The antibacterial effects of engineered nanomaterials: implications for wastewater treatment plants

Nanotechnology is currently at the forefront of scientific research and technological developments that have resulted in the manufacture of novel consumer products and numerous industrial applications using engineered nanomaterials (ENMs). With the increasing number of applications and uses of ENMs comes an increasing likelihood of nanoscale materials posing potential risks to the environment and engineered technical systems such as wastewater treatment plants (WWTPs). Recent scientific data suggests that ENMs that are useful in, for example, medical applications due to their novel physicochemical properties, may also cause adverse effects to the bacterial populations used in wastewater treatment systems. In this review, the toxicological effects of titanium nanoparticles (nTiO(2)), zinc oxide (nZnO), carbon nanotubes (CNTs), fullerenes (C(60)) and silver nanoparticles (AgNPs) to bacteria were examined. The results suggest that the potential ENMs risks to bacteria are non-uniform (need to be assessed case-by-case), and are dependent on numerous factors (e.g. size, pH, surface area, natural organic matter). Currently available data are therefore insufficient for evaluating the risks that ENMs pose in WWTPs. To fill these knowledge gaps, we recommend scenario specific studies aimed at improving our understanding on: (i) estimated volumes of ENMs in effluents, (ii) the antibacterial sensitivity of cultures within WWTPs towards selected ENMs, and (iii) processes improving the stability of ENMs in solutions. Two factors that merit consideration for elucidating the potential risks systematically are the toxicity mechanisms of ENMs to bacteria, and the influencing factors based on inherent physicochemical properties and environmental factors. Furthermore, the complexity of behaviour and fate of ENMs in real WWTPs requires case studies for assessing the ENMs risks to bacteria in vivo. The current laboratory results derived using simplified exposure media do not reflect actual environmental conditions.     

A dynamic analysis of the global warming potential associated with air conditioning at a city scale: an empirical study in Shenzhen,China

Heating, ventilation and air conditioning (HVAC) systems are a major source of energy consumption in buildings, directly and indirectly contributing to greenhouse gas (GHG) emissions. In the urban environment, and depending on local climatic conditions, air conditioning units attribute to these high energy demands. This study analyzes the use of residential air conditioning units and their associated global warming potential (GWP) between 2005 and 2030 for the city of Shenzhen, a fast-growing megacity located in Southern China. A life cycle assessment approach was adopted to quantify the GWP impacts which arise from both direct (refrigerant release) and indirect (energy consumption) sources, in combination with a materials flow analysis approach. The results show that the total GWP (expressed as carbon dioxide equivalents, CO₂ eq.) from residential air conditioning systems increased from 2.2 ± 0.2 to 5.1 ± 0.4 million tonnes (Mt) CO₂ eq. between 2005 and 2017, with energy consumption and refrigerant release contributing to 72.5% and 27.5% of the total demands, respectively. Immediate measures are required to restrict refrigerant release and reduce the energy consumption of air conditioning units, to help mitigate the predicted additional total emissions of 36.4 Mt. CO₂ eq. potentially released between 2018 and 2030. This amount equals to approximately New Zealand's national CO₂ emissions in 2017. The findings proposed in this study targets air conditioning units to reduce the GWP emissions in cities, and provide useful data references and insights for local authorities to incentivise measures for improving building energy efficiency management and performance.     

Monitoring of selected veterinary antibiotics in environmental compartments near a composting facility in Gangwon Province, Korea

Many studies have been recently reported that veterinary antibiotics released into the environment have a detrimental effect on humans such as the occurrence of antibiotic-resistant bacteria. However, only limited information is available regarding to the release of antibiotics in environmental compartments in Korea. Objectives of this study were to evaluate the concentrations of antibiotics in water, sediment, and soil adjacent to a composting facility in Korea and to determine the dilution effects of antibiotics when released into the environment. Seven antibiotics of chlortetracycline, oxytetracycline, tetracycline, sulfamethazine, sulfamethoxazole, sulfathiazole, and tylosin were evaluated by high-performance liquid chromatography?Ctandem mass spectrometry following pretreatment using solid-phase extraction to clean the samples. Results showed that the highest concentration of each antibiotic in both aqueous and solid samples was detected from a site adjacent to the composting facility. We also found that the studied water, sediment, and soil samples are contaminated by veterinary antibiotics throughout comparison with studies from other countries. However, relatively lower concentrations of each antibiotic were observed from the rice paddy soil located at the bottom of the water stream. Further research is necessary to continuously monitor the antibiotics release into ecosystems, thereby developing an environmental risk assessment.     

Logistic sequencing for improving environmental performance using ant colony optimization

A significant portion of air pollutions in a city comes from road transport. Shorter travelling distance and less fuel consumption would logically lead to lower emissions of greenhouse gases or particulate matters, thus relieve environmental burdens. In this regard, an appropriate selection of the logistic sequence may contribute significantly to the environment. The logistic sequence for pickup and delivery services are often determined based on decision makers' experience and intuitive judgements. While life cycle assessment (LCA), a well-versed approach, can be used for quantifying the environmental loads, it is often regarded as not suitable for making routine decisions because it takes significant time and resources for data collection as well as expert knowledge for result interpretation. Additionally, the results of LCA studies focus mainly on the environmental perspective and that other decision criteria cannot be taken into account in a single evaluation process. This paper attempts to develop a practical and objective tool, by combining a simplified LCA with the ant colony optimization algorithm, that supports evaluating several decision criteria simultaneously and determining the optimal or near optimal sequence for vehicle routing on pickup and delivery activities. This fit-for-purpose approach enables decision makers to pay attention to environmental impacts during the determination of the travelling sequences. The proposed approach has been successfully performed to identify the optimal solution through benchmarking against other possible sequences, with the aim to reducing environmental impact while balancing other decision criteria.     

江苏省环境与社会经济发展特征分析及对策

环境与社会经济发展既相互促进又相互制约,研究经济持续增长背景下的两者发展特征与关系,对于采取经济环境一体化的综合决策、促进可持续发展具有现实指导意义。利用1991—2010年江苏省社会经济、污染物排放和环境质量数据,采用相关性分析、趋势分析等方法,对江苏省主要社会经济与环境指标发展变化特征进行了系统分析。结果表明,1991—2010年间江苏省社会经济发展呈现持续增长态势,由此带来的资源能源与环境压力亦持续增加;同时,由于实施了一系列政策措施,有效减缓、控制了污染排放和环境质量恶化趋势,但仍面临环境承载能力薄弱、经济结构偏重、能源消费不合理、区域发展不均衡等影响环境与社会经济协调发展的问题。为此,提出进一步处理好经济发展、社会进步与生态环境保护关系的对策建议。     

Global warming implications of facade parameters: A life cycle assessment of residential buildings in Bahrain

On a global scale, the Gulf Corporation Council Countries (GCCC), including Bahrain, are amongst the top countries in terms of carbon dioxide emissions per capita. Building authority in Bahrain has set a target of 40% reduction of electricity consumption and associated CO₂ emissions to be achieved by using facade parameters. This work evaluates how the life cycle CO₂ emissions of buildings are affected by facade parameters. The main focus is placed on direct and indirect CO₂ emissions from three contributors, namely, chemical reactions during production processes (Pco₂), embodied energy (Eco₂) and operational energy (OPco₂). By means of the life cycle assessment (LCA) methodology, it has been possible to show that the greatest environmental impact occurs during the operational phase (80–90%). However, embodied CO₂ emissions are an important factor that needs to be brought into the systems used for appraisal of projects, and hence into the design decisions made in developing projects. The assessment shows that masonry blocks are responsible for 70–90% of the total CO₂ emissions of facade construction, mainly due to their physical characteristics. The highest Pco₂ emissions factors are those of window elements, particularly aluminium frames. However, their contribution of CO₂ emissions depends largely on the number and size of windows. Each square metre of glazing is able to increase the total CO₂ emissions by almost 30% when compared with the same areas of opaque walls. The use of autoclaved aerated concrete (AAC) walls reduces the total life cycle CO₂ emissions by almost 5.2% when compared with ordinary walls, while the use of thermal insulation with concrete wall reduces CO₂ emissions by 1.2%. The outcome of this work offers to the building industry a reliable indicator of the environmental impact of residential facade parameters.     

Life cycle assessment based environmental impact estimation model for pre-stressed concrete beam bridge in the early design phase

The late rise in global concern for environmental issues such as global warming and air pollution is accentuating the need for environmental assessments in the construction industry. Promptly evaluating the environmental loads of the various design alternatives during the early stages of a construction project and adopting the most environmentally sustainable candidate is therefore of large importance. Yet, research on the early evaluation of a construction project's environmental load in order to aid the decision making process is hitherto lacking. In light of this dilemma, this study proposes a model for estimating the environmental load by employing only the most basic information accessible during the early design phases of a project for the pre-stressed concrete (PSC) beam bridge, the most common bridge structure. Firstly, a life cycle assessment (LCA) was conducted on the data from 99 bridges by integrating the bills of quantities (BOQ) with a life cycle inventory (LCI) database. The processed data was then utilized to construct a case based reasoning (CBR) model for estimating the environmental load. The accuracy of the estimation model was then validated using five test cases; the model's mean absolute error rates (MAER) for the total environmental load was calculated as 7.09%. Such test results were shown to be superior compared to those obtained from a multiple-regression based model and a slab area base-unit analysis model. Henceforth application of this model during the early stages of a project is expected to highly complement environmentally friendly designs and construction by facilitating the swift evaluation of the environmental load from multiple standpoints.     

What is the influence of FDI and international people flows on environment and growth in OECD countries? A panel study

Recent years have witnessed an international increase of capital and human flows, this being accelerated by globalization. Several studies show that this phenomenon positively influences growth whilst being detrimental for the environment. This article aims to shed a light on the relationship between environment, growth and international capitalism and human flows. By making use of yearly data in a panel constructed around 36 OECD countries over the timespan 2000–2017, we run Pooled Ordinary Least Squares, Fixed Effects and Random Effects regressions with Driscoll-Kraay standard error correction, as well as the Generalized Method of Moments and the Dynamic Ordinary Least Squares, to obtain both short and long-run relationship. The main results provide evidence supporting the Environmental Kuznets Curve hypothesis in the short-run, while offering some variation in the long-run. The FDI bolster the economic growth by means of no green technologies. The international touristic demand just impacts on the growth, while the migration flows improve the environmental performance both in the short and long-run, implying that international human flows generate positive spill-over in terms of environmental behaviours and growth.     

Greenhouse gas emissions from two hydroelectric reservoirs in Mediterranean region

Water reservoirs are used for many purposes, such as water supply, irrigation, flood mitigation, and hydroelectric energy generation. Although hydroelectric energy is considered “green,” many studies show that the construction of a reservoir enhances greenhouse gas (GHG) emissions at the transformed area. These emissions, mainly of CO₂, CH₄, and N₂O gases, depend on the age of the reservoir, landscape and soil composition, fauna and flora remnants of the impounded area, climatic conditions, and basin runoffs. Consequently, GHG emissions significantly vary between reservoirs and depending on local specificities. Several studies have investigated GHG emissions from reservoirs around the world, focusing mainly on reservoirs located in cold regions, temperate regions, and tropical regions. Research is lacking for reservoirs in Mediterranean countries, like Greece, and similar regions. This work initially assesses the net GHG emissions of a newly created reservoir (Ilarion est. 2012) in Western Macedonia, Greece. The methodology for net GHG emission calculation was based on the use of literature data concerning pre-impoundment emission factors and local specificities of the reservoir (terrain type, canopy cover), as well as on the 2-year measurement data that were collected using a “static floating chamber.” Furthermore, in this work, the gross GHG emissions of an older, in-line reservoir (Polyfytos est. 1974) were also calculated, based on 2-year measurement data. The results show that the global warming potential (GWP) of the reservoirs is dictated by methane emissions; it minimizes during winter and spring and maximizes during summer and autumn. Hydroelectric energy production at Ilarion Reservoir results in 32 to 97 times less total CO₂ equivalent emissions in comparison to fossil fuels, while at Polyfytos Reservoir only 8 to 24 times less (based on gross emissions). It appears that the impact of a reservoir’s morphology on GHG emissions is more significant than that of a reservoir’s age.     

通讯基站环境电磁辐射监管平台设计及运用

从移动通信基站电磁辐射的特点及管理要素入手,针对通信基站环境监管环节中存在的问题,设计通讯基站环境电磁辐射监管平台,提出合理有效的环境监管措施,实现历史监测数据、环评、验收资料电子化,信息公开化;通过平台开展电磁知识宣传教育,建立网络互动,有效遏制通讯基站建设违规行为,提高环保监管效率。     

江苏省快速城镇化的资源环境影响及压力测算研究

通过测算江苏省城镇化每增长一个百分点引起的资源消耗与环境污染物产排放变化量,分析城镇化发展的边际资源环境效应。结果表明,1996年—2010年期间,城镇化每增长一个百分点带来的城镇生活用水量、城镇生活污水排放量、COD产生量、NH3-N产生量、NOx排放量、CO2排放量、垃圾产生量仍呈上升趋势,而城镇化每增长一个百分点带来的COD、NH3-N排放量和SO2排放量由"十五"的增加逐步转为"十一五"的减少。提出,江苏省应选择有特色的城镇化发展道路,合理把握城镇化发展速度和节奏,重视城镇化发展质量,促进城镇与环境协调发展。     

Circular economy application for a Green Stadium construction towards sustainable FIFA world cup Qatar 2022™

The construction industry is responsible for a significant amount of raw material consumption and environmental footprints. Therefore, sustainable construction became a hot topic, which strives to reduce material consumption, limit constructional waste disposal, and decrease contribution to climate change. In line with Qatar's commitment to organizing a sustainable FIFA World Cup in 2022, this study aims to conduct an environmental life cycle assessment (LCA) for the construction of the Education City Stadium. The work presented here provides the first empirical LCA for analyzing the environmental and economic impacts of circular economy application in a World Cup stadium. In this research, the cyclopean concrete (CYC) methodology was utilized, which incorporate the site excavated boulders with the concrete mix to cast the under-raft foundation of the stadium. This approach was compared to the conventional concrete (CC) casting approach to assess the extent to which the newly developed methodology can reduce the environmental and economic burdens. The obtained results have shown a 32% reduction in greenhouse gas emissions when adapting the CYC approach. Thus, the CYC holds a strong promise to achieve the required structural behavior with a low-cost alternative material from existing waste products in Qatar and a lower environmental impact than the CC.     

Hidden sources of mercury in clinical laboratories

The healthcare sector is an important contributor to mercury (Hg) pollution because of the potential presence of mercury in thermometers, blood pressure cuffs, amalgams, etc. There are also other potential sources of mercury in this sector which are used frequently and in high volumes where the presence of the metal is not obvious and which might be collectively contributing to pollution. For instance, some chemicals used for the clinical diagnosis of illness may contain mercury. The goal of this study was to investigate potential sources of mercury pollution, which originate from clinical laboratory discharges, using an exploratory approach. The focus was on the residue generated during automatic analysis of patients’ bodily fluids at a medical center in Hermosillo, Sonora, Mexico. This study shows an overview of what might be happening in the region or the country related to non-obvious sources of mercury in the healthcare sector. The results showed measurable levels of mercury in the residues coming from urine sediment analysis. These amounts do not exceed the maximum allowed by Mexican environmental regulations; nevertheless, the frequency and cumulative volume of residues generated, combined with the potential for persistence and the bioaccumulation of mercury in the environment, warrant attention. The work carried out in this study is being taken as a model for future studies for pollution prevention in the healthcare sector with the goal of measuring mercury emissions to the environment from clinical laboratory wastewater, including identifying sources which—while not obvious— could be important given the frequency and volume of their use in the clinical diagnosis.     

石河子市环境质量库兹涅茨曲线分析

选取石河子市1996—2005年经济与环境数据,建立人均GDP与工业“三废”排放量之间的计量模型,对经济发展与环境质量关系进行计量分析,得出石河子市环境库兹涅茨曲线（EKC）特征。研究表明：石河子市经济增长与环境污染程度之间不完全符合典型的EKC特征,废气与固体废物的环境质量改善转折点尚未到来。因此,应倡导发展循环经济,加大治污力度,实现地区经济发展与环境保护的双赢。     

A tiered procedure for assessing the formation of biotransformation products of pharmaceuticals and biocides during activated sludge treatment

Upon partial degradation of polar organic micropollutants during activated sludge treatment, transformation products (TPs) may be formed that enter the aquatic environment in the treated effluent. However, TPs are rarely considered in prospective environmental risk assessments of wastewater-relevant compound classes such as pharmaceuticals and biocides. Here, we suggest and evaluate a tiered procedure, which includes a fast initial screening step based on high resolution tandem mass spectrometry (HR-MS/MS) and a subsequent confirmatory quantitative analysis, that should facilitate consideration of TPs formed during activated sludge treatment in the exposure assessment of micropollutants. At the first tier, potential biotransformation product structures of seven pharmaceuticals (atenolol, bezafibrate, ketoprofen, metoprolol, ranitidine, valsartan, and venlafaxine) and one biocide (carbendazim) were assembled using computer-based biotransformation pathway prediction and known human metabolites. These target structures were screened for in sludge-seeded batch reactors using HR-MS/MS. The 12 TPs found to form in the batch experiments were then searched for in the effluents of two full-scale, municipal wastewater treatment plants (WWTPs) to confirm the environmental representativeness of this first tier. At the second tier, experiments with the same sludge-seeded batch reactors were carried out to acquire kinetic data for major TPs that were then used as input parameters into a cascaded steady-state completely-stirred tank reactor (CSTR) model for predicting TP effluent concentrations. Predicted effluent concentrations of four parent compounds and their three major TPs were corroborated by comparison to 3-day average influent and secondary effluent mass flows from one municipal WWTP. CSTR model-predicted secondary effluent mass flows agreed within a factor of two with measured mass flows and confidence intervals of predicted and measured mass flows overlapped in all cases. The observed agreement suggests that the combination of batch-determined transformation kinetics with a simple WWTP model may be suitable for estimating aquatic exposure to TPs formed during activated sludge treatment. Overall, we recommend the tiered procedure as a realistic and cost-effective approach to include consideration of TPs of wastewater-relevant compounds into exposure assessment in the context of prospective chemical risk assessment.     

MERCURY EMISSION INVENTORY IN ONTARIO

Mercury is released to the environment from various anthropogenic and natural sources. This work is a compilation of mercury emissions from anthropogenic sources in Ontario, Canada. The goal of our study was to identify all sources of mercury, and develop an emission inventory of anthropogenic mercury in Ontario. The result of our investigation revealed that combustion of fossil fuels and emissions from landfill sites are two primary sources of mercury to the atmosphere. Other sources of significance are emissions from waste incinerators, various industrial activities, and cement production. Total mercury emission in Ontario is estimated as 4100 kg per year.     

青浦工业园区B区大气环境影响分析及改善对策探讨

为探讨上海青浦工业园区B区对周边大气环境的影响及可持续发展对策,选取目前入住的化工企业(主要为树脂、表面活性剂和涂料类企业)所排放的臭气浓度等特征污染因子,模拟计算其对整个区域的环境影响。结果表明,这些污染物的挥发量不是很大,但其综合效应造成监测点位臭气浓度偏高。针对工业园区开发过程中对大气环境影响的特点,提出在现有基础上调整产业结构和布局,完善园区服务,促进企业升级等措施,从源头上切实减缓工业园区经济开发对周边大气环境的不利影响,最终达到可持续发展的目的。     

Emissions from gas processing platforms to the atmosphere-case studies versus benchmarks

This study compares oil and gas industry benchmark non-methane volatile organic compounds emission data with predicted and reported emissions from a number of recent case studies. Specifically, we contrast predicted emissions from the Tamar and Leviathan processing platforms in the Eastern Mediterranean with actual emissions where available, and with a compilation of industry benchmarks. This work reveals a series of flaws in the adopted EIA practices in the case studies discussed, starting from the emissions model that grossly underestimates intermittent NMVOC and benzene emissions relative to available data from other sites, and the unrealistic assumption of a constant and uniform emission profile in contrast to real world emission scenarios that are characterized by discrete large emission events. Furthermore, the dispersion model used in the EIAs as part of the request for a business (emissions) permit has a number of significant failings, including the use of an unsuitable model, use of over-simplistic meteorological inputs, and lack of consideration of critical dispersion phenomena. This study highlights the need to rethink the currently used environmental impact assessment and atmospheric permit request methodologies in the oil and gas industry, which rely on unrealistic uniform emission models.     

Brominated flame retardants in the environment of Asia-Pacific: an overview of spatial and temporal trends

In this paper, we summarize spatial and temporal trends of polybrominated diphenyl ethers (PBDEs) and hexabromocyclododecanes (HBCDs) in coastal and marine biota, and further assess human exposure to these brominated flame retardants (BFRs) in Asia-Pacific. The review is based mainly on the studies that were conducted in our laboratory and utilized samples archived in the environmental specimen bank (es-BANK) of Ehime University, Japan. The studies suggest that the target BFRs are ubiquitous in the environment of Asia-Pacific. Examination of spatial trends reveals that concentrations of these contaminants are relatively high in samples from Korea, South China and Japan. In general, the magnitude of environmental contamination by PBDEs in Asia-Pacific, as well as human exposure to these contaminants, seem to be comparable to or slightly higher than in Europe, but lower than in North America. Evaluation of temporal trends in concentrations of BFRs in marine mammals from the coastal waters of Japan and China showed drastic increase during the last 30 years. These changes in BFR levels in samples from Japan were in line with trends in production/use of the commercial formulations. Since the withdrawal of some PBDE products from the Japanese market in the 1990s, concentrations of HBCDs appear to exceed those of PBDEs, reflecting increasing usage of HBCDs over PBDEs. The increasing environmental contamination by BFRs in Chinese coastal waters indicates that contamination by BFRs has already become evident, even in developing countries. In view of the rising environmental levels and the high consumption volume of BFRs in Asia, further efforts should be made to monitor environmental contamination by these chemicals in order to identify sources and reduce emissions.