锅炉烟气湿式净化技术研究

湿式除尘技术作为抑制我国以煤烟型为主大气污染的有效手段之一，已越来越多地得到应用。这类除尘设备具有除尘效率高、结构简单、价格低廉等特点，能处理非纤维性粉尘和高温、易燃、易爆气体，具有吸收有害气体作用。但由于存在管道、设备腐蚀严重，易积灰堵塞，污水和污泥排放造成二次污染、脱水效果差、阻力损失大、能耗大、运行费用高、占地面积大、脱硫效率低等问题限制了推广使用。     

老机组实施烟气脱硫的烟囱防腐

针对老电厂实施湿法烟气脱硫后带来的烟囱腐蚀问题，探讨了旧烟囱的腐蚀机理及防腐方案。     

火电厂烟气脱硫装置腐蚀与防护（Ⅲ）

讨论了火电厂多种烟气脱硫技术装置的腐蚀处理，工艺环境对腐蚀的影响及其防腐蚀对策，分析我国引进及开发的烟气脱硫装置防腐蚀技术现状，比较了多种防腐蚀材料及技术的优劣特点，并着重论述了鳞片衬里技术在烟气脱硫环境中的耐蚀机理及特性。     

火电厂烟气脱硫装置腐蚀与防护（Ⅱ）

讨论火电厂多种烟气脱硫技术装置的腐蚀机理，工艺环境对腐蚀的影响及其防腐蚀对策。分析我国引进及开发的烟气脱硫装置防腐蚀技术现状，比较了多种防腐蚀材料及技术的优劣特点，并着重论述了鳞片衬里技术在烟气脱硫环境中的耐蚀机理及特性。     

热力设备停用保护技术的研究和开发

针对热力设备在停用状态下发生停用腐蚀，严重危害机组寿命及其安全经济性的情况，介绍目前国内外热力设备常用的停用保护方法，指出它们防止腐蚀的原理、实施方法、影响因素。讨论它们的适用范围和存在问题，并对存在的问题提出了一些改进建议。     

烟气脱硫系统的腐蚀与防腐

介绍了燃煤电厂烟气脱硫系统腐蚀的主要部位，产生腐蚀的原因及主要的防腐措施，防腐措施包括：用合金材料、玻璃纤维及增强热固性树脂材料制造设备；用橡胶、陶瓷等材料作衬里；控制烟气温度在露点以上等。     

铜合金最严重的几种腐蚀形态

本文描述了铜合金出现的几种最严重的腐蚀形态，影响因素，产生机理及其危害。     

承德热电厂循环冷却水化学处理的研究

采用ＹＪ系列水质稳定剂处理承德热电厂循环水，阻垢和缓蚀作用显著，有效地阻了该厂凝结品铜管的结垢和系统设备的腐蚀 。     

湿法烟气脱硫系统GGH腐蚀和结垢对策研究

湿法烟气脱硫系统GGH的运行存在着腐蚀和结垢、堵塞的现象.分析了湿法脱硫系统GGH在运行过程中腐蚀、结垢的原因,从运行、维护等方面提出来减轻GGH腐蚀、结垢的策略.     

植物秸秆的综合利用及防治造纸污染方法

该发明提供的是一种植物秸秆的综合利用及防治造纸污染方法：将植物秸秆粉碎后，加水进行高温水煮处理，再用热水洗涤；高温水煮后的固形物，加入H2SO4进行连续水解处理，水解结束后过滤，水解处理后的液体用作制造木糖的原料，水解处理后的固形物加入NaOH溶液进行高温碱蒸煮处理，     

A study of the corrosion products of mild steel in high ionic strength brines

The corrosion layer on steel surfaces that formed after exposure to waste isolation pilot plant (WIPP) brines under anoxic conditions was characterized for chemical composition, thickness and phase composition. The chemical composition of the corrosion layer was determined both by X-ray photoelectron spectroscopy (XPS) and by chemical analysis of acid solutions used to remove the corrosion layer. Atomic force microscopic (AFM) images indicated that the brine-corroded surface layer shows extensive granulation along the contours of the steel surface that is characteristic of sharp polishing marks. The corrosion layer seemed to be porous and could be dissolved and detached in dilute hydrochloric acid. The corrosion layer appears to be composed of iron oxides with some ionic substitutions from the brines. The 77 K M?ssbauer spectrum recorded for iron powder leached under similar conditions indicated the corrosion layer was comprised principally of green rust.     

Application of a Proposed Generic LLW Waste Package Analysis With Changing Infiltration in a Humid Environment

Corrosion of carbon steel boxes filled with low‐level radioactive waste and buried within a near surface disposal facility in a humid environment was evaluated using an integrated systems approach framework. The time to hydraulic failure from initial burial to development of holes through the wall of a given waste package from pitting corrosion was calculated for four corrosion scenarios under two different corrosion cases. The two corrosion cases chosen were a constant rate of corrosion and a slowing rate of corrosion. Corrosion rates were estimated for carbon steel buried in soil from several historical studies and related to the corrosivity and aeration profile of the soil. The scenarios were chosen to represent a range of possible conditions at current and future U.S. Department of Energy disposal facilities. For each scenario, once the time to hydraulic failure had been estimated, the amount of liquid present in each waste package at the time of failure was calculated as an estimate of leachate available for subsurface transport. The Savannah River E‐Area Engineered Trench was used as a basis for the hypothetical disposal facility. © 2016 Wiley Periodicals, Inc.     

石灰石—石膏湿法脱硫装置磨损腐蚀问题分析

分析了目前国内现有石灰石—石膏湿法脱硫装置的磨损防腐问题,简述了在运石灰石—石膏湿法脱硫装置的主要磨损腐蚀环境及相应的防护措施。     

Sulfur recirculation for increased electricity production in Waste-to-Energy plants

Sulfur recirculation is a new technology for reducing boiler corrosion and dioxin formation. It was demonstrated in full-scale tests at a Waste to Energy plant in Göteborg (Sweden) during nearly two months of operation. Sulfur was recirculated as sulfuric acid from the flue gas cleaning back to the boiler, thus creating a sulfur loop.The new technology was evaluated by extensive measurement campaigns during operation under normal conditions (reference case) and operation with sulfur recirculation. The chlorine content of both fly ash and boiler ash decreased and the sulfur content increased during the sulfur recirculation tests. The deposit growth and the particle concentration decreased with sulfur recirculation and the dioxin concentration (I-TEQ) of the flue gas was reduced by approximately 25%. Sulfuric acid dew point measurements showed that the sulfuric acid dosage did not lead to elevated SO₃ concentrations, which may otherwise induce low temperature corrosion.In the sulfur recirculation corrosion probe exposures, the corrosion rate decreased for all tested materials (16Mo3, Sanicro 28 and Inconel 625) and material temperatures (450 °C and 525 °C) compared to the reference exposure. The corrosion rates were reduced by 60–90%. Sulfur recirculation prevented the formation of transition metal chlorides at the metal/oxide interface, formation of chromate and reduced the presence of zinc in the corrosion products. Furthermore, measured corrosion rates at 525 °C with sulfur recirculation in operation were similar or lower compared to those measured at 450 °C material temperature in reference conditions, which corresponds to normal operation at normal steam temperatures. This implies that sulfur recirculation allows for higher steam data and electricity production without increasing corrosion.     

臭氧在循环冷却水中缓蚀作用的研究

循环冷却水处理是工业生产中的一个重要环节。臭氧作为单一的水质稳定剂在循环冷却水中具有缓蚀作用。研究结果表明：吸附在金属表面的臭氧使金属表面从活化腐蚀状态转变为钝化状态,使金属腐蚀电位由活化电位区跃变到钝化电位区,阻止金属的溶解;同时氧的传质速率加快,也可以降低由于浓差极化所产生的腐蚀作用;对于未经预膜处理的金属,臭氧改变金属表面状态,形成一层氧化钝化膜,从而起到了缓蚀作用。     

Influence of MSWI bottom ash used as unbound granular material on the corrosion behaviour of reinforced concrete

The reutilisation of MSWI natural weathered bottom ash (WBA) in many applications such as road and underground constructions, embankments or as an aggregate replacement is a common practice in many developed countries. Its potential environmental risk has regularly been evaluated from the point of view of the leaching of heavy metals and metalloids. Nevertheless, the influence over steel rebar when reinforced concrete is exposed to the contact with WBA has been poorly assessed before. In this study, it has been possible to evaluate in terms of days the probability of corrosion in a common case of WBA reutilisation, which is in contact with reinforced concrete formulated with conventional Portland cement. The corrosion monitoring indicates that the probability of corrosion of steel rebar is higher than 90 % with a corrosion rate (CI) estimated to be 11.6 µm year^?1. The aggressive conditions imposed by WBA suppose an important withdrawal if the application of reutilisation involves contact with steel rebar.     

湿法脱硫系统GGH结垢原因分析及对策

介绍了GGH运行中易出现的结垢、堵塞和腐蚀等问题,并对其产生的原因进行了分析,提出了减缓GGH结垢、堵塞和腐蚀趋势的措施和建议。     

Durability of recycled aggregate concrete using pozzolanic materials

In this study, pulverized fuel ash (PFA) and ground granulated blast furnace slag (GGBS) were used to compensate for the loss of strength and durability of concrete containing recycled aggregate. As a result, 30% PFA and 65% GGBS concretes increased the compressive strength to the level of control specimens cast with natural granite gravel, but the tensile strength was still lowered at 28 days. Replacement with PFA and GGBS was effective in raising the resistance to chloride ion penetrability into the concrete body, measured by a rapid chloride ion penetration test based on ASTM C 1202-91. It was found that the corrosion rate of 30% PFA and 65% GGBS concretes was kept at a lower level after corrosion initiation, compared to the control specimens, presumably due to the restriction of oxygen and water access. However, it was less effective in increasing the chloride threshold level for steel corrosion. Hence, it is expected that the corrosion time for 30% PFA and 65% GGBS concrete containing recycled aggregate mostly equates to the corrosion-free life of control specimens.