Contaminant mobility in diked containment areas

Nine dredged material land containment areas, located at upland, lowland, and island sites, were monitored during hydraulic dredging operations in fresh and brackish-water riverine, lake, and estuarine environments. Influent/effluent sampling at the diked disposal areas showed that, with proper retention of suspended solids, most chemical constituents could be removed to near background water levels. Most heavy metals, oil and grease, chlorinated pesticides, and PCBs were almost totally associated with solids in both the influent and effluent samples. The parameters that appear to have the greatest potential impact as a result of land disposal of dredged material are ammonia, soluble manganese, total mercury, and dissolved oxygen; soluble iron, zinc, and copper may occasionally exceed criteria or background levels.v However, none of these should present serious problems after dillution of the effluent discharge in the receiving waters. Actively growing vegetation in disposal areas appeared to be efficient in removing ammonium nitrogen to low levels and also for filtering out suspended solids. Dissolved oxygen in effluents ranged from 0.6 to 12.5 ppm. Geochemical phase partitioning of influent and effluent solids indicated that carbonate solids of several heavy metals tended to form during dredged slurry containment, promoted by high alkalinity and increased pH in site waters. Metal adsorption onto effluent suspended particles (exchangeable phase) increased slightly, along with a significant increase in cation exchange capacity.     

Availability and plant uptake of heavy metals from contaminated dredged material placed in flooded and upland disposal environments

The availability and plant uptake of heavy metals was evaluated from contaminated dredged material placed in flooded and upland disposal environments using a solid-phase plant bioassay. The objective of the study was to verify previous dredged material research results and to develop a plant bioassay procedure that could indicate phytotoxicity and bioaccumulation of heavy metals in contaminated dredged material. The plant bioassay indicated more uptake and bioaccumulations of cadmium and, to a lesser extent, zinc when contaminated dredged material was placed in an upland environment where the sediment was allowed to air-dry. Placing the contaminated dredged material in a flooded (reduced) environment lowered the availability and plant uptake of cadmium and, to a lesser extent, zinc. Factors that influenced the availability and plant uptake of heavy metals from contaminated sediments included sediment oxidation-reduction potential, organic matter content, total sulfur content, and pH. The plant bioassay showed phytotoxicity and bioaccumulation of arsenic under a flooded environment. Placing the arsenic-contaminated sediment in an upland environment reduced both the phytotoxicity and bioaccumulation of arsenic in the freshwater marsh plant Cyperus esculentus.     

Laboratory study on sustainable use of cement–fly ash–polypropylene fiber-stabilized dredged material

The major problem associated with gravity dam was siltation of reservoir which reduced its effective water storage capacity. In order to maintain effective storage capacity of reservoir, dredging of deposits was required and dredged material was disposed of haphazardly causing damage to the sensitive environment. A better alternative could be the possibility of utilization of dredged deposits in construction works involving large quantities of material. The dredged material consisted of very fine sandy silt possessing poor geotechnical characteristics and was required to be stabilized with suitable additives before use as construction material. This laboratory investigation evaluated geotechnical properties of dredged reservoir material stabilized with cement, fly ash and fiber for its probable use as subbase in lightly trafficked roads. Compaction, unconfined compressive strength and tensile strength tests were performed on appropriate combinations of the constituent materials. The results of study revealed significant improvement in unconfined compressive strength and split tensile strength after stabilization with cement and fly ash. The unconfined compressive strength and split tensile strength of cement–fly ash-stabilized dredged reservoir material improved further upon addition of polypropylene fiber. The composite possessed the potential to be utilized as sustainable material in subbase of roads subject to further validation before application in the field. The dredging of sediments improved effective storage capacity of reservoir and increased its sustainable life period. The utilization of fly ash could diminish the environmental and economic concerns arising out of its haphazard disposal.     

Studies on the Leaching of Radium and the emanation of radon from fertilizer process sludge

Radium-226 present in rock phosphate is carried to CaCO₃, the main process waste sludge of the fertilizer industry. Disposal of the sludge in the environment enhances the radiation background in the area. Two states of adherence of radium in the sludge have been identified, one loosely bound and the other chemically exchanged. The loosely bound fraction accounts for nearly 40% of the total activity, as demonstrated by leaching studies. Laboratory experiments show that activity leach-out by infiltration of water through the sludge is low. Lateral seepage is found to cause extensive areal contamination due to dispersal of suspended solids in the vicinity of the disposal area. The rate of emanation of radon from the sludge is found to be high, a factor of 10 over the normal background emanation rate. The radiation field in the waste disposal area also shows enhancement, with levels 4–6 times higher than natural background.     

Determining sediment quality for regulatory proposes using fish chronic bioassays

Sediment quality assessments for regulatory purposes (i.e. dredged material disposal) are characterized by linking chemical and acute ecotoxicological data. The design of chronic bioassays that incorporate more sensible endpoints than acute tests is discussed to address sediment quality for environmental quality assessment and regulatory proposes. The chronic tests use juveniles of commercial species of fish Sparus aurata and Solea senegalensis, to assess sediment toxicity in samples collected along different littoral areas in the North and the South of Spain. The organisms were exposed during 60 days and sublethal endpoints were selected including biomarkers of exposure to metals (metallothioneins - MTs) and to organic contaminants (ethoxyresorufin-O-deethylase activity - EROD activity) and biomarkers of effect (histopathology in different tissues, gill and liver). A Multivariate Analysis Approach was conducted in order to associate these biological responses with sediment metal concentration from the ports and with chemical residues in biological tissues exposed to sediments under laboratory conditions.     

The dispersion of 137Cs and 239,240Pu in the Rhone River plume: a numerical model

A numerical three dimensional model to simulate the transport of Cs and Pu by the Rhone River plume has been developed. The model solves the hydrodynamic equations, including baroclinic terms (that account for density variations) and a turbulence model, the suspended matter equations, including several particle classes simultaneously, settling, deposition and erosion of the sediment, and the radionuclide dispersion equations. Exchanges of radionuclides between the liquid and solid phases are described in terms of kinetic transfer coefficients. The dependence of these coefficients with water salinity is explicitly included in the model since it changes from freshwater to seawater values in the model domain. Computed activity levels in water, suspended matter and bed sediments are, in general, in agreement with measurements in the area. The model can also give a wide amount of information, as distribution coefficients for total suspended matter and sediments and for each particle class, fractions of radionuclides fixed to solid particles, and vertical profiles of radionuclides and distribution coefficients.     

Liquid versus solid phase bioassays for dredged material toxicity assessment

Since 1994 the results of the analyses of key chemical compounds (trace metals, polychlorinated biphenyls and polycyclic aromatic hydrocarbons) and the comparison with the corresponding sediment quality guidelines (SQGs) are used in decision-making for dredged material management in Spain. Nonetheless in the last decades a tiered testing approach is promoted for assessing the physical and chemical characteristics of dredged sediments and their potential biological effects in the environment. Bioassays have been used for sediment toxicity assessment in Spain but few or no experiences are reported on harbour sediments. We studied the incidence of toxicity in the 7 d bioassay using rotifers (Brachionus plicatilis) and the 48 h bioassay using sea urchin (Paracentrotus lividus) embryos over a series of experiments employing 22 different elutriates. The relative performance of this exposure phase was not comparable to data on the 10-d acute toxicity test using the burrowing amphipod Corophium volutator and the polychaete Arenicola marina, carried out on the whole sediments. These results evidence the importance of the exposure route and the test selected in decision-making, as the toxicity registered for the undiluted elutriates was largely due to the different solubility of sediment-bound contaminants. This work and other studies indicate that for many sediments, a complete battery of test is recommended together with physico-chemical analyses to decide whether dredged sediments are suitable for open water disposal or not.     

An empirical model for primary sedimentation of sewage

Theoretical mathematical models of primary sedimentation and column settling tests have failed until now to predict the behaviour of sedimentation tanks under actual operating conditions due to the difficulties in simulating the effect of the density currents and the complex phenomenon of flocculation. Therefore, empirical models can be helpful in the design of sedimentation tanks. Using performance data from three different pilot-scale sedimentation tanks, empirical mathematical models were developed in this paper relating suspended solids (SS) removal efficiency to surface overflow rate, influent SS concentration, and sewage temperature. The model coefficients were derived from the combined analysis of three well correlated sets of data, thus giving a good indication for their possible general applicability. The analysis of experimental data also gave a relationship between SS and chemical oxygen demand (COD) removal efficiencies.     

Containment facilities for pathological material

Microbiological Safety Cabinets are designed to provide protection to an operator from aerosol hazards that may be generated when handling infectious material. In addition, some types of cabinet can provide protection to the work being handled. Several national standards have been published in recent years which define the construction and performance of these devices; the three types of safety cabinet designated Classes I, II, and III are defined and described in this paper. A measured degree of operator protection is required at the front aperture of Class I and II cabinets, and a new method for assessing operator protection factor based upon a challenge aerosol of potassium iodide is described. Cabinet performance is discussed in relation to containment test results using this system. Working procedures and unsuitable environments can prejudice the containment performance of open-fronted cabinets by several orders of magnitude, and various aspects of this problem are discussed and illustrated. The importance of on-site commissioning tests to ensure adequate operator protection is emphasised. The application of safety cabinet testing techniques has been extended to assess the performance of fume cupboards (hoods), complete laboratories, and special “hybrid” installations such as may be used for handling carcinogenic or radiopharmaceutical material.     

Modelling the transport of radionuclides from land to water

This paper addresses some fundamental problems related to the structure and function of catchment areas in general and for seasonal (weekly, monthly) mass balance calculations of radionuclides (and metals, organics and nutrients) in particular. A new catchment area model has been developed and critically tested. This modelling approach is based on mechanistic principles. The catchment area is differentiated into inflow ( approximately dry land) areas and outflow (=wetland) areas. The model also accounts for time-dependent fixation of substances in the catchment related to single-pulse fallouts. The model has a general structure. It is simple to use since there are only two soil type classes and three categories for the outflow areas. In critical tests, the model was put within a framework where it is intended, i.e., within a more comprehensive lake model. Radiocesium was used as a tracer in these tests. Modelled values were compared to empirical data from 23 lakes (351 data on (137)Cs in water, as well as in sediments, small fish and on suspended particles) covering a very wide limnological domain (latitudes from 42 to 61 degrees V, altitudes from 0 to 1090 m ASL, catchment areas from 0.17 to 114,700 km(2), precipitation from 430 to 1840 mm/year, lake areas from 0.042 to 1147 km(2), mean depths from 1.1 to 90 m, pH from 5.1 to 9 units, potassium concentrations from 0.23 to 27.5 mg/l, total P concentrations from 8.3 to 100 microg/l and theoretical water retention times from 0.02 to 137 years). When modelled values were compared to empirical data, the slope was almost perfect (0.99) as well as the coefficient of determination (r2 = 0.96).     

Monitoring and evaluation of shallow well water quality near a waste disposal site

This study identifies shallow well water contamination sources near the Mae-Hia waste disposal site and the clarification of the extent of well water contamination caused by leachate generated from the disposal site. The water of 40 shallow wells around the Mae-Hia disposal site, where three potential sources of groundwater pollution exist, was sampled and analyzed for physical, chemical, and biological characteristics. Water samples were taken every month from June 1989 to May 1990 along with a measurement of well water levels in order to estimate the groundwater flow direction. Comparison with the drinking water standards/guidelines showed that well water in the study area was not suitable for drinking due to the high contamination of total and fecal coliforms and moderate contamination by nitrate and manganese. It was found that the level of conductivity, total solids, color, chloride, chemical oxygen demand, sodium, copper, and lead in the groundwater of wells located adjacent to the disposal site were higher than in other areas. In addition, higher concentrations of sodium, chloride, calcium, and magnesium in the wells located downstream of the groundwater flow were recorded. Estimation of a leachate plume using chloride as an indicator showed that the wells located in the eastern part of the disposal site, a dominant direction of groundwater flow, were contaminated by leachate generated from the waste disposal site.     

Optimisation of sampling for the temporal monitoring of technetium-99 in the Arctic marine environment

Monitoring of the marine environment for radioactivity, for both radiological protection and oceanographic purposes, remains an expensive and labour intensive activity due to the large sample volumes needed and the complex and lengthy analytical procedures required to measure low levels of contamination. Because of this, some consideration must be given to the design of sampling plans to ensure effective and efficient sampling that can be defended on the basis of scientific rationale. This article tests the hypothesis that geostatistical techniques may prove of use in the optimisation and design of sampling regimes for the monitoring of temporal fluctuations in the levels of technetium at a location in the Norwegian Arctic marine environment. The level of temporal correlation exhibited by two relevant time series was investigated and the information used to observe the effect of sampling frequency on the production of monthly estimates of activity of technetium in both seawater and seaweed. The results indicate that reduced sampling frequency allows production of estimates that acceptably replicate the actual data and that use of geostatistical procedures may offer advantages in the planning of monitoring systems for marine radioactivity. The use of an oceanographic model was also investigated as a means of assessing the temporal correlation prior to actual sampling, an approach that may offer significant advantages by reducing the need to have lengthy time series prior to designing sampling regimes.     

Compostability of lime-flocculated sewage sludge

Recent developments in wastewater treatment are resulting in the production of substantial amounts of chemically [Ca(OH)₂ and Al₂(SO₄)₃·H₂O] treated sludges in need of further treatment before disposal. Although a seemingly suitable method, an unfavorable pH and low volatile solids content constitute serious problems for composting. Hence, an investigation was made of the feasibility of window composting Ca(OH)₂ (lime) precipitated sludge (approximately 25% solids) when mixed with a bulking agent. Bulking agents tried were the paper fraction of municipal refuse and chipped tree and shrub trimmings. Both bulking agents were tried in their raw and in their composted states. Initial mixing was by way of a specially designed hammermill, and subsequent mixing was done manually. Compostability was measured by rate and extent of the temperature rise and fall and by destruction of volatile solids. According to the results, lime exerted no inhibitory influence on the composting process. However, the high ratio of biologically inert material to volatile solids resulted in a shortage of nutrients for the bacteria. Consequently, temperatures attained were neither sufficiently high nor of long enough duration to ensure the pathogen destruction required for public health safety.     

基于MODIS的长江中游河段悬浮泥沙浓度反演

监测和预报悬浮泥沙浓度的沿程分布和时间变化,无论是对于河流水利工程还是河流生态和环境保护都具有重要意义。卫星遥感反演同步性好、速度快、周期短,可以实时和全面地观测大尺度悬浮泥沙分布。旨在建立基于中分辨率成像光谱仪(MODIS)影像的长江中游河段悬浮泥沙浓度反演模型, 并利用建立的模型反演2002~2009 年长江中游河段丰水期的悬浮泥沙浓度, 分析其在时间和空间上的变化特征。研究揭示,MODIS Terra 影像红波段与悬浮泥沙浓度具有显著的相关性（R2=0877,n=125,RMSE=4057 mg/L）,可以用于长江中游丰水期悬浮泥沙浓度的反演。长江三峡工程经历三次蓄水,坝下游宜昌至汉口段悬浮泥沙含量显著减少,荆江河段、洞庭湖及城陵矶至武汉江段下降最为显著。洞庭湖来水来沙是长江中游城陵矶以下江段主要的悬浮泥沙来源之一,从预测结果可知,洞庭湖来水在城陵矶汇入长江后与江水混合以至形成数十公里的混合带,至洪湖以下江段逐渐混合均匀     

Radioactive contamination in the Arctic--sources, dose assessment and potential risks

Arctic residents, whose diets comprise a large proportion of traditional terrestrial and freshwater foodstuffs, have received the highest radiation exposures to artificial radionuclides in the Arctic. Doses to members of both the average population and selected indigenous population groups in the Arctic depend on the rates of consumption of locally-derived terrestrial and freshwater foodstuffs, including reindeer/caribou meat, freshwater fish, goat cheese, berries, mushrooms and lamb. The vulnerability of arctic populations, especially indigenous peoples, to radiocaesium deposition is much greater than for temperate populations due to the importance of terrestrial, semi-natural exposure pathways where there is high radiocaesium transfer and a long ecological half-life for this radionuclide. In contrast, arctic residents with diets largely comprising marine foodstuffs have received comparatively low radiation exposures because of the lower levels of contamination of marine organisms. Using arctic-specific information, the predicted collective dose is five times higher than that estimated by UNSCEAR for temperate areas. The greatest threats to human health and the environment posed by human and industrial activities in the Arctic are associated with the potential for accidents in the civilian and military nuclear sectors. Of most concern are the consequences of potential accidents in nuclear power plant reactors, during the handling and storage of nuclear weapons, in the decommissioning of nuclear submarines and in the disposal of spent nuclear fuel from vessels. It is important to foster a close association between risk assessment and practical programmes for the purposes of improving monitoring, formulating response strategies and implementing action plans.     

A new general dynamic model predicting radionuclide concentrations and fluxes in coastal areas from readily accessible driving variables

This paper presents a general, process-based dynamic model for coastal areas for radionuclides (metals, organics and nutrients) from both single pulse fallout and continuous deposition. The model gives radionuclide concentrations in water (total, dissolved and particulate phases and concentrations in sediments and fish) for entire defined coastal areas. The model gives monthly variations. It accounts for inflow from tributaries, direct fallout to the coastal area, internal fluxes (sedimentation, resuspension, diffusion, burial, mixing and biouptake and retention in fish) and fluxes to and from the sea outside the defined coastal area and/or adjacent coastal areas. The fluxes of water and substances between the sea and the coastal area are differentiated into three categories of coast types: (i) areas where the water exchange is regulated by tidal effects; (ii) open coastal areas where the water exchange is regulated by coastal currents; and (iii) semi-enclosed archipelago coasts. The coastal model gives the fluxes to and from the following four abiotic compartments: surface water, deep water, ET areas (i.e., areas where fine sediment erosion and transport processes dominate the bottom dynamic conditions and resuspension appears) and A-areas (i.e., areas of continuous fine sediment accumulation). Criteria to define the boundaries for the given coastal area towards the sea, and to define whether a coastal area is open or closed are given in operational terms. The model is simple to apply since all driving variables may be readily accessed from maps and standard monitoring programs. The driving variables are: latitude, catchment area, mean annual precipitation, fallout and month of fallout and parameters expressing coastal size and form as determined from, e.g., digitized bathymetric maps using a GIS program. Selected results: the predictions of radionuclide concentrations in water and fish largely depend on two factors, the concentration in the sea outside the given coastal area and/or adjacent coastal areas and the ecological half-life of the radionuclide in the sea. Uncertainties in these factors generally dominate all other uncertainties, e.g., concerning the surface water retention time, the settling velocity of the particulate fraction, the distribution coefficient regulating the fluxes in dissolved and particulate phases, the catchment area influences and the factors regulating biouptake and excretion of the radionuclide in fish. This means that the conditions in the sea are of paramount importance for the conditions in the coastal area, even for relatively enclosed coastal areas. This coastal model may be regarded as a tool for testing working hypotheses on the relative roles of different processes in different coastal areas. Such information is essential for getting realistic expectations of various remedial measures, such as coastal dredging discussed in this work.     

Distribution of tritium in estuarine waters: the role of organic matter

Tritium is an important environmental radionuclide whose reactivity with ligands and solids in aquatic systems is assumed to be limited. We studied the fractionation and sorption of tritium (added as tritiated water) in river water and seawater, and found that its distribution appears to be influenced by its affinity for organic matter. Tritium rapidly equilibrates with dissolved organic ligands that are retained by a reverse-phase C18 column, and with suspended sediment particles. Significantly, a measurable fraction of sorbed tritium associates with proteinaceous material that is potentially available to sediment-feeding organisms. These characteristics have not been reported previously and cannot be accounted for solely by isotopic exchange with hydrogen. Nevertheless, they are in qualitative agreement with available measurements of tritium in estuarine and coastal waters where its principal discharge is as tritiated water. Further research into the estuarine biogeochemical behaviour of tritium is required and radiological distribution coefficients and concentration factors that are assumed for this radionuclide may require reconsideration.     

生态旅游区环境变化与可持续旅游发展——以张家界为例

生态旅游区在扩大接待能力，增加旅游注入的同时，不可避免地破坏了景区生态环境。既要接持更多的过夜游客，增加旅游收入，又要使旅游区生态系统维持在安全的水平上，开发建设规模多大为宜，这是许多生态旅游区亟待解决的问题。本文提出了基于环境脆弱因子的建设规模容限值计量模型，并在典型的生态旅游区张家界进行了验证。通过计算得出了在不同的建设规模条件下，张家界景区最为脆弱的环境因子-总磷含量的变化状态。实证研究表明，宾馆规模容限值模型是分析生态旅游区环境变化可持续发展的有效工具。     

Potential for the desalination of a brackish groundwater aquifer under a background of rising sea level via salt intrusion prevention river gates in the coastal area of the Red River Delta,Vietnam

Additional freshwater sources are required in many parts of the world, including the coastal areas of the Red River Delta (RRD), where the groundwater (GW) is generally brackish. Determining a feasible method for desalinating brackish aquifers would help provide additional freshwater sources. However, substantial desalination of brackish aquifers cannot be achieved under the natural conditions of GW flow and precipitation recharge. Although rainfall recharge to the shallow Holocene aquifer has occurred for hundreds of years, the aquifer still remains brackish since the natural hydraulic conditions do not allow a complete mixing between the fresh recharged water and aquifer salinized water or the discharging of the aquifer salinized water. The planned salt intrusion prevention gates in the Red River, Tra Ly River and Hoa River in the RRD coastal area, combined with increased GW abstraction and associated aquifer recharge with fresh river water, could result in the gradual desalination of the shallow Holocene aquifer. These effects would help improve the area’s resilience to freshwater shortages and sea level rises and would allow for the creation of a long-term sustainable water resource development plan to manage the salinization of water resources caused by sea level rises. Finite element (FE) modeling of GW flow, solute transport via GW flow and dynamic programming (DP) have been used to study the potential desalination of brackish aquifers, the magnitude of GW abstraction quantities and the spatial and temporal aspects of desalination. FE modeling of GW flow coupled with DP was utilized to identify the magnitude of sustainable abstraction quantities and the GW flow field, which is required in salt transport models. Multiple sizes of elements and time steps were used to adapt to the unsteady state of GW flow and hydraulic head variables between the elements in the FE meshes in order to ensure reasonable accuracy of numerical modeling. The GW flow and salt transport modeling and DP allowed determining quasi-steady-state GW abstraction rates and aquifer salinity levels for conditions that did and did not include the shallow Holocene unconfined aquifer recharge from rainfall. The aquifer modeled domain which is supposed to serve the pumping well field is 1.5 km². The results showed that the Holocene aquifer may provide a stable abstraction rate of 100 m³/day starting in the 6th year (for the worst-case scenario with zero aquifer recharge from rainfall) to 130 m³/day starting in the 3rd year (for the scenario with aquifer recharge equal to 3% of the rainfall levels). During the first years of GW abstraction, the desalination of the brackish upper Holocene aquifer will mainly occur in the area close to the river, and at the 18th year of abstraction, almost the entire area between the river and line of pumping wells would be desalinized. From the 10th year of abstraction, the abstracted water has a total dissolved solids content lower than 0.5 g/l for the worst-case scenario with zero aquifer recharge from rainfall and lower than 0.42 g/l for the scenario with aquifer recharge equal to 3% of the rainfall. The modeling results indicate the simulated process by which abstraction of groundwater adjacent to the Tra Ly River could desalinize the brackish aquifer via freshwater recharge from the river.     

Detection of tritium sorption on four soil materials

In order to measure groundwater age and design nuclear waste disposal sites, it is important to understand the sorption behavior of tritium on soils. In this study, batch tests were carried out using four soils from China: silty clays from An County and Jiangyou County in Sichuan Province, both of which could be considered candidate sites for Very Low Level Waste disposal; silty sand from Beijing; and loess from Yuci County in Shanxi Province, a typical Chinese loess region. The experimental results indicated that in these soil media, the distribution coefficient of tritium is slightly influenced by adsorption time, water/solid ratio, initial tritium specific activity, pH, and the content of humic and fulvic acids. The average distribution coefficient from all of these influencing factors was about 0.1-0.2 mL/g for the four types of soil samples. This relatively modest sorption of tritium in soils needs to be considered in fate and transport studies of tritium in the environment.