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1.
Masahiro Funabashi Fumi Ninomiya Masao Kunioka 《Journal of Polymers and the Environment》2007,15(4):245-250
Returnable cups made of poly(lactic acid) (PLA) are employed as an example of products made of biodegradable plastics. Two
kinds of PLA samples plates and powders with different shapes were prepared from PLA cups. The plates were cut from a cup
using nippers. Powders were prepared using a rotation mechanical mixer for 45 min. PLA powders were separated by sieves with
60 meshes (250 μm) into a size ranging from 0 to 250 μm. An average diameter of powders separated by a sieve is 169 μm. Biodegradation
tests of PLA plates, PLA powders and cellulose powders in controlled compost at 58 °C were performed using a Microbial Oxidative
Degradation Analyzer (MODA) instrument according to ISO 14855-2. PLA powders showed almost the same biodegradation curve as
that of cellulose powders. PLA plates biodegraded at a slower rate than PLA powders. 相似文献
2.
Evaluation of the Biodegradation of Starch and Cellulose Under Controlled Composting Conditions 总被引:1,自引:1,他引:0
Francesco Degli-Innocenti Maurizio Tosin Catia Bastioli 《Journal of Polymers and the Environment》1998,6(4):197-202
In order to verify the response of the controlled composting test method (i.e., the ISO/DIS 14855:1997, the ASTM D 5338-92, or the CEN counterpart) to starch at different concentrations, the maximum amount prescribed by the test method (100 g) and lower amounts (60 and 30 g), as if starch were a coingredient in a blend, were tested. After 44 days of incubation (at a constant temperature of 58°C) the biodegradation curves were in a plateau phase, displaying the following final values (referred to a nominal starch initial amount of 100 g): starch 100 g, 97.5%; starch 60 g, 63.7%; and starch 30 g, 32.5%. The data show a CO2 evolution roughly equal, in each case, to the theoretical maximum, indicating a complete starch mineralization. We cannot discern whether the deviations found at lower concentrations are caused by a priming effect. In any case, the extent of the deviations is not high and is acceptable in biodegradation studies. The average biodegradation of cellulose, obtained gathering four independent experiments with 11 biodegradation curves, turned out to be 96.8 ± 6.7% (SD) after 47 ± 1 days. The data indicate that the controlled composting is a reliable test method also for starch and cellulose and, consequently, for starch-based and cellulose-based materials. 相似文献
3.
Hisaaki Yagi Fumi Ninomiya Masahiro Funabashi Masao Kunioka 《Journal of Polymers and the Environment》2012,20(3):673-680
The anaerobic biodegradation rates of four different sizes of poly (lactic acid) (PLA) films (thickness 25???m) in anaerobic sludge at 55?°C were examined. The anaerobic biodegradation rates of small pieces of PLA film were slower than for large pieces of PLA film. We also examined whether PLA film could also be used as a reference material in the anaerobic biodegradation test in addition to PLA powder. The anaerobic biodegradation rate of PLA film became slower with lower activity sludge, but the rate of decrease was gradual, and the anaerobic biodegradation rate of PLA film was faster than the PLA powder (125?C250???m). The anaerobic biodegradation rate of the PLA powder (125?C250???m) reflected the plastic anaerobic biodegradation activity of the sludge more accurately than the thin PLA film (thickness 25???m). Consequently, PLA powder (125?C250???m) is more suitable than thin PLA film (thickness?<?25???m) for use as a reference material to assess the plastic anaerobic biodegradation activity of the sludge in an anaerobic biodegradation test at 55?°C. 相似文献
4.
Zoran S. Petrović Yijin Xu Jelena Milić Gregory Glenn Artur Klamczynski 《Journal of Polymers and the Environment》2010,18(2):94-97
Thermoplastic urethanes based on polyricinoleic acid soft segments and MDI/BD hard segments with varied soft segment concentration
were prepared. Soft segment concentration was varied from, 40 to 70 wt%. Biodegradation was studied by respirometry. Segmented
polyurethanes with soft segments based on polyricinoleic acid degrade relatively slow losing about 11% carbon after 30 days,
but faster than corresponding petrochemical polyesterurethanes. Since biodegradation proceeds mainly through the soft segments,
higher soft segment content polymers displayed slightly higher biodegradation. Polyurethanes with dispersed hard domains in
the soft phase displayed slightly faster biodegradation than those with co-continuous morphology. Polyester diol degrades
slower than castor oil but significantly faster than the polyurethanes with built in soft segments from the same diol. Castor
oil biodegrades slower than soybean oil. 相似文献
5.
Josef Hrnčiřík Jiří Pšeja Jan Kupec Světlana Bernkopfová 《Journal of Polymers and the Environment》2010,18(2):98-103
This work focused on anaerobic biodegradation of blends composed of glycerol-plasticized polyvinyl alcohol (PVA) and biopolymer
(starch, gellan, xanthan) in an aqueous environment, after inoculation with digested activated sludge from a municipal wastewater
treatment plant. Glycerol degradability is comparable to degradability of used modifying agents. Modifying agents added in
the 20–40 wt% range proportionally increased biodegradation degree (Dt) calculated from balance of transformed carbon in the system. Biodegradation degree of polysaccharides and glycerol attained
95% and over. For PVA it was only 6.5% (in breakdown times up to 500 h). Content of polysaccharides favorably affects biodegradation
degree of polyvinyl alcohol blends, but at the expense of reduced mechanical properties of resultant products. 相似文献
6.
Masao Kunioka Fumi Ninomiya Masahiro Funabashi 《Journal of Polymers and the Environment》2007,15(4):281-287
The biobased contents of raw materials such as starches, sugar, chitin, or wood powders for biomass plastics were measured
using Accelerator Mass Spectrometry (AMS) based on ASTM D6866. AMS measures the isotope carbon ratio of 14C to 12C and 13C in graphite derived from sample powders. The biobased contents of starches, sugar or chitin were almost 100% which means
that they are fully biobased. The biobased contents of the wood powders were over 140% due to the effect of the post 1950s
14C injection due to nuclear testing. Poly(ε-caprolactone) (PCL) composite samples were prepared using the polymerization and
direct molding method. The starting compound was the ε-caprolactone monomer liquid combined with cellulose and inorganic fillers
using aluminum triflate as a catalyst at 80 °C for 6 or 24 h. PCL cylinder-shaped composite samples with a homogeneously dispersed
cellulose filler were prepared with Mn = 4,600 (Mw/Mn = 2.9). The biobased content of the PCL composite with 50 wt% cellulose filler (51.67%) measured using AMS was slightly higher
than the carbon ratio of cellulose in the starting powder samples (41.3 mol%). This is due to the higher biobased content
(112.70%) of the cellulose filler used in this study. The biobased content of the polymer composite powders by AMS was found
not to be affected by the presence of inorganic fillers, such as talc. 相似文献
7.
Akira Hoshino Maso Tsuji Masanori Momochi Akiko Mizutani Hideo Sawada Setsuo Kohnami Hiroki Nakagomi Michio Ito Hisato Saida Munehiro Ohnishi Michimasa Hirata Masao Kunioka Masahiro Funabash Shogo Uematsu 《Journal of Polymers and the Environment》2007,15(4):275-280
Several ISO standards for determining the ultimate aerobic/anaerobic biodegradability of plastic materials have been published.
In particular, ISO 14855-1 is a common test method that measures evolved carbon dioxide using such methods as continuous infrared
analysis, gas chromatography or titration and others (ISO 14855-1(2005.9)). This method is a small-scale test for determining
the ultimate aerobic biodegradability of plastic materials, where the amounts of compost inoculum and test sample in one tenth
comparing with that of ISO 14855-1. This method is well versed in ISO/DIS 14855-2 which the carbon dioxide evolved from test
vessel is determined by gravimetric analysis of carbon dioxide absorbent. The focus of this study is to elucidate statistically
the results of round robin test by seven countries used MODA, which were various deviations among the experiments. 相似文献
8.
Suvangshu Dutta Niranjan Karak Jyoti Prasad Saikia Bolin Kumar Konwar 《Journal of Polymers and the Environment》2010,18(3):167-176
Mesua ferrea L. seed oil (MFLSO) modified polyurethanes blends with epoxy and melamine formaldehyde (MF) resins have been studied for
biodegradation with two techniques, namely microbial degradation (broth culture technique) and natural soil burial degradation.
In the former technique, rate of increase in bacterial growth in polymer matrix was monitored for 12 days via a visible spectrophotometer
at the wavelength of 600 nm using McFarland turbidity as the standard. The soil burial method was performed using three different
soils under ambient conditions over a period of 6 months to correlate with natural degradation. Microorganism attack after
the soil burial biodegradation of 180 days was realized by the measurement of loss of weight and mechanical properties. Biodegradation
of the films was also evidenced by SEM, TGA and FTIR spectroscopic studies. The loss in intensity of the bands at ca. 1735 cm−1 and ca. 1050 cm−1 for ester linkages indicates biodegradation of the blends through degradation of ester group. Both microbial and soil burial
studies showed polyurethane/epoxy blends to be more biodegradable than polyurethane/MF blends. Further almost one step degradation
in TG analysis suggests degradation for both the blends to occur by breakage of ester links. The biodegradation of the blends
were further confirmed by SEM analyses. The study reveals that the modified MFLSO based polyurethane blends deserve the potential
to be applicable as “green binders” for polymer composite and surface coating applications. 相似文献
9.
Christopher Thellen Megan Coyne Danielle Froio Margaret Auerbach Carl Wirsen Jo Ann Ratto 《Journal of Polymers and the Environment》2008,16(1):1-11
A series of polyhydroxyalkanoates (PHA), all containing 1% nucleating agent but varying in structure, were melt-processed
into films through single screw extrusion techniques. This series consisted of three polyhydroxybutyrate (PHB) and three polyhydroxybutyrate-valerate
(PHBV) resins with varying valerate content. Processing parameters of temperature in the barrel (165–173 °C) and chill rolls
(60 °C) were optimized to obtain cast films. The gel-permeation chromatography (GPC) results showed a loss of 8–19% of the
polymer’s initial molecular weight due to extrusion processing. Modulated differential scanning calorimetry (MDSC) displayed
glass transition temperatures of the films ranging from −4.6 to 6.7 °C depending on the amount of crystallinity in the film.
DSC data were also used to calculate the percent crystallinity of each sample and slightly higher crystallinity was observed
in the PHBV series of samples. X-ray diffraction patterns did not vary significantly for any of the samples and crystallinity
was confirmed with X-ray data. Dynamic mechanical analysis (DMA) verified the glass transition trends for the films from DSC
while loss modulus (E′) reported at 20 °C showed that the PHBV (3,950–3,600 MPa) had the higher E′ values than the PHB (3,500–2,698 MPa) samples. The Young’s modulus values of the PHB and PHBV samples ranged from 700 to
900 MPa and 900 to 1,500 MPa, respectively. Polarized light microscopy images revealed gel particles in the films processed
through single-screw extrusion, which may have caused diminished Young’s modulus and tensile strength of these films. The
PHBV film samples exhibited the greatest barrier properties to oxygen and water vapor when compared to the PHB film samples.
The average oxygen transmission rate (OTR) and water vapor transmission rate (WVTR) for the PHBV samples was 247 (cc-mil/m2-day) and 118 (g-mil/m2-day), respectively; while the average OTR and WVTR for the PHB samples was 350 (cc-mil/m2-day) and 178 (g-mil/m2-day), respectively. Biodegradation data of the films in the marine environment demonstrated that all PHA film samples achieved
a minimum of 70% mineralization in 40 days when run in accordance with ASTM 6691. For static and dynamic incubation experiments
in seawater, microbial action resulting in weight loss as a function of time showed all samples to be highly biodegradable
and correlated with the ASTM 6691 biodegradation data. 相似文献
10.
Photodegradation and Biodegradation Study of a Starch and Poly(Lactic Acid) Coextruded Material 总被引:1,自引:0,他引:1
Alain Copinet Céline Bertrand Antoine Longieras Veronique Coma Yves Couturier 《Journal of Polymers and the Environment》2003,11(4):169-179
To simulate the behavior of agricultural mulch coextruded poly(lactic acid)(PLA)/starch films, two stages were carried out. The first was an ultraviolet treatment (UV) at 315 nm, during which glass transition temperature Tg, weight, and molecular weight (MW) decreased and a separation between PLA and starch phase was observed. For the second stage, the mineralization of the carbon of the material was followed using the ASTM (D 5209–92 and 5338–92) and ISO/CEN (14852 and 14855) standard procedures. To measure the biodegradability of polymer material, the assessment of the carbon balance allowed determination of the distribution between the carbon rate used to the biomass synthesis or the respiration process (released CO2), as well as the dissolved organic carbon into the culture medium and the carbon in the residual insoluble material. The influence of the nature of the medium and the standardized procedures on the final rate of biodegradation was investigated. Whatever the standardized method, the biodegradation percentage was significantly stronger in liquid medium (92.4–93.4) than on inert medium (80–83%). In the case of the compost process, only released CO2 was measured and corresponded to 79.1–80.3%. 相似文献
11.
Csaba Zoltán Kibédi-Szabó Marta Stroescu Anicuta Stoica-Guzun Sorin Ion Jinga Szabolcs Szilveszter Iuliana Jipa Tanase Dobre 《Journal of Polymers and the Environment》2012,20(2):422-430
The main objective of this study was to develop biodegradable, composite materials, based on poly (vinyl alcohol), bacterial cellulose and chitosan for possible application in packaging industry. Two composite materials were prepared, one containing poly (vinyl alcohol) (PVA) and bacterial cellulose (BC), named PVA/BC, and the other containing PVA, BC but also chitosan (CTS), named PVA/BC/CTS. The biodegradation behavior was studied in a fed-batch bioreactor, in aerobic and anaerobic conditions, using activated sludge. Biodegradation tests were based on weight loss measurements. Structural changes were confirmed by Fourier transform infrared spectroscopy (FTIR) and the morphological ones by scanning electron microscopy (SEM). After 4?weeks, the biodegradation experiments have shown a relative high degradation of the PVA/BC/CTS film compared with the PVA/BC one. These results were confirmed by spectral analysis and also by SEM images. Besides, the SEM images revealed that biodegradation occurs also inside the composite materials, not only on the surface. 相似文献
12.
Starch granules were modified with trisodium trimetaphosphate (TSTP) and characterized by P31-NMR, FTIR and DSC. Seventy-micron films were prepared from modified starch and polycaprolactone blends by solvent casting technique. Three different types of films—PCL (100% polycaprolactone), MOD-ST/PCL (50% modified starch and 50% polycaprolactone blend) and NONMOD-ST/PCL (50% nonmodified starch and 50% polycaprolactone blends)—were prepared, and their thermal, mechanical, and morphologic properties were investigated to show the increased performance of PCL with the addition of starch and also the effect of modification. It was observed that with the addition of starch the Young's modulus of polycaprolactone was increased and became less ductile, whereas tensile strength and elongation at break values decreased. Biodegradation of these films was inspected under different aerobic environments with the presence of Pseudomonas putida, activated sludge, and compost. It was observed that whereas P. putida had almost no effect on degradation during 90 days, with the presence of activated sludge, considerable deformation of films was observed even in the first 7 days of degradation. In a compost environment, degradation was even faster, and all polymer films were broken into pieces within first 7 days of degradation and no film remained after 15 days. 相似文献
13.
S. P. C. Gonçalves S. M. Martins-Franchetti D. L. Chinaglia 《Journal of Polymers and the Environment》2009,17(4):280-285
Films of poly(hydroxybutyrate-co-hydroxyvalerate) (PHBV) and poly(propylene) (PP), PP/PHBV (4:1), blends were prepared by
melt-pressing and investigated with respect to their microbial degradation in soil after 120 days. Biodegradation of the films
was evaluated by Fourier transform infrared spectroscopy, scanning electron microscopy, differential scanning calorimetry,
and X-ray diffraction. The biodegradation and/or bioerosion of the PP/PHBV blend was attributed to microbiological attack,
with major changes occurring at the interphases of the homopolymers. The PHBV film was more strongly biodegraded in soil,
decomposing completely in 30 days, while PP film presented changes in amorphous and interface phase, which affected the morphology. 相似文献
14.
S. P. C. Gon?alves S. M. Martins-Franchetti 《Journal of Polymers and the Environment》2010,18(4):714-719
Poly(hydroxybutyrate-co-valerate) (PHBV) and poly(ε-caprolactone) (PCL) PCL/PHBV (4:1) blend films were prepared by melt-pressing.
The biodegradation of the films in response to burial in soil for 30 days was investigated by Fourier transform infrared spectroscopy
(FTIR), scanning electron microscopy (SEM), differential scanning calorimetry (DSC) and thermogravimetry (TG). The PHBV film
was the most susceptible to microbial attack, since it was rapidly biodegraded via surface erosion in 15 days and completely
degraded in 30 days. The PCL film also degraded but more slowly than PHBV. The degradation of the PCL/PHBV blend occurred
in the PHBV phase, inducing changes in the PCL phases (interphase) and resulting in an increase of its crystalline fraction. 相似文献
15.
Serap Cesur 《Journal of Polymers and the Environment》2018,26(4):1425-1444
Because environmental pollution caused by plastic waste is a major problem investigations concerning biodegradable packaging are important and required. In this study, the biodegradation of PCL composite films with organic (glycerol monooleate and oleic acid) and inorganic additives (organo nano clay) was investigated to understand which additive and the amount of additive was more effective for biodegradation. The relationship between the degree of crystallinity and the effect of additives on the biodegradability of polycaprolactone (PCL) was examined. PCL composite films were prepared using organo nano clay (0.1–0.4–1–3 wt%) and oleic acid (1–3–5 wt%) or GMO (1–3–5 wt%). The 35 films prepared with PCL (P), clay (C), oleic acid (O), or glycerol monooleate (G) are coded as P_C#wt%_O (or G)#wt%. The composite films, P_C0.4_O5 contains 0.4 wt% clay and 5 wt% oleic acid and the P_C3_G1 contains 3 wt% clay and 1 wt% glycerol monooleate. The biodegradation of PCL films in simulated soil was studied for 36 months. The films were periodically removed from the simulated soil and film thicknesses, weight losses, visual changes, crystal structures, and a functional group analyses were performed. PCL composite films are separated into three groups, depending on degradation time, (1) films that degraded before 8 months (fast degradation), (2) films that degraded around 24 months (similar to neat PCL), and (3) films that take longer to degrade (slow degradation). The films in the first group are PCL films with 1 and 3 wt% clay additive and they begin to biodegrade at the 5th month. However, a composite film of PCL with only 0.4 wt% clay and 5 wt% GMO addition has the shortest degradation time and degraded in 5 months. The films in the last group are; P_G3, P_G5, P_C0.1, P_C0.1_O1, and P_C0.1_O5 and they took around 30 months for biodegradation. It was observed that increasing the organo nanoclay additive increases the biodegradability by disrupting the crystal structure and causing a defective crystal formation. The addition of GMO with organo nano clay also accelerates biodegradation. The addition of organo nano clay in an amount as small as 0.1 wt% acts as the nucleating agent, increases the degree of crystallinity of the PCL composites, and slows the biodegradation period by increasing the time. 相似文献
16.
Pilar D. S. C. Mariani Antonio P. Vinagre Neto José P. da Silva Jr. Elke J. B. N. Cardoso Elisa Esposito Lucia H. Innocentini-Mei 《Journal of Polymers and the Environment》2007,15(1):19-24
The biodegradability properties of poly(ɛ-caprolactone) (PCL) and modified adipate-starch (AS) blends, using Edenol-3203 (E)
as a starch plasticizer, were investigated in laboratory by burial tests of the samples in previously analyzed agricultural
soil. The biodegradation process was carried out using the respirometric test according to ASTM D 5988-96, and the mineralization
was followed by both variables such as carbon dioxide evolution and mass loss. The results indicated that the presence of
AS-E accelerated the biodegradation rate as expected. 相似文献
17.
Jung-Eun Lee 《Journal of Material Cycles and Waste Management》2011,13(3):259-263
Effective handling of municipal digested sludge requires that the product cake have low water content. To this end, we investigated
the change in sludge dewaterability after the addition of fly ash to municipal digested sludge, dewatering of which is difficult
because of its high organic content. The performance of the dewatering is compared with that of electroosmotic dewatering
(EDW) and conventional mechanical dewatering (CMD). Fly ash classified by sieving to the size of 25–75 μm and >75 μm is added
to the municipal digested sludge by 10, 20, and 50 wt% by wet base. When adding fly ash particles to municipal digested sludge,
dewatering efficiency improved with smaller fly ash particle size and with increase in the amount. When sludge was dewatered
using an electroosmotic dewatering method, the dewatering efficiency is improved about 40% by adding fly ash of 25–75 μm particle
size with 20 wt% when compared with conventional mechanical dewatering method without adding the fly ash. It is concluded
that fly ash particles rich in inorganic material are helpful in the dewatering process when added to municipal digested sludge
and EDW is more effective than CDW. 相似文献
18.
Comparative Biodegradation in Soil Behaviour of two Biodegradable Polymers Based on Renewable Resources 总被引:2,自引:0,他引:2
This work presents the last phase of long-term experimental studies on the biodegradation in soil behaviour of polymers destined
for agricultural applications. The paper focuses on comparative studies between the biodegradation in soil behaviour of two
important biodegradable polymers based on renewable resources: poly(lactic acid) (PLA) versus polyhydroxyalkanoates (PHA).
Full-scale experiments were carried out during the period June 2008–January 2009. Different methods of exposure were applied
in the case of polyhydroxyalkanoates, simulating the agricultural biodegradable mulching films use and their fate in soil
after the end of their useful lifetime. The field results were compared with the results of biodegradation under controlled
laboratory conditions simulating biodegradation in soil, using soil from the experimental field. Further, the field results
were compared against the results of biodegradation under farm composting conditions. 相似文献
19.
Leejarkpai T Suwanmanee U Rudeekit Y Mungcharoen T 《Waste management (New York, N.Y.)》2011,31(6):1153-1161
This study models and evaluates the kinetics of C-CO2 evolution during biodegradation of plastic materials including Polyethylene (PE), PE/starch blend (PE/starch), microcrystalline cellulose (MCE), and Polylactic acid (PLA). The aerobic biodegradation under controlled composting conditions was monitorated according to ISO 14855-1, 2004. The kinetics model was based on first order reaction in series with a flat lag phase. A non-linear regression technique was used to analyze the experimental data. SEM studies of the morphology of the samples before and after biodegradation testing were used to confirm the biodegradability of plastics and the accuracy of the model. The work showed that MCE and PLA produced the high amounts of C-CO2 evolution, which gave readily hydrolysable carbon values of 55.49% and 40.17%, respectively with readily hydrolysis rates of 0.338 day−1 and 0.025 day−1, respectively. Whereas, a lower amount of C-CO2 evolution was found in PE/starch, which had a high concentration of moderately hydrolysable carbon of 97.74% and a moderate hydrolysis rate of 0.00098 day−1. The mineralization rate of PLA was 0.500 day−1 as a lag phase was observed at the beginning of the biodegradability test. No lag phase was observed in the biodegradability testing of the PE/starch and MCE. The mineralization rates of the PE/starch and MCE were found to be 1.000 day−1, and 1.234 day−1, respectively. No C-CO2 evolution was observed during biodegradability testing of PE, which was used for reference as a non-biodegradable plastics sample. 相似文献
20.
Sandra M. Martins-Franchetti T. A. Egerton J. R. White 《Journal of Polymers and the Environment》2010,18(1):79-83
The biodegradation of blends of poly(caprolactone) (PCL) and poly(vinyl chloride) (PVC) has been studied. Blends of composition
PCL/PVC 1:1 and 1:2 w/w were tested. The 1:1 blend contained crystals in the as-cast state and became more crystalline on
exposure to different bio-active agents. The 1:2 blend was amorphous in the as-cast state but developed a significant crystal
component after 4 months exposure to the bio-agents. Three bio-active agents were used and all were found to produce qualitatively
similar behaviour but their activity was somewhat different. For both the 1:1 blend and the 1:2 blend the ranking of the three
bio-active agents tested, in increasing order, was Curvularia sp.; Trogia buccinalis; Phanerochaete chrysosporium. 相似文献