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研究pH值、温度、反应物比率对生成三元接枝共聚物的影响,三元接枝共聚物接枝率与接枝效率的计算,以及三元接枝共聚物对铜离子的吸附效果。实验与计算结果表明:生成三元接枝共聚物的最佳反应条件为引发剂(NH4)2S2O8用量6 mmol/L,反应温度50℃,壳聚糖(CTS)∶丙烯酰胺(AM)∶丙烯酸(AA)=1∶2.7∶0.3,pH值=7,反应时间5 h;在相同条件下,三元接枝共聚物对铜离子去除效果比壳聚糖有了明显的改善,对铜离子去除率最高达到90.06%,比壳聚糖对铜离子的去除率高49.72%。 相似文献
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水中微量有机物氯化物脱除复合膜的研制 总被引:1,自引:0,他引:1
采用溶液聚合法合成了丙烯酸及丙烯酸酯共聚物,并利用该共聚物可与环氧树脂交联的作用制备出交联聚丙烯酸及基酯的共聚物,并在聚砚底膜上涂膜形成可优先透过氯化有机物(THMs)的复合膜,以1,1,2-三氯乙烷,三氯乙烯等稀水溶液对丙烯酸酯系列复合膜进行了系统测试和研究,分别考察了不同制膜液、交联剂、操作压力、操作温度、进料液浓度、不同分离体系等条件对膜性能的影响,并优选出交联AB-AA-MAA/PS复合膜,表明效果良好,有很好的研究和发展前景。 相似文献
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以汞污泥为材料,分别用聚环氧琥珀酸(PESA)和丙烯酸-马来酸酐共聚物(MA/AA)作为萃取剂,研究了PESA和MA/AA在不同pH、萃取剂浓度、搅拌时间和土液比下对汞(Hg)的萃取效果。实验结果表明,PESA对污泥中Hg的萃取效果优于MA/AA。在萃取体系pH分别为6和9,土液比分别为1∶250和1∶300,萃取剂浓度均为30 mg/mL、搅拌时间均为60 min时,PESA和MA/AA对泥土中汞的萃取率分别为63%和28%。用PESA萃取后的污泥达到《危险废物鉴别标准·浸出毒性鉴别》堆放标准。PESA中不含有氮、磷等元素,不会引起水体的富营养化及环境污染,是一种环境友好型水溶性聚合物。 相似文献
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聚乙烯和聚乳酸微塑料对大豆生长和生理生化及代谢的影响 总被引:1,自引:0,他引:1
为揭示生物可降解性不同的微塑料对农作物的毒性效应,选择聚乳酸(polylactic acid可生物降解)和聚乙烯(polyethylene难生物降解)微塑料(microplastics)为供试材料,以大豆为供试植物,深入探究了不同暴露水平(0.1%,1%,W/W)下两种不同的微塑料对大豆(Glycine max)生长、光合作用、抗氧化性、营养品质以及代谢方面的影响.结果表明,聚乙烯微塑料(PEMPs)对大豆根部鲜重有促进作用,而0.1%聚乳酸微塑料(PLAMPs)则抑制根部长度.大豆的叶绿素含量在0.1% PEMPs作用下能够显著提高.PLAMPs则能够导致大豆过氧化氢酶(CAT)活性显著下降,而过氧化氢(H2O2)含量在0.1% PEMPs和1% PLAMPs下显著升高.此外,微塑料的暴露能够改变大豆根部中锰、铁以及铜的含量,其中0.1% PEMPs的效应最为显著.大豆叶片中的氨基酸代谢在PEMPs的作用下上调,而0.1% PLAMPs则引起有机酸以及糖类代谢下调.综上,微塑料的植物毒性效应与其生物可降解性及浓度密切相关,低浓度可生物降解微塑料的效应最强.这些发现有望为微塑料的植物毒理研究提供新的方向. 相似文献
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采用微波辐射技术,通过接枝共聚反应制备了阿拉伯胶(GA)-g-2-丙烯酰胺-2-甲基丙磺酸(AMPS)/丙烯酸(AA)/海泡石黏土(ST)(GA-g-PAMPS/AA/ST)复合水凝胶,利用FTIR、XRD、SEM对复合水凝胶进行了表征,研究了水凝胶对水溶液中亚甲基蓝(MB)染料的吸附性能.结果显示:GA、ST和AA与AMPS发生了接枝共聚反应,形成具有均匀三维网络结构的复合水凝胶.0.025g水凝胶可以使体积为50mL、pH值为6.4、浓度为600mg/L的MB溶液的吸附量和吸附率分别达1146mg/g和95.5%,水凝胶具有较好的重复利用性能.Freundlich等温模型和准二级动力学模型能更好地描述吸附过程.热力学研究表明水凝胶对亚甲基蓝吸附是自发、吸热和不可逆的过程.该水凝胶可用作阳离子染料和阳离子型污染物的潜在候选生物质吸附剂. 相似文献
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采用微波辐射技术,通过接枝共聚反应制备了阿拉伯胶(GA)-g-2-丙烯酰胺-2-甲基丙磺酸(AMPS)/丙烯酸(AA)/海泡石黏土(ST)(GA-g-PAMPS/AA/ST)复合水凝胶,利用FTIR、XRD、SEM对复合水凝胶进行了表征,研究了水凝胶对水溶液中亚甲基蓝(MB)染料的吸附性能.结果显示:GA、ST和AA与AMPS发生了接枝共聚反应,形成具有均匀三维网络结构的复合水凝胶.0.025g水凝胶可以使体积为50mL、pH值为6.4、浓度为600mg/L的MB溶液的吸附量和吸附率分别达1146mg/g和95.5%,水凝胶具有较好的重复利用性能.Freundlich等温模型和准二级动力学模型能更好地描述吸附过程.热力学研究表明水凝胶对亚甲基蓝吸附是自发、吸热和不可逆的过程.该水凝胶可用作阳离子染料和阳离子型污染物的潜在候选生物质吸附剂. 相似文献
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Yanyang Liu Haijian Ou Shangqing Li Qingliang You Huixian Liu Guiying Liao Dongsheng Wang 《环境科学学报(英文版)》2019,31(4):215-229
A novel polyimide-inlaid amine-rich porous organic block copolymer (PI-b-ARPOP) was prepared via one-step polymerization by using different molar ratios of melamine (MA)/terephthalaldehyde (TA)/pyromellitic dianhydride (PMDA), at molar ratios of 4/3/1, 4/2/2 and 4/1/3. The copolymer contained both aminal groups belonging to ARPOP and imide groups belonging to PI, and the bonding styles of the monomers and growth orientations of the polymeric chains were diversiform, forming an excellent porous structure. Notably, MA/TA/PMDA (4/2/2) had a surface area and pore volume of 487.27?m2/g and 1.169?cm3/g, respectively. The adsorption performance of the materials towards 2,4-dichlorophenol (2,4-DCP) in ultra-pure water was systematically studied. The pH value of 7 was optimal in aqueous solution. Na+ and Cl? ions did not negatively affect the adsorption process, while humic acid (HA) slightly decreased the capacity. The equilibrium time was 40 sec, and the maximum adsorption capacity reached 282.49?mg/g at 298?K. The removal process was endothermic and spontaneous, and the copolymer could maintain its porous structure and consistent performance after regeneration by treatment with alkali. Moreover, to further assess the practical applicability of the material, the adsorption performance towards 2,4-DCP in river water was also investigated. This paper demonstrated that the PI-b-ARPOP can be an efficient and practical adsorbent to remove chlorophenols from aqueous solution. 相似文献
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几种聚电解质的合成及絮凝性能研究 总被引:3,自引:0,他引:3
合成了5种水溶性聚电解质:①丙烯酰胺-二甲基二烯丙基氯化铵共聚物(AM-DM);②丙烯酰胺-三甲基烯丙基氯化铵共聚物(AM-TM);③水解聚丙烯酰胺(HPAM);④阳离子化聚丙烯酰胺(CPAM)和⑤丙烯酰胺-二甲基二烯丙基氯化铵-丙烯酸(AM-DM-AC)共聚物。对它们的结构进行了红外表征,并就絮凝能力进行了研究。结果表明:5种聚合物均具有絮凝能力且出现两个聚沉点,絮凝能力与聚合物的链结构有关。 相似文献
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利用氨基酸双子表面活性剂N,N'-双月桂酰基乙二胺二丙酸钠(DLMC)及其复配体系来提高四氯乙烯(PCE)在地下水中的溶解性,强化去除效果.测定了DLMC的初级生物降解性并将其与短链醇(异丙醇IPA,乙醇)和传统表面活性剂十二烷基硫酸钠(SDS),辛基苯基聚氧乙烯醚(TX-100)和聚氧乙烯脱水山梨醇单油酸酯(Tween80)复配.结果表明,DLMC的生物降解度超过99%,具备良好的生物降解性;筛选出DLMC-IPA (1:4)和DLMC-Tween80(1:1)两个PCE污染柱冲洗剂配方,40g/L作用浓度下其增溶浓度分别为18329,16906mg/L;DLMC-Tween80(1:1)对PCE污染柱的冲洗效果最好,冲洗效率为9.87(g PCE/L冲洗液),较DLMC单体系提升16%. 相似文献
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Humic acid superabsorbent polymer (P(AA/AM-HA)) and superabsorbent polymer (P(AA/AM)) were synthesized by aqueous solution polymerization method using acrylic acid (AA), acrylamide (AM) and humic acid (HA) as raw material. The effects of N,N'-methylenebisacrylamide (MBA) crosslinking agent, potassium peroxydisulfate (KPS) initiator, reaction temperature, HA content, ratio of AA to AM, concentration of monomer and neutralization of AA on water absorption were investigated. Absorption and desorption ratios of nitrogen fertilizer and phosphate fertilizer were also investigated by determination of absorption and desorption ratio of NH4+, PO43? on P(AA/AM-HA) and P(AA/AM). The P(AA/AM-HA) and P(AA/AM) were characterized by Fourier translation infrared spectroscopy, biological photomicroscope and scanning electron microscopy (SEM). The optimal conditions obtained were as follows: the weight ratio of MBA to AA and AM was 0.003; the weight ratio of KPS to AA and AM was 0.008; the weight ratio of HA to AA was 0.1; the mole ratio of AM to AA is 0.1; the mole ratio of NaOH to AA is 0.9; the reaction temperature was 60°C. P(AA/AM-HA) synthesized under optimal conditions, has a good saline tolerance, its water absorbency in distilled water and 0.9 wt.% saline solution is 1180 g/g and 110 g/g, respectively. P(AA/AM-HA) achieves half saturation in 6.5 min. P(AA/AM-HA) is superior to P(AA/AM) on absorption of NH4+, PO43?. The SEM micrograph of P(AA/AM-HA) shows a fine alveolate structure. The biological optical microscope micrograph of P(AA/AM-HA) shows a network structure. Graft polymerization between P(AA/AM) and HA was demonstrated by infrared spectrum. The P(AA/AM-HA) superabsorbent has better absorbing ability of water and fertilizer, electrolytic tolerance and fewer cost than P(AA/AM) superabsorbent. 相似文献
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为了阐明生活垃圾多组分的混合对其厌氧降解产气性能的影响,通过在中温(37±1)℃下对餐厨类、纸类和园林类垃圾组分进行单独和联合厌氧降解产甲烷实验,研究接种物来源对单组分和多组分物料厌氧降解产甲烷性能的影响,应用修正的Gompertz模型拟合和分析物料产甲烷过程动力学特征,并借鉴和发展评价混合物料联合厌氧降解性能的量化指标方法.试验与模型拟合结果均表明:接种物来源对各组分及其组合的厌氧生物可降解程度无显著影响,但对其降解速率存在明显影响.此外,尽管物料的混合对试验初期物料降解产甲烷速率存在促进作用,但仅有3组分混合试验组在最终累计甲烷产率方面表现出显著的协同促进,在2种接种物条件下,相比于3组分单独降解的甲烷产率分别增长了16%和14%. 相似文献