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考察了多种因素对高压脉冲电晕放电法降解水中苯酚效果的影响。调节成形电容、提高脉冲电压峰值和放电频率、延长放电时间、降低废水的电导率等均可大大提高降解效果。100mg/L的苯酚废水溶液成形电容为320pF,脉冲电压为29kV,脉冲频率为50Hz,电极间距为30mm,放电处理80min,最高降解率可达48.5%左右。 相似文献
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液相脉冲高压放电催化降解二甲基亚砜的研究 总被引:1,自引:0,他引:1
研究了液相脉冲高压放电Fenton催化对二甲基亚砜(dimethyl sulfoxide,DMSO)的降解.自制了脉冲上升前沿400 ns、放电重复率96.2 Hz、峰值电压20 kV的脉冲高压系统,它驱动液相高压放电发生.对脉冲高压电极侧壁做了绝缘以考察新型电极对单脉冲功率的影响.溶液电导率对液相高压放电H2O2产率和DMSO降解的影响及Fe(Ⅱ)和O2流量对液相高压放电DMSO降解的影响进行了考察,对液相高压放电Fenton催化降解DMSO的产物浓度、产物选择性随高压放电时间的变化也进行了研究.结果表明,新型电极的单脉冲功率随电导率增加有一极限值;溶液电导率和O2流量对DMSO降解起阻碍作用;Fe(Ⅱ)对DMSO降解起Fenton催化作用;液相高压放电Fenton催化降解DMSO的降解率在高压放电45min时为80%,可生化性至少提高32%~48%,最大能量效率按G37%计为0.008 7 mol/(kW.h).并对DMSO降解机制做了探讨.本研究显示了液相等离子体联用催化剂处理有机污染物的良好效果. 相似文献
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将双极性脉冲高压和工频交流高压分别引入无声放电反应器,对混合气态污染物间二甲苯/苯进行了降解实验.结果表明,双极性脉冲高压的引入对间二甲苯/苯的降解非常有效,间二甲苯与苯的去除率分别为100%、75.2%.气体成分不同降解特性不同,间二甲苯比苯容易降解.与单一组分相比,混合气体中苯受间二甲苯影响较大,最大降解率由单一组分的85.4%降到75.2%;而间二甲苯受苯的影响不大,降解特性基本不变.双极性脉冲高压供电中的脉冲形成电容对放电能量的注入和降解特性产生影响,当脉冲形成电容为2nF 时与反应器匹配较为理想. 相似文献
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脉冲电晕放电降解CH2Cl2的初步研究 总被引:13,自引:0,他引:13
对高压脉冲电晕放电降解CH2Cl2进行初步研究,比较了正负脉冲电晕降解的活性,正脉冲电晕优于负脉冲电晕。探讨了脉冲形成电容Cp之值及反应器的电晕线材料对降解反应活性的影响。为进一步提高室温下CH2Cl2的降解,在反应器中加入BaTiO3为催化剂,在高压脉冲电场下,BaTiO3受激产生局部电晕,增强了电晕放电流性,提高了反应活性,CH2Cl2的转化率达90%以上。 相似文献
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高压电晕放电对五氯酚的降解研究 总被引:1,自引:1,他引:0
研究了放电电压、溶液pH等因素对高压电晕放电降解PCP效果的影响,并对高压电晕放电处理PCP的动力学进行了初步探讨,同时对高压电晕放电降解PCP的COD和TOC的变化进行了分析。结果表明:放电电压和溶液pH值对PCP降解性能影响很大,放电电压和溶液pH值越高,PCP的降解速度越快。当溶液pH值为11.2、PCP初始质量浓度40 mg/L、电晕放电电压为25 kV时,经30 min电晕放电,PCP的降解率达90%以上,电晕放电降解PCP的反应符合一级反应动力学。在氧化过程中PCP可能转化为苯醌等中间产物,TOC几乎无变化,PCP分解成的小分子有机物使COD升高,可生化性提高。 相似文献
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脉冲电晕放电降解CFC-113和CCl4 总被引:13,自引:0,他引:13
催化降解CFC-133和CCl4难度较大。采用脉冲电晕与吸附相结合,在电晕反应器中加入吸附剂(如γ-Al2O3),显著提高了降解效果。实验结果揭示吸附剂的比表面与孔径大小显著影响CFC-113和CCl4的降解反应活性以及副产物臭氧浓度。本研究开发出一种Al2O3-Ⅱ吸附剂,它的比表面为94.4m^2/g,孔径〈0.5μm,当它与高压脉冲电晕放电相结合时,一方面提高了降解率,另一方面抑制了臭氧生成, 相似文献
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XU Fei LUO Zhongyang CAO Wei WANG Peng WEI Bo GAO Xiang FANG Mengxiang CEN Kefa 《环境科学学报(英文版)》2009,21(3):328-332
A process capable of oxidizing NO, SO2 and Hg0 was proposed simultaneously, which utilized a high-voltage and short-duration positive pulsed corona discharge. By focusing on NO, SO2, and Hg0 oxidation efficiencies, the influences of pulse peak voltage, pulse frequency, initial concentration, electrode number, residence time and water vapor addition were investigated. The results indicate that NO, SO2 and Hg0 oxidation efficiencies depend primarily on the radicals (OH, HO2, O) and the active species (O3, H2O2), etc. produced by the pulsed corona discharge. The NO, SO2 and Hg0 oxidation efficiencies improved as increasing pulse peak voltage, pulse frequency, electrode number and residence time, while they are reduced with an increasing initial concentration. By adding water vapor, SO2 oxidation efficiency is improved remarkably, while NO oxidation efficiency is decreased slightly. In our experiments, the simultaneous NO, SO2, and Hg0 oxidation efficiencies reached to 40%, 98% and 55% with the initial concentrations 479 mg/m3, 1040 mg/m3, and 15.0 ug/m3, respectively. 相似文献
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脉冲放电等离子体治理甲苯废气放大试验研究 总被引:13,自引:0,他引:13
应用脉冲放电等离子体技术,在线板式反应器内对低浓度甲苯废气的治理进行放大试验.采用闸流管开关脉冲电源,其最大输出功率1kW,最大脉冲电压峰值100kV. 试验规模4~16m3·h-1. 试验考察了峰值电压、重复频率、进口浓度和处理气量对甲苯去除率的影响.结果表明:峰值电场强度在9~12kV·cm-1范围内增加,甲苯去除率相应明显提高;当处理气量为4 m3·h-1、脉冲电压峰值69kV、进口浓度1 180mg·m-3、重复频率300pps时, 甲苯的去除率可达88%;反应器的能量利用率在16g·(kW·h)-1左右;甲苯的降解产物主要是CO2和H2O,还有少量CO. 结合甲苯去除率与能量密度、甲苯进口浓度的关系,建立反应器动力学模型,获得甲苯的反应速率常数为0.00356 L·J-1. 为进一步优化放大反应器设计及与电源匹配提供了基础数据. 相似文献
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The catalytic effect of alumina on the destruction of toluene, benzene, acetone and methanol, in DC pulsed corona discharge reactor was studied. In the presence of alumina the inlet concentration of the VOCs was varied from 5 x 10-6 mol/L to 80% x 10-6 mol/L, and their decomposition efficiency (conversion %) was found to be 99%-80% for toluene, 99%-97% for benzene, 95%-92% for acetone, and 72%-85% for methanol. Corresponding decomposition in the absence of alumina was 90%-38% for toluene, 89%-57% forbenzene, 42%-30% for acetone, and 47%-19% for methanol. Feed gas flow rate was 400 cm3/min and power reading from DC source was 7.4 W in all of the experiments. Alumina also shifted the CO/CO2 ratio in the by-products in favor of CO2. Ozone concentration at the reactor outlet was higher in the presence of alumina. Enhancement in VOCs decomposition by alumina was explained on the basis of higher concentration of ozone and its precursor atomic oxygen [O].Decomposition efficiency (conversion %) for individual compounds was found to be inversely proportional to the ionization potential of the compound, under identical conditions. Double DC high voltage sources pulse generator was tested and found to improve VOCs decomposition compared with the conventional single DC high voltage source. 相似文献
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Muhammad Arif Malik 《环境科学学报(英文版)》1998,10(3)
DestructionofVOCsbycombinationofcoronadischargeandcatalysistechniquesMuhammadArifMalik,JiangXuanzhenDepartmentofChemistry... 相似文献
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为探索新型产业化应用热脱附尾气处理技术,采用脉冲电晕放电等离子体技术对含DDTs的热脱附尾气进行处理,考察了工艺参数如脉冲电压、脉冲频率、ρ(DDTs)和停留时间对DDTs处理效果的影响,分析了DDTs经低温等离子体处理后的分解产物.结果表明,DDTs的去除率随脉冲电压的升高、脉冲频率的增大和停留时间的延长而增加,随进气中ρ(DDTs)的升高而降低,但去除量随进气中ρ(DDTs)的升高而增大.进气中的ρ(DDTs)为30.0 mg/m3,停留时间为10 s,脉冲电压为30.0 kV,脉冲频率为50 Hz时,DDTs的去除率为82.5%.低温等离子体处理后,尾气中的ρ(p,p'-DDT)、ρ(o,p'-DDT)和ρ(p,p'-DDD)降低,ρ(p,p'-DDE)反而升高,另有微量的二苯甲烷、二苯甲醇、4,4'-二氯二苯甲烷、2,4'-二氯苯甲酮和1,1-双(对氯苯)-2-氯乙烯等分解产物被检出.研究显示,脉冲放电等离子体技术具有去除效率高等特点,可有效去除含DDTs的热脱附尾气. 相似文献
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Effects of the voltage waveform, discharge tooth wheel number and CO2/NO/SO2 concentration in the simulated flue gas on Hg0
oxidation were investigated using a link tooth wheel-cylinder reactor energized by di erent high voltage power supplies. Negative DC
discharge induced more ozone production and a higher Hg0 oxidation e ciency than positive DC discharge and 12 kHz AC discharge.
The discharge tooth wheel number had almost no e ect on the maximum Hg0 oxidation e ciency. The allowable supplied voltage
decreased with the increase of discharge tooth wheel number. CO2 could stabilize the discharge process and increase the maximum
voltage for a stable discharge. It has also been found that NO consumed O3 induced by high voltage discharge, thereby decreased Hg0
oxidation e ciency; while SO2 had a slight promoting e ect on Hg0 oxidation. 相似文献