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Journal of Polymers and the Environment - Recently, the advantages of biopolymers over conventional plastic polymers are unprecedented, provided that they are used in situations in which they raise...  相似文献   

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Polyhydroxyalkanoates (PHAs) are biodegradable and biocompatible polyesters that can potentially replace certain plastics derived from petroleum. PHAs can be produced using a combination of renewable feedstocks and biological methods. Native and recombinant microorganisms have been generally used for making PHAs via fermentation processes. As much as 90 % of the microbial dry mass may accumulate as PHAs. A range of PHAs has been produced using fermentation methods, including copolymers and block copolymers. Alternative production schemes based on genetically modified plants are becoming established and may become the preferred route for producing certain PHAs. Production in plants is likely to be inexpensive compared to production by fermentation, but it does not appear to be as versatile as microbial synthesis in terms of the range of products that may be generated. Cell-free enzymatic production of PHAs in vitro is receiving increasing attention and may become the preferred route to some specialty products. This review discusses the recent advances in production of polyhydroxyalkanoates by the various methods. Methods of recovering the polymer from microbial biomass are reviewed. Established and emerging applications of PHAs are discussed.  相似文献   

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Although the reaction mechanics are somewhat mysterious, the use of iron for in situ groundwater treatment has recently gained considerable attention and respect in the remediation industry. The basic scientific principles of both applications of iron have been known for over a century; however, both were nearly unheard of as remediation technologies five years ago. Both technologies have a strong potential for widespread use. They are commercially available, have been proven in field studies, are less expensive than traditional pump and treat technologies, and, in many types of groundwater systems, may be able to meet difficult-to-achieve groundwater treatment standards. As these technologies continue to undergo development, there could be considerably more aggressive applications used to treat ground-water containing high concentrations of chlorinated organics and DNAPLs.  相似文献   

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Journal of Polymers and the Environment - This paper presents the effects of silane coupling agent, which includes interfacial adhesive strength, water treatment, polymer composites and coatings...  相似文献   

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Bacterial cellulose pellicles were produced by Gluconacetobacter xylinus using non conventional low-cost carbon sources, such as glycerol remaining from biodiesel production and grape bagasse, a residue of wine production. The carbon sources assayed showed their suitability for microbial cellulose production, with relatively high production values such as 10.0 g/l for the culture medium with glycerol from biodiesel as carbon source and corn steep liquor as nitrogen source; and 8.0 g/l for the culture medium containing grape bagasse and corn steep liquor. Glucose, commercial glycerol and cane molasses were also assayed as carbon sources for comparison. The bacterial celluloses produced were characterized by means of scanning electron microscopy, X-ray diffraction, Fourier transform infrared spectroscopy and thermogravimetric analysis. Morphological analysis showed that bacterial cellulose microfibrils produced from the non-conventional media used were several micrometers long and had rectangular cross-sections with widths and thicknesses in the range of 35–70 and 13–24 nm, respectively. X-ray patterns showed crystallinity levels in the range of 74–79 % (area method), whereas both X-ray patterns and infrared spectroscopy evidenced the presence of peaks characteristic of Cellulose I polymorph. Besides thermal properties were similar to those found for the pellicle obtained from glucose. The study performed showed the suitability of using wine residues or glycerol remaining from increasing biodiesel production as cheap carbon sources for production of bacterial cellulose microfibrils, with similar characteristics as those obtained by use of more expensive carbon sources such as glucose or commercial glycerol. On the other hand, the low cost nitrogen sources used (corn steep liquor or diammonium phosphate) also contributed to the economy of the bioprocess.  相似文献   

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The management of biomedical waste is a crucial issue in health and environmental management. Rules in India were promulgated in 1998, originally with a deadline of December 2000 and extended to December 2002; however, the actual situation remains far from satisfactory. A study conducted in 2001 by CEE, New Delhi; indicated an implementation deficit. To gauge the present situation, a survey was undertaken during 2005-2006. A systematic analysis of current biomedical waste management practices in smaller nursing homes and hospitals in Delhi was carried out. A total of 53 nursing homes, with bed strengths ranging from 20 to over 200, were included. The survey results show that there is a marked improvement in the segregation practices of biomedical waste in small private hospitals and nursing homes. The majority of nursing homes and hospitals were found to be using a service provider for the collection, management, and disposal of healthcare wastes. Data was collected through a questionnaire and field visits. This paper discusses the relevant data indicative of current practices of healthcare waste management in the nursing homes and small healthcare facilities in Delhi.  相似文献   

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