电厂循环冷却水中异养菌的检测与分析

通过对城市中水回用于火电厂循环冷却系统的微生物进行试验检测与分析,发现循环水进行前期处理后水中大肠菌群、铁细菌、硫酸盐还原菌含量分别为5个/ml、110个/ml和0.7个/ml以下,均在安全限度之内。对循环水中的异养菌检测分析发现其值在105～106个/mL范围内波动,形成火电厂循环水系统的主要危害,提出影响火电厂循环冷却系统的主要影响菌类为异养菌的结论,对循环冷却水系统微生物的控制具有一定指导意义。     

城市污水二级处理出水直接回用作工业循环冷却水铜管腐蚀研究

采用静态挂片法及动态模拟试验研究了将城市污水处理厂二级出水直接回用作工业循环冷却水,对污水中的氨氮、Cl-等组分及COD等对铜材的腐蚀影响.     

美国炼油厂循环冷却水处理与污水回用现状

介绍了美国炼油厂循环冷却水系统的水质指标及常用的水质稳定技术,简述了美国炼油厂污水回用于循环冷却水的水源和水质要求,论述了市政污水回用的深度处理技术,分析了回用水对炼油厂循环冷却水系统的影响及相应的水处理工艺的调整方法,为我国炼油厂循环冷却水处理及污水回用提供借鉴。     

二级处理后的城市污水用作电厂冷却水若干问题的探讨

介绍了二级处理后的城市污水（TSE）用作电厂开式循环冷却水时，由于城市污水中氨氮、微生物及菌类含量较高，可能给循环水系统带来的危害，并探讨了危害产生的原因及控制措施。     

循环冷却水系统中物质的转化规律及提高浓缩倍率的措施

介绍了城市污水处理厂二级出水回用于循环冷却水系统时,系统中几种物质的转换以及不同浓缩倍率对铜试片的腐蚀速率。采用混凝＋超滤＋反渗透的旁路系统工艺,降低循环水系统中物质的浓度,可以使系统的浓缩倍率达到4。     

曝气生物滤池在中水回用于循环冷却水中去除氨氮的探讨

介绍了曝气生物滤池（BAF）工艺应用于脱氮方面的特点，探讨以该工艺处理市政污水厂二级出水，以回用于火电厂循环冷却水的优越性。     

膜技术在城市中水回用于火电厂的应用研究

城市中水经过深度处理后回用于火电厂,不仅可解决电厂用水紧张的状况,而且可减轻污水排放对环境的影响.介绍了膜法在火电厂中水回用方面的原理、工艺并结合工程实践进行论证,指出了膜技术的发展方向.     

高效分离池—絮凝沉淀法处理火电厂工业废水

采用高效分离池－絮凝沉淀法新工艺处理新乡火电厂２００ＭＷ机组工业废水，１年的运行效果表明，处理后的水质良好，达到了循环冷却水的水质要求，回用于冷却水的补充水，每年可回收３５０万ｔ。系统运行正常，性能稳定。本工艺具有占地小、投资小、设施简单、处理效果好等优点。     

秦岭发电厂循环冷却水提高浓缩倍率的试验研究

通过系统调查试验，试验室静态及动态模拟试验，提出了解决秦岭电厂二期，三期工程两个循环冷却水系统浓缩倍率相差甚大的办法，并为配合回收灰场澄清水，提出了采用复合配方以提高循环冷却水的浓缩倍率。     

污泥为主要原料制成的过滤吸附材料

该发明涉及一种污泥为主要原料制成的新型过滤吸附材料在回用水处理中的应用。为了解决现有回用水处理中一些过滤吸附材料价格较高、化学需氧量和氨氮出水指标低的问题，该发明在处理回用水过程中：（1）利用该过滤吸附材料在曝气生物滤池中采用下向或上向流方式对回用水进行处理，此时曝气强度保持在溶解氧质量浓度为2—4mg／L，8—20d形成生物膜。     

Review of the kinetics of alkaline degradation of cellulose in view of its relevance for safety assessment of radioactive waste repositories

The degradation of cellulose (a substantial component of low- and intermediate-level radioactive waste) under alkaline conditions occurs via two main processes: a peeling-off reaction and a basecatalyzed cleavage of glycosidic bonds (hydrolysis). Both processes show pseudo-first-order kinetics. At ambient temperature, the peeling-off process is the dominant degradation mechanism, resulting in the formation of mainly isosaccharinic acid. The degradation depends strongly on the degree of polymerization (DP) and on the number of reducing end groups present in cellulose. Beyond pH 12.5, the OH^- concentration has only a minor effect on the degradation rate. It was estimated that under repository conditions (alkaline environment, pH 13.3-12.5) about 10% of the cellulosic materials (average DP = 1000-2000) will degrade in the first stage (up to 10⁵ years) by the peeling-off reaction and will cause an ingrowth of isosaccharinic acid in the interstitial cement pore water. In the second stage (10⁵-10⁶ years), alkaline hydrolysis will control the further degradation of the cellulose. The potential role of microorganisms in the degradation of cellulose under alkaline conditions could not be evaluated. Proper assessment of the effect of cellulose degradation on the mobilization of radionuclides basically requires knowing the concentration of isosaccharinic acid in the pore water. This concentration, however, depends on several factors such as the stability of ISA under alkaline conditions, sorption of ISA on cement, formation of sparingly soluble ISA-salts, etc. A discussion of all the relevant processes involved, however, is far beyond the scope of the presented overview.     

Study of Aging Characteristics of Ternary Blends of Polyethylenes—II

Six film samples of low-density polypropylene (LDPE)/linear LDPE (LLDPE)/high-density polypropylene (HDPE) with varying ratios of LDPE (20–45 ... wt%) and LLDPE (25–50 wt%) having a fixed amount of HDPE at 30 wt% were prepared by blown film extrusion technique. The samples were aged at four different temperatures, 55°, 70°, 85°, and 100°C, for four different time periods in the interval of between 150 hours and up to 600 hours. The change in the structure of various constituents and the formation of various oxygenated (peroxy and hydroperoxy) and unsaturated groups during thermo-oxidative degradation was discussed by infrared spectroscopy. The visiosity-average molecular weight was found to have decreased slowly in the initial aging hours and temperatures, whereas it decreased by 10% with its previous value tensile strength that is, 100°C when aged for 600 hours. The tensile strength of the sample first increased by 67% at 55°C and 89% at 70°C up to 450 hours, whereas the values increased by 52.5% at 85°C and 33.9% at 100°C when aged for 150 hours and then decreased. The percentage elongation at break increased by 2.7% at 55°C and 10.7% at 70°C for 150 and 300 hours of aging, respectively, whereas the percentage decreased when aged at 85°C and 100°C for up to 600 hours of aging. The values of gel content (percent) increased and initial degradation temperature decreased with aging time and temperature.     

Determination of the Burning Characteristics of a Slick of Oil on Water

The burning rate of a slick of oil on a water bed is characterized by three distinct processes, ignition, flame spread and burning rate. Although all three processes are important, ignition and burning rate are critical. The former, because it defines the potential to burn and the latter because of the inherent possibility of boilover. Burning rate is calculated by a simple expression derived from a one-dimensional heat conduction equation. Heat feedback from the flame to the surface is assumed to be a constant fraction of the total energy released by the combustion reaction. The constant fraction (χ) is named the burning efficiency and represents an important tool in assessing the potential of in situ burning as a counter-measure to an oil spill. By matching the characteristic thermal penetration length scale for the fuel/water system and an equivalent single layer system, a combined thermal diffusivity can be calculated and used to obtain an analytical solution for the burning rate. Theoretical expressions were correlated with crude oil and heating oil, for a number of pool diameters and initial fuel layer thickness. Experiments were also conducted with emulsified and weathered crude oil. The simple analytical expression describes well the effects of pool diameter and initial fuel layer thickness permitting a better observation of the effects of weathering, emulsification and net heat feedback to the fuel surface. Experiments showed that only a small fraction of the heat released by the flame is retained by the fuel layer and water bed (of the order of 1%). Ignition has been studied to provide a tool that will serve to assess a fuels ease to ignite under conditions that are representative of oil spills. Two different techniques are used, piloted ignition when the fuel is exposed to a radiant heat flux and flash point as measured by the ASTM D56 Tag Closed Cup Test. Two different crude oils were used for these experiments, ANS and Cook Inlet. Crude oils were tested in their natural state and at different levels of weathering, showing that piloted ignition and flash point are strong functions of weathering level.     

Calculation of carbon balances for evaluation of the biodegradability of polymers

Establishing carbon balances has been proven to be an applicable and powerful tool in testing biodegradability of polymers. In controlled degradation tests at a 4-L scale with the model polymer poly(-hydroxybutyrate) (PHB), it was shown that the degree of degradation could not be determined with satisfactory accuracy from CO₂ release alone. Instead, the course of degradation was characterized by means of establishing carbon balances for the degradation of PHB withAcidovorax facilis and a mixed culture derived from compost. Different analytical methods for determining the different carbon fractions were adapted to the particular test conditions and compared. Quantitative determination of biomass and residual polymer were the main problems in establishing carbon balances. Amounts of biomass derived from protein measurements depend strongly on assumptions of the protein content of the biomass. Selective oxidation of biomass with hypochlorite was used as alternative, but here problems arose from insoluble metabolic products. Determination of soluble components with the method of chemical oxygen demand (COD) also includes empirical assumptions but seems acceptable if the dissolved carbon fraction is in the range of some 10% total carbon. Results confirm both analytical assays and theoretical approaches, in ending up at values very close to 100%, within an acceptable standard deviation range under test conditions comparable to standard test practice.Paper presented at the Bio/Environmentally Degradable Polymer Society—Third National Meeting, June 6–8, 1994, Boston, Massachusetts.     

Model of technological alternatives of production of sodium chromate (VI) with the use of chromic wastes

This article presents a mathematical model which describes the sodium chromate (VI) production process with the use of chromic waste as a substitution of natural raw materials. This model is a function of selected process parameters common for all of the examined alternatives and based on equations of material balance. Optimization of the elaborated technological alternatives of the production process with use of recycling of chromic waste has been evaluated by determining the extreme value of the quality indicator WJ. This indicator defines the quantity of waste created in the process. Optimization results enabled the selection of the optimal technological solution from all of the alternatives possible for use in industrial practice. Negative values of the indicator prove that there is the possibility of introducing to the process a larger quantity of waste than the one obtained in the process and transported to the storage heaps.     

化学品生物降解性的评价与预测

介绍了有机化学物质生物降解性的测定方法及其预测方法研究概况，并讨论了生物降解性评价的发展前景。     

鼓泡式反应器高径比对氨法烟气脱碳性能的影响

以N2和CO2混合气模拟燃烧烟气,研究了鼓泡反应器的高径比以及反应条件对氨法烟气脱碳性能的影响。实验结果表明:在相同高径比的条件下,CO2吸收率随氨水质量分数的增加、反应温度的升高而逐渐增大,随进气CO2体积分数和模拟烟气流量的增加而逐渐减小;CO2吸收率随高径比的增加而增大,在高径比为3.98、氨水质量分数为28%、进气CO2体积分数为10%、模拟烟气流量为1.0L/min、反应温度为40℃的条件下,CO2吸收率最高可达100%。     

Mechanism of Microbial Degradation of Slow-Release Fertilizers

Methyleneureas are condensation products of urea and formaldehyde of different molecular mass and solubility; they are used in large amounts both as resins, binders, and insulating materials for industrial applications, as well as a slow-release nitrogen fertilizer for greens, lawns, or in bioremediation processes. In the present study, the microbial breakdown of these products was investigated. The nitrogen was released as ammonia and urea, and the formaldehyde released immediately oxidized via formiate to carbon dioxide. The enzymatic mechanism of metabolization of methyleneureas was studied in microorganisms isolated from soil, which were able to use these compounds as the sole source of nitrogen for growth. A strain of the Gram-negative bacterium Ralstonia paucula (formerly Alcaligenes sp. CDC group IVc-2) completely degraded methylenediurea and dimethylenetriurea to urea, ammonia, formaldehyde, and carbon dioxide. The enzyme initiating this degradation (methylenediurease) was purified and turned out to be different from the previously described enzyme from Ochrobactrum anthropi with regard to its regulation of expression and physicobiochemical properties. Fungal degradation of methyleneureas may occur via the formation of organic acids, thus leading to a nonenzymatic degradation of methyleneureas, which are unstable under acidic conditions.     

Structure-biodegradation relationships of polymeric materials. 1. Effect of degree of oxidation on biodegradability of carbohydrate polymers

The biodegradability of oxidized starch and inulin has been studied in relation to the degree of periodate oxidation to dialdehyde derivatives, by measuring oxygen consumption and mineralization to carbon dioxide. A higher degree of oxidation of dialdehyde starch and dialdchyde inulin results in a lower rate at which the polymers are biodegraded. It is demonstrated that the biodegradation rate of dialdehyde inulin derivatives decreases more than that of equivalent starch derivatives. The differences in biodegradation behavior between dialdehyde starch and dialdehyde inulin, resulting from comparable modifications, are discussed in terms of conformational structure.     

Effect of Degree of Substitution of Octenyl Succinate Starch on Enzymatic Degradation

Octenyl succinate starch of degree of substitution (ds) 0.03, 0.07, and 0.11 was synthesized in an aqueous medium. These compounds were then tested for the susceptibility to enzymatic degradation. The multiple-enzyme regime of -amylase, amyloglucosidase, and pullulanase was chosen for the evaluation. This combination of enzymes had been proven to degrade 99.5% of unmodified starch to glucose and hence was chosen for this study. It was found that even small amounts of subsituent caused a considerable decrease in the extent of degradation. The net extent of degradation decreased with increasing ds. Surprisingly, the amount of glucose from all three substituted substrates was quite similar, suggesting the effect small amounts of subtituent had on the enzymatic activity.