A two-component material (Fe3O4@CaSiO3) with an Fe3O4 magnetite core and layered porous CaSiO3 shell from calcium nitrate and sodium silicate was synthesized by precipitation. The structure, morphology, magnetic properties, and composition of the Fe3O4@CaSiO3 composite were characterized in detail, and its adsorption performance, adsorption kinetics, and recyclability for Cu2+, Ni2+, and Cr3+ adsorption were studied. The Fe3O4@CaSiO3 composite has a 2D core–layer architecture with a cotton-like morphology, specific surface area of 41.56 m2/g, pore size of 16 nm, and pore volume of 0.25 cm3/g. The measured magnetization saturation values of the magnetic composite were 57.1 emu/g. Data of the adsorption of Cu2+, Ni2+, and Cr3+ by Fe3O4@CaSiO3 fitted the Redlich–Peterson and pseudo-second-order models well, and all adsorption processes reached equilibrium within 150 min. The maximum adsorption capacities of Fe3O4@CaSiO3 toward Cu2+, Ni2+, and Cr3+ were 427.10, 391.59, and 371.39 mg/g at an initial concentration of 225 mg/L and a temperature of 293 K according to the fitted curve with the Redlich–Peterson model, respectively. All adsorption were spontaneous endothermic processes featuring an entropy increase, including physisorption, chemisorption, and ion exchange; among these process, chemisorption was the primary mechanism. Fe3O4@CaSiO3 exhibited excellent adsorption, regeneration, and magnetic separation performance, thereby demonstrating its potential applicability to removing heavy metal ions.
相似文献The problem of producing strong greenhouse gas of nitrous oxide (N2O) from biological nitrogen removal (BNR) process in wastewater treatment plants (WWTP) has elicited great concern from various sectors. In this study, three laboratory-scale wastewater treatment systems, with influent C/N ratios of 3.4, 5.4, and 7.5, were set up to study the effect of influent C/N ratio on N2O generation in anaerobic/anoxic/oxic (A2O) process. Results showed, with the increased influent C/N ratio, N2O generation from both nitrification and denitrification process was decreased, and the N2O-N conversion ratio of the process was obviously reduced from 2.23 to 0.05%. Nitrification rate in oxic section was reduced, while denitrification rate in anaerobic and anoxic section was elevated and the removal efficiency of COD, NH4 +-N, TN, and TP was enhanced in different extent. As the C/N ratio increased from 3.4 to 7.5, activities of three key denitrifying enzymes of nitrate reductase, nitrite reductase, and nitrous oxide reductase were increased. Moreover, microorganism analysis indicated that the relative abundance of ammonium-oxidizing bacteria (AOB) and nitrite-oxidizing bacteria (NOB) were positively correlated with N2O generation, which was reduced from (8.42 ± 3.65) to (3.61 ± 1.66)% and (10.38 ± 4.12) to (4.67 ± 1.62)%, respectively. NosZ gene copy numbers of the A2O system were increased from (1.19 ± 0.49) × 107 to (2.84 ± 0.54) × 108 copies/g MLSS with the influent C/N ratio elevated from 3.4 to 7.5. Hence, appropriate influent C/N condition of A2O process could optimize the microbial community structure that simultaneously improve treatment efficiency and decrease the N2O generation.
相似文献This research aims to compare the disinfection and degradation effectiveness in water of a commercial suspension of nano-TiO2 (TiO2Levenger) with the standard TiO2Degussa P25. Photo-inactivation and photo-degradation experiments were conducted with UVA-vis light. Concerning the disinfection, the effects of TiO2 dose (0–2 g/l), water matrix, bacterium type (Gram-positive or Gram-negative), and bacterial regrowth after the photo-treatments were studied for each catalyst. The experimental results show that Enterococcus sp. (Gram-positive) was more resistant to the photo-treatments than Escherichia coli (Gram-negative) for both catalyst; however, postirradiation trends showed similar behavior for both bacteria, favoring regrowth for short-treated cells and decay for longer-treated ones. Caffeine was selected as a model substance of pharmaceuticals and personal care products. In terms of caffeine removal, the effects of TiO2 dose (0–2 g/l) and water matrix were analyzed. Besides, the comparison between mechanical coagulation-flocculation-decantation and simple decantation of TiO2 was carried out. The results show that simple decantation allowed the recovery of 97.5% of TiO2 Degussa P25 and TiO2 Levenger within 1 day of simple decantation, while applying the proposed mechanical coagulation-flocculation decantation 99.7% of recovery of both catalysts was achieved in 2 hours. Finally, the subsequent reuse of both catalysts was proved with little loss of efficiency in terms of photo-disinfection during the four cycles. Nevertheless, the standard TiO2 Degussa P25 photo-degradation efficiency of caffeine decreases considerably as compared to commercial suspension of TiO2 Levenger concerning the reutilization.
相似文献Currently, activated coke is widely used in the removal of multiple pollutants from industrial flue gas. In this paper, a series of novel FexLayOz/AC catalysts was prepared by the incipient wetness impregnation for NH3-SCR denitrification reaction. The introduction of Fe-La bimetal oxides significantly improved the denitrification performance of activated coke at mid-high temperature, and 4% Fe0.3La0.7O1.5/AC exhibited a superior NOx conversion efficiency of 90.1% at 400 °C. The catalysts were further characterized by BET, SEM, XRD, Raman, EPR, XPS, FTIR, NH3-TPD, H2-TPR, et al., whose results showed that the perovskite-type oxide of LaFeO3 and oxygen vacancies were produced on the catalysts’ surfaces during roasting. Fe-La doping enhanced the amount of acid sites (mainly Lewis and other stronger acid sites) and the content of multifarious oxygen species, which were beneficial for NOx removal at mid-high temperature. Moreover, it was investigated that the effect of released CO from activated coke at mid-high temperature on the NOx removal through the lifetime test, in which it was found that a large amount of CO produced by pyrolysis of activated coke could promote the NOx removal, and long-term escaping of CO on the activated coke carrier did not have a significant negative impact on catalytic performance. The results of the TG-IR test showed that volatile matter is released from the activated coke while TG results showed that the weight loss rate of 4% Fe0.3La0.7O1.5/AC only was 0.0015~0.007%/min at 300–400 °C. Hence, 4% Fe0.3La0.7O1.5/AC had excellent thermal stability and denitrification performance to be continuously used at mid-high temperature. Finally, the mechanisms were proposed on the basis of experiments and characterization results.
相似文献Purpose
Degradation of 2,4-dichlorophenoxyacetic acid (2,4-D) in soils by Fe3O4 nanoparticles combined with soil indigenous microbes was investigated, and the effects of Fe3O4 nanoparticles on soil microbial populations and enzyme activities were also studied. 相似文献In this work, perovskite structure of BaTiO3 was coupled with Fe2O3 in different molar ratios achieving the best photocatalytic performance of CO2 reduction in the presence of CH4 as reducing agent; both of them are main greenhouse gases. The photocatalysts were synthesized by facile hydrothermal method. The samples were characterized by XRD, FTIR, FESEM, EDX, UV–Vis DRS, and photoluminescence (PL) analyses. The BaTiO3 synthesized in this research showed a weak PL signal which is due to the intrinsic ferroelectric property as has been observed in previous reports. Compared to the pure BaTiO3 and Fe2O3, the heterojunctions exhibited enhanced photocatalytic activity. The maximum CO2 reduction under visible light irradiation was obtained to be 22% during 60 min process time. The enhanced photocatalytic activity could be attributed to the increased optical absorption, the good separation, and immigration of photogenerated charge carriers that decreased the recombination rate of charge carriers in the n–n heterojunction.
相似文献The land disposal of waste and wastewater is a major source of N2O emission. This is due to the presence of high concentrations of nitrogen (N) and carbon in the waste. Abattoir wastewater contains 186 mg/L of N and 30.4 mg/L of P. The equivalent of 3 kg of abattoir wastewater-irrigated soil was sieved and taken in a 4-L plastic container. Abattoir wastewater was used for irrigating the plants at the rates of 50 and 100 % field capacity (FC). Four crop species were used with no crop serving as a control. Nitrous oxide emission was monitored using a closed chamber technique. The chamber was placed inside the plastic container, and N2O emission was measured for 7 days after the planting. A syringe and pre-evacuated vial were used for collecting the gas samples; a fresh and clean syringe was used each time to avoid cross-contamination. The collected gas samples were injected into a gas chromatography device immediately after each sampling to analyse the concentration of N2O from different treatments. The overall N2O emission was compared for all the crops under two different abattoir wastewater treatment rates (50 and 100 % FC). Under 100 % FC (wastewater irrigation), among the four species grown in the abattoir wastewater-irrigated soil, Medicago sativa (23 mg/pot), Sinapis alba (21 mg/pot), Zea mays (20 mg/pot) and Helianthus annuus (20 mg/pot) showed higher N2O emission compared to the 50 % treatments—M. sativa (17 mg/pot), S. alba (17 mg/pot), Z. mays (18 mg/pot) and H. annuus (18 mg/pot). Similarly, pots with plants have shown 15 % less emission than the pots without plants. Similar trends of N2O emission flux were observed between the irrigation period (4-week period) for 50 % FC and 100 % FC. Under the 100 % FC loading rate treatments, the highest N2O emission was in the following order: week 1 > week 4 > week 3 > week 2. On the other hand, under the 50 % FC loading rate treatments, the highest N2O emission was recorded in the first few weeks and in the following order: week 1 > week 2 > week 3 > week > 4. Since N2O is a greenhouse gas with high global warming potential, its emission from wastewater irrigation is likely to impact global climate change. Therefore, it is important to examine the effects of abattoir wastewater irrigation on soil for N2O emission potential.
相似文献The present study validates the oil-based paint bioremediation potential of Bacillus subtilis NAP1 for ecotoxicological assessment using a three-dimensional multi-species bio-testing model. The model included bioassays to determine phytotoxic effect, cytotoxic effect, and antimicrobial effect of oil-based paint. Additionally, the antioxidant activity of pre- and post-bioremediation samples was also detected to confirm its detoxification. Although, the pre-bioremediation samples of oil-based paint displayed significant toxicity against all the life forms. However, post-bioremediation, the cytotoxic effect against Artemia salina revealed substantial detoxification of oil-based paint with LD50 of 121 μl ml?1 (without glucose) and >?400 μl ml?1 (with glucose). Similarly, the reduction in toxicity against Raphanus raphanistrum seeds germination (%FG?=?98 to 100%) was also evident of successful detoxification under experimental conditions. Moreover, the toxicity against test bacterial strains and fungal strains was completely removed after bioremediation. In addition, the post-bioremediation samples showed reduced antioxidant activities (% scavenging?=?23.5?±?0.35 and 28.9?±?2.7) without and with glucose, respectively. Convincingly, the present multi-species bio-testing model in addition to antioxidant studies could be suggested as a validation tool for bioremediation experiments, especially for middle and low-income countries.
?
Agriculture P management practices elevate the level of inorganic phosphates in soil that results in phosphorous (P) seepage into water-bodies. This is one of the key factors that have accelerated the menace of eutrophication. Phytic acid (phytate)-P-rich plant metabolite is infamous for its anti-nutrient activity and regularly oozing in to environment though discharge of mono-gastric animals. That has amplified the magnitudes of eutrophication. In this work, for catalysis of phytate-P, the metal-organic framework fabricated towards metal oxides (Fe3O4) and phytase in highly ordered microcosms of silica was employed. The synthesized framework was characterized through transmission electron microscopy (TEM) and nitrogen isotherm analysis. Average pore diameter of synthesized bisect oval shaped structures was measured around ≈200 nm. Herein, phytase and Fe3O4 nanoparticles were loaded to the cavities of microcosms through glutaraldehyde-mediated crosslinking. Whereas Fe3O4 nanoparticles act as nano-absorbents that adsorb P liberated from phytase-mediated catalysis of phytate. Kinetic analysis of free and loaded phytase has shown relatively small reduction in catalytic efficiency. These loaded microcosms have removed 60–80% of phytate-phosphate. The optimized process has reduced the growth of photoautotrophs by 50%. Additionally the magnet-assisted separation of loaded microcosms eased the reapplication of loaded microcosms tested for six independent instances. The primary studies conducted to evaluate the geno-toxicity of loaded microcosms have not shown any harmful effect on the process like cell division and seed germination. The efficacy of this method has evaluated towards on-field testing in Changa (Gujarat, India) lake.
相似文献The present work provides an insight into the development of biochemical adaptations in mung beans against ozone (O3) toxicity. The study aims to explore the O3 stress tolerance potential of mung bean genotypes under exogenous application of growth regulators. The seeds of twelve mung bean genotypes were grown in plastic pots under controlled conditions in the glasshouse. Six treatments, control (ambient ozone level 40–45 ppb), ambient O3 with ascorbic acid, ambient ozone with silicic acid, elevated ozone (120 ppb), elevated O3 with ascorbic acid (10 mM), and elevated ozone with silicic acid (0.1 mM) were applied. The O3 fumigation was carried out using an O3 generator. The results revealed that ascorbic acid and silicic acid application decreased the number of plants with foliar O3 injury symptoms in different degrees, i.e., zero, first, second, third, and fourth degrees; whereas 0–4 degree symptoms represent, no symptoms, symptoms occupying?<?1/4, 1/4–1/2, 1/2–3/4, and?>?3/4 of the total foliage area, respectively. Application of ascorbic acid and silicic acid also prevented the plants from the negative effects of O3 in terms of fresh as well as dry matter production, leaf chlorophyll, carotenoids, soluble proteins and ascorbic acid, proline, and malondialdehyde (MDA) contents. Overall, silicic acid application proved more effective in reducing the negative effects of O3 on mung bean genotypes as compared to that of the ascorbic acid. Three mung bean genotypes (NM 20–21, NM-2006, and NM-2016) were identified to have a better adaptive mechanism for O3 toxicity tolerance and may be good candidates for future variety development programs.
相似文献Ethyl mercaptans which commonly exist in natural gas need to be removed due to their toxic, odorous, and corrosive properties. Herein, a novel Fe2O3-modified HNbMoO6 nanosheet catalyst (Fe2O3@e-HNbMoO6) was prepared by an exfoliation-impregnation method for the ethyl mercaptans removal. In the heterojunction catalyst, e-HNbMoO6 can be excited by visible light to generate the photogenic charge and has certain adsorption property for ethyl mercaptan with hydrogen bonding (Nb-OH or Mo-OH as the hydrogen bonding donor); Fe2O3 plays the role of accelerating photogenerated electrons and holes, and enhancing the adsorption of ethyl mercaptan with another hydrogen bonding (Fe-OH as the hydrogen bonding donor and receptor). Results showed that the adsorption capacity of Fe2O3@e-HNbMoO6 is 69.9 μmol/g for ethyl mercaptan. In addition, the photocatalytic conversion efficiency of ethyl mercaptan to diethyl disulfide is nearly 100% and it is higher than that of the other Nb-Mo based photocatalysts, such as LiNbMoO6, Fe1/3NbMoO6, Ce1/3NbMoO6, TiO2-HNbMoO6, e-HNbMoO6, CeO2@e-HNbMoO6, and Ag2O@e-HNbMoO6. Under the experimental conditions, the photocatalytic conversion efficiency is greater than the adsorption efficiency over Fe2O3@e-HNbMoO6, and there is no ethyl mercaptan output in the process of adsorption and photocatalytic conversion. Fe2O3@e-HNbMoO6 heterojunction catalyst has practical value and reference significance for purifying methane gas and enhancing photocatalytic conversion of ethyl mercaptan.
相似文献To eradicate the aquatic pollution caused by dyes, trendily the global researchers provide dedication to dye degradation using nanostructured photocatalyst. This research work is dedicated to explore an advanced, facile, bio-compact green fabricated nanostructure for water refinement. In this regard, plant-mediated syntheses of pure CeO2 and Mn-decorated CeO2 nano-powders have been inspected using seed extract of Cassia angustifolia. Investigations through UV-diffuse reflectance spectroscopy explored the significantly tuned band gap of Mn:CeO2. FT-IR spectroscopy shows the existing functional groups of high-potential phenolic compounds, proteins, and amino acids in Cassia angustifolia act as reducing and capping agents involved in the green fabricated nanostructured samples. X-ray diffraction pattern has been exposed to crystalline cubic fluorite morphology in a single phase and it leads to a regulated optimized amount of Mn on CeO2 nanostructure. The FESEM analysis predicts the morphology of CeO2 in spherical and Mn:CeO2 in flower-like structure. The HRTEM analysis has portrayed particle size of CeO2 is 11 nm and tuned Mn:CeO2 nanostructure is 9 nm. The HRTEM images revealed the average particle size in the range 10–12 nm in CeO2 and 8–9 nm in 5 mol% Mn:CeO2 nanoparticles. It showed a decrease in average particle size with an increase in Mn concentration and the reduction in size may be due to the replacement of Ce(IV) with Mn(II) ions. The elemental composition in nanostructure was predicted using energy-dispersive X-ray analysis. The rapid photocatalytic degradation efficiency of malachite green was effectually performed and compared with the kinetics model of Mn:CeO2 and pure CeO2 nanostructures. From the augmented results, tuned Mn:CeO2 was found to act as the finest green fabricated photocatalyst in the amputation of lethal and carcinogenic dye.
相似文献