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The protozoan, , metabolizes pentachloronitrobenzene to several products, including nitrite, pentachlorothioanisole and pentachloroaniline. The latter two metabolites were identified by gas chromatographymass spectrometry. Pentachlorothioanisole may be produced via a glutathione-dependent pathway, and two key enzymes of this pathway, glutathione transferase and thiol S-methyltransferase, have been detected in crude extracts of this microorganism. 相似文献
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This paper reports the bioaccumulation of three PCBs (2,4′-dichlorobiphenyl, 2,4,6,2′-tetrachlorobiphenyl and 2,4,6,2′,4′-pentachlorobiphenyl) by the green alga under various conditions. A probable pattern of the bioconcentration mechanism is suggested. No metabolites were extracted from algae or water 6 days after incubation with PCBs. 相似文献
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Killifish () were exposed in the laboratory to pentachlorophenol (PCP) at concentrations of 57 to 610 μg PCP/L. Bioaccumulation reached a plateau value of about 53 by 168 hrs and remained at this level for at least 72 hrs. One-half the plateau value was reached in about 25 hrs. Following exposure, fish placed in PCP-free aquaria lost PCP rather slowly (). The depuration data were suggestive of a pool of PCP which was lost more rapidly (). The results of this study are compared to similar studies in other species. The bioaccumulation factors measured in this study agree relatively well with those in other marine species, but are lower than reported for fresh water species. Possible reasons for this difference are discussed. 相似文献
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A.J.M. Baker 《Chemosphere》1984,13(4):585-589
This paper reports results of a study on cadmium tolerance in the grass which suggest that tolerance is inducible and can be lost in transplanting plants to uncontaminated soils. 相似文献
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Oral administration of 0.7 mg/kg/day of quinalphos to mals buffalo calves for 28 consecutive days produced marked inhibition of erythrocyte acetylcholinesterase and elevation in serum levels of aminotransferases and phosphatases without inducing apparent toxicity. The enzymic alterations were more pronounced following 1.4 and 2.1 mg/kg/day doses of quinalphos, which were lethal within 4–17 days. 相似文献
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This study described an experiment on biotransformation of 2,6-DIPN in carp hepatopancreas. It has already been revealed by the previous studies to be metabolized with enzymatic oxidation in the liver and been postulated a metabolic pathway. These results were confirmed by means of incubation with 2,6-DIPN in carp hepatic microsome preparation with NADPH, and G-6-P as co-factor. It was suggested that DIPN may be mainly metabolized in the hepatic cytochrome P-450 in the microsomes system. The kinetic parameters i.e. apparent Michaelis constant (Km) and maximum velocity (Vmax), in the metabolites formation were also calculated. 相似文献
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C.M. Tu 《Chemosphere》1981,10(1):127-134
A study of the effect of 5 fungicide seed treatments on alfalfa ( L. var. Vernal) growth and nodulation by 102F66 was conducted in a growth chamber. Captan, maneb and thiram exhibited greater toxicity to . and alfalfa plants than that of benomyl and zineb. Recovery of the inhibitory effect was rapid. 相似文献
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Accumulation of 14C labelled bis(tributyltin) oxide (TBTO) by the mud crab, , was determined through short-term exposure to labelled water and food. The potential for trophic accumulation during chronic low level exposure is emphasized. 相似文献
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Weddell seal samples taken from the Antarctic have been found to be contaminated with chlordane compounds. ΣChlordane () was present in blubber of seals at the range of 12 - 62 ng/g fresh weight. The order of chlordane compound concentrations was . Relative aboundance of -chlordane in Σchlordane is higher than that in humans. A probable explanation for their occurrence in the Antarctic is an airborne transport. 相似文献
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M.Yasar Ünlü 《Chemosphere》1979,8(5):269-275
The amount of ingested arsenic assimilated and eliminated by the crab appeared to depend on chemical form of arsenic present in the food. Arsenic-74 was translocated rapidly with a high percentage located in hepatopancreas and exoskeleton. The speciation of radioarsenic determined by sequential extraction of experimental food, feces, muscle and hepatopancreas showed that there is no efficient mechanism within the crab which can covert lipid and water soluble arsenic to arsenite and residual arsenic or vice-versa. The biological mechanism in crab selectively and effectively excretes soluble form of arsenite and residual arsenic much more readily than organic arsenic. 相似文献
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The joint toxicity of mixtures of phosphamidon and methidathion to adult lobsters () is greater than additive in tests with the combined 48-h toxicity unit of the mixtures totalling 0.25, 0.5 and 1.0 units. The largest magnification factor for greater than additive toxicity occurred where phosphamidon and methidathion contributed to the total toxicity unit in a ratio of 1:1.5 and was progressively smaller for ratios of 1:4.4 and 2:1. 相似文献
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Heavy metal pollution from a point source has been demonstrated by the levels of mercury in flesh of mussels, . 相似文献
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The livers of 53 female cod weighing about 2 kg, caught at three different sites off the Finnish coast, were analyzed for chlorinated hydrocarbons. The average concentrations of PCB-, DDT- and chlordane compounds varied from 2.3 to 5.3, 0.3 to 1.0 and 0.02 to 0.05 mg/kg, respectively. 相似文献
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The adsorption of the herbicide 14C-atrazine to the marine fungus was studied using sodium azide as an inhibitor of active uptake. Adsorption of atrazine (94 ppb) was found to reach equilibrium within six hours. Adsorption as a function of concentration (9.4 to 468 ppb) conformed to the empirically derived Freundlich equation giving a K value of 6.2. Atrazine on the fungal cell surface was easily desorbed by successive artificial seawater washes indicating a relatively loose binding. The ability of the marine fungus to remove 14C-atrazine from an artificial seawater medium suggests an environmental role in the transport and redistribution of atrazine in estuaries. 相似文献
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C.M. Tu 《Chemosphere》1982,11(10):1027-1033
The relative toxicity of 23 pesticides, including 21 fungicides and two pyrethroid insecticides, on , four soybean pathogens, , , and , and germination of soybean seeds was compared with a highly toxic broad spectrum germicide, HgCl2 under laboratory conditions. 相似文献