Improved management practice and process hazard analysis techniques for minimizing likelihood of process safety incidents in Taiwan

In Taiwan, process safety accidents often occur despite the prior implementation of process hazard analysis (PHA). One of the main reasons for this is the poor quality of the PHA process; with the main hazards not being properly identified, or properly controlled. Accordingly, based on the findings of 86 process safety management (PSM) audits, dozens of post-accident site resumption review meetings, and hundreds of PSM review sessions, this study examines the main deficiencies of management practice and PHA implementation in Taiwan, and presents several recommendations for improved PHA assessment techniques and procedures. The study additionally examines the feasibility for using PSM-related information, such as process safety information and process incident information, as a tool for further enhancing the PHA quality. Overall, the study suggests that, in addition to following the basic rules of PHA and requirements of OSHA (1992),management in Taiwan should also provide training in the enhanced assessment techniques proposed herein and take active steps to incorporate PSM information into the PHA framework in order to improve the general quality of PHA and reduce the likelihood of process safety accidents accordingly.     

A comparative analysis of process safety management (PSM) systems in the process industry

The root cause of most accidents in the process industry has been attributed to process safety issues ranging from poor safety culture, lack of communication, asset integrity issues, lack of management leadership and human factors. These accidents could have been prevented with adequate implementation of a robust process safety management (PSM) system. Therefore, the aim of this research is to develop a comparative framework which could aid in selecting an appropriate and suitable PSM system for specific industry sectors within the process industry. A total of 21 PSM systems are selected for this study and their theoretical frameworks, industry of application and deficiencies are explored. Next, a comparative framework is developed using eleven key factors that are applicable to the process industry such as framework and room for continuous improvement, design specification, industry adaptability and applicability, human factors, scope of application, usability in complex systems, safety culture, primary or secondary mode of application, regulatory enforcement, competency level, as well as inductive or deductive approach. After conducting the comparative analysis using these factors, the Integrated Process Safety Management System (IPSMS) model seems to be the most robust PSM system as it addressed almost every key area regarding process safety. However, inferences drawn from study findings suggest that there is still no one-size-fits-all PSM system for all sectors of the process industry.     

Lessons learned for process safety management in China

A number of chemical accidents have occurred in China over the past two decades with significant impact on humans and the environment. It is expected that lessons will have been learned from these accidents that will help industries to reduce the risk that catastrophic chemical accidents occur in future. In fact, to some extent there is evidence that lessons have been learned, to the extent that the Chinese government has substantially strengthened legislation and regulatory standards. Nonetheless, there remains a concern that much more still needs to be done to reduce chemical accidents risks in China. Important progress in this area requires not only government support but a commitment across all hazardous industries to learn from past accidents that may in many cases require establishment or considerable improvement of their safety management systems. To assist small and medium-sized enterprises (SMEs), in this effort, results of an analysis of common causes of the chemical accidents reported in the Major Accident Information (MAI) website of Chinese State Administration of Work Safety (SAWS) are presented in this paper In particular, inadequate process hazard analysis (PHA), training and emergency response planning (ERP) were identified as the top three process safety management (PSM) elements that contribute to most of the SMEs accidents in China. Seven recommendations are proposed in order to improve the effectiveness of lesson learning for government agencies and SMEs.     

A review of the past,present and future of the European loss prevention and safety promotion in the process industries

In 2013, the European Federation of Chemical Engineering (EFCE) celebrates its 60th anniversary. EFCE has continually promoted scientific collaboration and supported the work of engineers and scientists in thirty European countries. As for its mission statement, EFCE helps European Society to meet its needs through highlighting the role of Chemical Engineering in delivering sustainable processes and products. Within this organizational framework the Loss Prevention Symposium series, organized throughout Europe on behalf of the Loss Prevention Working Party of the EFCE, represents a fruitful tradition covering a time span of forty years. The tri-annual symposium gathers experts and scientists to seek technical improvements and scientific support for a growingly safer industry and quality of life. Following the loss prevention history in this paper, a time perspective on loss prevention and its future is presented.     

Methods and models in process safety and risk management: Past,present and future

The paper reviews past progress in the development of methods and models for process safety and risk management and highlights the present research trends; also it outlines the opinions of the authors regarding the future research direction in the field. Based on the open literature published in the leading journals in the field of safety, risk and reliability, the review covers the evolution of the methods and models developed for process safety and risk management. The methods and models are categorized as qualitative, semi-quantitative, quantitative and hybrid. The progress in the last few decades is discussed in the context of the past. Developments in the current decade formulate the basis of the present trends; future directions for research in these fields are also outlined. The aim of the article is to provide a historical development in this field with respect to the driving forces behind the development. It is expected that it will help researchers and industrial practitioners to gain a better understanding of the existing concepts. At the same time the aim is to provide direction to bridge the existing gaps through research and developments.     

Assessment of chemical process hazards in early design stages

A new method called SREST-layer-assessment method with automated software tool is presented that in a hierarchical approach reveals the degree of non-ideality of chemical processes with regard to SHE (safety, health and environment) aspects at different layers: the properties of the chemical substances involved (substance assessment layer (SAL)), possible interactions between the substances (reactivity assessment layer (RAL)), possible hazard scenarios resulting from the combination of substances and operating conditions in the various equipments involved (equipment assessment layer (EAL)), and the safety technologies that are required to run a process safely and in accordance with legal regulations (safety-technology assessment layer (STAL)). In RAL, EAL and STAL the main focus is put on process safety. A case study is used to show the principles of the method. It is demonstrated how the method can be used as a systematic tool to support chemical engineers and chemists in evaluating chemical process safety in early process development stages.     

Global process safety incidents in the pharmaceutical industry

The objective of this research is to analyse global process safety incidents within the pharmaceutical industry in terms of their consequences and factors contributing to the incidents. There were 73 process safety incidents leading to 108 fatalities found between 1985 and 2019. Trends between the number of incidents, number of fatalities, location, and contributing factors were identified and summarized. The most reported fatalities occurred in 2018 & 2019. 83% of fatalities occurred in China and India. Explosions were associated with 71% of incidents, which resulted in 89% of fatalities. For most of the international incidents, incident investigations were not available and thus insufficient details were available to determine the causes. Contributing factors were available or estimated from available data for about half of the incidents, with the following most common: hazard awareness & identification; operating procedures; design; safeguards, controls & layers of protection; safety culture; and preventive maintenance. These findings can be used as a basis to improve process safety performance in the pharmaceutical industry.     

Process loss prevention of petrochemical process: A case study of the flashing accident of the storage tank on acrylonitrile-butadiene-styrene powder in Taiwan

Qualitative analysis, process hazard analysis, thermal evaluation, and fault tree analysis were applied to a flashing accident involving a storage tank that contained acrylonitrile-butadiene-styrene (ABS) powder in Taiwan. The accident was caused by combustible powder attached to the inner wall of the tank reaching a high temperature and then melting. Thereafter, the molten powder became glue-like and dropped onto the ABS powder, burning at the tank bottom, causing decomposition of the styrene and butadiene derivatives as well as other combustible gases. The high concentration of combustible powder and low ignition temperature triggered the powder, initiating a dust explosion. Finally, we analyzed the findings of each method and examined the properties of ABS powder, realizing that the root cause of the accident included an insufficient understanding of the characteristics of ABS and the failure to comply with the management procedures of hot work. Recommendations and countermeasures were proposed that could proactively ameliorate process safety.     

Communicating costs and benefits of the chemical industry and chemical technology to society

Risk Communication is increasingly important to the chemical and manufacturing industries in the wake of a wave of major incidents in recent years. However, risk communication strategies as they are currently implemented tend to place the chemical industry on the defensive. Renewed attempts should be made to place the life-saving benefits of the chemical industry back in the public eye and counter-balance the popular political view that the chemical industry is often responsible for loss of life. In truth, while the chemical industry suffers on the job fatalities like many industries, the frequency is much less than many common industries and the chemical industry provides benefits to society that ultimately save far more lives.     

Recent application of Computational Fluid Dynamics (CFD) in process safety and loss prevention: A review

In recent years, significant progress has been made to ensure that process industries are among the safest workplaces in the world. However, with the increasing complexity of existing technologies and new problems brought about by emerging technologies, a strong need still exists to study the fundamentals of process safety and predict possible scenarios. This is attained by conducting the corresponding consequence modeling and risk assessments. As a result of the continuous advancement of Computational Fluid Dynamics (CFD) tools and exponentially increased computation capabilities along with better understandings of the underlying physics, CFD simulations have been applied widely in the areas of process safety and loss prevention to gain new insights, improve existing models, and assess new hazardous scenarios. In this review, 126 papers from 2010 to 2020 have been included in order to systematically categorize and summarize recent applications of CFD for fires, explosions, dispersions of flammable and toxic materials from accidental releases, incident investigations and reconstructions, and other areas of process safety. The advantages of CFD modeling are discussed and the future of CFD applications in this research area is outlined.     

Evaluation of process safety indicators collected in conformance with ANSI/API Recommended Practice 754

At the request of the U.S. Chemical Safety and Hazard Investigation Board (CSB), we examined some of the possible uses of the process safety event metrics proposed by the American Petroleum Institute and published as ANSI/API Recommended Practice 754. We examined many sources to try to estimate what the likely number of Tier 1 and Tier 2 process safety events would be at refineries. Then we calculated the statistical power that would be available to compare rates, both over time and across facilities and firms. As Tier 1 and Tier 2 are defined, it appears that the event frequencies estimated for U.S. refineries (i.e., 0.12 per 100 employees for Tier 1 and 0.26 for Tier 2) would make it unlikely that even two-fold differences in the rates would be statistically significant, except at large refineries with several thousand workers.     

Assessing the hazards from a BLEVE and minimizing its impacts using the inherent safety concept

Many worlds' major process industry accidents are due to BLEVE such as at Feyzin, France, 1966 and San Juan Ixhuatepec, Mexico City, 1984. One of the approaches to eliminate or minimize such accidents is by the implementation of inherently safer design concept. This concept is best implemented where the consequence of BLEVE can be evaluated at the preliminary design stage, and necessary design improvements can be done as early as possible. Thus, the accident could be avoided or minimized to as low as reasonably practicable (ALARP) without resorting to a costly protective system. However, the inherent safety concept is not easy to implement at the preliminary design stage due to lack of systematic technique for practical application. To overcome these hurdles, this paper presents a new approach to assess process plant for the potential BLEVE at the preliminary design stage and to allow modifications using inherent safety principles in order to avoid or minimize major accidents. A model known as Inherent Fire Consequence Estimation Tool (IFCET) is developed in MS Excel spreadsheet to evaluate BLEVE impacts based on overpressure, radiation heat flux and missile effects. In this study, BLEVE impacts are the criteria used as the decision-making for the acceptability of the design. IFCET is integrated with iCON process design simulator for ease of data transfer and quick assessment of potential BLEVE during the design simulation stage. A case study was conducted to assess of potential BLEVE from a propane storage vessel at the design simulation stage using this new approach. The finding shows promising results that this approach has a potential to be developed as a practical tool.     

Integration of process safety engineering and fire protection engineering for better safety performance

Since the inception of the process industries, there have been a great number of process incidents causing significant loss of life and property damage. Even the establishment and implementation of a series of rigorous regulations has not prevented the occurrence of process incidents. In order to protect people, property and the environment a more robust safety program is needed and the safety performance of process industries must continue to improve. In this work, the common ground and the unique characteristics of process safety engineering (PSE) and fire protection engineering (FPE) is reviewed to demonstrate the potential benefits of unifying the two fields or improving the coordination between them to create a more robust safety program, thereby enhancing the safety performance of process industries. Recommendations are made to facilitate and encourage continued discussion and efforts toward the integration of process safety engineering and fire protection engineering.     

History of Dutch process equipment failure frequencies and the Purple Book

In the middle of 70s concerns of the public in the Netherlands about fire, explosion and toxic risks due to mishaps in the expanding process industry, causing political pressure led to the embracement of quantitative risk analysis as tool for licensing and land-use planning. Probabilistic treatment of risk had been exercised before to design flood defense. A ‘test’ on six different plants, the COVO study, favored the idea. Failure rate values were in immediate need. For storage vessels AKZO’s chlorine vessel data and British steam boiler data have been the first. Risk criteria to make decisions on were also developed and in 1985 embodied in legislation. As licensing and land-use planning are tasks of provincial authorities, under the auspices of the Inter-Provincial Consultation (IPO), further details such as failure frequency values have been worked out. In the late 90s the Purple Book consolidated the information as a guideline for Dutch quantitative risk assessment of process installations.The paper will give a condensed historical overview, guidance to published papers; it will further make comments, explain policy backgrounds, present comparison with other data and will briefly indicate in which direction developments should go to improve QRA.     

Guidance to improve the effectiveness of process safety management systems in operating facilities

The Process Safety Management (PSM) systems at the operating facilities in the Oil & Gas and in Chemical manufacturing industries have matured over the years and have become, at most facilities, very robust and sophisticated. These programs are administrated by Process Safety (PS) teams at both the corporate business units and plant levels and have been effective in reducing the number and severity of PS events across the industries over the past 25 years or so. Incidents however are occurring at a regular interval and in recent times several noteworthy PS events have occurred in the United States which have brought into question the effectiveness of the PSM programs at play. These facilities have been applying their PSM programs with the expectation that the number and severity of PS events would decrease over time. The expected result has not been realized, especially in context to those facilities that have undergone the recent incidents. Current paper reviews a few publicly available PS performance reports of Oil & Gas and Chemical manufacturing industries. The authors identified a few factors at play that have led to these PS events based on their experience, literature review, and incident investigation reports. Most of the factors are intertwined with multiple PSM elements and it requires a holistic approach to address them. Each of the factors is described and the path forward is proposed to improve the effectiveness of PSM programs.     

Joint analysis of process and operator performance in chemical process operational safety

Independent studies of case histories by the Health and Safety Commission in the UK and by a Honeywell led industrial consortium world-wide showed that human errors represent the major cause of failure in process plant operation. In contrast to this discovery the majority of previous studies on computer aided systems for fault detection and diagnosis has focused on the process side. This paper presents a methodology, which can involve human factors into the development of systems for automatic identification and diagnosis of abnormal operations and develops methods and techniques that can be used to simultaneously capture, characterise and assess the performance of operators as well as of the process. A joint process–operator simulation platform is developed which is used as a test-bed for carrying out the study. The process part is a simulator, which simulates in high fidelity the dynamic behaviour of the process that is subject to the influence of various disturbances and operators’ interventions. The operator module is developed as a real-time expert system, which emulates operator’s behaviour in interpretation of received signals, and planning and execution of decisions. The interaction between the two modules is managed through an interaction module, which handles the real-time exchange of data using Dynamic Data Exchange. The interaction module also contains the toolkits for analysing the dynamic behaviour of the joint process–operator system. The method and system are illustrated using a simulated case study.     

工艺安全管理系统中的工艺危害分析方法比较

简要介绍了工艺安全管理系统,其中工艺危害分析是工艺安全管理系统中的核心要素。对通常采用的故障假设/检查表、故障类型及影响分析、事故树分析、危险与可操作性研究、保护层分析五种分析方法进行了比较,得出了它们的优点、缺点、适用范围及应用时机。故障假设/检查表分析法比较容易使用,适用于工艺的初次评估;故障类型及影响分析、事故树分析适用于高危险性工艺中的工段、组件或单元操作的分析;危险与可操作性研究可以非常系统、全面的对工艺进行分析,是最有效的工艺危害分析方法。保护层分析方法是一种半定量的风险评价方法,它通过分析系统中各个防护层的失效概率来评估潜在事故的危险性,并与可接受标准进行比较,从而实现对防护系统防护性能的判断。通过对分析方法的比较可以指导化工企业选用合适的分析方法来进行工艺危害分析。     

Reaction mechanism and process safety assessment of acid-catalyzed synthesis of tert-butyl peracetate

Esterification during the synthesis of tert-butyl peracetate (TBPA) is highly exothermic. Since peroxides (tert-butyl hydroperoxide TBHP and TBPA) are intrinsically thermosensitive, this synthesis process is potentially dangerous. In this work, the exothermic process and mechanism of TBPA synthesis using acetic anhydride (Ac₂O) and TBHP under the catalysis of sulphuric acid (H₂SO₄) were clarified by calorimetry, infrared spectroscopy, and high-performance liquid chromatography. To substantially alleviate the thermal risk of the reaction, and to feasibly select appropriate synthesis conditions for ensuring the process safety of the synthesized products, several sets of isothermal and isoperibol experiments were performed using calorimetry. The intermediates formed and concentration changes during the reaction were monitored using in-situ Fourier-transform infrared spectroscopy. Differential scanning calorimetry and adiabatic calorimetry were used to assess the thermal hazard of the materials during the synthesis process. The reaction mechanism was verified using density functional theory calculations. The results revealed that a controlled increase in exothermicity could be achieved by adding aqueous TBHP to Ac₂O in semi-batch experiments in isothermal mode, and accordingly, the highest yield was 95.71%. Experiments combined with theoretical calculations revealed that the primary exothermic event was the TBPA formation reaction, and the removal of a large amount of water from TBHP prior to this is favourable for the reaction. The criticality classes of this reaction were of Grade 2.     

Learning from the Bhopal disaster to improve process safety management in Singapore

The Singapore process industry is mainly made up of chemical and energy companies such as Mitsui Chemicals, Clariant, Exxon Mobil, Shell, Sumitomo, Petrochemical Corporation of Singapore and Infineum. Majority of these companies are located on Jurong Island, southwest of Singapore. Jurong Island houses nearly 100 leading petroleum, petrochemicals and specialty chemicals companies and the total investment is about S$42 billion in total. With a land surface area of only 716 km² and a high concentration of process plants, the Singapore government places strong emphasis on safety and risk management. In this paper, four process industry veterans from the government, academic and private sectors were interviewed. Through the interviews, the authors sought to understand the veterans’ perspectives on lessons that the Singapore process industry should learn from the Bhopal disaster. The veterans expanded their thoughts beyond the Bhopal disaster and provided many insights and suggestions critical to process safety management in Singapore and other countries. A systemic model of process safety management was derived from the interviews and key elements of operational process safety management were identified. In addition, a research agenda was identified based on the inputs from the veterans.