利用废泡沫塑料制备防水涂料

介绍了利用废聚苯乙烯泡沫塑料制备水乳型防水涂料的工艺流程、配方及其性能测试方法。     

废电视机显像管的再生利用

综述了显像管的结构、材料组成、再生利用途径以及为再利用而开发的各种废显像管的分离技术,重点介绍了采用金属丝(带)加热冷却切割分离废显像管屏锥玻璃的工艺及试制的废显像管切割机.     

石化工业废硫酸的净化处理及回收利用

本文介绍了国外近年来对石化工业生产中产生的废硫酸采用稀释和中和、燃烧、水解与再浓缩、热解、萃取、氧化、盐析及冷冻结晶等方法净化处理,并加以回收,以及利用废硫酸直接制化工产品的新动向。     

利用废发泡聚苯乙烯生产化学建材

由于聚苯乙烯发泡后质量轻 ( 2 5kg/m3 ) ,低吸水性、耐酸碱、隔音性好及防震性好可装饰性强 ,易成型等诸多优点 ,所以在建材、家用电器等方面有着广泛的用途 ,但也造成了较为严重的白色污染 ,其回收利用率几乎不到 2 0 %。废弃的发泡聚苯乙烯废物大量散落对环境造成严重的污染与危害 ,即便是深埋 ,因其不易老化 ,难以降解 ,还会污染地下水源 ,破坏土壤结构 ,使粮食作物减产 30 %。如简单焚烧处理 ,则又会严重污染空气及大气环境。　　针对以上问题 ,人们纷纷探索及实践将发泡聚苯乙烯废料用于化学建材工业 ,并取得了令人满意的结果 ,创造了…     

废聚苯乙烯泡沫塑料的回收利用

本文以从事工程设计和开发新产品的研究试验为基础,并参考有关文献资料,对废聚苯乙烯泡沫塑料回收利用的四种可行性工艺进行了论述。文中还对推广实施这些工艺的生产流程,城乡环卫条件的改善,化工原料资源渠道的开拓,及国外回收利用废聚苯乙烯泡沫塑料的概况均作了介绍。     

废聚丙烯塑料的回收利用技术

介绍了废聚丙烯塑料能源化的方法(焚烧、无氧及有氧条件下的热分解)与资源化回收利用技术(简单再利用、改性再生利用),并对国内外相关方面的研究和应用情况进行了报道。     

浅谈废有色金属再生利用

有色金属工业对于能源及资源的消耗量极为巨大,并在生产过程中产生大量废气、废水和废渣等,如果不能够有效控制污染并加以回收循环利用,不仅会造成资源浪费,还会对环境带来严重的污染。因此,有色金属工业,必须要走循环经济的可持续发展道路。     

利用废硫酸生产过磷酸钙的工艺、设备及经济效益

许多化工企业以及医药、轻工、冶金企业在生产过程中排出Ｈ２ＳＯ４质量分数大都低于８５％的废硫酸,其中绝大部分可以利用。将各种浓度的废硫酸混合（以下简称混合废硫酸）,用于生产过磷酸钙,可大幅度降低过磷酸钙的生产成本,给磷肥厂带来巨大的经济效益,也可提高废...     

发达国家废玻璃回收利用经验及借鉴

介绍了发达国家处理和再利用废玻璃的经验,提出我国应借鉴发达国家经验,从科研、政策、法律等方面加强废玻璃的再利用工作。     

利用废锂渣制备碳酸锂

介绍了用生产丁基过程中的渣制备碳酸锂的工艺过程及最佳工艺条件,在碳酸钠加入量为理论需要量的110％、pH为9－10、陈化时间为12h、干燥温度为450℃、干燥时间为2h的条件下,碳酸锂的总收率为70.3%左右,产品的纯度为98％左右,产品质量达到GB11075－89的三级标准。     

Solid Waste Recycling And Reuse In Bangkok

Materials recovered from solid waste in Bangkok are mainly glass bottles, paper and paper products, plastic products and metals. Materials are separated at three different stages of the collection process: at the source, prior to collection; by the crews of the collection vehicle; and by the scavengers at the dump site. The total daily tonnage of recyclable garbage collected at the source by the waste pickers is estimated at 286 tonnes, about 5% of the garbage collected by the city. There are small scale recycling shops (SSR) located around the main disposal sites where collected materials are sold by the collection crews and the scavengers. The quantity of materials delivered to the SSR shops by the collection crew vary between 1-6 tonnes per day. The amount of materials recovered by the scavengers (at the dump site) varies between 50-150 kg person^-1 day^-1. Therefore around 7.5% of the solid waste is recycled. In Bangkok both formal and informal sectors manufacture paper pulp, cardboard boxes and magazines from the recyclable paper. Paper products which account for 55% of the total waste stream are considered as the largest "product group" in the municipal solid waste. Recyclable glass (1-3% of the total waste stream) or cullet is used to manufacture plain glasses or cups. Plastics constitute about 10-15% of the waste stream. The benefit/cost ratios of production of most of these industries were reported to be higher than 1.5. In order to enhance recycling, legislative measures need to be introduced and enforced. In Thailand, there is, however, no law concerning recycling. There is no incentive for the consumer to separate solid waste for recycling, as the prices of waste in Bangkok are low and inconsistent. Therefore the pricing system should be more organized for recycling to be more effective.     

Potential To Use Waste Tires As Supplemental Fuel In Pulp And Paper Mill Boilers,Cement Kilns And In Road Pavement

The objective of this paper is to evaluate the recycling potential of waste tires as an energy source and for use in road pavement. North Carolina, U.S.A., is used as a case study. Scrap tires may be burned for supplemental fuel in pulp and paper mill boilers and cement kilns. Five pulp and paper mill boilers in North Carolina could consume over 90% of the 6 million tires generated annually in the state. Cement kilns located within 400 km of North Carolina population centers could consume about 6.6 million tires annually. Based on the quantity of pavement laid in North Carolina, nonproprietary and proprietary versions of asphalt rubber concrete have the potential to consume 1.8 and 7.2 million tires, respectively. Rubber modified asphalt concrete has the potential to consume up to 16.5 million tires. However, technological and economic limitations suggest that large scale implementation is unlikely for the short term. Environmental considerations pertaining to each alternative are discussed. Estimates of this nature are critical as planning regions formulate solid waste management plans which include recycling.     

A Comparative Overview Of Recycling In London And Hamburg

The level of recycling for household waste is significantly higher in Hamburg than in London, yet the extent of materials recovery in both cities is well below technically achievable levels. This paper shows that the higher level of recycling in Hamburg can be accounted for by three main factors: a higher density of recycling facilities combined with the use of more sophisticated collection systems such as a dual-bin service for putrescible wastes; a unified administrative structure for waste management under direct control of an elected regional government; and finally, a system of proportional representation in local government allowing environmentalist political demands to be directly translated into public policy. Despite these differences however, both cities face difficulties with the expansion of recycling derived from the weakness of the secondary materials market, the lack of legislative control over the size and composition of the waste stream, the fiscal constraints on local government and the expense of comprehensive recycling programmes in comparison with alternative forms of waste disposal. This paper concludes that the high cost of recycling presents a fundamental political dilemma for sustainable waste management policy in developed economies.     

Cardanol Polymerization Under Acid Conditions By Addition And Condensation Reactions

Cashew nut shell liquid (CNSL) is a byproduct of the cashew nut industry and consists predominantly of phenolic compounds that have an side chain with different degrees of unsaturation. Cardanol, one of these components, is biodegradable and widely available. Studies have revealed several polymerization reactions involving cardanol. However, the mechanisms and detailed structures of polymerization reactions have not been explored, although the final product shows different applications. In this work, we evaluated the mechanism and the products structure of the reaction of cardanol with: (i) boron trifluoride diethyl etherate (BF₃O(CH₂CH₃)₂), and (ii) formaldehyde. The characterizations were performed by FTIR, ¹H NMR, SEC and TGA. The results show that the reaction of cardanol with aldehyde produces the expected like-comb structure with a long hydrocarbon pendent chain. Nevertheless, the reaction of cardanol with BF₃O(CH₂CH₃)₂ can exhibits a more complex structure since it was identified aromatic ring linkages, besides the expected polymerization through C=C.     

Effective Waste Management: Understanding And Dealing With Public Concerns

Effective waste management is dependent upon achieving informed consensus amongst interested parties. Public concerns and opposition present a challenge to this consensus which must be tackled. This paper reviews our understanding of the basis of public concerns about waste management activities and suggests some means for dealing with these. The paper identifies a need for better understanding of the complexity of concerns, which are based not only upon risk perceptions but also a lack of trust and credibility in waste managers, decision-makers, and the decision processes and control mechanisms for waste facility siting and operation. Suggestions for dealing with these concerns are discussed relating to risk communication, improving decision processes, the control and management of waste activities, and improvement in "expert" understanding of the risks.     

A Forecast Model Of Refuse Tonnage With Recapture And Uncertainty Bounds

A spreadsheet model for forecasting solid waste tonnages is described. The model uses generation coefficients from the technical literature associated with individual material components (paper, glass, metals, plastics and rubber, organic materials, construction waste, inerts and other) to express the amount of waste produced per capita and per employee in the labor force. Estimates of quantities being generated by two major groups, namely domestic and industrial/commercial/institutional sources are reflected in the model's output. Using this disaggregated format, the model estimates total waste, recaptured waste (as a result of policy initiatives), and net refuse. Confidence intervals are developed using a regression model related to the business cycle. Two worked examples are given for data obtained in Canada.     

Bioremediation Of Petroleum- And Creosote-contaminated Soils: A Review Of Constraints

The evaluation and selection of technologies for the effective remediation of hydrocarbon-contaminated sites requires careful consideration of the waste/site/soil characteristics that determine their ultimate success. The presence of weathered hydrocarbon wastes and sub-optimal environmental conditions places technical restraints on the bioremediation of polynuclear aromatic hydrocarbon-contaminated soils. A brief overview of applicable bioremediation technologies is followed by an indepth critical evaluation of limiting factors that can influence the efficacy of biotreatment options, including waste composition, temperature, substrate, bioavailability, accompanying toxicants and soil structure.     

The Origin And Fate Of Volatile Trace Components In Municipal Solid Waste Landfills

The content of readily volatile halogenated hydrocarbons (chlorinated and chlorinated, fluorinated hydrocarbons (VCCs/CFCs)) and the BTEX aromatic substances (benzene, toluene, ethylbenzene and xylene) in municipal solid waste (MSW) was determined by two different methods. Moreover, the emission potential of these substances via the gas and leachate phase was investigated during the different biological degradation phases in the landfill. Trichlorofluoromethane (R11), dichlorodifluoromethane (R12) and dichloromethane (R30) were the dominating halogenated trace substances detected in the MSW. In the acid phase, with some VCCs/CFCs the emittance may take place up to 30% via the water phase. Hexane, benzene, and toluene could be detected in all tests. Toluene often occurred in relatively high concentrations in MSW. It could be shown that R11 degraded into dichlorofluoromethane (R21).     

Short-term/Long-term Solutions In Waste Management: Economics And The Transition Process

Cleaner technology and recycling, as the preferred solution to waste management, is increasing in implementation but not at the rate expected given the successes and paybacks associated with those strategies. The reasons for the delay in implementation lie in the conflict between short-term and long-term solutions. The factors that contribute to hindrance or facilitation of the transition are found in: a) the distinction between the short-term and the long-term at a technical level; b) the distinction between the short-term and the long-term at a political level; c) the investment decision at the firm level; and d) related investments in infrastructure, organization, and institutions. This article identifies which constraints will disappear with time, which constraints are institutional and will require deliberate modification, and which constraints are permanent and must be considered part of the costs of the long-term solution. The goal is not to argue against short-term solutions, but for the need to acknowledge unavoidable costs associated with the transition from the short-term to the long-term solution.