Assessing the impact of source-zone remediation efforts at the contaminant-plume scale through analysis of contaminant mass discharge

The long-term impact of source-zone remediation efforts was assessed for a large site contaminated by trichloroethene. The impact of the remediation efforts (soil vapor extraction and in-situ chemical oxidation) was assessed through analysis of plume-scale contaminant mass discharge, which was measured using a high-resolution data set obtained from 23 years of operation of a large pump-and-treat system. The initial contaminant mass discharge peaked at approximately 7kg/d, and then declined to approximately 2kg/d. This latter value was sustained for several years prior to the initiation of source-zone remediation efforts. The contaminant mass discharge in 2010, measured several years after completion of the two source-zone remediation actions, was approximately 0.2kg/d, which is ten times lower than the value prior to source-zone remediation. The time-continuous contaminant mass discharge data can be used to evaluate the impact of the source-zone remediation efforts on reducing the time required to operate the pump-and-treat system, and to estimate the cost savings associated with the decreased operational period. While significant reductions have been achieved, it is evident that the remediation efforts have not completely eliminated contaminant mass discharge and associated risk. Remaining contaminant mass contributing to the current mass discharge is hypothesized to comprise poorly accessible mass in the source zones, as well as aqueous (and sorbed) mass present in the extensive lower-permeability units located within and adjacent to the contaminant plume. The fate of these sources is an issue of critical import to the remediation of chlorinated-solvent contaminated sites, and development of methods to address these sources will be required to achieve successful long-term management of such sites and to ultimately transition them to closure.     

Climate of the earth: an overview

Climate has varied over a large range in the recent history of the Earth, with extremes represented by equable environments of the Cretaceous and Eocene and the comparatively frigid conditions of the ice ages that punctuated the past few million years. It is suggested that major shifts in climate are controlled largely by variations in CO(2) with related fluctuations in modes of ocean circulation. Changes in climate can proceed rapidly, on time scales as short as centuries or even decades, as indicated by data for the Younger Dryas (a period of globally cold conditions interrupting recovery of the Earth from the last ice age) and the Little Ice Age (a cold snap extending from about 1250 to about 1850 ad). Rapid fluctuations in climate appear to be linked to changes in production of deep water in the North Atlantic, possibly also to variations in circulation of intermediate waters in the Pacific. Mechanisms are discussed whereby changes in ocean circulation can result in shifts of climate on a global scale. A 10 000 year record of climate from Norway is used to provide context for a discussion of possible changes in climate today arising as a result of the build-up of industrially related greenhouse gases. Brief, somewhat pessimistic, comments are offered concerning the prospects for meaningful near-term predictions of the response of climate to increased concentrations of greenhouse gases. Studies of past climates, by drawing attention to important processes and feedbacks, can play a valuable role in the development of credible models for the future.     

Development of an immunochromatographic assay for the rapid detection of bromoxynil in water

A rapid immunochromatographic one-step strip test was developed to specifically determine bromoxynil in surface and drinking water by competitive inhibition with the nano colloidal gold-conjugated monoclonal antibody (mAb). Bromoxynil standard samples of 0.01–10 mg L⁻¹ in water were tested by this method and the visual limit was 0.06 mg L⁻¹. The assay only required 5 min and one-step by dispensing a drop of sample solution onto a strip. Parallel analysis of water samples with bromoxynil showed comparable results from one-step strip test and ELISA. Therefore, the one-step strip test is very useful as a screening method for qualitative detection of bromoxynil in water.     

The use of XAD-resins for the detection of mutagenic activity in water: II. Studies with drinking water

The combined XAD-4/8-Ames test procedure for concentrating and detecting trace amounts of organic mutagens, as already described for surface water, is shown to be suitable for drinking water as well. DMSO is as effective as acetone in eluting the adsorbed mutagens, and optimal recovery of overall mutagenic activity is observed at a flow rate of 2–4 bed volumes/min. The drinking water of 6 cities in The Netherlands, which prepare their drinking water from the rivers Rhine and Meuse, has been tested for mutagenic activity. Mutagenic activity could be demonstrated in 4 cities. Dose-related responses are observed with concentrates of as little as 500 ml of drinking water and the 4 cities clearly differ with regard to the type of mutations induced (TA 98 or TA 100) and the effect of metabolic activation. The absence of mutagenic activity in drinking water of 2 cities indicates that by a proper combination of treatment processes the organics which are responsible for the detected mutagenic activity in drinking water can be removed to a high degree.     

The use of XAD-resins for the detection of mutagenic activity in water: I. Studies with surface water

A study of the effects of different XAD-resins, bed volume, flow rate, pH and type of eluent on the extraction of organic mutagens from surface water is presented. XAD-4/8 is as effective as XAD-2 in concentrating organic mutagens from surface water and dimethylsulfoxide (DMSO) is as efficient as acetone in eluting the adsorbed organic mutagens. The latter allows direct testing up to 0.5 ml of DMSO concentrate in the Ames test. Variation of the pH of the water after passing the XAD-4/8, followed by readsorption, shows that the majority of the mutagenic activity due to dissolved organics is adsorbed at neutral pH. Only a minor fraction is readsorbed at pH 3. Further a XAD-4/8 concentrate and a similar concentrate prepared by freeze drying gives similar mutagenic activity. This indicates that many of the organic mutagens are recovered in the XAD-4/8 concentrate.It is concluded that adsorption on XAD-4/8, followed by direct testing of the DMSO eluates in the Ames test, presents a rapid and relatively simple way to detect low concentrations of organic mutagens in surface water. The general suitability of the method is shown for different types of surface water.     

Evaluating technological innovation impact: an empirical analysis of the offshore wind sector

Environmental Science and Pollution Research - This study analyzed the determinants that impact innovation on offshore wind energy (OSW) for a select group of countries, applying mixed-method...     

Bioeconomic modelling and salmon aquaculture: an overview of the literature

Bioeconomic models can be used to assist producers and decision-makers in identifying optimal production system designs, operation management strategies, and alternative development and policy approaches. This paper reviews the literature on bioeconomic modelling in aquaculture since 1993 and builds on an earlier article by Leung (1994) which examines this literature for the 1974-1993 period. In order to identify the papers reviewed in the present study, a thorough online search in various databases and some specific journals was conducted. Observations on the general state-of-the-art of bioeconomic modelling in aquaculture are discerned based on a comparative analysis of work in the field, with specific reference to salmon aquaculture. Implications for salmon aquaculture systems in Chile and elsewhere are discussed.     

Development of an in-line system for the analysis of 4,4'-DDT in water

An in-line system for trace persistent organic pollutants (POPs) in water was developed by using a laboratory-made hollow fiber membrane (HFM) unit connected with a high-resolution gas chromatograph-mass spectrometer (HRGC-MS). The semivolatile organic compound, 4,4'-Dichlorodiphenyl trichloroethane (4,4'-DDT), was chosen as a representative of a persistent organic compound. The synthetic water contaminated with 4,4'-DDT was passed through the HFM unit, the extraction occurred by the analyte pervaporated and permeated, then stripped into HRGC-MS. Several factors were investigated for the high extraction efficiency. The best performance was obtained at sample and stripping gas flow rates of 6 and 9 mLmin-1, respectively, and desorption temperature of 60 degrees C. At this temperature, the diffusion rate was enhanced by 15 times over 25 degrees C. A wide linear dynamic range was obtained, i.e., 0.10-1.0 mgL-1, with a limit of detection (LOD) of 90 microgL-1. The extraction efficiency of 4,4'-DDT in real water samples was in the range of 83-94%. Real water samples were analyzed and 0.6 microgL-1 of 4,4'-DDT was found in unregistered bottled water and 7.0 microgL-1 in tap water.     

Removal of pollutants from surface water and groundwater by nanofiltration: overview of possible applications in the drinking water industry

During the last decade, nanofiltration (NF) made a breakthrough in drinking water production for the removal of pollutants. The combination of new standards for drinking water quality and the steady improvement of the nanofiltration process have led to new insights, possible applications and new projects on lab-scale, pilot scale and industrial scale. This paper offers an overview of the applications in the drinking water industry that have already been realised or that are suggested on the basis of lab-scale research. Applications can be found in the treatment of surface water as well as groundwater. The possibility of using NF for the removal of hardness, natural organic material (NOM), micropollutants such as pesticides and VOCs, viruses and bacteria, salinity, nitrates, and arsenic will be discussed. Some of these applications have proven to be reliable and can be considered as known techniques; other applications are still studied on laboratory scale. Modelling is difficult due to effects of fouling and interaction between different components. The current insight in the separation mechanisms will be briefly discussed.     

Development of an improved optical transmission technique for black carbon (BC) analysis

A new optical transmission technique for black carbon (BC) analysis was developed to minimize interferences due to scattering effects in filter samples. A standard thermal analysis method (VDI, 1999) is used to link light attenuation by the filter samples to elemental carbon (EC) concentration. Scattering effects are minimized by immersion of the filters in oil of a similar refractive index, as is often done for microscopy purposes. Light attenuation was measured using both a white light source and a red LED of 650 nm. The usual increase in overestimation of BC concentrations with decreasing BC amount in filter samples was found considerably reduced. Some effects of BC properties (e.g. fractal dimension, microstructure and size distribution) on the specific attenuation coefficient B_ATN, however, are still present for the treated samples. B_ATN was found close to 1 m² g⁻¹ for dry-dispersed industrial BC and 7 m² g⁻¹ for nebulized BC. Good agreement was found between the oil immersion, integrating sphere and a polar photometer technique and Mie calculations. The average specific attenuation coefficient of ambient samples in oil varied between 7 and 11 m² g⁻¹ for white light and 6 and 9 m² g⁻¹ for red light (LED). B_ATN was found to have much less site variation for the treated than for the untreated samples. The oil immersion technique improved also the correlation with thermally analyzed EC. This new immersion technique therefore presents a considerable improvement over conventional optical transmission techniques and may therefore serve as a simple, fast and cost-effective alternative to thermal methods.     

Deciphering the role of nanoparticles for management of bacterial meningitis: an update on recent studies

Environmental Science and Pollution Research - Meningitis is an inflammation of the protective membranes called meninges and fluid adjacent the brain and spinal cord. The inflammatory progression...     

Salt marsh restoration: an overview of techniques and success indicators

Environmental Science and Pollution Research - Coastal wetlands including salt marshes are among the most productive ecosystems on Earth. They are known for improving the quality of coastal water...     

Spiking organic chemicals onto sediments for ecotoxicological analyses: an overview of methods and procedures

Environmental Science and Pollution Research - Laboratory testing with spiked sediments with organic contaminants is a valuable tool for ecotoxicologists to study specific processes such as effects...     

The impact of greenhouse gas emissions on the performance of water companies: a dynamic assessment

Environmental Science and Pollution Research - The water industry plays an important role in reducing greenhouse gas (GHG) emissions and therefore, moving to a low-carbon urban water cycle is of...     

Irrigation water intensity and climate variability: an agricultural crops analysis of Italian regions

Environmental Science and Pollution Research - This paper examines the relationship between the requirement of water resources for irrigation and climate variability and analyses the ranking of the...     

Contaminant-induced irreversible changes in properties of the soil-vadose-aquifer zone: an overview

Most studies on contaminant interactions with the subsurface environment focus on contaminant transport, retention and persistence, and on potential remediation of polluted soils, vadose zones and aquifers. Changes in the soil-vadose-aquifer zone (SVAZ) matrix and properties, caused by human activities, are thus usually considered to be deviations from a normal geochemical environment, which will disappear by natural processes or by specific remediation procedures. However, contaminants may also cause, under specific conditions, irreversible changes in SVAZ properties. In this critical overview, we discuss a different aspect of contaminant-SVAZ interactions: irreversible changes in natural SVAZ properties as a result of anthropogenically-induced chemical contamination. We survey selected research results that illustrate various aspects of such phenomena, in soils, aquifers and the vadose zone. Grouping contaminants according to major and trace elements, we observe that major elements can irreversibly affect water transmission and other physical and chemical properties of the SVAZ, mainly in the liquid phase, while trace elements affect mostly the solid phase matrix.     

Terrestrial water cycle and the impact of climate change

The terrestrial water cycle and the impact of climate change are critical for agricultural and natural ecosystems. In this paper, we assess both by running a macro-scale water balance model under a baseline condition and 2 General Circulation Model (GCM)-based climate change scenarios. The results show that in 2021-2030, water demand will increase worldwide due to climate change. Water shortage is expected to worsen in western Asia, the Arabian Peninsula, northern and southern Africa, northeastern Australia, southwestern North America, and central South America. A significant increase in surface runoff is expected in southern Asia and a significant decrease is expected in northern South America. These changes will have implications for regional environment and socioeconomics.