NUTRIENT FLUXES IN PRECIPITATION,THROUGHFALL, AND STEMFLOW IN AN OAK-HICKORY FOREST1

ABSTRACT: Nutrient fluxes in precipitation, throughfall, and stemflow were studied in an oak-hickory forest in southern Illinois for a three-year period beginning in 1973. Nutrient inputs in these water related pathways were approximately one-half those of litterfall; a major nutrient return mechanism. Considering these water carried nutrients (116 kg/ha/yr), 38% was contributed by precipitation, 35% by throughfall and approximately 27% by stemflow. Although the total nutrient input is only one-half that of litterfall, the net impact on short-term nutrient requirements is considerable because of their immediate availability. Nutrient inputs in litter represent a delayed return mechanism because of the relatively slow decomposition process.     

NUTRIENT BALANCES FOR THE EVALUATION OF NUTRIENT SOURCES IN WATER QUALITY MANAGEMENT1

ABSTRACT. This paper describes the methodology for a nutrient balance to evaluate the sources and distribution of nutrients in a small river basin. Loadings for total nitrogen and phosphorus are calculated from measured nutrient concentration and river discharge data. Using a special retrieval program and a data storage and processing system, loadings are accumulated over a given time period to allow for time of passage through the basin and seasonal changes in nutrient distribution. Nutrient balances are made with the accumulated loadings to obtain the relative contribution of each nutrient source and the retention of nutrients within the basin through sedimentation and aquatic growth. The methodology has been used to study nutrients in the Qu'Appelle River Basin, Saskatchewan, Canada.     

ASSESSMENT OF NUTRIENT EFFECTS AND NUTRIENT LIMITATION IN LAKE OKEECHOBEE1

ABSTRACT: Lake Okeechobee, the third largest lake in the United States, is a shallow, mixing basin with annual total phosphorus concentrations ranging from 50–100 μg P/L. Data, mainly from unpublished agency reports, are analyzed to determine if nutrients limit phytoplankton, to describe spatial and temporal variability in trophic state parameters, and to evaluate conclusions obtained from empirical trophic state models. Algal bioassay experiments that have been used to assess nutrient limitation have produced equivocal results. However, seasonal minima in orthophosphorus and inorganic nitrogen indicate that both nutrients may be limiting seasonally. Strong, but reverse north-south gradients and large seasonal changes in phosphorus and nitrogen concentrations, show that empirical models based on annual phosphorus loadings or concentrations are not adequate to predict chlorophyll concentrations or other trophic state variables. Spatially-segmented, multi-class phytoplankton-nutrient models of seasonal phytoplankton responses that are coupled with hydrodynamic models may provide predictability in assessing effects of changing nutrient loads on phytoplankton composition and standing crop. Successful modeling efforts of responses to nutrients also must deal with resuspended and benthic algae, periphyton, and emergent and submergent aquatic plants that must play important trophic roles in some of the lake basin.     

NITROGEN AND PHOSPHORUS IN SURFACE WATERS OF THE UPPER COLORADO RWER BASIN1

ABSTRACT: As part of a basinwide water-quality study, nitrogen and phosphorus data for the Upper Colorado River Basin from the Colorado-Utah State line to the Continental Divide were analyzed for spatial distributions, concentrations associated with various land uses, and temporal trends. Nitrogen and phosphorus concentrations generally increased in a downstream direction. Some nutrient concentrations were elevated at some sites in the upper parts of the basin in areas influenced by increasing urbanization. Sites were grouped according to land use and site type, and median nutrient concentrations were compared among groups. Sites within the agricultural areas of the basin generally had the highest concentrations of nitrogen and phosphorus; concentrations for main-stem, tributary, and urbanization sites were slightly lower than for the agricultural sites. Background sites, or sites with minimal land-use impacts, had very low median nutrient concentrations. Several sites with long-term data were analyzed for temporal trends in concentrations. Several statistically significant downward trends of low and moderate magnitude were observed for nitrogen and phosphorus species. No upward trends were observed in the data at any site.     

NUTRIENT LOADS TO WISCONSIN LAKES: PART II. RELATIVE IMPORTANCE OF NUTRIENT SOURCES1

ABSTRACT: A comparison of municipal wastewater treatment plant (WWTP) and nonpoint source nutrient loads to Wisconsin's 14,927 inland lakes was performed. Only 65 of the 2,925 Wisconsin lakes having surface areas of at least eight ha and a maximum depth of at least 2.4 m had one or more WWTP's located within 40 km upstream; 99 of Wisconsin's 477 WWTP's were identified to be upstream of these 65 lakes. WWTP total nitrogen and total phosphorus loads to these 65 lakes were estimated using per capita influent loads and removal efficiencies based on wastewater treatment types. Nonpoint source nutrient loads were calculated utilizing nutrient export coefficients derived specifically for Wisconsin. Total nitrogen inputs to the lakes were dominated by nonpoint sources. The effectiveness of various phosphorus control programs to produce water quality improvements visible to the public was estimated to be as follows (going from most to least effective): municipal phosphorus removal and agricultural reductions, municipal phosphorus removal alone, agricultural reduction plus phosphate detergent ban, agricultural reductions alone, and phosphate detergent ban alone. The last option would not be expected to produce water quality improvement visible to the public in any Wisconsin lakes. The differences between the distributions in Wisconsin of population and inland lakes highlights the need to consider regional characteristics in any statewide water quality management plan.     

LAKE RESTORATION BY SEDIMENT REMOVAL1

ABSTRACT: Fresh water lake sediment removal is usually undertaken to deepen a lake and increase its volume to enhance fish production, to remove nutrient rich sediment, to remove toxic or hazardous material, or to reduce the abundance of rooted aquatic plants. Review of more than 60 projects and five case histories reveals that the first three objectives are usually met through sediment removal. Dredging to control aquatic plants has not been well documented. Disadvantages of dredging include cost, temporary phosphorus release from sediment, increased phytoplankton productivity, noise, lake drawdown, temporary reduction in benthic fish food organisms, the potential for toxic material release to the overlying water and potential for environmental degradation at the dredged material disposal site. The technique is recommended for deepening and for long range reduction of phosphorus release from sediment. Sediment removal to control toxic materials is possible with minimal environmental impact when proper equipment is used, but it may more than double the cost. Lack of definitive information about rooted plant regrowth rates in dredged areas prohibits explicit recommendations on sediment removal to control plant growth.     

A SEDIMENT RESUSPENSION AND WATER QUALITY MODEL OF LAKE OKEECHOBEE1

ABSTRACT: The influence of sediment resuspension on the water quality of shallow lakes is well documented. However, a search of the literature reveals no deterministic mass-balance eutrophication models that explicitly include resuspension. We modified the Lake Okeechobee water quality model - which uses the Water Analysis Simulation Package (WASP) to simulate algal dynamics and phosphorus, nitrogen, and oxygen cycles - to include inorganic suspend. ed solids and algorithms that: (1) define changes in depth with changes in volume; (2) compute sediment resuspension based on bottom shear stress; (3) compute partition coefficients for ammonia and ortho-phosphorus to solids; and (4) relate light attenuation to solids concentrations. The model calibration and validation were successful with the exception of dissolved inorganic nitrogen species which did not correspond well to observed data in the validation phase. This could be attributed to an inaccurate formulation of algal nitrogen preference and/or the absence of nitrogen fixation in the model. The model correctly predicted that the lake is light-limited from resuspended solids, and algae are primarily nitrogen limited. The model simulation suggested that biological fluxes greatly exceed external loads of dissolved nutrients; and sediment-water interactions of organic nitrogen and phosphorus far exceed external loads. A sensitivity analysis demonstrated that parameters affecting resuspension, settling, sediment nutrient and solids concentrations, mineralization, algal productivity, and algal stoichiometry are factors requiring further study to improve our understanding of the Lake Okeechobee ecosystem.     

NUTRIENT CONCENTRATIONS IN WASTEWATER TREATMENT PLANT EFFLUENTS,SOUTH PLATTE RWER BASIN1

ABSTRACT: Accurate data about nutrient concentrations in wastewater treatment plant effluents are needed for river basin water-quality studies. As part of the U.S. Geological Survey's National Water-Quality Assessment Program in the South Platte River Basin, nutrient data were requested from 31 wastewater-treatment plants located in the basin. This article describes the types of nutrient data available from the plants, examines the variability of effluent nutrient concentrations, and discusses methods for estimation of nutrient concentrations where data are lacking. Ammonia was monitored at 88 percent of the plants, nitrite plus nitrate was monitored at 40 percent of the plants, and organic nitrogen and phosphorus were monitored at less than 25 percent of the plants. Median total nitrogen concentrations and median total phosphorus concentrations were small compared to typical literature estimates for wastewater-treatment plants with secondary treatment. Nutrient concentrations in effluent from wastewater-treatment plants varied widely between and within plants. For example, ammonia concentrations varied as much as 5 mg/L during a day, as much as 10 mg/L from day to day, and as much as 30 mg/L from summer to winter within a plant. In the South Platte River Basin, estimates of median annual ammonia and nitrite plus nitrate concentrations can be improved based on plant processes; and nitrite plus nitrate and organic nitrogen concentrations can be estimated based on ammonia concentrations. However, to avoid large estimation errors, more complete nutrient data from wastewater-treatment plants are needed for integration into river basin water quality studies. The paucity of data hinders attempts to evaluate the relative importance of point source and nonpoint source nutrient loadings to rivers.     

LOADING FUNCTIONS FOR PREDICTING NUTRIENT LOSSES FROM COMPLEX WATERSHEDS1

ABSTRACT: A loading function methodology is presented for predicting runoff, sediment, and nutrient losses from complex watersheds. Separate models are defined for cropland, forest, urban and barnyard sources, and procedures for estimating baseflow nutrients are provided. The loading functions are designed for use as a preliminary screening tool to isolate the major contributors in a watershed. Input data sources are readily available and the functions do not require costly calibrations. Data requirements include watershed land use and soil information, daily precipitation and temperature records and rainfall erosivities. Comparison of predicted and measured water, sediment, and nutrient runoff fluxes for the West Branch Deleware River in New York, indicated that runoff was underpredicted by about 14 percent while dissolved nutrients were within 30 percent of observed values. Sediment and solid-phase nutrients were overpredicted by about 50 percent. An annual nutrient budget for the West Branch Delaware River showed that cornland was the major source of sediment, solid phase nutrients, and total phosphorus. Waste water treatment plants and ground water discharge contributed the most dissolved phosphorus and dissolved nitrogen, respectively.     

SUSPENDED SEDIMENT AND TURBIDITY FOLLOWING ROAD CONSTRUCTION AND LOGGING IN WESTERN MONTANA1

ABSTRACT: Forest management activities in a second order drainage basin increased suspended sediment yields 7.7 fold in the first year following road construction, and two-fold following logging in the second year. Sediment supply limitations resulted in poor correlations between sediment concentrations with discharge. Sediment transport was strongly hysteretic, with the highest sediment concentrations occurring on the rising limbs of snowmelt hydrographs and individual peaks. In addition to discharge, hydrograph characteristics such as limb, dQ/dt, and the product of dQ/dt and limb aided in explaining variability of observed sediment concentrations. Sediment-turbidity relationships were strongly discharge dependent, reflecting the changing composition of the suspended load with stream power and sediment supplies.     

BMP IMPACTS ON WATERSHED RUNOFF,SEDIMENT, AND NUTRIENT YIELDS1

ABSTRACT: To quantify the effectiveness of best management practice (BMP) implementation on runoff, sediment, and nutrient yields from a watershed, the Nomini Creek watershed and water quality monitoring project was initiated in 1985, in Westmoreland County, Virginia. The changes in nonpoint source (NPS) loadings resulting from BMPs were evaluated by comparing selected parameters from data series obtained before, during, and after periods of BMP implementation. The results indicated that the watershed-averaged curve number, sediment, and nutrient (N and P) concentrations were reduced by approximately 5, 20, and 40 percent, respectively, due to BMP implementation. The nutrient yield model developed by Frere et al. (1980) was applied to the water quality parameters from 175 storms, but it failed to adequately describe the observed phenomena. Seasonal changes in nutrient availability factors were not consistent with field conditions, nor were they significantly different in the pm- and post-BMP periods. An extended period of monitoring, with intensive BMP implementation over a larger portion of the watershed, is required to identify BMP effectiveness.     

A MULTICOMPONENT MODEL OF PHOSPHORUS DYNAMICS IN RESERVOIRS1

The models available for simulating phosphorus dynamics and trophic state in impoundments vary widely. The simpler empirically derived phosphorus models tend to be appropriate for long-term, steady or near steady state analyses. The more complex ecosystem models, because of computational expense and the importance of input parameter uncertainty, are impractical for very long-term simulation and most applicable for time-variable water quality simulations generally of short to intermediate time frames. An improved model for time variable, long-term simulation of trophic state in reservoirs with fluctuating inflow and outflow rates and volume is needed. Such a model is developed in this paper representing the phosphorus cycle in two-layer (i.e., epilimnion and hypolimnion) reservoirs. The model is designed to simulate seasonally varying reservoir water quality and eutrophication potential by using the phosphorus state variable as the water quality indicator. Long-term simulations with fluctuating volumes and variable influent and effluent flow rates are feasible and practical. The model utility is demonstrated through application to a pumped storage reservoir characteristic of these conditions.     

NUTRIENT LOADS TO WISCONSIN LAKES: PART I. NITROGEN AND PHOSPHORUS EXPORT COEFFICIENTS1

ABSTRACT: Export coefficients (kg/km²/yr) for dissolved ortho-phosphate (OP), total phosphorus (TP), total inorganic nitrogen (TIN), and total nitrogen (TN) were derived for watersheds in Wisconsin using data bases available for 17 basins from the U.S. Environmental Protection Agency — National Eutrophication Survey, U.S. Geological Survey, and the Wisconsin Department of Natural Resources. Three general land use categories, representative of most regions in Wisconsin, were established: forest, mixed, and agricultural. Data for the 17 basins indicated greater exports of OP. TP, TIN, and TN as the percentage of forest decreased and agriculture increased. These region-specific coefficients are compared to the values reported in the literature representing much broader areas of the U.S.     

SPNM,A MODEL FOR PREDICTING SEDIMENT,PHOSPHORUS, AND NITROGEN YIELDS FROM AGRICULTURAL BASINS1

ABSTRACT: A model called SPNM from the words “sediment-phosphorus-nitrogen model” was developed for simulating agricultural contributions to water pollution. SPNM is designed to predict sediment, P, and N yields for individual storms on small basins and to route these yields through streams and valleys of large basins. Users need no computer programming experience because the model is a problem-oriented computer language. SPNM is useful in planning water resources projects and in research. Tests of the model on a watershed provided realistic results.     

ANALYSIS OF LAKE-BOTTOM SEDIMENT TO ESTIMATE HISTORICAL NONPOINT-SOURCE PHOSPHORUS LOADS1

ABSTRACT Bottom sediment in Hillsdale Lake, Kansas, was analyzed to estimate the annual load of total phosphorus deposited in the lake from nonpoint sources. Topographic, bathymetric, and sediment-core data were used to estimate the total mass of phosphorus in the lake-bottom sediment. Available streamflow and water-quality data were used to compute the mean annual mass of phosphorus (dissolved plus suspended) exiting the lake. The mean annual load of phosphorus added to the lake from point sources was estimated from previous studies. A simple mass balance then was used to compute the mean annual load of phosphorus from non-point sources. The total mass of phosphorus in the lake-bottom sediment was estimated to be 924,000 kg, with a mean annual load of 62,000 kg. The mean annual mass of phosphorus exiting in the lake outflow was estimated to be about 8,000 kg. The mean annual loads of phosphorus added to the lake from point and nonpoint sources were estimated to be 5,000 and 65,000 kg, respectively. Thus, the contribution to the total mean annual phosphorus load in Hillsdale Lake is about 7 percent from point sources and about 93 percent from nonpoint sources.     

PHOSPHATE IN WATERS: I. REDUCTION USING NORTHERN LIGNITE FLY ASH1

Fly ashes fiom lignite coal fixed steam electric plants contain appreciable amounts of materials that can, in principle, decrease the phosphorus concentration in surface waters. Typical samples of un-weathered fly ash were used to test efficacies of removal of phosphorus from standard phosphate solutions and actual lake water samples. The effects of changing parameters such as contact time, pH, fly ash/water ratios, and solution temperature are presented. Water soluble and insoluble factors in the ash both appear to be reactive constituents. Trials with municipal waste waters showed near quantitative removal of ortho-phosphate.     

HYDROLOGIC BUDGET FOR A FRESHWATER MARSH IN FLORIDA1

ABSTRACT: Accurate water balance calculations are essential for water resource and environmental management decisions, but many of the terms used in the equation are difficult to measure. In this study, a method for measuring rates of evapotranspiration and net seepage from a freshwater marsh in southwest Florida is described. The results are compared to evaporation pan estimates as well as to calculations that balanced all the terms in the hydrologic budget. The measured rates of evapotranspiration showed a. distinct seasonal trend ranging from an average high of 0.24 in/d during July 1992 to a low of 0.06 in/d in January 1993. Evapotranspiration rates were higher than Class A evaporation pan measurements during July and August, indicating transpiration by plants exceeded evaporation by pans. Net ground water seepage flowed out of the marsh except during periods of high water table conditions. When all terms in the hydrologic budget were evaluated, the equation balanced on a yearly basis with an error of 2 percent, on a seasonal basis with errors less than 7 percent, but on a monthly basis errors were as great as 30 percent. Total annual rainfall on the marsh was 45 percent of the total marsh hydrologic input and was approximately equal to the loss by evapotranspiration of 41 percent.     

PHOSPHORUS LOADING TO A MOUNTAIN RESERVOIR IN SOUTHERN CALIFORNIA1

Phosphorus loading from precipitation and more than a dozen tributaries of Big Beat Lake, Woman, was determined for the period from January to December 1978. Direct precipitation contributed 1120 kg·P·yr^-1 (0.096 g P·m^-2·yr^-1) while tributary runoff contributed 21,560 kg for a total P loading of 1.84 g P·m^-2 Rathbone creek, although accounting for only 4 percent of the hydro-logic input to Big Bear Lake, contributed >27 percent of the annual phosphorus load. Phosphorus loading increased with increased impervious geology and increased development. Nitrogen loading exhibited similar loading patterns. Big Beat Lake is currently eutrophic and is likely to remain eutrophic. Calculations based on Vollenweider's critical phosphorus loading concept indicated that tributary P-loading would have to be reduced by >95 percent to achieve mesotrophic conditions. The completion of Big Bear Dam created a “naturally” eutrophic re mix which dl require proper management to enhance its resource potential.     

WASTE LOADINGS FROM A FRESHWATER ATLANTIC SALMON FARM IN SCOTLAND1

ABSTRACT: Recent studies suggest that waste generation from the freshwater phase of Atlantic salmon (Salmo salar L.) production varies considerably on an annual basis. A fish farm on the West Coast of Scotland was visited regularly during a two-year period to determine inflow and outflow water quality. Waste output budgets of suspended solids (SS), biochemical oxygen demand (BOD), total nitrogen (TN), total phosphorus (TP), total ammonia nitrogen (TAN = NH₃+NH₄⁺), dissolved reactive phosphorus (DRP) and total phosphorus (TP) were produced. The annual waste loadings obtained were 71 kg TN t fish^?1 yr^?1 (one year of data only), 10.9–11.1 kg TP t fish^?1 yr^?1, 1.2–2.1 kg DRP t fish^?1 yr^?1, 422–485 kg BOD₅ t fish^?1 yr^?1, 327–337 kg SS t fish^?1 yr^?1, and 30–35 kg TAN-N t fish^?1 yr^?1. Simple linear regression models relating waste parameter production to water temperature and feeding regime were developed. When compared to existing data for other salmonid production systems, greater ranges of daily waste loadings were observed. Wide variations in concentrations of these parameters during a daily cycle were also observed, suggesting that mass balance estimates of waste production will provide more robust estimates of waste output than frequent monitoring of outflow water quality.