Pesticides in surface water,sediment, and rainfall of the northeastern Pantanal basin,Brazil

Within the last 25 years an intensive agriculture has developed in the highland regions of Mato Grosso state (Brazil), which involves frequent pesticide use in highly mechanized cash-crop cultures. To provide information on pesticide distribution and dynamics in the northeastern Pantanal basin (located in southern Mato Grosso), we monitored 29 pesticides and 3 metabolites in surface water, sediment, and rainwater of the study area during the main application season. In environmental samples, 19 pesticides and 3 metabolites were detected in measurable quantities, resulting in at least one pesticide detection in 68% of surface water samples (n = 139), 62% of sediment samples (n = 26), and 87% of rainwater samples (n = 91). Surface water samples were most frequently contaminated by endosulfan compounds (alpha-, beta-, -sulfate), ametryn, metolachlor, and metribuzin, although in low (< 0.1 microgram L-1) concentrations. Sediment samples exhibited concentrations up to 4.5 micrograms kg-1 of p,p'-DDT, p,p'-DDE, endosulfan-sulfate, beta-endosulfan, and ametryn. In contrast, rainwater was polluted with substantial amounts of endosulfan, alachlor, metolachlor, trifluralin, monocrotofos, and profenofos (maximum concentrations = 0.3 to 2.3 micrograms L-1) in the highlands. Lowland rainwater samples taken 75 km from the next application area contained 5- to 10-fold lower mean pesticide concentration than in the highlands. Cumulative deposition rates of the pesticide sum within the study period ranged from 423 micrograms m-2 in the highlands to 14 micrograms m-2 in the lowlands. The atmospheric input of pesticides to ecosystems seemed to be of higher relevance in the tropical study area than known from temperate regions.     

Sources of water pollution and evolution of water quality in the Wuwei basin of Shiyang river, Northwest China

Based on surveys and chemical analyses, we performed a case study of the surface water and groundwater quality in the Wuwei basin, in order to understand the sources of water pollution and the evolution of water quality in Shiyang river. Concentrations of major chemical elements in the surface water were related to the distance downstream from the source of the river, with surface water in the upstream reaches of good quality, but the river from Wuwei city to the Hongya reservoir was seriously polluted, with a synthetic pollution index of 25. Groundwater quality was generally good in the piedmont with dominant bicarbonate and calcium ions, but salinity was high and nitrate pollution occurs in the northern part of the basin. Mineralization of the groundwater has changed rapidly during the past 20 years. There are 23 wastewater outlets that discharge a total of 22.4 x 10(6)m(3)y(-1) into the river from Wuwei city, which, combined with a reduction of inflow water, were found to be the major causes of water pollution. Development of fisheries in the Hongya reservoir since 2000 has also contributed to the pollution. The consumption of water must be decreased until it reaches the sustainable level permitted by the available resources in the whole basin, and discharge of wastes must also be drastically reduced.     

Integrated water management for the Rhine river basin, from pollution prevention to ecosystem improvement

The river Rhine has been in humanity's use for many centuries for a variety of activities. However, in our time, considerable changes in the course and the natural conditions of the river and the increasing use of the river for the discharge of wastewater has caused serious floods and major ecological problems. Since 1950, the International Commission for the Protection of the Rhine (ICPR) acts as the coordination point between the states bordering the Rhine for the development of programmes for river protection. The Sandoz disaster in 1986 was a turning point in the approach of the ICPR and the starting point for the present strategy of integrated riverbasin management. Recent developments have indicated the success of the current approach.     

A historical perspective of river basin management in the Pearl River Delta of China

Three innovations in water and soil conservancy technology in the Pearl River Delta of South China, i.e., dike building, land reclamation, and dike-pond systems, were examined from a historical perspective. They were found to best reflect local farmers' efforts to cope with the challenges of various water disasters and to build a harmonious relationship with the changed environment. These technologies were critical to the agricultural success and sustainability over the past 2000 years, and reflected local farmers' wisdom in balancing land use and environmental conservation. Imprudent use of a new agricultural technology could damage the environment, and could disturb the human-environment relationship, as evidenced by the more frequent flooding that followed inappropriate dike building and premature reclamation. It is suggested that as the urbanization and industrialization process in the delta region continues, the kind of thinking that made the water and soil conservancy sustainable needs to be incorporated into the design of similar technologies for water use and river basin management today.     

An online water quality monitoring and management system developed for the Liming River basin in Daqing, China

This paper describes an online water quality monitoring and management system that was developed by combining a chemical oxygen demand sensor with an artificial neural network technology and a virtual instrument technique. The system was used to model the hydrological environment of the Liming River basin in Daqing City, China, in an effort to maintain the water quality in this basin at a level compatible with the status of Daqing City as a scenic resort. Operation of the system during the past 2 years has shown that an optimal allocation of water (including water released from an environmental reservoir to mitigate pollution events) could be achieved for the basin using the information gathered by the system; using mathematic models established for this system, the quantity of water released from the reservoir is adequate to improve the overall water environment. The results demonstrate that the system provides an effective approach to water quality control for environmental protection.     

Phosphorus load to surface water from bank erosion in a Danish lowland river basin

Phosphorus loss from bank erosion was studied in the catchment of River Odense, a lowland Danish river basin, with the aim of testing the hypothesis of whether stream banks act as major diffuse phosphorus (P) sources at catchment scale. Furthermore, the study aimed at analyzing the impact of different factors influencing bank erosion and P loss such as stream order, anthropogenic disturbances, width of uncultivated buffer strips, and the vegetation of buffer strips. A random stratified procedure in geographical information system (GIS) was used to select two replicate stream reaches covering different stream orders, channelized vs. naturally meandering channels, width of uncultivated buffer strips (≤ 2 m and ≥ 10 m), and buffer strips with different vegetation types. Thirty-six 100-m stream reaches with 180 bank plots and a total of 3000 erosion pins were established in autumn 2006, and readings were conducted during a 3-yr period (2006-2009). The results show that neither stream size nor stream disturbance measured as channelization of channel or the width of uncultivated buffer strip had any significant ( < 0.05) influence on bank erosion and P losses during each of the 3 yr studied. In buffer strips with natural trees bank erosion was significantly ( < 0.05) lower than in buffer strips dominated by grass and herbs. Gross and net P input from bank erosion amounted to 13.8 to 16.5 and 2.4 to 6.3 t P, respectively, in the River Odense catchment during the three study years. The net P input from bank erosion equaled 17 to 29% of the annual total P export and 21 to 62% of the annual export of P from diffuse sources from the River Odense catchment. Most of the exported total P was found to be bioavailable (71.7%) based on a P speciation of monthly suspended sediment samples collected at the outlet of the river basin. The results found in this study have a great importance for managers working with P mitigation and modeling at catchment scale.     

Susceptibility indexing method for irrigation water management planning: applications to K. Menderes river basin, Turkey

A susceptibility indexing method was developed based on vulnerability and quality indices. The contamination susceptibility index (SI) at a given location was calculated by taking the product of the vulnerability index (VI) and the quality index (QI): SI = VI × QI. This method incorporates both hydrogeological and hydrochemical data for a comprehensive index mapping. The DRASTIC index methodology was used for the hydrogeological data evaluations. The quality index calculation procedure based on a water quality classification scheme was introduced to evaluate hydrochemical data. The suggested susceptibility indexing method was applied to the Küçük Menderes river basin located in western Turkey. The susceptibility index map shows both hydrogeological and hydrochemical data related to the contamination problem including areas that should be taken into consideration during water management planning. The index map indicates that the most susceptible groundwater is located along the river channel between Kiraz and Tire towns, in the Selçuk area and along the Fertek stream channel to the north of Torbal? town. The results indicate that the incorporation of both hydrogeological and hydrochemical datasets enables more realistic evaluations than those of an individual dataset to estimate the groundwater contamination susceptibility of an aquifer. The numerical procedure applied could be extended further by including other parameters such as retardation, potential contaminant sources, etc. that affect the water quality in a given basin.     

Water resource management in Kabul river basin, eastern Afghanistan

Severe drinking water shortage affects all resident of the Kabul river basin. Two and a half decades of civil war in Afghanistan (it began in late 1978) have resulted in widespread environmental degradation and water resource development throughout the country. The war has already finished and, therefore, water resource management for supplying water is one of the most important tasks for Afghanistan’s government. The Kabul river basin which is the most populated area in the country is located in the eastern part of Afghanistan. This article deals with the water resource properties of the Kabul river basin and also water demand in the important cities of the basin, such as Kabul, the capital and the largest city in the country. Also a few suggestions for providing water for domestic and agriculture purposes in short term, medium time and long term have been discussed.     

Planning for change and sustainability in water development in Lao PDR and the Mekong River basin

With its recent opening to the global market economy, the natural resources of the Lao People's Democratic Republic (Lao PDR, referred to in this paper as Laos) – especially its water resources–have attracted external interest and investment. The overall level of water development is low. While even modest development would help Laos meet some of its urgent needs, past experience in Southeast Asia and other tropical regions suggests that fast-paced water development may damage the natural resource base. This article examines some efforts in water development from Southeast Asia and other regions and their relevance to water policy formulation in Laos. Future social and environmental changes in Laos are inevitable, but the nature and direction of these changes are uncertain. It thus makes sense to design policies that are flexible and can be adjusted to, and even take advantage of, a changing social and environmental context. Smaller-scale, deliberately-paced projects which merge local knowledge and external expertise fulfil the requirements of flexibility and adjustability, and are also appropriate for other important reasons: they do not require massive inputs of funding, and they do not initiate large-scale environmental and socio-economic changes. Current knowledge of the complex ecological and social systems in Laos is only sketchy. A slower-paced development will allow developers the necessary time to learn more about these important aspects.     

Vegetation and carbon sequestration and their relation to water resources in an inland river basin of Northwest China

In the Heihe River Basin in the arid inland area of northwest China, the distribution of water resources in vegetation landscape zones controls the ecosystems. The carbon sequestration capacity of vegetation is analyzed in relation to water resources and vegetation growing conditions. During the last 20 years, the vegetation ecosystems have degenerated in the Heihe River Basin. Simulation using the C-FIX model indicates that, at present, the total amount of NPP of vegetation accounts for about 18.16 TgC, and the average value is 106 gC/m(2)/yr over the whole basin. NPP has generally the highest value in the upperstream mountain area, middlestream artificial oases area, downstream river bank area, alluvial fan and the terminal lake depression where vegetation grows relatively well. The lowest value is found in the vast downstream desert and Gobi area. Protection of vegetation ecosystems and enhancement of carbon sequestration require such inland river basins as the Heihe River Basin to be brought under management in a comprehensive way, taking water as a key, to carry out a rational and efficient allocation and utilization of water resources.     

A spatial analysis of phosphorus in the Mississippi river basin

Phosphorus (P) in rivers in the Mississippi River basin (MRB) contributes to hypoxia in the Gulf of Mexico and impairs local water quality. We analyzed the spatial pattern of P in the MRB to determine the counties with the greatest January to June P riverine yields and the most critical factors related to this P loss. Using a database of P inputs and landscape characteristics from 1997 through 2006 for each county in the MRB, we created regression models relating riverine total P (TP), dissolved reactive P (DRP), and particulate P (PP) yields for watersheds within the MRB to these factors. Riverine yields of P were estimated from the average concentration of each form of P during January to June for the 10-yr period, multiplied by the average daily flow, and then summed for the 6-mo period. The fraction of land planted in crops, human consumption of P, and precipitation were found to best predict TP yields with a spatial error regression model ( = 0.48, = 101). Dissolved reactive P yields were predicted by fertilizer P inputs, human consumption of P, and precipitation in a multiple regression model ( = 0.42, = 73), whereas PP yields were explained by crop fraction, human consumption of P, and soil bulk density in a spatial error regression model ( = 0.49, = 61). Overall, the Upper Midwest's Cornbelt region and lower Mississippi basin had the counties with the greatest P yields. These results help to point out specific areas where agricultural conservation practices that reduce losses to streams and rivers and point source P removal might limit the intensity or spatial occurrence of Gulf of Mexico hypoxia and improve local water quality.     

Recent experiences with river basin development in the tropics and subtropics

This paper utilizes experiences gained since the first United Nations studies were prepared on river basin planning and development in 1958. The author's experiences, mainly in the tropical and subtropical areas of Africa and Asia, set the stage for a brief consideration of the role of institutions in achieving a process of integrated river basin development. In emphasizing these experiences, this paper has three purposes. First, the author assesses the influence and adequacy of the vision expressed in the earlier United Nations reports. Second, he examines the experience with attempts to implement river basin development, including resettlement problems. Third, he suggests ways in which lessons learned can be applied to future development. The case studies utilized in this paper draw more on the author's experience than on the literature. While the focus is on transnational river basin development, experiences within states are also included when they provide relevant insights.     

Mercury distribution in medium-size rivers and reservoirs of the Sao Paulo state (southeast Brazil)

The aim of this work was to investigate mercury (Hg) levels in six meso-scale watersheds (Upper Paranapanema, Aguapeí, Peixe, S?o José dos Dourados, Mogi-Gua?u, and Piracicaba) of the S?o Paulo state to contribute to a more comprehensive understanding of Hg contamination in Brazil. Water, sediment, bivalves, and fish samples were collected during 2001 at 11 sites. Fish were also collected in the Jurumirim and Salto Grande Reservoirs which are 39 and 52 yr old since impoundment, respectively. Results showed that Hg concentrations were low in almost all samples, except fish from Jurumirim Reservoir (total mercury [T-Hg] = 1.14 +/- 0.55 mg kg(-1) wet wt.). In spite of industrialization and high population, the results showed that there was no important source of Hg contamination in the investigated areas. The higher concentrations found in fish from Jurumirim seem to be the result of processes that favor Hg mobilization and methylation as a consequence of the impoundment of the reservoir area. The same levels were not observed in the Salto Grande Reservoir, probably because these are no longer significant due to the long time since the impoundment. To understand the dynamics of methylmercury (MeHg) production and its accumulation in fish, further studies are needed in the Jurumirim Reservoir. The results show that even at low T-Hg concentrations in sediment and water, concentrations in fish can reach values that pose concerns for consumption. This emphasizes the importance of designing an optimized biomonitoring program that can provide warning of biogeochemical conditions that promote formation of MeHg.     

Nutrient chemistry of the Densu River in Ghana

The impact of anthropogenic activities on the fluctuation of nutrients along the Densu River and its tributaries was studied. High concentrations of nutrients were observed in the study area but the river was found to be circumneutral and fresh with pH ranging between 6.54 and 7.84. The levels of NH₄ ⁺–N ranged between 0.21 and 2.1 mg L⁻¹ with mean concentration of 1.19 ± 0.02 mg L⁻¹ while that of nitrate is between 0.13 and 5.21 mg L⁻¹ with a mean concentration of 2.07 ± 0.01 mg L⁻¹. The levels of PO₄ ³⁻–P fluctuated within the range 0.54 and 1.04 mg L⁻¹ with a mean of 0.84 ± 0.01 mg L⁻¹. The Densu River Basin was also found to be with organic matter with depleted dissolved oxygen. The river recorded high BOD values ranging from 6.91 to 18.8 mg L⁻¹. Concentration of nutrients and organic pollutants increased as a consequence of anthropogenic inputs particularly from domestic, agricultural and municipal sources. The highly impaired sites were those located close to the urbanized, agricultural and high-density residential areas. The relatively high concentration of nitrate and phosphate in the river indicated that it was quite eutrophic.     

Nitrogen contamination in the Yellow River basin of China

Nitrogen contamination is one of the most serious problems in the Yellow River of China. This study was conducted to analyze monitoring data on nitrogen contamination for the Yellow River basin in the years 1980, 1990, 1997, and 1999. Several significant results have arisen from the study. First, in conjunction with an increase in economic indexes from the Yellow River's upper basin to its lower basin, the nitrogen concentration in the tributaries also showed an increasing trend from the upper to the lower basin, which, in turn, led to an increase in the nitrogen concentration of the mainstream from the upper to the lower reaches. Second, nitrogen in the river water in the mainstream and the tributaries of the Yellow River was attributed mainly to point sources. In spite of the fact that the ratio of point to nonpoint sources decreased from 2.7 in 1990 to 1.8 in 1997 for total inorganic nitrogen in river water at the Tongguan Station in the lower basin, point sources increased more than nonpoint sources. Third, the ammonium nitrogen and total inorganic nitrogen content of the river water increased significantly in the mainstream and the tributaries during the 1980-1999 period, a change caused by an increase in wastewater discharge and nitrogenous fertilizer application in the Yellow River catchment.     

The value of cooperation in resolving international river basin disputes

This paper reviews the phenomenon of international river basins, and concludes that the sharing of river basins between and among countries is the rule rather than the exception for the major river systems of the world. The growth of the nation state with rivers as agreed-upon boundaries, as cease-fire lines and as natural defensive lines has led to the carving up of most river basins around the world. More than 200 river basins, accounting for more than 50% of the land area of the Earth, are shared by two or more countries. When population densities were low, there was plenty of water for all and major conflicts were avoided. With the rapid population and economic growth experienced in the past few decades, conflicts over use of water are becoming more important. It is expected that in the near future such conflicts will become much more severe. The paper reviews the literature on attempts to analyse river basin conflicts and negotiate solutions. Some rudimentary game models are examined, and some tentative conclusions, based upon various game theory concepts of stability, are applied to the Ganges-Brahmaputra basin. The paper ends with suggestions on how to plan Pareto-Admissible outcomes for international basins.     

Saltcedar control and water salvage on the Pecos river, Texas, 1999-2003

A large scale ecosystem restoration program was initiated in 1997 on the Pecos River in Western Texas. Saltcedar (Tamarix spp.), a non-native invasive tree, had created a near monoculture along the banks of the river by replacing most native vegetation. Local irrigation districts, private landowners, federal and state agencies, and private industry worked together to formulate and implement a restoration plan, with a goal of reducing the effects of saltcedar and restoring the native ecosystem of the river. An initial management phase utilizing state-of-the-art aerial application of herbicide began in 1999 and continued through 2003. Initial mortality of saltcedar averaged about 85-90%. Monitoring efforts were initiated at the onset of the project to include evaluating the effects of saltcedar control on salinity of the river water, efficiency of water delivery down the river as an irrigation water source, and estimates of water salvage. To date, no effect on salinity can be measured and irrigation delivery was suspended in 2002-2003 due to drought conditions. Water salvage estimates show a significant reduction in system water loss after saltcedar treatment. However, a flow increase in the river is not yet evident. Monitoring efforts will continue in subsequent years.     

The planning and management of African river and lake basin development and conservation

The success of river and lake basin development and management is rooted in the knowledge of its resources, both physical and human. Within the framework of an integrated basin plan, each economic sector depends on the adequacy of such data for its individual development. The management and conservation of the basin itself in turn depends on knowing the requirements of those sectors and their probable impact on each other and on the status of the basin's resources, its ecology and environment. The development of African river basin resources is subject to various constraints, some for physical and climatic reasons, others tied to socio-cultural characteristics and the priorities of national economies. These are reflected in financial, manpower and institutional limitations, problems of finding technologies suited to specific local conditions and concern for human health. The scale and complexity of river basin development make it difficult to predict precise outcomes of planned proposals, but a progressive approach which links long-term activities with achievable, shorter term production projects offers prospects for ultimate success.     

The challenges and implications of collaborative management on a river basin scale

Collaboration has rapidly become the dominant paradigm in natural resource management, but there are many dilemmas about how it is applied effectively. In southwest Oregon, agencies, watershed councils and other stakeholders are developing a river basin approach to assess ecological health and set priorities for restoration. An analysis of this process reveals considerable progress in this innovative effort and it reveals several implications for collaboration at a regional scale, including: tensions between technical complexity and open participation, difficulties with information exchange for joint management, the relationships between technical issues and policy issues, the role of regional policy in supporting collaborative efforts, and the importance of institutional arrangements.     

Studies on the primary production in a river basin in eastern India

Measurement of the primary production has been estimated over a study area of approximately 25 km² of the North Koel River, in the Palamau District, in Bihar, India. A caustic chemical factory which is discharging effluent into the river is situated at Rehala, Palamau, on the bank of the North Koel. Huge amounts of mercury are released into the river. The physical and chemical characters of the caustic chemicals in the effluent have a significant influence on the primary production on the North Koel river. The gross production is compared with other fresh water habitats (riverine and other) in India. It is observed that the gross production value is the lowest (at 1.14 gc/m²/day) of any recorded riverine ecosystem in India.