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1.
Abstract: Knowledge of headwater influences on the water‐quality and flow conditions of downstream waters is essential to water‐resource management at all governmental levels; this includes recent court decisions on the jurisdiction of the Federal Clean Water Act (CWA) over upland areas that contribute to larger downstream water bodies. We review current watershed research and use a water‐quality model to investigate headwater influences on downstream receiving waters. Our evaluations demonstrate the intrinsic connections of headwaters to landscape processes and downstream waters through their influence on the supply, transport, and fate of water and solutes in watersheds. Hydrological processes in headwater catchments control the recharge of subsurface water stores, flow paths, and residence times of water throughout landscapes. The dynamic coupling of hydrological and biogeochemical processes in upland streams further controls the chemical form, timing, and longitudinal distances of solute transport to downstream waters. We apply the spatially explicit, mass‐balance watershed model SPARROW to consider transport and transformations of water and nutrients throughout stream networks in the northeastern United States. We simulate fluxes of nitrogen, a primary nutrient that is a water‐quality concern for acidification of streams and lakes and eutrophication of coastal waters, and refine the model structure to include literature observations of nitrogen removal in streams and lakes. We quantify nitrogen transport from headwaters to downstream navigable waters, where headwaters are defined within the model as first‐order, perennial streams that include flow and nitrogen contributions from smaller, intermittent and ephemeral streams. We find that first‐order headwaters contribute approximately 70% of the mean‐annual water volume and 65% of the nitrogen flux in second‐order streams. Their contributions to mean water volume and nitrogen flux decline only marginally to about 55% and 40% in fourth‐ and higher‐order rivers that include navigable waters and their tributaries. These results underscore the profound influence that headwater areas have on shaping downstream water quantity and water quality. The results have relevance to water‐resource management and regulatory decisions and potentially broaden understanding of the spatial extent of Federal CWA jurisdiction in U.S. waters.  相似文献   

2.
ABSTRACT: A large number of agricultural drainage wells (ADWs) are located in north-central Iowa. These wells permit sediments, pesticides, nitrate, and bacteria in surface and subsurface drainage water to enter regional aquifers that are currently being used for drinking-water supplies, mostly by rural families and communities. This paper reports some possible alternatives to control the entry of surface and subsurface drainage waters into groundwater systems, and describes a methodology to make comprehensive economic feasibility studies of alternative drainage outlets. The estimated cost of providing main subsurface drains varied from $220 to $960 per hectare. If the use of ADWs was completely eliminated without providing alternative drainage, it is estimated that the average annual loss to the farmers of the area would be at least $270 per hectare in reduced crop yields. Of course, losses would be weather dependent and highly variable. Management practices to reduce the pollutant load in water draining to ADWs are also discussed.  相似文献   

3.
Modeling potential herbicide loss to surface waters on the Swiss plateau   总被引:1,自引:0,他引:1  
Lack of sufficiently detailed data often limits the applicability of complex transport-reaction models for estimating potential herbicide loss to surface waters. Therefore, there is also a need for simple models that are easy to apply but still capture the main features of the underlying processes.In this study, a simple regression model was developed to assess the vulnerability of catchments in the Swiss Plateau to diffuse herbicide loss to surface waters. The model is designed as a screening tool to rank the catchments in a relative sense and not to calculate Predicted Environmental Concentrations (PEC) of pesticides. The main goal is to capture two dominating factors controlling diffuse herbicide transport into streams and rivers. These factors are herbicide application and fast flow processes that are mainly responsible for herbicide transport. In a first step vulnerability of sites to herbicide loss is estimated based on site-specific conditions irrespective of actual herbicide application. In the second step, this vulnerability assessment is combined with actual herbicide application data to estimate the potential herbicide loss.The fast flow index (FFI), derived from discharge data using a base flow separation method, was applied as a proxy for the amount of fast flow occurring. The influence of catchment attributes (including topographic, climatic and soil data) on the FFI was analyzed using a multiple regression approach based on data from 57 catchments of the Swiss Plateau. By combining regression analysis with mechanistic knowledge, a two factor non-linear model based on river density and soil permeability as dominant input factors was selected as the best model for FFI prediction given the available data. Higher dimensional models had to be excluded because the strong correlation between the potential input factors led to unrealistic dependences while only minimally improving the quality of the fit.The spatial pattern of the predicted FFI as a measure for the vulnerability to diffuse herbicide losses shows a clearly increasing trend from the western to the eastern part of the Swiss Plateau and towards the pre-alpine/alpine regions in the south.In general the pattern of herbicide use corresponds to site conditions typical of a low FFI. However, the spatial analysis revealed exceptions, namely areas in which high actual herbicide use coincides with a high FFI.Despite the uncertainties in the model, this simple approach seems to be useful for supporting site-adapted agricultural practice whenever the higher accuracy of more detailed models is not required or too expensive to achieve. In addition, in combination with data on actual herbicide application, it can support the design of monitoring strategies by identifying critical areas of actual herbicide loss.  相似文献   

4.
Rainfall can transport herbicides from agricultural land to surface waters, where they become an environmental concern. Tile drainage can benefit crop production by removing excess soil water but tile drainage may also aggravate herbicide and nutrient movement into surface waters. Water management of tile drains after planting may reduce tile drainage and thereby reduce herbicide losses to surface water. To test this hypothesis we calculated the loss of three herbicides from a field with three water management systems: free drainage (D), controlled drainage (CD), and controlled drainage with subsurface irrigation (CDS). The effect of water management systems on the dissipation of atrazine (6-chloro-N2-ethyl-N4-isopropyl-1,3,5-triazine-2,4-diamine), metribuzin [4-amino-6-(1,1-dimethylethyl)-3-(methylthio)-1,2,4-triazine-5(4H)-one), and metolachlor [2-chloro-N-(2-ethyl-6-methylphenyl)-N-(2-methoxy-1-methylethyl)acetamide] in soil was also monitored. Less herbicide was lost by surface runoff from the D and CD treatments than from CDS. The CDS treatment increased surface runoff, which transported more herbicide than that from D or CD treatments. In one year, the time for metribuzin residue to dissipate to half its initial value was shorter for CDS (33 d) than for D (43 d) and CD (46 d). The half-life of atrazine and metolachlor were not affected by water management. Controlled drainage with subsurface irrigation may increase herbicide loss through increased surface runoff when excessive rain is received soon after herbicide application. However, increasing soil water content in CDS may decrease herbicide persistence, resulting in less residual herbicide available for aqueous transport.  相似文献   

5.
There is continuing concern over potential impacts of widespread application of nutrients and pesticides on ground- and surface-water quality. Transport and fate of nitrate and pesticides were investigated in a shallow aquifer and adjacent stream, Cow Castle Creek, in Orangeburg County, South Carolina. Pesticide and pesticide degradate concentrations were detected in ground water with greatest frequency and largest concentrations directly beneath and downgradient from the corn (Zea mays L.) field where they were applied. In almost all samples in which they were detected, concentrations of pesticide degradates greatly exceeded those of parent compounds, and were still present in ground waters that were recharged during the previous 18 yr. The absence of both parent and degradate compounds in samples collected from deeper in the aquifer suggests that this persistence is limited or that the ground water had recharged before use of the pesticide. Concentrations of NO(-)(3) in ground water decreased with increasing depth and age, but denitrification was not a dominant controlling factor. Hydrologic and chemical data indicated that ground water discharges to the creek and chemical exchange takes place within the upper 0.7 m of the streambed. Ground water had its greatest influence on surface-water chemistry during low-flow periods, causing a decrease in concentrations of Cl(-), NO(-)(3), pesticides, and pesticide degradates. Conversely, shallow subsurface drainage dominates stream chemistry during high-flow periods, increasing stream concentrations of Cl(-), NO(-)(3), pesticides, and pesticide degradates. These results point out the importance of understanding the hydrogeologic setting when investigating transport and fate of contaminants in ground water and surface water.  相似文献   

6.
ABSTRACT: Agricultural and urban activities in the West Wellfield Interim Protection Area (WWIPA), located in West Dade County in South Florida, have the potential to impact both the environmentally sensitive Everglades and the Biscayne Aquifer. The Hydrological Simulation Program-FORTRAN (HSPF) is used to simulate surface runoff, ground water recharge, and transport of sediments, nutrients, and pesticides in the WWIPA, as a basis to quantify impacts and evaluate alternatives. Presented are four model test runs that consider current conditions, the effect of future urbanization of the agricultural land, as well as two preventive actions to minimize pollution levels. Preventive actions include application of minimum required rates of fertilizers and replacement of fertilizers by sewage sludge. Model results show that under current practices, sediments, nutrients, and pesticides are present in surface runoff and nutrients enter the ground water, and that both urbanization and preventive actions result in pollutant reductions.  相似文献   

7.
Land use planning is an important element of the integrated watershed management approach. It not only influences the environmental processes such as soil and stream bed erosion, sediment and nutrient concentrations in streams, quality of surface and ground waters in a watershed, but also affects social and economic development in that region. Although its importance in achieving sustainable development has long been recognized, a land use planning methodology based on a systems approach involving realistic computational modeling and meta-heuristic optimization is still lacking in the current practice of integrated watershed management. The present study proposes a new approach which attempts to combine computational modeling of upland watershed processes, fluvial processes and modern heuristic optimization techniques to address the water-land use interrelationship in its full complexity. The best land use allocation is decided by a multi-objective function that minimizes sediment yields and nutrient concentrations as well as the total operation/implementation cost, while the water quality and the production benefits from agricultural exploitation are maximized. The proposed optimization strategy considers also the preferences of land owners. The runoff model AnnAGNPS (developed by USDA), and the channel network model CCHE1D (developed by NCCHE), are linked together to simulate sediment/pollutant transport process at watershed scale based on any assigned land use combination. The greedy randomized adaptive Tabu search heuristic is used to flip the land use options for finding an optimum combination of land use allocations. The approach is demonstrated by applying it to a demonstrative case study involving USDA Goodwin Creek experimental watershed located in northern Mississippi. The results show the improvement of the tradeoff between benefits and costs for the watershed, after implementing the proposed optimal land use planning.  相似文献   

8.
Three mathematical models, the runoff curve number equation, the universal soil loss equation, and the mass response functions, were evaluated for predicting nonpoint source nutrient loading from agricultural watersheds of the Mediterranean region. These methodologies were applied to a catchment, the gulf of Gera Basin, that is a typical terrestrial ecosystem of the islands of the Aegean archipelago. The calibration of the model parameters was based on data from experimental plots from which edge-of-field losses of sediment, water runoff, and nutrients were measured. Special emphasis was given to the transport of dissolved and solid-phase nutrients from their sources in the farmers' fields to the outlet of the watershed in order to estimate respective attenuation rates. It was found that nonpoint nutrient loading due to surface losses was high during winter, the contribution being between 50% and 80% of the total annual nutrient losses from the terrestrial ecosystem. The good fit between simulated and experimental data supports the view that these modeling procedures should be considered as reliable and effective methodological tools in Mediterranean areas for evaluating potential control measures, such as management practices for soil and water conservation and changes in land uses, aimed at diminishing soil loss and nutrient delivery to surface waters. Furthermore, the modifications of the general mathematical formulations and the experimental values of the model parameters provided by the study can be used in further application of these methodologies in watersheds with similar characteristics.  相似文献   

9.
Abstract: A primary water quality problem caused by non-point source pollution (NPSP) is eutrophication, from excess nutrients in receiving water bodies. The control of nutrients arising from NPSP is difficult because the source areas can be hard to identify and typical treatment methods are infeasible due to the distributed nature of the pollutants. It may be possible to reduce nutrient related water quality problems through the restoration of highly disturbed watersheds with best management practices (BMPs). While restoration attempts may provide significant returns, they can be costly to implement and often are met with resistance in agricultural communities. Extending model results beyond the range of calibration to model future conditions such as for restoration scenarios requires the use of physically-based models that include the important processes that generate streamflow and material transport, uptake, loss, transformation, and recycling of nutrients and other material. The research and development objectives of the US. Army Engineer Research and Development Center (ERDC) in Vicksburg, Mississippi, are to develop a watershed assessment and management model to simulate transport, uptake, loss, transformation, and recycling of nutrients such as nitrogen and phosphorus and associated material such as sediment and organic matter. In this study we will discuss current efforts at the ERDC's Environmental Laboratory to develop a state-of-the-art watershed water quality model.  相似文献   

10.
An unsaturated-zone transport model was used to examine the transport and fate of metolachlor applied to an agricultural site in Maryland, USA. The study site was instrumented to collect data on soil-water content, soil-water potential, ground water levels, major ions, pesticides, and nutrients from the unsaturated zone during 2002-2004. The data set was enhanced with site-specific information describing weather, soils, and agricultural practices. The Root Zone Water Quality Model was used to simulate physical, chemical, and biological processes occurring in the unsaturated zone. Model calibration to bromide tracer concentrations indicated flow occurred through the soil matrix. Simulated recharge rates were within the measured range of values. The pesticide transport model was calibrated to the intensive data collection period (2002-2004), and the calibrated model was then used to simulate the period 1984 through 2004 to examine the impact of sustained agricultural management practices on the concentrations of metolachlor and its degradates at the study site. Simulation results indicated that metolachlor degrades rapidly in the root zone but that the degradates are transported to depth in measurable quantities. Simulations indicated that degradate transport is strongly related to the duration of sustained use of metolachlor and the extent of biodegradation.  相似文献   

11.
Agricultural runoff contributes nutrients to nonpoint-source pollution of surface waters. This study was conducted to investigate the potential use of alternative farming practices to improve water quality. The study examined the effects of both alternative and conventional farming practices on subsurface drainage and nitrogen and phosphorus loss through subsurface drainage from glacial till soils (i.e., Calciaquolls, Endoaquolls, Eutrudepts, Hapludolls) in southwest Minnesota. Alternative farming practices included organic management practices, species biodiversity, and/or practices that include reduced inputs of synthetic fertilizer and pesticides. Conventional farming practices include corn-soybean (Zea mays L.-Glycine max L., respectively) rotations and their associated recommended fertilizer rates as well as pesticide usage. Precipitation was highly variable during the 3-yr study period including a below-average year (2003), an average year (2002), and an above-average year (2004). Results indicate that alternative farming practices reduced subsurface drainage discharge by 41% compared with conventional practices. Flow-weighted mean nitrate-nitrogen (nitrate N) concentrations during tile flow were 8.2 and 17.2 mg L(-1) under alternative and conventional farming practices, respectively. Alternative farming practices reduced nitrate N losses by between 59 and 62% in 2002 and 2004 compared with conventional practices. Ammonium-nitrogen (ammonium N), orthophosphorus, and total phosphorus losses in subsurface drainage were very low and did not pose a substantial risk of pollution. Results suggest that alternative farming practices have the potential to reduce agricultural impacts on water quality.  相似文献   

12.
Abstract: The transport of reactive contaminants in the subsurface is generally affected by a large number of nonlinear and often interactive physical, chemical, and biological processes. Simulating these processes requires a comprehensive reactive transport code that couples the physical processes of water flow and advective-dispersive transport with a range of biogeochemical processes. Two recently developed coupled geochemical models that are both based on the HYDRUS-1D software package for variably saturated flow and transport are summarized in this paper. One model resulted from coupling HYDRUS-1D with the UNSATCHEM module. While restricted to major ion chemistry, this program enables quantitative predictions of such problems as analyzing the effects of salinity on plant growth and the amount of water and amendments required to reclaim salt-affected soil profiles. The second model, HPI, resulted from coupling HYDRUS-1D with the PHREEQC biogeochemical code. The latter program accounts for a wide range of instantaneous or kinetic chemical and biological reactions, including complexation, cation exchange, surface complexation, precipitation dissolution and/or redox reactions. The versatility of HP1 is illustrated in this paper by means of two examples: the leaching of toxic trace elements and the transport of the explosive TNT and its degradation products.  相似文献   

13.
14.
Riparian buffers are known to mitigate hydrologic losses of nutrients and other contaminants as they exit agricultural fields. The vegetation of riparian buffers can also trap atmospheric contaminants, and these pollutants can subsequently be delivered via rain to the riparian buffer floor. These processes, however, are poorly understood especially for pesticide residues. Therefore, we conducted a four‐year study examining stemflow and throughfall to a riparian buffer which was adjacent a cultured Zea mays field treated with atrazine and metolachlor. Stemflow is rain contacting the tree canopy traveling down smaller to larger branches and down the tree trunk, whereas throughfall is rain that may or may not contact leaves and branches and reaches the earth. Stemflow concentrations of the herbicides were larger than throughfall concentrations and accounted for 5‐15% of the atrazine and 6‐66% of the metolachlor depositional fluxes under the canopy. Larger depositional fluxes were measured when leaves were more fully emerged and temperatures and humidity were elevated. Rain collected outside the riparian buffer on the field side and on the back side revealed the trees trapped the herbicide residues. Herbicide loading to the riparian buffer stream was found to be linked to tree canopy deposition and subsequent washoff during rain events. These results indicate that in agricultural areas canopy washoff can be an important source of pesticides to surface waters.  相似文献   

15.
The transport of nutrients and soil sediments in runoff has been recognized as a noteworthy environmental issue. Vegetative Filter Strips (VFS) have been used as one of the best management practices (BMPs) for retaining nutrients and sediments from surface runoff, thus preventing the pollutants from reaching receiving waters. However, the effectiveness of a VFS when combined with a subsurface drainage system has not been investigated previously. This study was undertaken to monitor the retention and transport of nutrients within a VFS that had a subsurface drainage system installed at a depth of 1.2 m below the soil surface. Nutrient concentrations of NO3-N (Nitrate Nitrogen), PO4 (Orthophosphorus), and TP (Total Phosphorus) were measured in surface water samples (entering and leaving the VFS), and subsurface outflow. Soil samples were collected and analyzed for plant available Phosphorus (Bray P1) and NO3-N concentrations. Results showed that PO4, NO3-N, and TP concentrations decreased in surface flow through the VFS. Many surface outflow water samples from the VFS showed concentration reductions of as much as 75% for PO4 and 70% for TP. For subsurface outflow water samples through the drainage system, concentrations of PO4 and TP decreased but NO3-N concentrations increased in comparison to concentrations in surface inflow samples. Soil samples that were collected from various depths in the VFS showed a minimal buildup of nutrients in the top soil profile but indicated a gradual buildup of nutrients at the depth of the subsurface drain. Results demonstrate that although a VFS can be very effective in reducing runoff and nutrients from surface flow, the presence of a subsurface drain underneath the VFS may not be environmentally beneficial. Such a combination may increase NO3-N transport from the VFS, thus invalidating the purpose of the BMP.  相似文献   

16.
ABSTRACT: Much of north-central Iowa is characterized by flat topography, shallow depressions, and poor natural surface drainage. Land drainage systems comprising of tile drains and agricultural drainage wells (ADWs) are used as outlets for subsurface drainage of cropland under corn and soybean production. Studies have shown that these drainage systems, mainly the ADWs, are potential routes for agricultural chemicals to underground aquifers. To protect the region's vital groundwater resource, researchers are evaluating alternative outlets ranging from complete closure of existing ADWs (and creation of wetlands) to continued use of ADWs and chemical management in a comprehensive policy framework. This paper presents the results of a study designed to provide government jurisdictions, farmers, and land managers information for assessing the impact of closing ADWs on crop production. The study couples a geographic information systems database for a 471-hectare watershed in Humboldt County, Iowa, with a groundwater flow model (MODFLOW) and an empirical crop yield loss model to predict long-term effects of complete closure of ADWs on crop production. The cropland areas inundated and the relative crop yield loss due to ADW closure are determined as a function of long-term climatic data. The results indicate that elimination of drainage outlets in the watershed could result in ponding of low-lying areas and poorly drained soils, making them unsuitable for crop production. Such wetness also decreases the efficiency of production in the no-ponding areas by isolating fields, and the crop yield loss can be reduced by an annual average of about 18 percent.  相似文献   

17.
Moore, Richard B., Craig M. Johnston, Richard A. Smith, and Bryan Milstead, 2011. Source and Delivery of Nutrients to Receiving Waters in the Northeastern and Mid‐Atlantic Regions of the United States. Journal of the American Water Resources Association (JAWRA) 47(5):965‐990. DOI: 10.1111/j.1752‐1688.2011.00582.x Abstract: This study investigates nutrient sources and transport to receiving waters, in order to provide spatially detailed information to aid water‐resources managers concerned with eutrophication and nutrient management strategies. SPAtially Referenced Regressions On Watershed attributes (SPARROW) nutrient models were developed for the Northeastern and Mid‐Atlantic (NE US) regions of the United States to represent source conditions for the year 2002. The model developed to examine the source and delivery of nitrogen to the estuaries of nine large rivers along the NE US Seaboard indicated that agricultural sources contribute the largest percentage (37%) of the total nitrogen load delivered to the estuaries. Point sources account for 28% while atmospheric deposition accounts for 20%. A second SPARROW model was used to examine the sources and delivery of phosphorus to lakes and reservoirs throughout the NE US. The greatest attenuation of phosphorus occurred in lakes that were large relative to the size of their watershed. Model results show that, within the NE US, aquatic decay of nutrients is quite limited on an annual basis and that we especially cannot rely on natural attenuation to remove nutrients within the larger rivers nor within lakes with large watersheds relative to the size of the lake.  相似文献   

18.
Non-point sources of pollution are difficult to identify and control, and are one of the main reasons that urban rivers fail to reach the water quality objectives set for them. Whilst sustainable drainage systems (SuDS) are available to help combat this diffuse pollution, they are mostly installed in areas of new urban development. However, SuDS must also be installed in existing built areas if diffuse loadings are to be reduced. Advice on where best to locate SuDS within existing built areas is limited, hence a semi-distributed stochastic GIS-model was developed to map small-area basin-wide loadings of 18 key stormwater pollutants. Load maps are combined with information on surface water quality objectives to permit mapping of diffuse pollution hazard to beneficial uses of receiving waters. The model thus aids SuDS planning and strategic management of urban diffuse pollution. The identification of diffuse emission 'hot spots' within a water quality objectives framework is consistent with the 'combined' (risk assessment) approach to pollution control advocated by the EU Water Framework Directive.  相似文献   

19.
Subsurface tile drainage from row-crop agricultural production systems has been identified as a major source of nitrate entering surface waters in the Mississippi River basin. Noncontrollable factors such as precipitation and mineralization of soil organic matter have a tremendous effect on drainage losses, nitrate concentrations, and nitrate loadings in subsurface drainage water. Cropping system and nutrient management inputs are controllable factors that have a varying influence on nitrate losses. Row crops leak substantially greater amounts of nitrate compared with perennial crops; however, satisfactory economic return with many perennials is an obstacle at present. Improving N management by applying the correct rate of N at the optimum time and giving proper credits to previous legume crops and animal manure applications will also lead to reduced nitrate losses. Nitrate losses have been shown to be minimally affected by tillage systems compared with N management practices. Scientists and policymakers must understand these factors as they develop educational materials and environmental guidelines for reducing nitrate losses to surface waters.  相似文献   

20.
ABSTRACT: Significant errors in estimating surface runoff and erosion rates are possible if a watershed is assumed to contribute runoff uniformly over the entire area, when actually only a portion of the entire area may be contributing. Generation of overland flow on portions of small semiarid watersheds was analyzed by three methods: an average loss rate procedure, a lumped-linear model, and a distributed-nonlinear model. These methods suggested that, on the average, 45, 60, and 50% of the drainage area was contributing runoff at the watershed outlet. Infiltrometer data support the partial area concept and indicate that the low infiltration zones are the runoff source areas as simulated with the distributed-nonlinear model.  相似文献   

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