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1.
John F. Haasbeek 《补救:环境净化治理成本、技术与工艺杂志》1994,4(3):331-341
Under the purview of EPA's Remedial Engineering Management (REM III) Superfund contract, a CERCLA RI/FS was performed at the Pinettes Salvage Yard site located in Washburn, Maine (EPA Region I). The purpose of the RI/FS was to fully characterize the nature, extent, and fate and transport of PCB contamination resulting from an alleged surface spill of transformer dielectric fluid containing Arochlor 1260 (a polychlorinated biphenyl) and various volatile and semivolatile organic constituents. The RI/FS was performed subsequent to both an immediate removal action (IRA) and a deletion remedial investigation (DRI) performed by EPA contractors. Results of both efforts indicated that the site was unsuitable for deletion from the National Priorities List (NPL) because the site soils contained elevated levels of PCBs. This article presents a case history of the extensive field investigations performed to characterize the contaminant source and evaluate the fate and transport of PCBs in site soils. These investigations included on-site mobile laboratory gas chromatograph (GC) analytical techniques for PCBs and targeted volatile and semivolatile organic compounds; confirmatory Contact Laboratory Program (CLP) laboratory analyses of soils, sediments, surface water, and groundwater samples; statistical analyses and correlation of field mobile laboratory GC data with CLP laboratory analytical results; and an evaluation of the potential effects of cosolvency in the fate and transport of PCBs in subsurface soils. 相似文献
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刘敏清 《再生资源与循环经济》2012,5(6):23-25
广州市作为国家再生资源回收体系建设试点城市,在大力发展循环经济、推进再生资源回收利用网络体系建设方面进行了先行先试探索,取得了明显成效。“广州模式”对推进广东省加快转型升级具有启示借鉴意义。 相似文献
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超声波技术降解水中氯代有机物的研究进展 总被引:2,自引:0,他引:2
介绍了超声波技术的基本原理,概述了超声波和各种超声联用(超声波与紫外光、过氧化氢、臭氧、Fenton试剂等联用)技术降解氯代有机物的效果和影响因素,总结了氯代有机物降解机理与动力学的研究进展,并在此基础上提出了今后超声波及其联用技术降解水中氯代有机物的研究方向。 相似文献
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Within the European monitoring network (EMEP, ) several different sampling procedures for measuring the main air components have been applied. This has contributed to systematic
concentration differences and a comparability problem. Since 1997 co-located experiments in 15 countries have been carried
out to quantify these differences. In addition, three major measurement campaigns were organized by EMEP between 1985 and
1991. Differences among results depend on the concentration level and methods used. The decrease in SO2 concentrations over the last twenty years has placed greater demands on the methodology. Absorbing solutions methods for
SO2, (H2O2 and tetrachloromercurate (TCM)) typically have higher detection limits than the reference method, which uses KOH impregnated
filters. The TCM method also has problems with negative interference, especially in summertime. UV fluorescence monitors have
in a few cases proven to give good results, but interferences, detection limit and poor maintenance can be problems. For NO2, many countries are using the TGS absorption solution method, which has a higher detection limit than the reference method
using NaI impregnated glass sinters. The Salzmann method gives unreliable results at concentrations below 1 μgN/m3, and even at higher concentrations the uncertainty is rather unsatisfactory. The chemiluminescence monitor with molybdenum
converters tends to systematically overestimate NO2 concentrations, possibly because zero-drift problems and the non-specific response to NO2. Particulate sulphate measurements in general have lower bias and uncertainties than gas and other aerosol measurements. 相似文献
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The research concerns the Wielkopolski National Park (West Poland), which suffered a huge human impact in the 1970s and 1980s
owing to the nearby location of an industrial plant. Since then, fundamental technological changes that it introduced into
its production of phosphate fertilizers have radically reduced the amount of pollution emitted. A three-year study (2002–2004)
of fluorides in precipitation in open terrain and under tree crowns showed their concentrations to range from levels below
the detection limit (0.003 mg/l) to 0.560 mg/l. Those registered under tree crowns were several times higher and indicated
substantial dry deposition of fluorides on the trees. The highest values were recorded in 2003, with 43% of samples ranging
from 0.01 to 0.05 mg/l, and with 51% of throughfall ranging from 0.10 to 0.50 mg/l. A strong connection was shown to exist
between fluoride and sulphate concentrations in the precipitation. An analysis was made of the available data on F concentrations
in the air and the dust levels around the factory, but these figures did not show an unequivocal effect on F concentrations
in precipitation. A great similarity was found to occur between the fluoride content in rainwater in the Wielkopolski National
Park and in the centre of the nearby Poznań metropolitan area, which indicates that there are also other F sources besides
the local factory. 相似文献
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Assessment of the leaching of metallic elements in the technology of solidification in aqueous solution 总被引:2,自引:0,他引:2
Results are presented of experiments performed to optimize the solidification/stabilization system for metallic elements in aqueous solution. This system involves mixing cement and a solution of metallic elements in a conventional mixer: the paste thus obtained is transferred drop by drop into a recipient filled with an aqueous solution of NaOH at 20% by weight, in which it solidifies immediately. The separate use of chloride solutions of Li+, Cr3+, Pb2+ and Zn2+ makes it possible to obtain granules displaying various levels of compressive strength. Three different inertization matrices were used in the experiments, the first consisting solely of Portland cement, the second of Portland cement and a superplasticizer additive, and the third of Portland cement partially replaced with silica-fume and superplasticizer. The results of the tests performed showed a very low level of leaching into the alkaline solidification solution for Cr3+, the quantity leached being under 2% as against higher levels for the other metallic elements. For all the considered elements, the best results were obtained by using silica-fume in the inertization matrix. 相似文献
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针对各省市冰箱报废量统计数据缺失问题,研究了趋势外推法和市场供给模型测算我国各省市冰箱报废量的可行性,预测了我国31个省市2011—2017年冰箱报废量,以及东、中、西部地区冰箱1999—2017年冰箱报废量。研究结果表明:各省市冰箱报废量预测结果误差小于10%;2011—2017年各省市冰箱报废量逐年上升;东部和中、西部地区分别于2011,2013年进入冰箱报废量直线增长阶段。 相似文献
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Synthetic musk fragrances (SMFs) have been shown to be micropollutants in various aquatic and groundwater systems, often occurring at microgram per liter concentrations. Studies have shown that the most commonly detected SMFs in water are nitro musks and polycyclic musks. The SMFs are typically introduced into the environment in continuous streams such as from wastewater and land application of wastewater or sludge generated during wastewater treatment. Various studies for the treatment of SMFs have been undertaken for wastewater but studies for the treatment of SMFs in groundwater are limited, especially for in situ treatment. A pilot‐scale test was conducted to determine if the use of colloidal activated carbon (CAC) could effectively reduce dissolved concentrations of nitro and polycyclic synthetic musk compounds including musk xylene, musk ketone, galaxolide, and tonalide. The pilot test was carried out downgradient of a septic system in Central Canada where a series of nitrification and denitrification reactions are occurring in an unconfined aquifer. A 10‐weight percent CAC solution was injected into a series of temporary direct push injection points to target the synthetic musk plume. The plume contained galaxolide and tonalide concentrations up to 687 and 187 nanograms per liter (ng/L), respectively, while the concentrations of musk ketone and musk xylene were below the method detection limit (20 ng/L). A total of 13,950 liters of CAC solution was injected during one injection event. The pilot test results indicated that the CAC was effectively delivered to the target injection zone resulting in an increase in total organic carbon concentrations within the saturated soil greater than two orders of magnitude compared to the background concentrations. Analyses of the groundwater chemistry before and post‐injection indicated that the CAC had no detrimental impact on the groundwater quality while reducing the concentration of dissolved galaxolide and tonalide within the plume to below the method detection limits within 51 days of injection with the exception of two of the 14 wells monitored which had galaxolide and tonalide concentrations up to 78 and 35 ng/L. Within 6 months of application, the concentrations of galaxolide and tonalide had decreased to below the method detection limits. Subsequent monitoring of the groundwater quality over a one‐year period failed to detect galaxolide and tonalide, suggesting that the CAC was effective in attenuating the galaxolide and tonalide. 相似文献
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稀土在废水处理中的应用进展 总被引:3,自引:1,他引:2
综述了国内稀土金属在废水处理中的最新应用进展,总结了稀土复合吸附剂的制备方法及其在含磷、氨氮、砷、氟、铬、镉等废水处理中的效果,讨论了稀土复合混凝剂和稀土催化剂在染料、助剂、化工等高浓度有机废水处理中的应用,为找到高效环保的处理工业废水的方法提供了依据. 相似文献
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李湘洲 《再生资源与循环经济》2012,5(1):30-33
介绍了我国电子垃圾回收利用存在的问题与现状、国外可供借鉴的经验,以及电子垃圾分类情况,最后提出我国电子垃圾再生利用的产业化发展方向。 相似文献
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This work investigates the colloid-facilitated migration of radionuclides with radioactive decay in porous media. The sorption processes for radionuclides with both the solid matrix and colloids are treated as equilibrium or nonequilibrium. An analytical solution is obtained from a simplified linear equilibrium interaction mechanism. In addition, the adsorption processes for radionuclides with colloids and porous rock can be assumed as nonequilibrium and modeled by the linear kinetic adsorption. The numerical method is employed to solve the coupled colloid and radionuclide transport equations under nonequilibrium sorption assumption. Moreover, the reaction rates of the adsorption processes for radionuclides with the solid matrix and colloids affect the transport characteristics of radionuclides. The fast reaction rate of radionuclides with colloids causes a higher concentration of radionuclides adsorbed on colloids in a dispersed phase and enlarges acceleration caused by colloids. However, the fast reaction rate for radionuclides with solid matrix increases the retardation effect caused by the solid matrix. This work developed a predictive model for the transport of colloid-facilitated radionuclides in porous medium and to assess the importance of various phenomenological coefficients, particularly parameters for the adsorption interactions. 相似文献
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我国报废汽车回收拆解企业发展的关键问题研究 总被引:1,自引:0,他引:1
报废汽车回收拆解具有巨大的经济、环境和社会效益。我国报废汽车回收拆解企业正面临极佳的发展环境,但目前存在着诸多问题,需要进行转型升级。提出报废汽车回收拆解企业转型升级过程中存在的若干关键问题,即回收阶段中的报废汽车量预测、回收模式选择、报废汽车回收网络构建;拆解阶段中的拆解工艺选择、拆解设备选择;产品销售阶段中的产品分类及市场分析、销售模式确定及销售网络构建、产品定价等问题,并对这些问题进行分析,提供解决方法和措施。 相似文献
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Industrial firms that kill and process chickens generate wastewater that contains fat, oil, and grease (FOG). The FOGs are located in the fatty waste that is collected by floatation in grease traps. Chemical and physical characterisation of FOGs would provide useful information that would help in the development of methods designed to decrease the extent of pollution caused by disposal of the waste and to utilise commercially some of its lipid constituents. Employing these methods would enhance the profitability and competitive potential of these commercial organisations. Samples of grease trap waste from 14 firms in central Thailand have been examined. Due to the very different schemes of waste management employed by these firms, the physical appearance of their fatty wastes showed considerable variation. The chemical and physical properties of the FOGs present in these wastes showed considerable variation also. Large amounts of free fatty acids (10–70% as oleic acid) were detected in most of the 14 wastes and palmitic, cis-9-oleic, cis,cis-9,12-linoleic, stearic, and palmitoleic acids were the predominant species of free and esterified acids. Most of the FOGs were solid at temperatures below 40 °C. Many of them contained traces of heavy metals (Cu and Pb) and some contained traces of the pesticides dimethoate and cypermethrin. The content of these potentially hazardous substances would have to be considered very carefully before discarding the fatty wastes and during the development of methods designed to isolate their potentially profitable lipid constituents. 相似文献
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Yuya Takuwa Tadao Matsumoto Kazuyuki Oshita Masaki Takaoka Shinsuke Morisawa Nobuo Takeda 《Journal of Material Cycles and Waste Management》2009,11(4):305-311
Because landfill gas (LFG) contains an abundance of methane, the utilization of LFG as a renewable energy source is becoming
popular in many countries. LFG, however, contains various trace constituents, some of which may pose problems during utilization.
For example, siloxanes and halogenated volatile organic compounds (VOCs) can cause difficulties when present in the fuel of
gas engines. In addition, many VOCs and mercury have harmful effects on human health, especially on the health of workers
at landfill sites and people living near the landfills. Energy recovery from LFG is expected to make great progress in the
near future, particularly in Asia, but we found little information on the trace constituents of LFG in this region. Therefore,
we sought to characterize the trace components in LFG generated in two landfill sites in China and one site in Japan, to determine
the typical concentrations of these trace components in LFG, and to compare their concentrations among landfill sites in Asia.
We concluded that the trace components in LFG at the sites studied were mainly siloxanes generated from sewage sludge and
harmful benzene, toluene, ethylbenzene, and xylene compounds from petroleum products. 相似文献
20.
SCR系统中板式和蜂巢式催化剂的选取 总被引:9,自引:0,他引:9
选择性催化氧化还原法(SCR)是当今国际上最为成熟、有效的烟气脱硝技术。催化剂作为SCR工艺流程中最重要的设备部件,对SCR工艺的效率起着决定性的作用。分析了2种脱硝催化剂的物理、化学特性,以及它的优缺点,为催化剂的选取提供参考。 相似文献