PVC废物及其处理技术

PVC广泛应用于工业和日常生活中 ,PVC废物的产生量将会在将来一段时间内持续增长 ,对PVC废物处理处置问题研究成为固体废物处理处置的一个方向。目前 ,PVC废物还缺乏系统、完善的管理手段和处理技术。本文在分析PVC废物特点其环境潜在危害特性的基础上 ,比较分析各种PVC废物处理技术的优势和存在的问题 ,及国内外在PVC废物处理处置方面的具体实践 ,以期探讨PVC废物的处理对策并提出今后PVC废物处理的发展趋势和研究方向     

脱硫反应器及其应用

脱硫反应器是脱硫工艺的核心装置 ,其技术和脱硫指标将制约和决定脱硫工艺的效率。在分析中 ,比较全面地介绍和比较了近年来主要的烟气脱硫反应器设备和研究成果及应用情况 ,指出了脱硫反应器的发展方向     

生态工业园区及其建设

生态工业园区是实现生态工业和工业生态学的重要途径 ,代表了未来工业生态系统发展方向。本文从生态工业园区的概念出发 ,分析了生态工业园区的基本特征与功能 ,阐述了生态工业园区的类型及其建设的重点内容 ,介绍了生态工业园区建设实践 ,提出了生态工业园区建设的对策与措施     

New Fabrics and their Potential Application

Considering fabric filtration, particularly the fabrics and their ability to handle submicron particulate and fumes, it is noted that the value of new developments are measured in terms of both improved operational and economic efficiency. The types of available fibers dictate fabric production characteristics as well as the limits of application for the manufactured fabric.     

Ship emissions and their externalities for Greece

The existing and emerging international and European policy framework for the reduction of ship exhaust emissions dictates the need to produce reliable national, regional and global inventories in order to monitor emission trends and consequently provide the necessary support for future policy making. Furthermore, the inventories of ship exhaust emissions constitute the basis upon which their external costs are estimated in an attempt to highlight the economic burden they impose upon the society and facilitate the cost–benefit analysis of the proposed emission abatement technologies, operational measures and market-based instruments prior to their implementation.The case of Greece is of particular interest mainly because the dense ship traffic within the Greek seas directly imposes the impact of its exhaust emission pollutants (NO_x, SO₂ and PM) upon the highly populated, physically sensitive and culturally precious Greek coastline, as well as upon the land and seas of Greece in general, whereas the contribution of Greece in the global CO₂ inventory at a time of climatic change awareness cannot be ignored. In this context, this paper presents the contribution of Greece in ship exhaust emissions of CO₂, NO_x, SO₂ and PM from domestic and international shipping over the last 25 years (1984–2008), utilizing the fuel-based (fuel sales) emission methodology. Furthermore, the ship exhaust emissions generated within the Greek seas and their externalities are estimated for the year 2008, through utilizing the fuel-based (fuel sales) approach for domestic shipping and the activity-based (ship traffic) approach for international shipping.On this basis, it was found that during the 1984 to 2008 period the fuel-based (fuel sales) ship emission inventory for Greece increased at an average annual rate of 2.85%. In 2008, the CO₂, NO_x, SO₂ and PM emissions reached 12.9 million tons (of which 12.4 million tons of CO₂) and their externalities were found to be around 3.1 billion euro. With regard to shipping within the Greek seas, the utilization of the fuel-based (fuel sales) analysis for domestic shipping and the activity-based (ship traffic) analysis for international shipping shows that the ship-generated emissions reached 7.4 million tons (of which 7 million tons of CO₂) and their externalities were estimated at 2.95 billion euro. Finally, the internalization of external costs for domestic shipping was found to produce an increase of 12.96 and 2.71 euro per passenger and transported ton, respectively.     

油气吸附剂及其改性方法

吸附剂的性能对油气吸附分离的效果起着决定性的作用。介绍了活性炭、活性炭纤维、疏水硅胶和疏水沸石等油气吸附剂的吸附性能及改性工艺,提出了吸附剂的改性、复合吸附剂的使用、配套吸附器的开发、新型吸附剂对油气的吸附及解吸工艺将是今后研究的重点。     

Occurrence of organo-arsenicals in jellyfishes and their mucus

Water-soluble arsenic compound fractions were extracted from seven species of jellyfishes and subjected to analysis by high-performance liquid chromatography-inductively coupled plasma mass spectrometry (HPLC-ICP-MS) for arsenicals. A low content of arsenic was found to be the characteristic of jellyfish. Arsenobetaine (AB) was the major arsenic compound without exception in the tissues of the jellyfish species and mucus-blobs collected from some of them. Although the arsenic content in Beroe cucumis, which preys on Bolinopsis mikado, was more than 13 times that in B. mikado, the chromatograms of these two species were similar in the distribution pattern of arsenicals. The nine species of jellyfishes including two species treated in the previous paper can be classified into arsenocholine (AC)-rich and AC-poor species. Jellyfishes belonging to Semaostamae were classified as AC-rich species.     

Arsenic-transforming microbes and their role in biomining processes

It is well known that microorganisms can dissolve different minerals and use them as sources of nutrients and energy. The majority of rock minerals are rich in vital elements (e.g., P, Fe, S, Mg and Mo), but some may also contain toxic metals or metalloids, like arsenic. The toxicity of arsenic is disclosed after the dissolution of the mineral, which raises two important questions: (1) why do microorganisms dissolve arsenic-bearing minerals and release this metal into the environment in a toxic (also for themselves) form, and (2) How do these microorganisms cope with this toxic element? In this review, we summarize current knowledge about arsenic-transforming microbes and their role in biomining processes. Special consideration is given to studies that have increased our understanding of how microbial activities are linked to the biogeochemistry of arsenic, by examining (1) where and in which forms arsenic occurs in the mining environment, (2) microbial activity in the context of arsenic mineral dissolution and the mechanisms of arsenic resistance, (3) the minerals used and technologies applied in the biomining of arsenic, and (4) how microbes can be used to clean up post-mining environments.     

Polychlorinated biphenyls in Mexican cereals and their packings

The content of polychlorinated biphenyls in Mexican cereals and in their packaging materials was determined. All the samples had polychlorinated biphenyls. In all the food samples and in 73% of the packings, the concentrations of polychlorinated biphenyls exceeded the tolerance limits established by the U.S. Food and Drug Administration. A correlation was found between the values for polychlorinated biphenyls in the cereals and those in their packings, therefore, it is concluded that the main source of polychlorinated biphenyls in Mexican cereals is the transference of those present in the recycled paperboard used for the packings.     

Mice exposure to tannery effluents changes their olfactory capacity,and their response to predators and to the inhibitory avoidance test

Environmental Science and Pollution Research - The current study has assessed whether the oral and/or dermal exposure of C57Bl/6 J mice to tannery effluent (a complex pollutant consisting of...     

脱氮复合菌群的构建及其效果

为探讨复合菌群对含氮废水的脱氮效果,从鱼池养殖废水中分离筛选出3株脱氮能力较强的菌株LAB004、AD012和NSP101。分析3株菌株在不同复配比下的脱氮效果,从而构建脱氮复合菌群并对该复合菌群进行生长条件优化,最后以乙酸钠、麦芽糖、蔗糖和葡萄糖为碳源,分析了不同碳源对复合菌群生长和脱氮性能的影响。结果显示,当复配比为LAB004∶AD012∶NSP101=3∶2∶4(菌体体积比)时构建的复合菌群的脱氮效果最佳,该复合菌群经生长条件优化后,在接种量为8%(体积分数)、C/N(质量比)为15、pH为7.0的条件下脱氮效果较好,当以乙酸钠为唯一碳源时复合菌群18h左右达到生长峰值,脱氮率达到90%以上。由菌株LAB004、AD012和NSP101组成的复合菌群具有良好的脱氮效果,在水体氮污染治理方面具有一定的应用潜力。     

Vapor-phase concentrations of PAHs and their derivatives determined in a large city: Correlations with their atmospheric aerosol concentrations

Thirteen PAHs, five nitro-PAHs and two hydroxy-PAHs were determined in 55 vapor-phase samples collected in a suburban area of a large city (Madrid, Spain), from January 2008 to February 2009. The data obtained revealed correlations between the concentrations of these compounds and a series of meteorological factors (e.g., temperature, atmospheric pressure) and physical–chemical factors (e.g., nitrogen and sulfur oxides). As a consequence, seasonal trends were observed in the atmospheric pollutants. A “mean sample” for the 14-month period would contain a total PAH concentration of 13 835 ± 1625 pg m⁻³ and 122 ± 17 pg m⁻³ of nitro-PAHs. When the data were stratified by season, it emerged that a representative sample of the coldest months would contain 18 900 ± 2140 pg m⁻³ of PAHs and 150 ± 97 pg m⁻³ of nitro-PAHs, while in an average sample collected in the warmest months, these values drop to 9293 ± 1178 pg m⁻³ for the PAHs and to 97 ± 13 pg m⁻³ for the nitro-PAHs. Total vapor phase concentrations of PAHs were one order of magnitude higher than concentrations detected in atmospheric aerosol samples collected on the same dates. Total nitro-PAH concentrations were comparable to their aerosol concentrations whereas vapor phase OH-PAHs were below their limits of the detection, indicating these were trapped in airborne particles.     

Microbial siderophores and their potential applications: a review

Siderophores are small organic molecules produced by microorganisms under iron-limiting conditions which enhance the uptake of iron to the microorganisms. In environment, the ferric form of iron is insoluble and inaccessible at physiological pH (7.35–7.40). Under this condition, microorganisms synthesize siderophores which have high affinity for ferric iron. These ferric iron-siderophore complexes are then transported to cytosol. In cytosol, the ferric iron gets reduced into ferrous iron and becomes accessible to microorganism. In recent times, siderophores have drawn much attention due to its potential roles in different fields. Siderophores have application in microbial ecology to enhance the growth of several unculturable microorganisms and can alter the microbial communities. In the field of agriculture, different types of siderophores promote the growth of several plant species and increase their yield by enhancing the Fe uptake to plants. Siderophores acts as a potential biocontrol agent against harmful phyto-pathogens and holds the ability to substitute hazardous pesticides. Heavy-metal-contaminated samples can be detoxified by applying siderophores, which explicate its role in bioremediation. Siderophores can detect the iron content in different environments, exhibiting its role as a biosensor. In the medical field, siderophore uses the “Trojan horse strategy” to form complexes with antibiotics and helps in the selective delivery of antibiotics to the antibiotic-resistant bacteria. Certain iron overload diseases for example sickle cell anemia can be treated with the help of siderophores. Other medical applications of siderophores include antimalarial activity, removal of transuranic elements from the body, and anticancer activity. The aim of this review is to discuss the important roles and applications of siderophores in different sectors including ecology, agriculture, bioremediation, biosensor, and medicine.     

Monitoring of raptors and their contamination levels in Norway

This article summarizes results from raptor monitoring and contamination studies in Norway of the golden eagle, gyrfalcon, white-tailed sea eagle, osprey, peregrine, and merlin. Golden eagle and gyrfalcon populations have been monitored since 1990 as part of the "Monitoring Programme for Terrestrial Ecosystems" (TOV). No long-term trend in the population size or productivity of golden eagle has been shown in any of the 5 study areas. The reproductive output of gyrfalcon is monitored in 3 areas. It is positively correlated with the populations of its main prey species, the rock ptarmigan and the willow ptarmigan. The white-tailed sea eagle population has been monitored since 1974 by the Norwegian Ornithological Society, and the population is increasing. The levels of pesticides and polychlorinated biphenyls are low in the eggs of both the golden eagle and the gyrfalcon, but elevated levels and effects on reproduction have been indicated for a coastal subpopulation of golden eagle. The pollutant levels in white-tailed sea eagle are lower than in the Baltic population of sea eagles, and shell thinning was never severe overall, but individual eggs have contained pollutant concentrations above critical levels. The levels of pollutants in the bird-eating falcons, peregrine, and merlin were higher than in other species. New emerging pollutants, like brominated diphenylethers and perfluorinated organic compounds, could be detected in all species. By incorporating available published and unpublished data, we were able to produce time trends for pollutants and shell thickness over 4 decades.     

指示水体病原污染的微生物及其检测

受粪便污染的水体可能含有严重威胁人类和动物健康的致病微生物,由于病原微生物在水环境中往往数量较少、检测比较困难,通常采用检测与病原微生物具有密切关系的指示微生物来指示和估计病原污染.指示微生物包括总大肠菌群及其替代微生物,已被广泛应用于水体污染程度检测等方面.总结了各种指示微生物的特性、应用范围以及检测方法等方面的最新研究进展.初步介绍了指示微生物和水环境之间的关系,着重介绍了判断病原微生物污染来源的指示微生物及其最新检测方法.     

Atrazine sorption by hydroxy-interlayered clays and their organic complexes

This study examined the sorption of atrazine by hydroxy-Fe interlayered montmorillonite (FeMt) and its hydroquinone (FeMtHQ), citrate (FeMtCt) and catechol (FeMtCC) complexes as well as by hydroxy-Al interlayered montmorillonite (AlMt) and its hydroquinone (AlMtHQ) and citrate (AlMtCt) complexes. Found among the clays were sorption distribution coefficients (K(d)) ranging from 24 to 123 mL g(-1) and maximum sorption (M) ranging from 2.2 to 16.8 microg g(-1). Both K(d) and M decreased in the order of FeMtCC > FeMtHQ > AlMtHQ > (AlMt = FeMt) > (AlMtCt = FeMtCt). The pH was negatively correlated with both K(d) (r = -0.90, p < 0.001) and M (r = -0.81, p < 0.001). When interlayered clays were associated with humified material (FeMtCC, FeMtHQ, AlMtHQ), both K(d) (r > 0.96, p < 0.01) and M (r > 0.94, p < 0.01) were highly positively correlated with total organic C and alkali-soluble C. However, clays with non-humified organic compounds (FeMtCt and AlMtCt) sorbed less atrazine than clays without any organic C (FeMt and AlMt). This suggests that functional groups of Fe-OH and Al-OH in FeMt and AlMt reduced the available sorption sites for atrazine by making complexes with citrate ions while forming FeMtCt and AlMtCt. The atrazine was sorbed through the hydrophobic interactions with organic compound surfaces as well as through H-bonding and ionic bonding with clay-mineral surfaces.     

Biocatalytic amidation of carboxylic acids and their antinemic activity

A series of novel N-alkyl substituted amides, synthesized by enzyme catalysis, were evaluated against root-knot nematode, Meloidogyne incognita and found to have potential antinemic activity. The corresponding amides were prepared by the condensation of equimolar amounts of carboxylic acids with different alkyl amines in the presence of Candida antarctica lipase at 60–90°C in 16–20 h. The reactions were carried out in a non - solvent system without the use of any activating agents. All the products were obtained in appreciable amounts and the yields for different compounds varied between 77.4–82.3%. The synthesized compounds were characterized using spectroscopy techniques namely Infra Red (IR) and Nuclear Magnetic Resonance (NMR) (¹H and ¹³C). Nematicidal activity of synthesized amides was evaluated against J₂s of Meloidogyne incognita at 500, 250, 125 and 62.5 ppm concentrations after 24 h, 48 h and 72 h of exposure. Among all the tested compounds, N-propyl-butyramide, N-propyl-pentanamide and N-propyl-hexanamide were found to possess significant activity with LC₅₀ values of 67.46, 83.49 and 96.53 respectively. N-propyl-butyramide with LC₅₀ value of 67.46 ppm was found to be most active amide against J₂s of Meloidogyne incognita. The bioactivity study showed that an increase in alkyl chain significantly decreased the activity of amides against root-knot nematode.