高纯超细氧化铝的清洁生产工艺

对硫酸铝铵热分解法生产高纯超细氧化铝的工艺进行了分析，将此过程所产生的废气（含SO3和NH3）进行吸收、中和、浓缩，使其作为生产硫酸铝铵的硫酸铵溶液，减少SO3和NH3的排放，实现了氧化铝的清洁生产。     

一种由含铝矿物制备氧化铝的方法

该专利公开了一种由含铝矿物制备氧化铝的方法。该方法包括：细磨、磁选、酸处理、过滤分离、加热脱水分解和回收SO3等步骤。采用该法制得的高纯度氧化铝,经检测完全符合有色金属冶金行业YS／T274-1998《氧化铝》的标准,产品纯度达到99．5％。该方法的优点：物料全部循环利用、工艺流程简单、设备简便,没有固、液、气废弃物的排放,     

一种利用粉煤灰生产二氧化硅和氧化铝的方法

该专利公开了一种从粉煤灰中提取二氧化硅和氧化铝的方法。其处理方法是：对粉煤灰进行活化处理后，用质量分数大于40％的NaOH溶液浸取，将其中的硅以硅酸钠的形式溶出，通入CO2气体制备SiO2，碱浸渣中配入CaO或CaCO，煅烧成熟料，采用拜尔法制备氧化铝，废渣用于生产水泥。     

聚合氯化铝钙的合成与应用

以氧化铝和碳酸钙为原料制备新型的无机高效水处理剂聚合氯化铝钙,研究了合成条件,确定了最佳的工艺参数。实验表明,升高温度有利于产品的合成,在10g铝酸钙粉末中盐酸加人量为70mL,酸溶时间为3h,焙烧反应中氧化铝与碳酸钙的适宜配比为3：2（质量比）。将合成的产品用于高炉煤气洗涤废水处理中,处理后的水质达到国家的排放标准和该厂的循环使用标准。     

蒽醌法制过氧化氢工艺中废水废料的处理研究

本文对蒽醌法生产过氧化氢工艺中所产生的废氧化铝,废碳酸钾溶液和工作液洗水的处理进行了研究。确定了回收利用与处理的工艺路线。     

废聚苯乙烯泡沫塑料的催化裂解

为了对废聚苯乙烯泡沫塑料（WPS）资源化利用,通过对WPS进行催化裂解的方法,研究了催化剂种类和裂解温度对裂解时间、裂解油产率、苯乙烯回收率以及裂解油纯度的影响。研究结果表明,催化剂种类和裂解温度对裂解反应有着重要影响。裂解温度升高,裂解油产率提高,裂解时间缩短,但苯乙烯选择性下降;低于380 ℃时,氧化钙的裂解油产率和裂解时间优于氧化铝和氯化铝,但苯乙烯的选择性劣于氧化铝和氯化铝;高于400 ℃时,氯化铝、氧化铝和氧化钙的催化活性接近。在实验条件下,WPS催化裂解的最佳催化剂为氯化铝,380 ℃下的裂解时间为25 min,裂解油产率为85.48%,裂解油中苯乙烯含量为80.66%（w）,且副产物较少。     

氧化铝厂赤泥附液湿法脱硫研究

对氧化铝厂赤泥附液吸收净化SO2废气进行了研究.赤泥附液吸收SO2具有吸收效率高、吸收容量大、易控制、操作简便等优点,在较长时间内对SO2的吸收效率保持在99%以上.     

浅谈粉煤灰的资源化利用现状

粉煤灰是电力行业排放的主要固体废弃物,对其的资源化利用已成为环保的首要任务。对粉煤灰进行高附加值的资源化回收利用,是实现可持续发展的必经之路。介绍了大唐国际成功开发研制的从高铝粉煤灰中提取氧化铝技术,开辟了粉煤灰综合利用的新途径。     

“高铝粉煤灰提取氧化铝多联产技术开发与产业示范”科技成果评价会议成功召开

正2017年4月22日,中国循环经济协会在北京市组织召开了由内蒙古大唐国际再生资源开发有限公司等单位完成的"高铝粉煤灰提取氧化铝多联产技术开发与产业示范"项目科技成果评价会议。评价组由中国矿业大学(北京)、北京有色金属研究总院单位的院士、专家组成。工信部节能司、内蒙古自治区经信委、大唐国际内蒙古分公司、大唐国际发电     

以煤矸石为原料合成Y型沸石

煤矸石中的煤系高岭岩，可用来生产氧化铝、氢氧化铝及硫酸铝、白炭黑等。而以煤矸石为原料制备沸石分子筛，则是一条更经济实用的应用途径，目前已合成A型、X型等沸石。作者以煤矸石为原料，采用导向剂法成功合成Y型沸石。     

一种高效废铝再生熔炼炉

高效铝屑再生熔炼炉主要由熔化室、循环泵、加料井、循环管路四部分组成。该炉采用循环泵为铝液流动提供动力,使铝液在特殊结构的加料井中形成非接触式漩涡。该漩涡强度大,对铝屑的沉熔效果好,铝屑氧化烧损小,是一种技术先进、高效的铝屑再生熔炼炉。     

铝熔炼设备及再生铝回收新技术分析

熔炼是铝合金生产过程中的重要环节.分析了铝熔炼过程中各个阶段的特点,对反射式熔铝炉各部位要求进行阐述;在反射式熔炼炉的基础上,介绍了目前再生铝行业较先进的熔炼设备——双室炉,同时提出了铝熔炼设备的发展方向.     

Abiotic hydrogen production in fresh and altered MSWI-residues: Texture and microstructure investigation

Long-term hydrogen generation was observed in a Bavarian mono-landfill for municipal solid waste incineration (MSWI) residues. Hydration reactions of non-noble metals, especially aluminum, predominantly produce hydrogen at alkaline reaction conditions. Microscopic investigations show that aluminum metal may occur in different forms: as larger single grains, as small particles embedded in a vitrified matrix or less frequently in blowholes together with metallic silica.Four types of corrosion texture were observed, indicating different reaction mechanisms: aluminum hydroxide rims caused by hydration reactions at alkaline reaction conditions (reaction type 1) and multiphase rims with ettringite and hydrocalumite due to the reaction of aluminum hydroxide with sulfate and chloride ions which are solved in the pore water (reaction type 2). Galvanic corrosion textures due to the electric potential difference between aluminum and embedded intermetallic Fe- or Cu-rich exsolution phases lead to two further corrosion textures: Strong hydration effects of aluminum except a border of aluminum remnant directly beside the Fe- or Cu-rich segregations were only observed in fresh samples (reaction type 3). The reaction type 4 shows a network of Al-hydroxide veins occurring along the embedded intermetallic Fe- or Cu-rich exsolution segregation pattern within the metallic aluminum grain. Metal particles enclosed in vitrified particles offers the potential for future corrosion processes.The occurrence of corrosion types 1, 2 and 3 in fresh bottom ashes indicates that these reaction mechanisms predominate during the first reaction period in the presence of chlorine in an alkaline solution. Corrosion type 4, however, was additionally observed in aged samples. Here aluminum acts as sacrificed anode implying electrochemical reaction due to electrolytic pore water. Chloride in the system keeps the reaction alive as Al-hydroxide is solved which normally builds a protection shield around the aluminum metal particles.Due to field observations and experimental results we have reasonable indications that after an initial strong formation of hydrogen the reaction time for hydrogen production in the landfill is lengthened for several decades by the presence of chloride in the alkaline pore water.     

铝盐混凝法去除氟离子的一般作用规律

通过混凝除氟、絮体氟吸附和释放等试验考察了铝盐混凝除氟的作用特,探讨了除氟随铝盐投加量、混凝pH等操作参数及铝盐混凝剂本身形态不同时的变化规律。结果表明,铝盐混凝除氟效果与混凝pH密切相关,在pHo 5.8-7.0条件下除氟效果最佳;在相同投加量和各自的最佳混凝条件下,单体铝盐的除氟效果好于聚合铝盐,但其絮体的持氟性能不及聚合铝盐。     

电解铝工业危险废物处理技术的发展方向

针对电解铝工业产生的大量含氟危险废物,综述了国内外该类危险废物处理技术的发展历程和研究进展,并就目前国内电解铝工业危险废物的两种典型处理工艺进行了对比分析。指出:分类处理和浮选—浸出是目前处理电解铝工业危险废物的最佳工艺;湿法处理是实现电解铝工业危险废物资源化的技术发展方向;有价元素的进一步高效回收需要对工艺条件进行精细控制,从理论层面和分子水平进行深入研究。     

Recovery and distribution of incinerated aluminum packaging waste

A study was performed into relations between physical properties of aluminum packaging waste and the corresponding aluminum scraps in bottom ash from three typical incineration processes. First, Dutch municipal solid waste incineration (MSWI) bottom ash was analyzed for the identifiable beverage can alloy scraps in the +2mm size ranges using chemical detection and X-ray fluorescence. Second, laboratory-scale pot furnace tests were conducted to investigate the relations between aluminum packaging in base household waste and the corresponding metal recovery rates. The representative packaging wastes include beverage cans, foil containers and thin foils. Third, small samples of aluminum packaging waste were incinerated in a high-temperature oven to determine leading factors influencing metal recovery rates. Packaging properties, combustion conditions, presence of magnesium and some specific contaminants commonly found in household waste were investigated independently in the high-temperature oven. In 2007, the bottom ash (+2mm fraction) from the AEB MSWI plant was estimated to be enriched by 0.1 wt.% of aluminum beverage cans scrap. Extrapolating from this number, the recovery potential of all eleven MSWI plants in the Netherlands is estimated at 720 ton of aluminum cans scrap. More than 85 wt.% of this estimate would end up in +6mm size fractions and were amenable for efficient recycling. The pot furnace tests showed that the average recovery rate of metallic aluminum typically decreases from beverage cans (93 wt.%) to foil containers (85 wt.%) to thin foils (77 wt.%). The oven tests showed that in order of decreasing impact the main factors promoting metallic aluminum losses are the packaging type, combustion temperature, residence time and salt contamination. To a lesser degree magnesium as alloying element, smaller packaging size and basic contaminations may also promote losses.     

Metallic aluminum in MSWI fly ash: quantification and influence on the properties of cement-based products

This article focuses on the effects of metallic aluminum contained in municipal solid waste incineration (MSWI) fly ashes on cement-based materials in which they are added. The ash under study was treated by an industrial physicochemical process of neutralization. The paper also presents a method to quantify the metallic aluminum content of ash: it consists in measuring the amount of hydrogen gas produced by the oxidation reaction of metallic aluminum. This method is simple and fast. Results show that studied ash contains an appreciable amount of metallic aluminum. Investigations were carried out to study the incorporation of the ash in concrete: in this case, the presence of metallic aluminum is worrying because it could be responsible for disorders in concrete. In fact, swellings are observed on cement pastes and mortars containing ash during the first 24 h of hydration. A test based on hydrostatic weighing permits to quantify the swelling of fresh cement paste and to study the evolution of this swelling. Causes of swelling are analyzed. Results show that ettringite formation occurs after the end of the expansion reaction. So it can be concluded that metallic aluminum is the sole responsible for the observed swelling. Consequences of swelling are also analyzed by measuring compressive strength of ash-containing mortars: this swelling leads to cracks in the mortars and significant decrease of their compressive strength.     

用废铝渣制备聚合硫酸铝

将铝材厂前处理过程产生的废铝渣用硫酸溶解,然后加入有机添加剂等进行聚合反应,制备新型水处理剂——聚合硫酸铝（PAS）。用PAS与聚合氯化铝（PAC）进行絮凝对比实验,结果表明,对于硅藻土浊度水、水源水和工业废水等,PAS比PAC具有更优异的除浊、脱色、去除COD和悬浮物的效果。该工艺既可回收利用废铝渣,又可省去废渣处置费用,为废铝渣的综合利用提供了实用技术。     

响应面法优化铝灰中氮化铝脱除工艺

为了优化二次铝灰中AlN氧化焙烧脱除工艺,基于响应面法建立了焙烧温度、焙烧时间、铝灰粒径等工艺参数与AlN脱除率之间的数学模型,并进行了方差分析,对铝灰中AlN的脱除工艺参数进行了优化设计.结果表明,所建立的回归模型能够准确预测AlN脱除率,预测值与实验值误差为0.93％.经优化设计得到铝灰中AlN的最佳脱除工艺参数为...     

利用含铝废硫酸和废铝渣制备聚合硫酸铝

以含铝废硫酸和废铝渣为原料制备聚合硫酸铝（PAS）。优化了废铝渣的酸溶条件,确定了合适的稳定剂和碱化剂。实验结果表明：在酸溶反应温度为80 ℃、酸溶反应时间为40 min、以20 g/L Ca（OH）₂溶液为碱化剂、以加入量为60 mg/L的固体柠檬酸为稳定剂的条件下,制备的PAS比聚合氯化铝（PAC）和Al₂（SO₄）₃具有更优异的混凝性能。该工艺可回收利用废铝渣和含铝废硫酸,从而达到综合利用的目的。