共查询到20条相似文献,搜索用时 10 毫秒
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以静置沉降后的工业酚醛树脂废水为研究对象,磷酸三丁酯(TBP)为萃取剂,NaOH溶液为反萃取剂,研究了不同因素对萃取和反萃取效果的影响,并通过红外吸收光谱表征TBP与苯酚可能的络合形式。结果表明:(1)TBP对苯酚在一个较大的浓度范围内都有较高且稳定的分配系数。(2)红外吸收光谱图显示,TBP的P=O特征吸收峰和苯酚的C—O特征吸收峰较未缔合前发生了较大的红移,说明TBP的P=O与苯酚C—O形成了较稳定的氢键缔合。(3)经TBP对苯酚的分配系数与温度关系的线性拟合,可以求得TBP对苯酚的焓变为-10.1kJ/mol,可以确定TBP与苯酚的络合过程是一个放热的过程。(4)TBP对苯酚的最佳萃取条件:室温,油水比1∶3(体积比),萃取时间20min,4级萃取。在最佳萃取条件下,4级萃取后苯酚残留质量浓度平均值为0.45mg/L,达到《污水综合排放标准》(GB 8978—1996)中挥发酚一级排放标准(0.5mg/L)。(5)最佳反萃取条件:0.50mol/LNaOH溶液,油碱比1∶1(体积比),反萃取级数2级。在此最佳反萃取条件下,可回收90%左右的固体苯酚。 相似文献
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铁炭法处理高浓度难降解表面活性剂废水的研究 总被引:5,自引:0,他引:5
就铁炭法对高浓度难降解拉开粉(阴离子表面活性剂)废水的处理效果进行了接近工业化的动态模型实验研究,结果表明酸化铁炭工艺对橡胶工业拉开粉废水具有显著的去除效果。在Fe:C=2:1,pH=4,停留时间60min,曝气量0.1m^3/h时,拉开粉(BX)和COD的总去除率分别约为80%和45%。 相似文献
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概述了含酚废水的无害化处理技术现状及其进展。着重介绍了传统生物处理工艺的改良、高效菌种的选育、酶及固定化细胞等技术在含酚废水生物处理中的研究与应用 ,分析了先进氧化技术与焚烧技术的特点和存在的主要问题及应用前景 ,并探讨了含酚废水无害化处理技术的发展趋势 相似文献
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高浓度钻井废水的混凝-催化氧化处理 总被引:2,自引:0,他引:2
以华北油田某深井的高浓度钻井废水(COD高达14 460.0 mg/L)为研究对象,提出了酸化-混凝-催化氧化-吸附的组合处理工艺。重点研制了钻井废水催化氧化处理催化剂(镍基催化剂),通过实验确定了最佳工艺参数条件。着重考察了催化氧化处理的工艺条件,在pH值为4,次氯酸钙投加量为4.4 g/L,催化剂投加量为1.6 g/L的条件下COD降至403.5 mg/L,进一步吸附处理后COD降至139.9 mg/L、色度为30倍、石油类含量为3.8 mg/L、pH为8.0和SS浓度为52mg/L,最终出水水质达到《污水综合排放标准》(GB 8978-1996)二级标准,处理成本为84.8元/m3。 相似文献
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Sampaio Emanuel F. S. Rodrigues Carmen S. D. Lima Vanessa N. Madeira Luis M. 《Environmental science and pollution research international》2021,28(6):6437-6449
Environmental Science and Pollution Research - The present study assesses the treatability of a real industrial wastewater (WW) with a high organic load (chemical oxygen demand (COD) above 5800... 相似文献
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合理高效地处理含酚废水是工业废水处理的主要任务之一。重点介绍了高级氧化技术 ,如超声波氧化、超临界水氧化、湿式氧化和光催化氧化等在含酚废水处理中的研究近况和应用前景 ,探讨了各种技术的应用和发展趋势 相似文献
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Degradation of phenols in olive oil mill wastewater by biological,enzymatic, and photo-Fenton oxidation 总被引:1,自引:0,他引:1
Celine Justino Ana Gabriela Marques Kátia Reis Duarte Armando Costa Duarte Ruth Pereira Teresa Rocha-Santos Ana Cristina Freitas 《Environmental science and pollution research international》2010,17(3):650-656
Background, aim, and scope
Olive oil mill wastewater (OOMW) environmental impacts minimization have been attempted by developing more effective processes, but no chemical or biological treatments were found to be totally effective to mitigate their impact on receiving systems. This work is the first that reports simultaneously the efficiency of three different approaches: biological treatment by two fungal species (Trametes versicolor or Pleurotus sajor caju), enzymatic treatment by laccase, and chemical treatment by photo-Fenton oxidation on phenols removal. 相似文献11.
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改性粉煤灰处理低浓度含磷废水的研究 总被引:1,自引:0,他引:1
以酸改性粉煤灰为吸附剂,处理低质量浓度(1 mg/L左右)磷酸盐溶液,探讨了改性剂的种类、改性剂用量、吸附剂用量、反应时间、pH以及温度对除磷效果的影响.结果表明:(1)经过酸改性后粉煤灰的磷去除率显著提高,而且硫酸改性粉煤灰的除磷效果更好,磷去除率最高可达97.68%.(2)最佳条件:选择硫酸用量为5 mL/g进行改性,硫酸改性粉煤灰投加量为2.0g,反应时间为60 min,pH为7.2~10.8,温度为25℃(即室温).(3)改性粉煤灰对磷的吸附更符合Freundlich吸附等温模型,既有物理吸附,也有化学吸附,并以Ca、Mg氧化物与磷形成磷的沉淀物为主. 相似文献
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Pınar Aytar Serap Gedikli Mesut Sam Burhanettin Farizoğlu Ahmet Çabuk 《Environmental science and pollution research international》2013,20(5):3060-3067
Olive oil mill wastewater (OMWW), a recalcitrant pollutant, has features including high phenolic content and dark color; thereby, several chemical or physical treatments or biological processes were not able to remediate it. In this study, the treatment efficiencies of three treatments, including adsorption, biological application, and photo-Fenton oxidation were sequentially evaluated for OMWW. Adsorption, biological treatment, and photo-Fenton caused decreasing phenolic contents of 48.69 %, 59.40 %, and 95 %, respectively. However, after three sequential treatments were performed, higher reduction percentages in phenolic (total 99 %) and organic contents (90 %) were observed. Although the studied fungus has not induced significant color reduction, photo-Fenton oxidation was considered to be an attractive solution, especially for color reduction. Besides, toxicity of OMWW treatment was significantly reduced. 相似文献
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Natalia Villota Luis M. Camarero Jose M. Lomas Jonatan Perez 《Environmental science and pollution research international》2014,21(21):12208-12216
Turbidity presented by phenol solutions oxidized with Fenton reagent shows the tendency of a first order intermediate kinetics. Thus, turbidity can be considered a representative parameter of the presence of intermediate oxidation species, which are generated along the decomposition of toxic and reluctant contaminants, such as phenol. Moreover, that parameter presents a linear dependence with the catalyst dosage, but is also determined by the initial contaminant load. When analyzing the oxidation mechanism of phenol, it is found that the maximum turbidity occurs when the treatment is carried out at oxidant to phenol molar ratios R?=?4.0. These oxidation conditions correspond to the presence of a reaction mixture mainly composed of dihydroxylated rings, precursors of the muconic acid formation. The oxidation via “para” comprises the formation reactions of charge transfer complexes (quinhydrone), between the para-dihydroxylated intermediates (hydroquinone) and the para-substituted quinones (p-benzoquinone), which are quite unstable and reactive species, quickly decomposed into hydroxyhydroquinones. Working with oxidant ratios up to R?=?6.0, the maximum observed value of turbidity in the oxidized solutions is kept almost constant. It is found that, in these conditions, the pyrogallol formation is maximal, what is generated through the degradation of ortho-species (catechol and ortho-benzoquinone) and meta-substituted (resorcinol). Operating with ratios over R?=?6.0, these intermediates are decomposed into biodegradable acids, generating lower turbidity in the solution. Then, the residual turbidity is a function of the molar ratio of the ferrous ions vs. moles of oxidant utilized in the essays, that lets to estimate the stoichiometric dosage of catalyst as 20 mg/L at pH?=?3.0, whereas operating in stoichiometric conditions, R?=?14.0, the residual turbidity of water results almost null. 相似文献
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Silva Lídia Gaudêncio Ribeiro Costa Elizângela Pinheiro Starling Maria Clara Vieira Martins dos Santos Azevedo Taíza Bottrel Sue Ellen Costa Pereira Renata Oliveira Sanson Ananda Lima Afonso Robson José Cassia Franco Amorim Camila C. 《Environmental science and pollution research international》2021,28(19):24067-24078
Environmental Science and Pollution Research - The goal of this work was to evaluate the performance of the LED irradiated photo-Fenton process on the removal of (i) estrogenic activity and (ii)... 相似文献
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铁炭微电解预处理高浓度高盐制药废水 总被引:2,自引:1,他引:2
采用铁炭微电解法预处理高浓度高盐制药废水,并对反应条件、处理效果、反应动力学和机理进行研究。通过单因素实验初步研究进水pH、铁用量、反应时间和铁炭比对处理效果的影响;通过正交实验表明进水pH对处理效果影响最大,并得到最佳反应条件为:进水pH为4.5,铁投加量40 g/L,铁炭质量比1∶1,反应时间4 h,COD去除率可达40%以上,并可以提高废水的可生化性,后续通过厌氧生物处理出水可达二级污水综合排放标准。通过对各级反应动力学方程进行回归分析,表明微电解处理制药废水基本遵循一级反应动力学。铁炭微电解处理制药废水效果好,并可以提高可生化性,同时具有操作简单和成本低的优点,为制药废水的预处理提供新的途径。 相似文献
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SBR法处理豆制品废水工艺条件的研究 总被引:7,自引:0,他引:7
用SBR法处理豆制品废水的试验表明,该系统具有较好的抗负荷冲击能力,进水COD在300—2000mg/L之间变化,对系统不造成任何影响;考察了曝气时间、曝气量和污泥浓度等对去除效果的影响,试验结果表明,曝气时间和曝气量对处理效果影响很大。确定该反应系统最佳曝气时间是8h,适宜的曝气量是800L/h,而污泥浓度控制在4000mg/L左右时,处理效率最高,采用进水顶出水的排水方式是可行的,确定系统的最佳排水比是3/5。厌氧段的插入可以减少剩余污泥的产量。 相似文献