Phosphorus budgets and riverine phosphorus export in northwestern Ohio watersheds

Phosphorus (P) budgets for large watersheds are often used to predict trends in riverine P export. To test such predictions, we calculated annual P budgets for 1975-1995 for soils of the Maumee and Sandusky watersheds of northwestern Ohio and compared them with riverine P export from these watersheds. Phosphorus inputs to the soils include fertilizers, manure, rainfall, and sludge while outputs include crop removal and nonpoint-source export via rivers. Annual P inputs decreased due to reductions in fertilizer and manure inputs. Annual outputs increased due to increasing crop yields. Net P accumulation decreased from peak values of 13.4 and 9.5 kg P ha(-1) yr(-1) to 3.7 and 2.6 kg P ha(-1) yr(-1) for the Maumee and Sandusky watersheds, respectively. Thus, P budget analysis suggests that riverine P export should have increased throughout the study period, with smaller increases during more recent years. However, detailed water quality studies show that riverine export of total phosphorus (TP) has decreased by 25 to 40% and soluble reactive phosphorus (SRP) by 60 to 89%, both due primarily to decreases from nonpoint sources. We suggest that these decreases are associated with farmers' adoption of practices that minimize transport of recently applied P fertilizer and of sediments via surface runoff, coupled with changes in winter weather conditions. In comparison with most Midwestern watersheds, rivers draining these watersheds have high unit area yields of TP, low unit area yields of SRP, and high ratios of nonpoint source- to point source-derived P.     

Pesticide risk reduction on crops in the Province of Ontario

We analyzed the changes in pesticide use and risk in the Province of Ontario, Canada, from 1973 to 1998 to monitor the success of Food Systems 2002, a program to reduce pesticide use by 50%. Pesticide risk was calculated by multiplying the amount of pesticide used (kilograms of active ingredient) by the Environmental Impact Quotient (EIQ), a score for the potential risk of pesticides to farmworkers, consumers, and the environment. Pesticide use increased by 46% from 1973 to 1983. From 1983, the baseline year for Food Systems 2002, to 1998, pesticide use decreased by 38.5% and risk declined 39.5%. The reductions in pesticide use and risk were primarily on corn (Zea mays L.) and tobacco (Nicotiana tabacum L.), the crops with the highest pesticide use in 1983. Total pesticide use on soybean [Glycine max (L.) Merr.] did not change, but the mean application rate (kg ha(-1)) decreased by 57%. Corn and soybean account for 65% of pesticide use, but have a relatively low pesticide use and risk per hectare and per tonne of production. Total pesticide use on tobacco, fruits, and vegetables was lower than on corn or soybean, but the pesticide use and risk per hectare were much higher. Small reductions in pesticide use on corn and soybean may allow a 50% reduction in pesticide use, but greater reductions in risk can be achieved by reducing the use of "high risk" pesticides on fruit and vegetables.     

Evaluating agricultural nonpoint-source pollution programs in two Lake Erie tributaries

During the past three decades, numerous government programs have encouraged Lake Erie basin farmers to adopt practices that reduce water pollution. The first section of this paper summarizes these state and federal government agricultural pollution abatement programs in watersheds of two prominent Lake Erie tributaries, the Maumee River and Sandusky River. Expenditures are summarized for each program, total expenditures in each county are estimated, and cost effectiveness of program expenditures (i.e., cost per metric ton of soil saved) are analyzed. Farmers received nearly $143 million as incentive payments to implement agricultural nonpoint source pollution abatement programs in the Maumee and Sandusky River watersheds from 1987 to 1997. About 95% of these funds was from federal sources. On average, these payments totaled about $7000 per farm or about $30 per farm acre (annualized equivalent of $2 per acre) within the watersheds. Our analysis raises questions about how efficiently these incentive payments were allocated. The majority of Agricultural Conservation Program (ACP) funds appear to have been spent on less cost-effective practices. Also, geographic areas with relatively low (high) soil erosion rates received relatively large (small) funding.     

Climatic and agricultural factors in nutrient exports from two watersheds in Ohio

Export of agricultural nutrients and sediment to lakes and oceans is of great environmental concern in many agricultural watersheds. Recent years have seen efforts to reduce loads through agricultural practices such as conservation tillage, efficient fertilization, and reservation of erodible areas. Monitoring the efficacy of such efforts is complicated by the fact they take place against a varying climatic and hydrologic background. In this study, statistical analysis was used to identify those climatic, hydrologic, and agricultural variables that best explained variations in nitrate, phosphorus, and total suspended solids over the period 1976-1995 in two large agricultural watersheds that feed Lake Erie, those of the Maumee and Sandusky Rivers. The dominant variable was stream discharge; after curvefits to remove its influence, the residual loads were tested via stepwise linear regression to reveal the most significant explanatory variables. Loads of nitrate, total suspended solids, and total phosphorus tended to decrease when previous months were wet, except in the summer, and to decrease when snow cover was extensive. It is speculated that stores of nitrate in the soil were lost during wet periods through increased crop uptake and/or leaching. Nitrogen fertilizer application in the Maumee watershed decreased following dry periods, but not enough to decrease stream loads. Soluble reactive phosphorus loads were negatively correlated to conservation tillage and reserves, and positively correlated to fertilizer and manure sources. Results for total phosphorus were similar to those for total suspended solids, on which most transported phosphorus is adsorbed.     

Climatic and agricultural contributions to changing loads in two watersheds in Ohio

Trends in climatic variables, streamflow, agricultural practices, and loads of nutrients and suspended solids were estimated for 1976-1995 in the Maumee and Sandusky watersheds, two large agricultural basins draining to Lake Erie. To understand the contributions that various factors may have made to the trends in loads, earlier results of models linking loads to explanatory variables were combined with estimated trends in those variables. The study period was characterized by increases in temperature, wintertime precipitation and streamflow, conservation farming, and loads of nitrate and total suspended solids; decreases in snowfall and snow cover, fertilizer, manure from livestock, and loads of soluble reactive phosphorus; and relatively steady exports of total phosphorus. After removing the effects of trends in streamflow, nitrate loads increased much less while total suspended solids and total phosphorus loads declined. The analysis suggests that the nitrate increases were due largely to climatic factors, particularly increases in winter streamflow, decreases in snowfall and snow cover, and declining annual precipitation. Decreases in soluble reactive phosphorus were associated with changes in agricultural practices, particularly declines in fertilizer deliveries and head of livestock.     

Quantifying phosphorus retention and release in rivers and watersheds using extended end-member mixing analysis (E-EMMA)

Extended end-member mixing analysis (E-EMMA) is presented as a novel empirical method for exploring phosphorus (P) retention and release in rivers and watersheds, as an aid to water-quality management. E-EMMA offers a simple and versatile tool that relies solely on routinely measured P concentration and flow data. E-EMMA was applied to two river systems: the Thames (U.K.) and Sandusky River (U.S.), which drain similar watershed areas but have contrasting dominant P sources and hydrology. For both the Thames and Sandusky, P fluxes at the watershed outlets were strongly influenced by processes that retain and cycle P. However, patterns of P retention were markedly different for the two rivers, linked to differences in P sources and speciation, hydrology and land use. On an annual timescale, up to 48% of the P flux was retained for the Sandusky and up to 14% for the Thames. Under ecologically critical low-flow periods, up to 93% of the P flux was retained for the Sandusky and up to 42% for the Thames. In the main River Thames and the Sandusky River, in-stream processes under low flows were capable of regulating the delivery of P and modifying the timing of delivery in a way that may help to reduce ecological impacts to downstream river reaches, by reducing ambient P concentrations at times of greatest river eutrophication risk. The results also suggest that by moving toward cleaner rivers and improved ecosystem health, the efficiency of P retention may actually increase.     

Impact of glyphosate-tolerant soybean and glufosinate-tolerant corn production on herbicide losses in surface runoff

Residual herbicides used in the production of soybean [Glycine max (L.) Merr] and corn (Zea mays L.) are often detected in surface runoff at concentrations exceeding their maximum contaminant levels (MCL) or health advisory levels (HAL). With the advent of transgenic, glyphosate-tolerant soybean and glufosinate-tolerant corn this concern might be reduced by replacing some of the residual herbicides with short half-life, strongly sorbed, contact herbicides. We applied both herbicide types to two chiseled and two no-till watersheds in a 2-yr corn-soybean rotation and at half rates to three disked watersheds in a 3-yr corn/soybean/wheat (Triticum aestivum L.)-red clover (Trifolium pratense L.) rotation and monitored herbicide losses in runoff water for four crop years. In soybean years, average glyphosate loss (0.07%) was approximately 1/7 that of metribuzin (0.48%) and about one-half that of alachlor (0.12%), residual herbicides it can replace. Maximum, annual, flow-weighted concentration of glyphosate (9.2 microg L(-1)) was well below its 700 microg L(-1) MCL and metribuzin (9.5 microg L(-1)) was well below its 200 microg L(-1) HAL, whereas alachlor (44.5 microg L(-1)) was well above its 2 microg L(-1) MCL. In corn years, average glufosinate loss (0.10%) was similar to losses of alachlor (0.07%) and linuron (0.15%), but about one-fourth that of atrazine (0.37%). Maximum, annual, flow-weighted concentration of glufosinate (no MCL) was 3.5 microg L(-1), whereas atrazine (31.5 microg L(-1)) and alachlor (9.8 microg L(-1)) substantially exceeded their MCLs of 3 and 2 microg L(-1), respectively. Regardless of tillage system, flow-weighted atrazine and alachlor concentrations exceeded their MCLs in at least one crop year. Replacing these herbicides with glyphosate and glufosinate can reduce the occurrence of dissolved herbicide concentrations in runoff exceeding drinking water standards.     

Comparative losses of glyphosate and selected residual herbicides in surface runoff from conservation-tilled watersheds planted with corn or soybean

Residual herbicides regularly used in conjunction with conservation tillage to produce corn ( L.) and soybean [ (L.) Merr] are often detected in surface water at concentrations that exceed their U.S. maximum contaminant levels (MCL) and ecological standards. These risks might be reduced by planting glyphosate-tolerant varieties of these crops and totally or partially replacing the residual herbicides alachlor, atrazine, linuron, and metribuzin with glyphosate, a contact herbicide that has a short half-life and is strongly sorbed to soil. Therefore, we applied both herbicide types at typical rates and times to two chisel-plowed and two no-till watersheds in a 2-yr corn/soybean rotation and at half rates to three disked watersheds in a 3-yr corn/soybean/wheat-red clover ( L.- L.) rotation and monitored herbicide losses in surface runoff for three crop years. Average dissolved glyphosate loss for all tillage practices, as a percentage of the amount applied, was significantly less ( ≤ 0.05) than the losses of atrazine (21.4x), alachlor (3.5x), and linuron (8.7x) in corn-crop years. Annual, flow-weighted, concentration of atrazine was as high as 41.3 μg L, much greater than its 3 μg L MCL. Likewise, annual, flow-weighted alachlor concentration (MCL = 2 μg L) was as high as 11.2 and 4.9 μg L in corn- and soybean-crop years, respectively. In only one runoff event during the 18 watershed-years it was applied did glyphosate concentration exceed its 700 μg L MCL and the highest, annual, flow-weighted concentration was 3.9 μg L. Planting glyphosate-tolerant corn and soybean and using glyphosate in lieu of some residual herbicides should reduce the impact of the production of these crops on surface water quality.     

Effects of watershed-scale land use change on stream nitrate concentrations

The Walnut Creek Watershed Monitoring Project was conducted from 1995 through 2005 to evaluate the response of stream nitrate concentrations to changing land use patterns in paired 5000-ha Iowa watersheds. A large portion of the Walnut Creek watershed is being converted from row crop agriculture to native prairie and savanna by the U.S. Fish and Wildlife Service at the Neal Smith National Wildlife Refuge (NSNWR). Before restoration, land use in both Walnut Creek (treatment) and Squaw Creek (control) watersheds consisted of 70% row crops. Between 1990 and 2005, row crop area decreased 25.4% in Walnut Creek due to prairie restoration but increased 9.2% in Squaw Creek due to Conservation Reserve Program (CRP) grassland conversion back to row crop. Nitrate concentrations ranged between <0.5 to 14 mg L(-1) at the Walnut Creek outlet and 2.1 to 15 mg L(-1) at the downstream Squaw Creek outlet. Nitrate concentrations decreased 1.2 mg L(-1) over 10 yr in the Walnut Creek watershed but increased 1.9 mg L(-1) over 10 yr in Squaw Creek. Changes in nitrate were easier to detect and more pronounced in monitored subbasins, decreasing 1.2 to 3.4 mg L(-1) in three Walnut Creek subbasins, but increasing up to 8.0 and 11.6 mg L(-1) in 10 yr in two Squaw Creek subbasins. Converting row crop lands to grass reduced stream nitrate levels over time in Walnut Creek, but stream nitrate rapidly increased in Squaw Creek when CRP grasslands were converted back to row crop. Study results highlight the close association of stream nitrate to land use change and emphasize that grasslands or other perennial vegetation placed in agricultural settings should be part of a long-term solution to water quality problems.     

Nitrate and chloride loading to groundwater from an irrigated north-central U.S. sand-plain vegatable field

Groundwater pollution and associated effects on drinking water have increased with the expansion of irrigated agriculture in north-central U.S. sand plains. Controlling this pollution requires an ability to measure and predict pollutant loading by specific agricultural systems. We measured NO3 and Cl loading to groundwater beneath a Wisconsin central sand plain irrigated vegetable field using both a budget method and a new monitoring-based method. By relying on frequent monitoring of shallow groundwater, the new method overcomes some limitations of other methods. Monitoring-based and budget methods agreed well, and indicated that loading to groundwater was 165 kg ha(-1) NO3-N and 111 kg ha(-1) Cl for sweet corn (Zea mays L.) in 1992, and 228 kg ha(-1) NO3-N and 366 kg ha(-1) Cl for potato (Solanum tuberosum L.) in 1993. Nitrate N loading was 56 to 60% of available N, or 66 to 70% of fertilizer N. Sweet corn NO3 loading was about typical for this region, but potato NO3 loading was probably 50% greater than typical because heavy rains provoked extra fertilizer application. Our results imply that typical NO3-N loading would be 119 kg ha(-1) for sweet corn and 203 kg ha(-1) for potato, even with strict adherence to University Extension fertilizer recommendations. To keep average groundwater NO3-N within the 10 mg L(-1) U.S. drinking water standard, each irrigated vegetable field would need to be offset by five to eight times as much land supplying NO3-free groundwater recharge.     

Tillage system, application rate, and extreme event effects on herbicide losses in surface runoff

Conservation tillage can reduce soil loss; however, the residual herbicides normally used to control weeds are often detected in surface runoff at high levels, particularly if runoff-producing storms occur shortly after application. Therefore, we measured losses of alachlor, atrazine, linuron, and metribuzin from seven small (0.45-0.79-ha) watersheds for 9 yr (1993-2001) to investigate whether a reduced-input system for corn (Zea mays L.) and soybean [Glycine max (L.) Merr.] production with light disking, cultivation, and half-rate herbicide applications could reduce losses compared with chisel and no-till. As a percentage of application, annual losses were highest for all herbicides for no-till and similar for chisel and reduced-input. Atrazine was the most frequently detected herbicide and yearly flow-weighted concentrations exceeded the drinking water standard of 3 microg L(-1) in 20 out of 27 watershed years that it was applied. Averaged for 9 corn yr, yearly flow-weighted atrazine concentrations were 26.3, 9.6, and 8.3 microg L(-1) for no-till, chisel, and reduced-input, respectively. Similarly, flow-weighted concentrations of alachlor exceeded the drinking water standard of 2 microg L(-1) in 23 out of 54 application years and in all treatments. Thus, while banding and half-rate applications as part of a reduced-input management practice reduced herbicide loss, concentrations of some herbicides may still be a concern. For all watersheds, 60 to 99% of herbicide loss was due to the five largest transport events during the 9-yr period. Thus, regardless of tillage practice, a small number of runoff events, usually shortly after herbicide application, dominated herbicide transport.     

EPIC modeling of soil organic carbon sequestration in croplands of Iowa

Depending on management, soil organic carbon (SOC) is a potential source or sink for atmospheric CO(2). We used the EPIC model to study impacts of soil and crop management on SOC in corn (Zea mays L.) and soybean (Glycine max L. Merr.) croplands of Iowa. The National Agricultural Statistics Service crops classification maps were used to identify corn-soybean areas. Soil properties were obtained from a combination of SSURGO and STATSGO databases. Daily weather variables were obtained from first order meteorological stations in Iowa and neighboring states. Data on crop management, fertilizer application and tillage were obtained from publicly available databases maintained by the NRCS, USDA-Economic Research Service (ERS), and Conservation Technology Information Center. The EPIC model accurately simulated state averages of crop yields during 1970-2005 (R(2) = 0.87). Simulated SOC explained 75% of the variation in measured SOC. With current trends in conservation tillage adoption, total stock of SOC (0-20 cm) is predicted to reach 506 Tg by 2019, representing an increase of 28 Tg with respect to 1980. In contrast, when the whole soil profile was considered, EPIC estimated a decrease of SOC stocks with time, from 1835 Tg in 1980 to 1771 Tg in 2019. Hence, soil depth considered for calculations is an important factor that needs further investigation. Soil organic C sequestration rates (0-20 cm) were estimated at 0.50 to 0.63 Mg ha(-1) yr(-1) depending on climate and soil conditions. Overall, combining land use maps with EPIC proved valid for predicting impacts of management practices on SOC. However, more data on spatial and temporal variation in SOC are needed to improve model calibration and validation.     

Examining Landscape Dynamics at a Watershed Scale Using Landsat TM Imagery for Detection of Wintering Hooded Crane Decline in Yashiro,Japan

It is usually inappropriate to define rectangular land areas or administrative units as the extent for quantifying landscapes that possess hierarchical structure. As a functional unit established by geophysical relationships, the watershed is one of many natural scales in the hierarchical landscape. We examined the dynamics of the Yashiro watershed of Japan at the landscape level using pattern metrics based on Landsat thematic mapper (TM) imagery from 1985 to 1998. This watershed provides important habitats for the hooded crane (Grus monachus), a vulnerable species. While its world population has remained stable, the number wintering at Yashiro has declined in recent years. Changes in landscape metrics reveal that the spatial pattern within the watershed underwent homogenization due to depopulation of local people and shifts in local energy requirements and forest management policy at Yashiro. Specific changes include: a decrease in bare land area from 6.2% to 1.0% of the landscape, increased forest cover from 69.2% to 76.1%, reduction in patch number from 1194 to 616 and enlarged mean patch size, and a decrease in total edge from 223,740 m to 158,040 m. The rate of change in landscape metrics indicates a rapid change towards homogeneity in the landscape since 1990. The temporal changes in hooded crane populations corresponded to the changes in landscape. An alternative explanation has been proposed that decline of the species is influenced by landscape dynamics affecting both habitat selection and food resources. Conservation at the watershed scale is suggested to be complementary to the current conservation measures of the species.     

Nitrate-nitrogen losses through subsurface drainage under various agricultural land covers

Nitrate-nitrogen (NO?-N) loading to surface water bodies from subsurface drainage is an environmental concern in the midwestern United States. The objective of this study was to investigate the effect of various land covers on NO?-N loss through subsurface drainage. Land-cover treatments included (i) conventional corn ( L.) (C) and soybean [ (L.) Merr.] (S); (ii) winter rye ( L.) cover crop before corn (rC) and before soybean (rS); (iii) kura clover ( M. Bieb.) as a living mulch for corn (kC); and (iv) perennial forage of orchardgrass ( L.) mixed with clovers (PF). In spring, total N uptake by aboveground biomass of rye in rC, rye in rS, kura clover in kC, and grasses in PF were 14.2, 31.8, 87.0, and 46.3 kg N ha, respectively. Effect of land covers on subsurface drainage was not significant. The NO?-N loss was significantly lower for kC and PF than C and S treatments (p < 0.05); rye cover crop did not reduce NO?-N loss, but NO?-N concentration was significantly reduced in rC during March to June and in rS during July to November (p < 0.05). Moreover, the increase of soil NO?-N from early to late spring in rS was significantly lower than the S treatment (p < 0.05). This study suggests that kC and PF are effective in reducing NO?-N loss, but these systems could lead to concerns relative to grain yield loss and change in farming practices. Management strategies for kC need further study to achieve reasonable corn yield. The effectiveness of rye cover crop on NO-N loss reduction needs further investigation under conditions of different N rates, wider weather patterns, and fall tillage.     

Nitrate loss in subsurface drainage as affected by nitrogen fertilizer rate

The relationships between N fertilizer rate, yield, and NO3 leaching need to be quantified to develop soil and crop management practices that are economically and environmentally sustainable. From 1996 through 1999, we measured yield and NO3 loss from a subsurface drained field in central Iowa at three N fertilizer rates: a low (L) rate of 67 kg ha(-1) in 1996 and 57 kg ha(-1) in 1998, a medium (M) rate of 135 kg ha(-1) in 1996 and 114 kg ha(-1) in 1998, and a high (H) rate of 202 kg ha(-1) in 1996 and 172 kg ha(-1) in 1998. Corn (Zea mays L.) and soybean [Glycine max (L.) Merr.] were grown in rotation with N fertilizer applied in the spring to corn only. For the L treatment, NO3 concentrations in the drainage water exceeded the 10 mg N L(-1) maximum contaminant level (MCL) established by the USEPA for drinking water only during the years that corn was grown. For the M and H treatments, NO3 concentrations exceeded the MCL in all years, regardless of crop grown. For all years, the NO3 mass loss in tile drainage water from the H treatment (48 kg N ha(-1)) was significantly greater than the mass losses from the M (35 kg N ha(-1)) and L (29 kg N ha(-1)) treatments, which were not significantly different. The economically optimum N fertilizer rate for corn was between 67 and 135 kg ha(-1) in 1996 and 114 and 172 kg ha(-1) in 1998, but the net N mass balance indicated that N was being mined from the soil at these N fertilizer levels and that the system would not be sustainable.     

Sources of nitrate yields in the Mississippi River Basin

Riverine nitrate N in the Mississippi River leads to hypoxia in the Gulf of Mexico. Several recent modeling studies estimated major N inputs and suggested source areas that could be targeted for conservation programs. We conducted a similar analysis with more recent and extensive data that demonstrates the importance of hydrology in controlling the percentage of net N inputs (NNI) exported by rivers. The average fraction of annual riverine nitrate N export/NNI ranged from 0.05 for the lower Mississippi subbasin to 0.3 for the upper Mississippi River basin and as high as 1.4 (4.2 in a wet year) for the Embarras River watershed, a mostly tile-drained basin. Intensive corn (Zea mays L.) and soybean [Glycine max (L.) Merr.] watersheds on Mollisols had low NNI values and when combined with riverine N losses suggest a net depletion of soil organic N. We used county-level data to develop a nonlinear model ofN inputs and landscape factors that were related to winter-spring riverine nitrate yields for 153 watersheds within the basin. We found that river runoff times fertilizer N input was the major predictive term, explaining 76% of the variation in the model. Fertilizer inputs were highly correlated with fraction of land area in row crops. Tile drainage explained 17% of the spatial variation in winter-spring nitrate yield, whereas human consumption of N (i.e., sewage effluent) accounted for 7%. Net N inputs were not a good predictor of riverine nitrate N yields, nor were other N balances. We used this model to predict the expected nitrate N yield from each county in the Mississippi River basin; the greatest nitrate N yields corresponded to the highly productive, tile-drained cornbelt from southwest Minnesota across Iowa, Illinois, Indiana, and Ohio. This analysis can be used to guide decisions about where efforts to reduce nitrate N losses can be most effectively targeted to improve local water quality and reduce export to the Gulf of Mexico.     

Simulating nitrate drainage losses from a Walnut Creek watershed field

This study was designed to evaluate the improved version of the Root Zone Water Quality Model (RZWQM) using 6 yr (1992-1997) of field-measured data from a field within Walnut Creek watershed located in central Iowa. Measured data included subsurface drainage flows, NO3-N concentrations and loads in subsurface drainage water, and corn (Zea mays L.) and soybean [Glycine mar (L.) Merr.] yields. The dominant soil within this field was Webster (fine-loamy, mixed, superactive, mesic Typic Endoaquolls) and cropping system was corn-soybean rotation. The model was calibrated with 1992 data and was validated with 1993 to 1997 data. Simulations of subsurface drainage flow closely matched observed data showing model efficiency of 99% (EF = 0.99), and difference (D) of 1% between measured and predicted data. The model simulated NO3-N losses with subsurface drainage water reasonably well with EF = 0.8 and D = 13%. The simulated corn grain yields were in close agreement with measured data with D < 10%. Nitrogen-scenario simulations demonstrated that corn yield response function reached a plateau when N-application rate exceeded 90 kg ha(-1). Fraction of applied N lost with subsurface drainage water varied from 7 to 16% when N-application rate varied from 30 to 180 kg ha(-1) after accounting for the nitrate loss with no-fertilizer application. These results indicate that the RZWQM has the potential to simulate the impact of N application rates on corn yields and NO3-N losses with subsurface drainage flows for agricultural fields in central Iowa.     

Agricultural practices influence flow regimes of headwater streams in western Iowa

Agricultural tillage influences runoff and infiltration, but consequent effects on watershed hydrology are poorly documented. This study evaluated 25 yr (1971-1995) hydrologic records from four first-order watersheds in Iowa's loess hills. Two watersheds were under conventional tillage and two were under conservation (ridge) tillage, one of which was terraced. All four watersheds grew corn (Zea mays L.) every year. Flow-frequency statistics and autoregressive modeling were used to determine how conservation treatments influenced stream hydrology. The autoregressive modeling characterized variations in discharge, baseflow, and runoff at multi-year, annual, and shorter time scales. The ridge-tilled watershed (nonterraced) had 47% less runoff and 36% more baseflow than the conventional watershed of similar landform and slope. Recovery of baseflow after drought was quicker in the conservation watersheds, as evidenced by 365-d moving average plots, and 67% greater baseflow during the driest 2 yr. The two conventional watersheds were similar, except the steeper watershed discharged more runoff and baseflow during short (<30 d), wet periods. Significant multi-year and annual cycles occurred in all variables. Under ridge-till, seasonal (annual-cycle) variations in baseflow had greater amplitude, showing the seasonality of subsurface contaminant movement could increase under conservation practices. However, deviations from the modeled cycles of baseflow were also more persistent under conservation practices, indicating baseflow was more stable. Indeed, flow-frequency curves showed wet-weather discharge decreased and dry-weather discharge increased under conservation practices. Although mean discharge increased in the conservation watersheds, variance and skewness of daily values were smaller. Ridge tillage with or without terraces increased stream discharge but reduced its variability.     

Demonstration of methods to reduce E. coli runoff from dairy manure application sites

Contamination by bacteria is a leading cause of impairment in U.S. waters, particularly in areas of livestock agriculture. We evaluated the effectiveness of several practices in reducing Escherichia coli levels in runoff from fields receiving liquid dairy (Bos taurus) manure. Runoff trials were conducted on replicated hay and silage corn (Zea mays L.) plots using simulated rainfall. Levels of E. coli in runoff were approximately 10(4) to 10(6) organisms per 100 mL, representing a significant pollution potential. Practices tested were: manure storage, delay between manure application and rainfall, manure incorporation by tillage, and increased hayland vegetation height. Storage of manure for 30 d or more consistently and dramatically lowered E. coli counts in our experiments, with longer storage providing greater reductions. Manure E. coli declined by > 99% after approximately 90 d of storage. On average, levels of E. coli in runoff were 97% lower from plots receiving 30-d-old and > 99% lower from plots receiving 90-d-old manure than from plots where fresh manure was applied. Runoff from hayland and cornland plots where manure was applied 3 d before rainfall contained approximately 50% fewer E. coli than did runoff from plots that received manure 1 d before rainfall. Hayland vegetation height alone did not significantly affect E. coli levels in runoff, but interactions with rainfall delay and manure age were observed. Manure incorporation alone did not significantly affect E. coli levels in cornland plot runoff, but incorporation could reduce bacteria export by reducing field runoff and interaction with rainfall delay was observed. Extended storage that avoids additions of fresh manure, combined with application several days before runoff, incorporation on tilled land, and higher vegetation on hayland at application could substantially reduce microorganism loading from agricultural land.     

The myth of nitrogen fertilization for soil carbon sequestration

Intensive use of N fertilizers in modern agriculture is motivated by the economic value of high grain yields and is generally perceived to sequester soil organic C by increasing the input of crop residues. This perception is at odds with a century of soil organic C data reported herein for the Morrow Plots, the world's oldest experimental site under continuous corn (Zea mays L.). After 40 to 50 yr of synthetic fertilization that exceeded grain N removal by 60 to 190%, a net decline occurred in soil C despite increasingly massive residue C incorporation, the decline being more extensive for a corn-soybean (Glycine max L. Merr.) or corn-oats (Avena sativa L.)-hay rotation than for continuous corn and of greater intensity for the profile (0-46 cm) than the surface soil. These findings implicate fertilizer N in promoting the decomposition of crop residues and soil organic matter and are consistent with data from numerous cropping experiments involving synthetic N fertilization in the USA Corn Belt and elsewhere, although not with the interpretation usually provided. There are important implications for soil C sequestration because the yield-based input of fertilizer N has commonly exceeded grain N removal for corn production on fertile soils since the 1960s. To mitigate the ongoing consequences of soil deterioration, atmospheric CO(2) enrichment, and NO(3)(-) pollution of ground and surface waters, N fertilization should be managed by site-specific assessment of soil N availability. Current fertilizer N management practices, if combined with corn stover removal for bioenergy production, exacerbate soil C loss.