Water quality trends and changing agricultural practices in a midwest U.S. watershed, 1994-2006

Sediment and nutrient concentrations in surface water in agricultural regions are strongly influenced by agricultural activities. In the Corn Belt, recent changes in farm management practices are likely to affect water quality, yet there are few data on these linkages at the landscape scale. We report on trends in concentrations of N as ammonium (NH(4)) and nitrate (NO(3)), soluble reactive phosphorus (SRP), and suspended sediment (SS) in three Corn Belt streams with drainage areas of 12 to 129 km(2) for 1994 through 2006. During this period, there has been an increase in conservation tillage, a decline in fertilizer use, and consolidation of animal feeding operations in our study watersheds and throughout the Corn Belt. We use an autoregressive moving average model to include the effects of discharge and season on concentrations, LOWESS plots, and analyses of changes in the relation between discharge and concentration. We found significant declines in mean monthly concentrations of NH(4) at all three streams over the 13-yr period, declines in SRP and SS in two of the three streams, and a decline in NO(3) in one stream. When trend coefficients are converted to percent per year and weighted by drainage, area changes in concentration are -8.5% for NH(4), -5.9% for SRP, -6.8% for SS, and -0.8% for NO(3). Trends in total N and P are strongly tied to trends in NO(3), SRP, and SS and indicate that total P is declining, whereas total N is not.     

Tillage and nutrient source effects on surface and subsurface water quality at corn planting

This study quantified the effects of tillage (moldboard plowing [MP], ridge tillage [RT]) and nutrient source (manure and commercial fertilizer [urea and triple superphosphate]) on sediment, NH4+ -N, NO3- -N, total P, particulate P, and soluble P losses in surface runoff and subsurface tile drainage from a clay loam soil. Treatment effects were evaluated using simulated rainfall immediately after corn (Zea mays L.) planting, the most vulnerable period for soil erosion and water quality degradation. Sediment, total P, soluble P, and NH4+ -N losses mainly occurred in surface runoff. The NO3- -N losses primarily occurred in subsurface tile drainage. In combined (surface and subsurface) flow, the MP treatment resulted in nearly two times greater sediment loss than RT (P < 0.01). Ridge tillage with urea lost at least 11 times more NH4+ -N than any other treatment (P < 0.01). Ridge tillage with manure also had the most total and soluble P losses of all treatments (P < 0.01). If all water quality parameters were equally important, then moldboard plow with manure would result in least water quality degradation of the combined flow followed by moldboard plow with urea or ridge tillage with urea (equivalent losses) and ridge tillage with manure. Tillage systems that do not incorporate surface residue and amendments appear to be more vulnerable to soluble nutrient losses mainly in surface runoff but also in subsurface drainage (due to macropore flow). Tillage systems that thoroughly mix residue and amendments in surface soil appear to be more prone to sediment and sediment-associated nutrient (particulate P) losses via surface runoff.     

Phosphorus losses through agricultural tile drainage in Nova Scotia, Canada

Tile drainage water from agricultural fields commonly exceeds environmental guidelines for phosphorus (P) in rivers and streams. The loss of P through artificial drainage is spatially and temporally variable, and is related to local factors. This study characterizes variability in total P (TP) and soluble reactive P (SRP) concentrations in weekly drainage samples from 39 agricultural fields in Nova Scotia, Canada, from April 2002 through December 2003. We examined connections between P concentrations and the factors: (i) soil texture; (ii) discharge flow rate; (iii) soil test P (STP); (iv) manure type; and (v) crop cover. Generally, variability between fields and samples was great, and fields with standard deviations exceeding the mean for TP, SRP, and flow rate were 71, 54, and 79%, respectively. It was evident that poultry and swine manure contributed to high STPs, and to constantly high TP concentrations with high proportions of SRP. Concentrations varied from week to week, and particularly in April, May, October, and November when the greatest TP, SRP, and flow rate averages were measured. Mean TP concentrations exceed the USEPA (1994) TP guideline of 0.10 mg L(-1) at 82% of the fields, and periodically concentrations more than 10 times, and occasionally more than 50 times higher than the guideline were found. The proportion of SRP in TP had a tendency to be higher when TP levels were high in coarse textured soils. In Nova Scotia, dairy manure is most often applied on permanent cover crops, which did not show as much P concentration variability as crop rotations. Daily or hourly observation of short-term increases in P concentrations related to the described factors would help to characterize the changes in P concentrations observed during frequent heavy drainage flow events.     

Variations in stream water and sediment phosphorus among select Ozark catchments

Stream sediments play a large role in the transport and fate of soluble reactive phosphorus (SRP) in stream ecosystems, and equilibrium P concentrations (EPC 0) of benthic sediments at which P is neither adsorbed nor desorbed are often related to stream water SRP concentrations. This study evaluated (i) the variation among water chemistry and sediment-P interactions among streams draining catchments that varied in the land use; (ii) the relations between SRP concentration, sediment EPC 0, and other measured abiotic factors (e.g., particle size distribution, slope of linear sorption isotherms, etc.) in the stream sediments; and (iii) the use of the traditional Mehlich-3 (M3) soil extraction on stream sediments to elucidate other abiotic factors (e.g, M3P, P saturation ratio, etc.) related to SRP concentration in stream sediments. Stream water and sediments were sampled at 22 selected Ozark streams in northwest Arkansas during fall 2003 and spring 2004. Nitrate-N concentrations in the water column (r = 0.69) and modified P saturation ratios (PSR mod) ) of the benthic sediments (r = 0.79) at the selected streams increased with an increase in percent pasture in the catchments, whereas SRP concentration (r = -0.56) and Mehlich-3-extractable P (M3P) content (r = -0.47) decreased with an increase in the percent forested area. Soluble reactive P concentrations in the stream water were positively correlated to sediment EPC 0 (r = 0.51), although sediment EPC(0) was generally greater than SRP. The M3 soil extraction was useful in identifying abiotic factors related to SRP concentrations in the selected streams, in particular SRP concentrations were positively correlated to M3P contents (r = 0.50) and PSR mod (r = 0.71) of the benthic sediments. Thus, M3P and EPC 0 estimates from stream sediments may be valuable yet simple indicators of whether benthic sediments act as sinks or sources of P in fluvial systems, as well as estimating changes in stream SRP concentrations.     

Using the soil and water assessment tool to estimate achievable water quality targets through implementation of beneficial management practices in an agricultural watershed

Runoff from crop production in agricultural watersheds can cause widespread soil loss and degradation of surface water quality. Beneficial management practices (BMPs) for soil conservation are often implemented as remedial measures because BMPs can reduce soil erosion and improve water quality. However, the efficacy of BMPs may be unknown because it can be affected by many factors, such as farming practices, land-use, soil type, topography, and climatic conditions. As such, it is difficult to estimate the impacts of BMPs on water quality through field experiments alone. In this research, the Soil and Water Assessment Tool was used to estimate achievable performance targets of water quality indicators (sediment and soluble P loadings) after implementation of combinations of selected BMPs in the Black Brook Watershed in northwestern New Brunswick, Canada. Four commonly used BMPs (flow diversion terraces [FDTs], fertilizer reductions, tillage methods, and crop rotations), were considered individually and in different combinations. At the watershed level, the best achievable sediment loading was 1.9 t ha(-1) yr(-1) (89% reduction compared with default scenario), with a BMP combination of crop rotation, FDT, and no-till. The best achievable soluble P loading was 0.5 kg ha(-1) yr(-1) (62% reduction), with a BMP combination of crop rotation and FDT and fertilizer reduction. Targets estimated through nonpoint source water quality modeling can be used to evaluate BMP implementation initiatives and provide milestones for the rehabilitation of streams and rivers in agricultural regions.     

Phosphorus loss to runoff water twenty-four hours after application of liquid swine manure or fertilizer

Phosphorus (P) added to soil from fertilizer or manure application could pose a threat to water quality due to its role in eutrophication of fresh water resources. Incorporating such amendments into the soil is an established best management practice (BMP) for reducing soluble P losses in runoff water, but could also lead to higher erosion. The objective of this study was to test whether incorporation of manure or fertilizer 24 h before an intense rain could also reduce sediment-bound and total phosphorus (TP) losses in runoff. A rainfall simulation study was conducted on field plots (sandy loam with 6-7% slope, little surface residue, recently cultivated) that received two application rates of liquid swine manure or liquid ammonium polyphosphate fertilizer, using either surface-broadcast or incorporated methods of application. Incorporation increased the total suspended solids (TSS) concentrations in runoff but mass losses were not affected. Incorporation also reduced flow-weighted concentrations and losses of dissolved reactive phosphorus (DRP) and TP by as much as 30 to 60% depending on source (fertilizer vs. manure) and application rate. Phosphorus is moved below the mixing zone of interaction on incorporation, and thus the effect of the amount and availability of P in this zone is more important than cultivation on subsequent P losses in runoff. Incorporating manure or fertilizer in areas of intense erosive rain, recent extensive tillage, and with little or no surface residue is therefore a best management practice that should be adhered to in order to minimize contamination of surface water. Results also show comparatively lower P losses from manure than fertilizer.     

The effect of flow path and mixing layer on phosphorus release: physical mechanisms and temperature effects

Soil phosphorus (P) concentrations typically are greater in surface soils compared with subsurface soils. Surface soils have a greater chance to interact with runoff leading to P transport to streams. The thin surface layer where P concentrates is referred to as the mixing layer denoting where water and chemicals mix during transport. The objective of this study was to evaluate the effect of hydrologic flow paths on soluble reactive phosphorus (SRP) loss at two temperatures. Laboratory flumes were built to simulate infiltration, return flow, saturation excess, and interflow, and subsequent interaction with the mixing layer. The sandy loam soil in the flumes was kept at saturation throughout all experiments, so that biochemical effects were normalized. Flow through the flumes was maintained at 3.6 mm/h for 24 to 99 h (at 6 and 25 degrees C) with water entering and exiting the flumes at different ports (to simulate different flow paths) or as low intensity rainfall. Experiments were performed with and without an artificially created P-enriched surface layer (5 mm thick, total P increased from 1010 mg/kg in the original soil to 2310 mg/kg by addition of dissolved phosphate). Results indicated that (i) SRP release was greater in soil with a mixing layer than in soil without a mixing layer; (ii) SRP release was greater during experiments at 25 degrees C than at 6 degrees C; (iii) at 25 degrees C, SRP release was greatest when water traversed the mixing layer in the upward direction (i.e., in return flow), and by flow parallel to the mixing layer (i.e., surface runoff); and (iv) at 6 degrees C, SRP release in subsurface flow following rainfall was slightly greater than in return flow and infiltration. Our results confirmed the presence of a variable, temperature-dependent desorption process when runoff water interacted with the mixing layer. Our findings have important implications for how different water flow paths in and over the soil interact with P in the soil, and what the ultimate concentration will be in runoff and interflow.     

Development of a phosphorus index for pastures fertilized with poultry litter--factors affecting phosphorus runoff

Currently, several state and federal agencies are proposing upper limits on soil test phosphorus (P), above which animal manures cannot be applied, based on the assumption that high P concentrations in runoff are due to high soil test P. Recent studies show that other factors are more indicative of P concentrations in runoff from areas where manure is being applied. The original P index was developed as an alternative P management tool incorporating factors affecting both the source and transport of P. The objective of this research was to evaluate the effects of multiple variables on P concentrations in runoff water and to construct a P source component of a P index for pastures that incorporates these effects. The evaluated variables were: (i) soil test P, (ii) soluble P in poultry litter, (iii) P in poultry diets, (iv) fertilizer type, and (v) poultry litter application rate. Field studies with simulated rainfall showed that P runoff was affected by the amount of soluble P applied in the fertilizer source. Before manure applications, soil test P was directly related to soluble P concentrations in runoff water. However, soil test P had little effect on P runoff after animal manure was applied. Unlike most other P indices, weighting factors of the P source components in the P index for pastures are based on results from runoff studies conducted under various management scenarios. As a result, weighting factors for the P source potential variables are well justified. A modification of the P index using scientific data should strengthen the ability of the P index concept to evaluate locations and management alternatives for P losses.     

Associated release of magnesium and phosphorus from active and abandoned dairy soils

Dairy manure application to soils can result in phosphorus (P)-related degradation of water quality. The P in these manure-impacted soils can be labile even years after abandonment and under conditions normally associated with high P stability. Failure of P to stabilize with time compounds the environmental consequences of dairy manure disposal, especially on sandy soils. The objectives of this study were to compare chemical characteristics of active and abandoned dairy manure-impacted soils and minimally impacted soils and to assess the continuous release of P in relation to sparingly soluble salts using repeated water extractions, X-ray diffraction, and speciation modeling of column leachates. Soil samples from Ap horizons were collected from nine highly manure-impacted (total P > 1000 mg P kg(-1) soil) areas on four active and five abandoned dairies and four minimally impacted soils (total P < 200 mg P kg(-1) soil). Soil extracts were analyzed for electrical conductivity (EC), soluble reactive phosphorus (SRP), Ca, Mg, Na, and K. The EC of the soil solutions decreased as active dairy > abandoned dairy > minimally impacted soils. Release of Mg and SRP were significantly correlated (r2 = 0.68) and did not decline after abandonment; Ca release was not correlated with SRP (r2 = 0.01), and declined significantly (p < 0.05) after abandonment. Speciation data from column leachates suggested that Mg-P phases and/or the most soluble Ca-P phases could control P solution activities. An implication of this study is that P stabilization via crystallization of calcium phosphates (even at near-neutral pH) may be preempted by Mg-P association. Thus, mechanisms to minimize P release may require P-retaining soil amendments or management of animal rations to eliminate Mg-P formation.     

Spatial Considerations in Wet and Dry Periods for Phosphorus in Streams of the Fort Cobb Watershed,United States

The Fort Cobb Watershed in Oklahoma has diverse biogeophysical settings and provides an opportunity to explore the association of water quality with a diverse set of landscapes during both wet (April 2007‐December 2009) and dry (January 2005‐March 2007) periods. The objective of this work was to identify spatial patterns in phosphorus (P) (soluble reactive P [SRP] and bioavailable P [BAP]) associated with landscape metrics for two distinct streamflow regimes. Spatial autocorrelation of P was evaluated using contiguous (side‐by‐side) and upstream (upstream:downstream) connectivity matrices. Biogeophysical metrics were compiled for each contributing area, and were partitioned based on association to P concentrations. Results for both SRP and BAP indicated that spatial autocorrelation was present (p < 0.05). There was more spatial autocorrelation and stream P concentrations were three to five times higher in the Wet phase than in the Dry phase (p < 0.05). Analysis with recursive partitioning resulted in higher R² with spatial autocorrelation than without spatial autocorrelation and indicated that lateral metrics (topography, soil, geology, management) were better predictors for SRP than instream metrics. During Wet phase, lateral metrics indicative of rapid surface and subsurface water movement were associated with higher P stream concentrations. This research demonstrated that we can detect landscapes more vulnerable to P losses and/or contaminations in either drought or very wet periods.     

Increase in phosphorus losses from grassland in response to Olsen-P accumulation

The Olsen-P status of grazed grassland (Lolium perenne L.) swards in Northern Ireland was increased over a 5-yr period (March 2000 to February 2005) by applying different rates of P fertilizer (0, 10, 20, 40, or 80 kg P ha(-1) yr(-1)) to assess the relationship between soil P status and P losses in land drainage water and overland flow. Plots (0.2 ha) were hydrologically isolated and artificially drained to v-notch weirs, with flow proportional monitoring of drainage water and overland flow. Annually, the collectors for overland flow intercepted between 11 and 35% of the surplus rainfall. Single flow events accounted for up to 52% of the annual dissolved reactive phosphorus (DRP) load. The Olsen-P status of the soil influenced DRP and total phosphorus (TP) concentrations in land drainage water and overland flow. Annual TP loss was highly variable and ranged from 0.19 to 1.55 kg P ha(-1) yr(-1) for the plot receiving no P fertilizer and from 0.35 to 2.94 kg P ha(-1) yr(-1) for the plot receiving 80 kg P ha(-1) yr(-1). Despite the Olsen-P status in the soils ranging from 22 to 99 mg P kg(-1), after 5 yr of fertilizer P applications it was difficult to identify a clear Olsen-P concentration at which P losses increased. Any relationship was confounded by annual variability of hydrologic events and flows and by hydrologic differences between plots. Withholding P fertilizer for over 5 yr was not long enough to lower P losses or to have an adverse effect on herbage P concentrations.     

Halting the upward trend in soluble phosphorus transported from a grassland catchment

An upward trend in soluble reactive phosphorus (SRP) concentrations in Northern Ireland rivers leading to increased eutrophication has been reported for the last two decades. To identify if a similar trend could be observed in land drainage waters SRP and other P fractions were measured weekly from 1989 to 1997 in land drainage from a 9-ha grassland catchment in Northern Ireland that had a mean P surplus applied of 23.4 kg P ha(-1) yr(-1). Regressions of annual median concentrations of P fractions in land drainage waters against time for 1989 through to 1997 showed significant increases of SRP and soluble unreactive phosphorus (SUP) of 2.4 and 1.2 microg P L(-1) yr(-1), respectively. However, the annual flow-weighted concentrations and loads of all P fractions did not show significant increases with time. During the period 1998-2000 a change of management was introduced when only maintenance dressings of P were applied to the catchment according to Ministry of Agriculture, Fisheries and Food guidelines. This resulted in significant reductions in SRP concentrations in 2000 compared with 1997.     

SURFACE WATER QUALITY IMPACTS OF TILLAGE PRACTICES UNDER LIQUID SWINE MANIJRE APPLICATION1

ABSTRACT: Field studies were conducted to investigate the effects of tillage practices on the saturated hydraulic conductivity, and quantity and quality of surface runoff water resulting from the application of the liquid swine manure as a fertilizer. As part of the study, infiltration experiments were conducted on silt-loam soil with no-tillage (NT) and disk tillage (DT) practices. Liquid swine manure was applied on test plots, and the rainfall was applied by the portable rainfall simulator. The infiltration data was analyzed for the saturated hydraulic conductivity (K8) and runoff volume determinations. The surface runoff water was analyzed for total N, total P, ammonia, and nitrate concentration determinations. The study indicated that the tillage had significant effects on K_s, and quantity and quality of runoff water. The K_s values of the NT plots were found to vary from 0.693 to 1.734 mm/min, with a mean of 1.494 mm/min, while they varied from 1.056 to 2.543 mm/min, with a mean of 2231 mm/mm in the DT plots. The total N, total P, ammonium nitrogen and nitrate nitrogen concentrations were lower in runoff generated from DT plots, compared to that from the NT plots. The chemical concentration levels were significantly different in runoff waters collected one-day after manure application than in those collected 40-days after the manure application. Study suggested that the DT practice must be preferred over the NT practice if liquid swine manure is used as the fertilizer. The study is further continued to assess the long-term impacts of swine manure application and tillage on the quantity and quality of surface runoff water.     

Herbicide and nutrient transport from an irrigation district into the South Saskatchewan River

Pesticides and nutrients can be transported from treated agricultural land in irrigation runoff and thus can affect the quality of receiving waters. A 3-yr study was carried out to assess possible detrimental effects on the downstream water quality of the South Saskatchewan River due to herbicide and plant nutrient inputs via drainage water from an irrigation district. Automated water samplers and flow monitors were used to intensively sample the drainage water and to monitor daily flows in two major drainage ditches, which drained approximately 40% of the flood-irrigated land within the irrigation district. Over three years, there were no detectable inputs of ethalfluralin into the river and those of trifluralin were less than 0.002% of the amount applied to flood-irrigated fields. Inputs of MCPA, bromoxynil, dicamba and mecoprop were 0.06% or less of the amounts applied, whereas that for clopyralid was 0.31%. The relatively higher input (1.4%) of 2,4-D to the river was probably due its presence in the irrigation water. Corresponding inputs of P (as total P) and N (as nitrate plus ammonia) were 2.2 and 1.9% of applied fertilizer, respectively. Due to dilution of the drainage water in the river, maximum daily herbicide (with the exception of 2,4-D) and nutrient loadings to the river would not have resulted in significant concentration increases in the river water. There was no consistent remedial effect on herbicides entering the river due to passage of the drainage water through a natural wetland. In contrast, a considerable portion of the nutrients entering the river originated from the wetland.     

Efficacy of natural wetlands to retain nutrient, sediment and microbial pollutants

Wetlands can improve water quality through natural processes including sedimentation, nutrient transformations, and microbial and plant uptake. Tailwater from irrigated pastures may contribute to nonpoint source water pollution in the form of sediments, nutrients, and pathogens that degrade downstream water quality. We examined benefits to water quality provided by a natural, flow-through wetland and a degraded, channelized wetland situated within the flood-irrigation agricultural landscape of the Sierra Nevada foothills of Northern California. The non-degraded, reference wetland significantly improved water quality by reducing loads of total suspended sediments, nitrate, and Escherichia coli on average by 77, 60, and 68%, respectively. Retention of total N, total P, and soluble reactive P (SRP) was between 35 and 42% of loads entering the reference wetland. Retention of pollutant loads by the channelized wetland was significantly lower than by the reference wetland for all pollutants except SRP. A net export of sediment and nitrate was observed from the channelized wetland. Decreased irrigation inflow rates significantly improved retention efficiencies for nitrate, E. coli, and sediments in the reference wetland. We suggest that maintenance of these natural wetlands and regulation of inflow rates can be important aspects of a best management plan to improve water quality as water runs off of irrigated pastures.     

Phosphorus losses from agricultural areas in river basins: effects and uncertainties of targeted mitigation measures

In this paper we show the quantitative and relative importance of phosphorus (P) losses from agricultural areas within European river basins and demonstrate the importance of P pathways, linking agricultural source areas to surface water at different scales. Agricultural P losses are increasingly important for the P concentration in most European rivers, lakes, and estuaries, even though the quantity of P lost from agricultural areas in European catchments varies at least one order of magnitude (<0.2 kg P ha(-1) to >2.1 kg P ha(-1)). We focus on the importance of P for the implementation of the EU Water Framework Directive and discuss the benefits, uncertainties, and side effects of the different targeted mitigation measures that can be adopted to combat P losses from agricultural areas in river basins. Experimental evidence of the effects of some of the main targeted mitigation measures hitherto implemented is demonstrated, including: (i) soil tillage changes, (ii) treatment of soils near ditches and streams with iron to reduce P transport from source areas to surface waters, (iii) establishment of buffer zones for retaining P from surface runoff, (iv) restoration of river-floodplain systems to allow natural inundation of riparian areas and deposition of P, and (v) inundation of riparian areas with tile drainage water for P retention. Furthermore, we show how river basin managers can map and analyze the extent and importance of P risk areas, exemplified by four catchments differing in size in Norway, Denmark, and the Netherlands. Finally, we discuss the factors and mechanisms that may delay and/or counteract the responses of mitigation measures for combating P losses from agricultural areas when monitored at the catchment scale.     

EFFECTS OF SLUDGE AND CHEMICAL FERTILIZER APPLICATION ON RUNOFF WATER QUALITY1

ABSTRACT: Simulated rainfall was used on experimental field plots to compare the effect of chemical fertilizer and sludge application on sediment, nitrogen, and phosphorus in runoff from no-till and conventional tillage systems. Chemical fertilizer application under the no-till system resulted in the least amount of total N and P in surface runoff. However, sludge application under the no-till system resulted in the least amount of NO₃-N and sediment in surface runoff. The worst water quality scenarios were observed when either sludge or chemical fertilizer were surface-applied under a conventional tillage system. Nitrogen losses from the conventional tillage system were minimized when sludge was incorporated into the soil. However, phosphorus and sediment yield from such a system were significantly higher when compared to phosphorus and sediment yield from the no-till system. The results from this study indicate that the use of sludge on agricultural land under a no-till system can be a viable alternative to chemical fertilizer for nitrogen and phosphorus control in runoff. A more cautious approach is recommended when the sludge is incorporated into the soil in a conventional tillage system because of potential for high sediment and phosphorus yield in surface runoff.     

Phosphorus transport through subsurface drainage and surface runoff from a flat watershed in east central Illinois, USA

A long-term water quality monitoring program was established to evaluate the effects of agricultural management practices on water quality in the Little Vermilion River (LVR) watershed, IL. This watershed has intensive random and irregular subsurface drainage systems. The objective of this study was to assess the fate and transport of soluble phosphorus (soluble P) through subsurface drainage and surface runoff. Four sites (sites A, B, C, and E) that had subsurface and surface monitoring programs were selected for this study. Three of the four study sites had corn (Zea mays L.) and soybeans (Glycine max L.) planted in rotations and the other site had seed corn and soybeans. Subsurface drainage and surface runoff across all sites removed an average of 16.1 and 2.6% of rainfall, respectively. Annual flow-weighted soluble P concentrations fluctuated with the precipitation, while concentrations tended to increase with high precipitation coupled with high application rates. The long-term average flow-weighted soluble P concentrations in subsurface flow were 102, 99, 194, and 86 microg L(-1) for sites A, B, C, and E, respectively. In contrast, the long-term average flow-weighted soluble P concentrations in surface runoff were 270, 253, 534, and 572 microg L(-1) for sites As, Bs, Cs, and Es, respectively. These values were substantially greater than the critical values that promote eutrophication. Statistical analysis indicated that the effects of crop, discharge, and the interactions between site and discharge and crop and discharge on soluble P concentrations in subsurface flow were significant (alpha = 0.05). Soluble P mass loads in surface runoff responded to discharge more consistently than in the subsurface flow. Subsurface flow had substantially greater annual average soluble P mass loads than surface runoff due to greater flow volume.     

Phosphorus release from a biosolids-amended sandy spodosol

Most regulations governing biosolids land application do not consider that phosphorus (P) solubility can vary widely among biosolids. Current regulations typically group all biosolids together in one category or group biosolids together with manures. Research has shown that not all biosolids have the same potential to affect the environment when land applied, but the database is limited. The purpose of this study was to characterize P release from several biosolids produced and/or marketed in Florida. A small soil column dynamic laboratory incubation was conducted to assess P release potential. Eleven biosolids and a mineral fertilizer (triple super phosphate) were individually mixed with a typical low-P sorbing Florida soil (Immokalee fine sand) at 56 and 224 kg P ha(-1). Columns were periodically leached over 5.5 mo to attain 60 mL (1/2 pore volume) of drainage in each leaching. Soluble reactive P was determined and summed over the eight leachings to represent total P source release. Cumulative P release (as a percentage of P applied) was greatest from biological P removal (BPR) and BPR-like biosolids and least from heat-dried materials. Phosphorus release from biosolids depends on biosolids treatment type (digestion) and P chemistry, suggesting that biosolids regulations must account for differences in P lability to accurately gauge environmental risk.     

Soils, water quality, and watershed size: interactions in the Maumee and Sandusky river basins of northwestern Ohio

Soil variability in watersheds accounts for the problem of partitioning downstream water quality data and evaluating sources of non-point pollution. This review of previous water quality studies was conducted to examine more closely the influence of soil properties on pollutant export. The approach used in this paper was to start with data from the two largest watersheds (Maumee and Sandusky) and then compare them on a unit area export basis with data from intermediate-size and smaller watersheds. General relationships between pollutant levels at the river mouth and upstream soil conditions are vague and seemingly contradictory at the large-watershed scale. With smaller watersheds, it can be determined that soil texture, slope, and internal drainage are controlling factors for pollutant export. Although Paulding (very-fine, illitic, nonacid, mesic Typic Epiaquept) and Roselms (very-fine, illitic, mesic Aeric Epiaqualf) soils occupy only 5% of the Maumee basin, they generate more than 10 times as much sediment per unit area as the tile-drained Hoytville (fine, illitic, mesic Mollic Epiaqualf) soils that occupy 16% of the Maumee basin. Tile drainage of very poorly drained soils that are formed from either glacial till or silty to sandy lake deposits reduces runoff and increases downward movement of soluble nutrients into tile drains. The assumption that sloping moraine areas are the primary source of pollutants should be reexamined based on this review.