovery of about 99% of the contained copper. The retention capacity of the treated bark is almost constant after five cycles of chelation–elution, suggesting that the ‘life time cycle' is sufficiently long for continuous industrial application. The spent copper loaded barks can either be incinerated or pyrolysed. It generates solids containing either ≈80% of CuO or ≈14% of Cu°, respectively. Such materials can be used either in the secondary or primary copper production, thus offering a friendly environmental solution of effluents' treatment. The suggested process can be used as an alternative to the classical technologies for effluent decontamination. It is also efficient for polishing effluents treated by other methods.     

Experimental investigation of adsorption capacity of anthill in the removal of heavy metals from aqueous solution

In the present work, the adsorption capacity of anthill was investigated as a low‐cost adsorbent to remove the heavy metal ions, lead (II) ion (Pb²⁺), and zinc (II) ion (Zn²⁺) from an aqueous solution. The equilibrium adsorption isotherms of the heavy metal ions were investigated under batch process. For the study we examined the effect of the solution's pH and the initial cations concentrations on the adsorption process under a fixed contact time and temperature. The anthill sample was characterized using a scanning electron microscope (SEM), X‐ray fluorescence (XRF), and Fourier transform infrared (FTIR) techniques. From the SEM analysis, structural change in the adsorbent was a result of heavy metals adsorption. Based on the XRF analysis, the main composition of the anthill sample was silica (SiO₂), alumina (Al₂O₃), and zirconia (ZrO₂). The change in the peaks of the spectra before and after adsorption indicated that there was active participation of surface functional groups during the adsorption process. The experimental data obtained were analyzed using 2‐ and 3‐parameter isotherm models. The isotherm data fitted very well to the 3‐parameter Radke–Prausnitz model. It was noted that Pb²⁺ and Zn²⁺ can be effectively removed from aqueous solution using anthill as an adsorbent.     

Growth and macronutrient removal of water hyacinth in a small secondary sewage treatment plant

Studies have been made of the growth characteristics of water hyacinth, Eichhornia crassipes (Mart.) Solms, and its ability to remove N, P and K, in a secondary settling pond of a small secondary sewage treatment plant serving both the academic and residential blocks of the Swire Marine Laboratory, University of Hong Kong. The treatment plant consists of, in series, a primary settling tank, a trickling filter compartment and a secondary settling pond from which part of the treated wastewater is recycled to the primary settling tank while the remaining effluent (1 to 2 m³ daily) mixes with and hence is diluted by the outflowing seawater from the aquarium system of the Swire Marine Laboratory before discharge to the sea. Samples of wastewater have been taken regularly from the primary sedimentation pond, the outflow of the trickling filter, the secondary settling pond and the effluent of the treatment plant (before mixing with aquarium outflow) since January, 1992. Physical, chemical and biological characteristics of the samples have been determined and are typical of secondary effluents, with a mean pH of about 7.5, total solids 1200 mg L⁻¹, suspended solids 45 mg L⁻¹, conductivity 2000 μS cm⁻¹, salinity 1 ppt, dissolved oxygen 2 mg L⁻¹, BOD₅ 45 mg L⁻¹, Kjeldahl-N 30 mg L⁻¹, NH₄,-N 25 mg L⁻¹, NO₃-N 4 mg L⁻¹, total P 10 mg L⁻¹, K 35 mg L⁻¹ and total coliforms of less than 10⁵ colonies 100 ml⁻¹.Water hyacinth plants have been stocked in the secondary settling pond as an integral part of the treatment plant so as to improve the quality of, as well as to retrieving and recycling nutrient elements from, the wastewater. The plants are periodically harvested to maintain an active growing crop. The growth rate, standing crop biomass, tissue nutrient composition, nutrient storage and accumulation rate of two growth cycles, one from February 25 to March 18 (mean temperature 17.6°C) and the other from 22 April to 12 May (24.8°C) are reported. The water hyacinth assumed a relatively high standing crop biomass of 10 kg m⁻² (5 to 6 t DM ha⁻¹), and growth rates of 48 and 225 g m⁻² day⁻¹, respectively, for the first and second growth period. Nutrient storage capacities were relatively high, at about 20, 7.5 and 16.5 g m⁻² for N, P and K, respectively. The nutrient composition was very high, reaching 5.42% for N, 1.97 for P, and 4.57 for K. Both the stem and lamina accumulated high levels of N, while the petiole had the highest level of P and K. Apart from nutrient removal, the water hyacinth also helped to decrease the suspended solids, BOD₅ value and total coliforms of the wastewater.It is concluded that water hyacinth improves the quality of wastewater in such small-scale sewage treatment plants and it is recommended that frequent harvests of water hyacinth would increase the treatment efficiency, especially during the active growing season with high temperatures coupled with intense solar radiation.     

Water/acid gas interfacial tensions and their impact on acid gas geological storage

Acid gas geological disposal is a promising process to reduce CO₂ atmospheric emissions and an environment-friendly and economic alternative to the transformation of H₂S into sulphur by the Claus process. Acid gas confinement in geological formations is to a large extent controlled by the capillary properties of the water/acid–gas/caprock system, because a significant fraction of the injected gas rises buoyantly and accumulates beneath the caprock. These properties include the water/acid gas interfacial tension (IFT), to which the so-called capillary entry pressure of the gas in the water-saturated caprock is proportional. In this paper we present the first ever systematic water/acid gas IFT measurements carried out by the pendant drop technique under geological storage conditions. We performed IFT measurements for water/H₂S systems over a large range of pressure (up to P = 15 MPa) and temperature (up to T = 120 °C). Water/H₂S IFT decreases with increasing P and levels off at around 9–10 mN/m at high T (≥70 °C) and P (>12 MPa). The latter values are around 30–40% of water/CO₂ IFTs, and around 20% of water/CH₄ IFTs at similar T and P conditions. The IFT between water and a CO₂ + H₂S mixture at T = 77 °C and P > 7.5 MPa is observed to be approximately equal to the molar average IFT of the water/CO₂ and water/H₂S binary mixtures. Thus, when the H₂S content in the stored acid gas increases the capillary entry pressure decreases, together with the maximum height of acid gas column and potential storage capacity of a given geological formation. Hence, considerable attention should be exercised when refilling with a H₂S-rich acid gas a depleted gas reservoir, or a depleted oil reservoir with a gas cap: in the case of hydrocarbon reservoirs that were initially (i.e., at the time of their discovery) close to capillary leakage, acid gas leakage through the caprock will inevitably occur if the refilling pressure approaches the initial reservoir pressure.     

Unexpected difference in phenol sorption on PTMA- and BTMA-bentonite

The comparison of phenol sorption on phenyltrimethylammonium (PTMA)- and benzyltrimethylammonium (BTMA)-bentonite shows a clear difference as far as phenol sorption isotherms are concerned. For PTMA-bentonite the sorption isotherm is of a straight-line character which results from simple partitioning of phenol between the aqueous and organic phases sorbed on the bentonite surface. For BTMA-bentonite the isotherm has a convex shape, characteristic of physicochemical sorption.For the first time a three-parametric model, including the dissociation constant of phenol pK_a, distribution constant of phenol Kd_phen and phenolate anion Kd_phen⁻ between the aqueous phase and the bentonite phases is used for the evaluation of phenol sorption on organoclays with pH change. The model shows that the values of Kd_phen are higher than those of Kd_phen⁻ for all investigated initial phenol concentrations.The inspection of the FTIR spectrum of BTMA-bentonite loaded with phenol in the regions 1300–1600 and 1620–1680 cm⁻¹ shows the features of π–π electron interaction between the benzene rings of phenol and the BTMA cation together with the phenol–water hydrogen bond strengthened by this interaction.     

Assessment of the spring water quality in The Shoubak area,Jordan

The present study investigates the physical, chemical, and biological characteristics of spring water samples in Shoubak area in the southern Jordan. The samples were collected from May 2004 to May 2005. All samples were analyzed for temperature, conductivity, dissolved oxygen, pH, major cations (Ca²⁺, Mg²⁺, K⁺, Na⁺), major anions (Cl⁻, NO₃⁻, HCO₃⁻, SO₄²⁻, PO₄³⁻, F⁻), and trace metals (Fe²⁺, Al³⁺, Mn²⁺, Cu²⁺, Cr³⁺, Ni²⁺, Zn²⁺, Pb²⁺, Cd²⁺). Water quality for available springs showed high salinity through long period of contact with rocks. The ion concentrations in the water samples were from dissolution of carbonate rocks and ion exchange processes in clay. The general chemistry of water samples was typically of alkaline earth waters with prevailing bicarbonate chloride. Some springs showed elevated nitrate and sulfate contents which could reflect to percolation from septic tanks, cesspools, and agricultural practices. The infiltration of wastewater from cesspools and septic tanks into groundwater is considered the major source of water pollution. The results showed that there were great variations among the analyzed samples with respect to their physical, chemical and biological parameters, which lie below the maximum permissible levels of the Jordanian and WHO drinking water standards. The results indicate that the trace metals of spring’s water of Shoubak area do not generally pose any health or environmental problems. Factor analysis was used to identify the contributers to water quality. The first factor represents major contribution from anthropogenic activities, while the second one represents major contribution from natural processes.     

Kinetics of carbon dioxide absorption into mixed aqueous solutions of MDEA and MEA using a laminar jet apparatus and a numerically solved 2D absorption rate/kinetics model

New comprehensive numerically solved 1D and 2D absorption rate/kinetics models have been developed, for the first time, to interpret the experimental kinetic data obtained with a laminar jet apparatus for the absorption of carbon dioxide (CO₂) in CO₂ loaded mixed solutions of mixed amine system of methyldiethanolamine (MDEA) and monoethanolamine (MEA). Three MDEA/MEA weight ratios ranging from 27/03 to 23/07, over a concentration range of 2.316–1.996 kmol/m³ for MDEA and of 0.490–1.147 kmol/m³ for MEA were studied. The models take into account the coupling between chemical equilibrium, mass transfer, and the chemical kinetics of all possible chemical reactions involved in the CO₂ reaction with MDEA/MEA solvent. The partial differential equations of the 1D model were solved by two numerical techniques; the finite difference method (FDM) based on in-house coded Barakat–Clark scheme and the finite element method (FEM) based on COMSOL software. The FEM comprehensive model was then used to solve the set of partial differential equations in the 2D cylindrical coordinate system setting. Both FDM and FEM produced very accurate results for both the 1D and 2D models, which were much better than our previously published simplified model. The reaction rate constant obtained for MEA blended into MDEA at 298–333 K was k_MEA = 5.127 × 10⁸ exp(−3373.8/T). In addition, the 2D model, for the first time, has provided the concentration profiles of all the species in both the radial and axial directions of the laminar jet, thereby enabling an understanding of the correct sequence in which the reaction steps involved in the reactive absorption of CO₂ in aqueous mixed amines occur.     

Trapping and decomposing of color compounds from recycled water by TiO2 coated activated carbon

Five types of commercially available activated carbons (ACs) were coated with TiO₂ nanoparticles prepared using a sol–gel method. Color and trace organics remaining in the actual treated effluent were adsorbed by TiO₂ coated ACs. The absorbed organic compounds were then decomposed using a photocatalytic process, and the ACs were regenerated for reuse. The efficiency of the process was assessed by the characterization of true color and A₂₅₄ (the organics absorption at the wavelength of 254 nm) at the beginning and the end of the experiment. The effects of UV light source, UV irradiation time, hydrogen peroxide and ultrasound on the efficiency of photocatalytic regeneration were also investigated. Significant differences in the efficiency were observed between uncoated ACs and TiO₂ coated samples. Among the 5 types of ACs tested, AC-3, AC-4 and their coated ones achieved better efficiency in color and A₂₅₄ removal, with around 90% or more color and A₂₅₄ being removed within 1 h of treatment. The data obtained in this study also demonstrated that the photocatalytic process was effective for decomposing the adsorbed compounds and regenerating the spent TiO₂/AC-3. Finally, it was found that this regeneration process could be greatly enhanced with the assistance of H₂O₂ and ultrasound by reducing the required regeneration time.     

Pipeline design for a least-cost router application for CO2 transport in the CO2 sequestration cycle

CO₂ capture and geological storage (CCS) is considered as a viable option to mitigate greenhouse gas emissions during the transition phase towards the use of clean and renewable energy. This paper concentrates on the transport of CO₂ between source (CO₂ capture at plants) and sink (geological storage reservoirs). In the cost estimation of CO₂ transport, the pipeline diameter plays an important role. In this respect, the paper reviews equations that were used in several reports on CO₂ pipeline transport. As some parameters are not taken into account in these equations, alternative formulas are proposed which calculate the proper inner diameter size based on flow rate, pressure drop per unit length, CO₂ density, CO₂ viscosity, pipeline material roughness and topographic height differences (the Darcy–Weisbach solution) and, in addition, on the amount and type of bends (the Manning solution). Comparison between calculated diameters using the reviewed and the proposed equations demonstrate the important influence of elevation difference (which is not considered in the reviewed equations) and pipeline material roughness-related factor on the calculated diameter. Concerning the latter, it is suggested that a Darcy–Weisbach roughness height of 0.045 mm better corresponds to a Manning factor of 0.009 than higher Manning values previously proposed in literature. Comparison with the actual diameter of the Weyburn pipeline confirms the accuracy of the proposed equations. Comparison with other existing CO₂ pipelines (without pressure information) indicate that the pipelines are designed for lower pressure gradients than 25 Pa/m or for (future) higher flow rates. The proposed Manning equation is implemented in an economic least-cost route planner in order to obtain the best economic solution for pipeline trajectory and corresponding diameter.