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1.
多氯联苯对离体人红细胞的毒性机理 总被引:1,自引:0,他引:1
本实验研究了多氯联苯(PCB_s)对人离体红细胞自由基生成和脂质过氧化作用的影响。红细胞悬液在含有不同剂量Aroclorl254的培养液中37℃温育一定时间,然后测定超氧阴离子自由基(O_2~-)、丙二醛(MDA)、超氧化物歧化酶(SOD)和还原型谷胱甘肽(GSH)的含量。测定结果表明,红细胞脂质过氧化作用与PCB_s存在着剂量——效应及时间——效应关系,Aroclorl254可以直接诱导离体人红细胞的脂质过氧化作用。其中O_2~-、MDA、GSH 3项指标均有良好的剂量——效应及时间——效应关系,SOD活力在温育后迅速增加,之后基本稳定,9h后活力出现下降。 相似文献
2.
该文分析了饮用水消毒的现状,提出保持氯消毒不变,用羟基自由基氧化法对饮用水进行后处理,去除氯消毒产生的卤代烃,以提高饮用水的质量。 相似文献
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准确运用环境行政自由裁量权是各级环境保护行政主管部门依法行政的一个重要方面。通过阐述环境行政自由裁量权的概念、合理性的界定,提出环境保护行政主管部门应从坚持立法目的、正当考虑、保持连续性等方面规范自由裁量权的行政行为。 相似文献
4.
高级氧化技术在废水处理中的应用研究进展 总被引:18,自引:0,他引:18
探讨了高级氧化技术(Advanced Oxidation Processes,即AOPs)如:O3/H2O2Fenton试剂均相湿式催化氧化;H2O2/UV、O3/UV、O3/H2O2/UV均相光催化氧化;多相湿式催化氧化,多相光催化氧化,多相催化和生化氧化等过程处理废水及其反应机理,论述了AOPs技术在工业废水处理方面的研究进展。 相似文献
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甲醛致DNA断裂作用的机制及修复的研究 总被引:1,自引:0,他引:1
应用单细胞凝胶电泳技术研究了甲醛致DNA断裂作用、作用机制以及断裂的修复.结果表明,甲醛在低浓度下可以诱导DNA的断裂(P<0.01);该断裂作用可以显著地被羟基自由基(·OH)清除剂甘露醇和二甲基亚砜抑制(P<0.01),以及受到超氧阴离子自由基(O·-2)清除剂超氧化物歧化酶(SOD)显著抑制(P<0.01),但其抑制效果要弱于甘露醇和二甲基亚砜.甲醛引起DNA断裂作用是通过活性氧自由基介导的,且在90min时基本上可被完全修复. 相似文献
7.
对弹性地基上圆环形薄板的振动问题进行了分析和求解,给出了计算固有频率的计算公式和必要的数据,所考虑的边界条件是内外周边固支和内外周边简支两种情况,外径与内径的比值是2.5,3.0,3.5,4.0,4.5,5.0六种情况. 相似文献
8.
高压电晕放电对五氯酚的降解研究 总被引:1,自引:1,他引:0
研究了放电电压、溶液pH等因素对高压电晕放电降解PCP效果的影响,并对高压电晕放电处理PCP的动力学进行了初步探讨,同时对高压电晕放电降解PCP的COD和TOC的变化进行了分析。结果表明:放电电压和溶液pH值对PCP降解性能影响很大,放电电压和溶液pH值越高,PCP的降解速度越快。当溶液pH值为11.2、PCP初始质量浓度40 mg/L、电晕放电电压为25 kV时,经30 min电晕放电,PCP的降解率达90%以上,电晕放电降解PCP的反应符合一级反应动力学。在氧化过程中PCP可能转化为苯醌等中间产物,TOC几乎无变化,PCP分解成的小分子有机物使COD升高,可生化性提高。 相似文献
9.
In a chemical sense, the positive muon is a light proton. It is obtained at the ports of accelerators in beams with a spin
polarization of 100%, which makes it a highly sensitive probe of matter. The muonium atom is a light hydrogen isotope, nine
times lighter than H, with a muon as its nucleus. It reacts the same way as H, and by addition to double bonds it is implemented
in free radicals in which the muon serves as a fully polarized spin label. It is reviewed here how the muon can be used to
obtain information about muonium and radical reaction rates, radical structure, dynamics, and local environments. It can even
tell us what a fragrance molecule does in a shampoo. 相似文献
10.
Sulfonamides are used in human therapy, animal husbandry and agriculture but are not easily biodegradable, and are often detected in surface water. Sulfamethazine (SMZ) and sulfadiazine (SDZ) are two widely used sulfonamide antibiotics that are used heavily in agriculture. In this study, they were degraded in an aqueous system by chlorination after pre-oxidation with ferrate(VI) (FeVIO42 ?, Fe(VI)), an environmentally friendly oxidation technique that has been shown to be effective in degrading various organics. The kinetics of the degradation were determined as a function of Fe(VI) (0–1.5 mg/L), free chlorine (0–1.8 mg/L) and temperature (15–35°C). According to the experimental results, SMZ chlorination followed second-order kinetics with increasing Fe(VI) dosage, and the effect of the initial free chlorine concentration on the reaction kinetics with pre-oxidation by Fe(VI) fitted a pseudo-first order model. The rate constants of SDZ and SMZ chlorination at different temperatures were related to the Arrhenius equation. Fe(VI) could reduce the levels of THMs formed and the toxicity of the sulfonamide degradation systems with Fe(VI) doses of 0.5–1.5 mg/L, which provides a reference for ensuring water quality in drinking water systems. 相似文献
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许多国家正将主要经贸政策重点转向自贸区,环境与贸易成为自贸区谈判的重要内容。我国应该抓住自贸区环境服务贸易谈判的重要机遇,加快中国经济又好又快发展及环境服务业战略转型。当前需要:加强自贸区谈判对环境及可持续发展的影响研究,解决战略转型的可持续性问题;加强不同环境服务分类影响研究,解决战略转型的对象问题;实施国内环境服务企业的走出去战略,解决战略转型的途径问题;加快环境服务业发展和战略转型的法规和政策体系建设,制定针对国内环境服务企业的扶持战略,解决战略转型的保障问题。 相似文献
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We believe non-invasive prenatal diagnosis is about to have a massive impact on the way fetal medicine is practised. There will be many great advantages and improvements, but the technology also has the potential to be used for non-medical reasons such as sex selection and paternity testing. We discuss some of the issues that may face obstetricians in the future as a result of this emerging technology. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
14.
James N. Macri Kevin Spencer David Aitken Kenneth Garver Philip D. Buchanan Françoise Muller Andre Boue 《黑龙江环境通报》1993,13(7):557-562
Maternal serum free beta (hCG) levels are elevated (median 2·20 MOM) in the first trimester of pregnancy in 38 Down syndrome cases as compared with appropriate controls. This observation may form the basis for its use as a marker in screening for Down syndrome in the first trimester. Altered levels of the free beta analyte are observed in pregnancy conditions or complications other than Down syndrome. 相似文献
15.
With the rapid increase in the application of biochars as amendments, studies are needed to clarify the possible environmental risks derived from biochars to use safely the biomass resources. This work reported selected dark sides of maize straw-and swine manurederived biochars pyrolyzed at 300 and 500°C. During the pyrolysis processes, total heavy metals in the biochars were enriched greatly accompanying with considerable emission of the heavy metals into atmosphere and the trends became increasingly obvious with pyrolysis temperature. Meanwhile, the biochars showed distinctly decreased available heavy metals compared with raw feedstocks, which could be mainly attributed to the sorption by the inorganics in the biochars. The water-and acid-washing treatments significantly increased the releasing risks of heavy metals from biochars into the environments. Electron paramagnetic resonance analysis indicated that persistent free radicals, emerged strongly in the biochars as a function of the aromatization of biomass feedstocks, were free from the influence of water-, acid-, or organic-washing of the biochars and could remain stable even after aged in soils for 30 days. Dissolved biochars, highly produced during pyrolysis processes, showed distinct properties including lower molecular weight distribution while higher aromaticity compared with soil dissolved organic carbon.The results of this study provide important perspectives on the safe usage of biochars as agricultural/environmental amendments. 相似文献
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Anaerobic acidogenic fermentation with high-solid sludge is a promising method for volatile fatty acid (VFA) production to realize resource recovery. In this study, to model inhibition by free ammonia in high-solid sludge fermentation, the anaerobic digestion model No. 1 (ADM1) was modified to simulate the VFA generation in batch, semi-continuous and full scale sludge. The ADM1 was operated on the platform AQUASIM 2.0. Three kinds of inhibition forms, e.g., simple inhibition, Monod and non-inhibition forms, were integrated into the ADM1 and tested with the real experimental data for batch and semi-continuous fermentation, respectively. The improved particle swarm optimization technique was used for kinetic parameter estimation using the software MATLAB 7.0. In the modified ADM1, the Ks of acetate is 0.025, the km,ac is 12.51, and the KI_NH3 is 0.02, respectively. The results showed that the simple inhibition model could simulate the VFA generation accurately while the Monod model was the better inhibition kinetics form in semi-continuous fermentation at pH 10.0. Finally, the modified ADM1 could successfully describe the VFA generation and ammonia accumulation in a 30 m3 full-scale sludge fermentation reactor, indicating that the developed model can be applicable in high-solid sludge anaerobic fermentation. 相似文献
18.
Guoying Wang Shiming Ji Xiuli Niu Haoqi Tian Yanrong Liu Zhong Xie Chao Liu Yucan Dong Ying Su Jianglei Yu Gaofeng Shi Xuefu Chen Lan Li Peng Zhang 《环境科学学报(英文版)》2019,31(7):205-213
Atmospheric particulate pollution in China has attracted much public attention. Occasionally, the particle number concentration increases sharply in a short time period, which is defined as a “particulate matter explosive increase”. Heavy particulate matter pollution not only reduces visibility but also has an adverse effect on human health. Hence, there is an urgent need to discover the causes of particulate matter explosive increase. During this campaign, the particle number concentration and free radicals were measured at a tall building on the campus of Lanzhou University of Technology. Additionally, we examined a series of chemicals to reproduce the observed particulate matter explosive increase in a smog chamber to determine its potential factors. Then, we analyzed the mechanism of particulate matter explosive increase in the presence of free radicals. We found that, among the potential inorganic and organic sources analyzed, a mixture of organic and SO2 in the research region had a major effect on particulate matter explosive increase. Moreover, free radical oxidation has a large effect, especially in the formation of organic particulates. 相似文献
19.
Tropospheric ozone(O_3) is a major air pollutant and causes serious injury to vegetation. To protect sensitive plants from O_3 damage, several agrochemicals have been assessed,including cytokinin(e.g., kinetin, KIN) and ethylenediurea(EDU) with cytokinin-like activity.In higher plant, leaves are primarily injured by O_3 and protective agrochemicals are often applied by leaf spraying. To our knowledge, the mitigating abilities of EDU and KIN have not been compared directly in a realistic setup. In the present research, impacts of elevated O3(2 × ambient O_3, 24 hr per day, for 8 days) on an O_3 sensitive line(S156) of snap bean(Phaseolus vulgaris), which is often used for biomonitoring O_3 pollution, were studied in a free air controlled exposure system. The day before starting the O_3 exposure, plants were sprayed with a solution of EDU(300 ppm), KIN(1 mmol/L) or distilled water, to compare their protective abilities. The results demonstrated that 2 × ambient O_3 inhibited net photosynthetic rate and stomatal conductance, increased the minimal fluorescence yield of the dark-adapted state, decreased the maximal quantum yield of PSII photochemistry, and led to visible injury. KIN and EDU alleviated the reduction of the photosynthetic performance, and visible injury under O_3 fumigation. The plants sprayed with EDU showed greater ability to mitigate the O_3 damage than those sprayed with KIN. Chlorophyll fluorescence imaging may have detected more precisely the differences in O_3 response across the leaf than the conventional fluorometer. 相似文献
20.
Zhaoming Zheng Jun LiJing M Jia DuFan Wang Wei BianYanzhuo Zhang Baihang Zhao 《环境科学学报(英文版)》2017,29(3):60-67
The aim of the present work was to evaluate the anaerobic ammonium oxidation (anammox) activity of simultaneous partial nitrification, anammox and denitrification (SNAD) biofilm with different substrate concentrations and pH values. Kaldnes rings taken from the SNAD biofilm reactor were incubated in batch tests to determine the anammox activity. Haldane model was applied to investigate the ammonium inhibition on anammox process. As for nitrite inhibition, the NH4+-N removal rate of anammox process remained 87.4% of the maximum rate with the NO2−-N concentration of 100 mg/L. Based on the results of Haldane model, no obvious difference in kinetic coefficients was observed under high or low free ammonia (FA) conditions, indicating that ammonium rather than FA was the true inhibitor for anammox process of SNAD biofilm. With the pH value of 7.0, the rmax, Ks and KI of ammonium were 0.209 kg NO2−-N/kg VSS/day, 9.5 mg/L and 422 mg/L, respectively. The suitable pH ranges for anammox process were 5.0 to 9.0. These results indicate that the SNAD biofilm performs excellent tolerance to adverse conditions. 相似文献