Heavy Metals in Organs and Tissues of the European Black Vulture (Aegypius monachus): Dependence on Living Conditions

The distribution of Fe, Zn, Cu, Cd, Mn, Pb, and Ni in the organs and tissues (kidneys, liver, lungs, brain, heart, muscles, and feathers) of the European black vulture (Aegypius monachus) was studied. It was shown that heavy metals were not responsible for the mass mortality of these birds in southern Primorye in the winter of 2001–2002. The level of pollution with heavy metals of the range of European black vultures wintering in this region (northern China and western Mongolia) may be regarded as insignificant.     

Indicator based approach for monitoring natural resources of village ecosystems: findings from select ecosystems of southern India

Indian village ecosystems are diverse with respect to population pressures, agricultural activities and production, livestock composition, energy sources, economics and infrastructural capabilities. Natural resource degradation is a major global concern and the factors and processes leading to degradation are regional and scale up from the micro levels such as village ecosystems. There is need for integrated multidisciplinary approaches for monitoring the resource status and environmental issues at the decentralized level. This paper presents an approach to assess village ecosystems using a set of key indicators developed and tested across fourteen diverse village ecosystems of the Southern India. The concept of ecosystem services associated with village ecosystems of India has been described and adopted to identify indicators and assess issues and trends. Comparison across villages has been demonstrated and the indicators successfully reflected the key environmental issues at each village level as well as differences across villages. We also report unique cases of stabilized land use and ‘desakota-like’ trends from village ecosystem studied.     

Intra-annual dynamics of water stress in the central Indian Highlands from 2002 to 2012

India’s continued development depends on the availability of adequate water. This paper applies a data-driven approach to estimate the intra-annual dynamics of water stress across the central Indian Highlands over the period 2002–2012. We investigate the spatial distribution of water demanding sectors including industry, domestic, irrigation, livestock and thermal power generation. We also examine the vulnerability of urban centers within the study area to water stress. We find that 74 % of the area of the central Indian Highlands experienced water stress (defined as demand exceeding supply) for 4 or more months out of the year. The rabi (winter) season irrigation drives the intra-annual water stress across the landscape. The Godavari basin experiences the most surface water stress while the Ganga and Narmada basins experience water stress due to groundwater deficits as a result of rabi irrigation. All urban centers experience water stress at some time during a year. Urban centers in the Godavari basin are considerably water stressed, for example, Achalpur, Nagpur and Chandrapur experience water stress 8 months out of the year. Irrigation dominates water use accounting for 95 % of the total water demand, with substantial increases in irrigated land over the last decade. Managing land use to promote hydrologic functions will become increasingly important as water stress increases.     

Construction and demolition waste generation in cities in India: an integrated approach

ABSTRACT

This paper quantifies construction and demolition waste (C&DW) generation rate in Indian cities using bottom-up material flow analysis approach. A dynamic model was applied to different classes of cities in India to investigate how C&DW generation rate varies across different classes of cities. The data on construction and demolition activities in different classes of cities were estimated from information reported in secondary literature. The results show that urban areas in India generated over 150 million tonnes of C&DW in 2016, and almost 50% of waste was generated in small to medium towns. The paper concludes with discussion on opportunities for recycling of C&DW and closing the material loops in Indian cities.     

Occurrence, distribution and possible sources of organochlorine pesticide residues in tropical coastal environment of India: an overview

Organochlorine pesticides (OCPs) are an important potential component of chemical pollutants used extensively for agriculture and sanitation purposes in India as these are comparatively cheap and effective. These persistent organic compounds such as HCH isomers, DDT and its metabolites are the predominant chemical contaminants found along the Indian coast and thus constitute both alluring and grave areas of scientific research. Our objective in the paper is to provide a comprehensive account of the distribution of organochlorine pesticides in biotic and abiotic compartments of the Indian coastal environment, make some comments on their environmental sources, their movement through the food chain and possible ecotoxicological risk of health in biota including humans. The prevalent HCH, DDT and HCB concentrations differ markedly in eastern and western coast of India reflecting differing agricultural and other usage and their ultimate input into the coastal environment by several rivers and the bioturbation activities of macrozoobenthos (bivalve mollusks, polychaetous annelids, etc.). In several cases, the DDT levels exceeded the effects range-low (ER-L) and could thus cause acute biological impairments, in comparison with the sediment quality guidelines. Contributions of DDT metabolites (DDT, DDD and DDE residues) vary in different Indian coastal regions predominated by pp'-DDT and pp'-DDD. Measured concentrations of HCHs were lower than DDTs that might be due to higher water solubility, vapor pressure and biodegradability of the latter. HCH and DDT residues in fish in India were lower than those in the temperate countries indicating a lower accumulation in tropical fish, which might be related to rapid volatilization of this insecticide in the tropical environment. The concentrations of other chlorinated pesticides (aldrin, dieldrin, eldrin, methoxychlor, endosulfan sulphate) were lower and not generally of great concern.     

Second generation anticoagulant rodenticides in predatory birds: Probabilistic characterisation of toxic liver concentrations and implications for predatory bird populations in Canada

Second-generation anticoagulant rodenticides (SGARs) are widely used to control rodent pests but exposure and poisonings occur in non-target species, such as birds of prey. Liver residues are often analysed to detect exposure in birds found dead but their use to assess toxicity of SGARs is problematic. We analysed published data on hepatic rodenticide residues and associated symptoms of anticoagulant poisoning from 270 birds of prey using logistic regression to estimate the probability of toxicosis associated with different liver SGAR residues. We also evaluated exposure to SGARs on a national level in Canada by analysing 196 livers from great horned owls (Bubo virginianus) and red-tailed hawks (Buteo jamaicensis) found dead at locations across the country. Analysis of a broader sample of raptor species from Quebec also helped define the taxonomic breadth of contamination. Calculated probability curves suggest significant species differences in sensitivity to SGARs and significant likelihood of toxicosis below previously suggested concentrations of concern (<0.1mg/kg). Analysis of birds from Quebec showed that a broad range of raptor species are exposed to SGARs, indicating that generalised terrestrial food chains could be contaminated in the vicinity of the sampled areas. Of the two species for which we had samples from across Canada, great horned owls are exposed to SGARs to a greater extent than red-tailed hawks and the liver residue levels were also higher. Using our probability estimates of effect, we estimate that a minimum of 11% of the sampled great horned owl population is at risk of being directly killed by SGARs. This is the first time the potential mortality impact of SGARs on a raptor population has been estimated.     

Distribution of pesticides, PAHs and heavy metals in prawn ponds near Kolleru lake wetland, India

This paper discussed the distribution of pesticides, polycyclic aromatic hydrocarbons (PAHs) and heavy metals in water, sediment and prawn from intensive prawn ponds (n=8) near the Kolleru lake wetland, India and assessed the quality of prawn for human consumption and also discussed the possible effects of these pollutants on pond environment and aquatic environment. The chemicals and other products used in prawn ponds near the Kolleru lake wetland were documented. The sediment, prawn and water samples were collected six times from selected prawn ponds during the production period of 3 months. Water samples were analyzed for selected physico-chemical parameters. The levels of pesticides, PAHs and heavy metals were found to decrease in the order sediment followed by prawn and water. The maximum concentrations of pesticides in sediment, prawn and water were alpha-BHC (174.2 microg g(-)(1)), gamma-BHC (234 microg g(-)(1)), malathion (256 microg g(-)(1)), chloripyrifos (198.5 microg g(-)(1)), endosulfan (238 microg g(-)(1)), dieldrin (19.6 microg g(-)(1)) and p,p'-DDT (128.6 microg g(-)(1)). Isodrin was found below detectable limit. The maximum concentrations of PAHs in sediment, prawn and water are anthracene (0.901 microg kg(-)(1)), fluranthene (0.601 microg kg(-)(1)), pyrene (0.786 microg kg(-)(1)), chrysene (0.192 microg kg(-)(1)), benzo(a)pyrene (0.181 microg kg(-)(1)) and benzo(ghi)perylene (227 microg kg(-)(1)). Benzo(e)pyrene, perylene, isomers of dibenzoanthracene and coronene were found below detectable limits. The maximum concentrations of heavy metals in sediment, prawn and water and also in prawn feed are Cu (791 microg g(-)(1)), Pb (270 microg g(-)(1)), Cd (1.07 microg g(-)(1)), Mn (4417 microg g(-)(1)), Ni (8.1 microg g(-)(1)), Co (5.8 microg g(-)(1)), Zn (1076 microg g(-)(1)), Cr (36.4 microg g(-)(1)), As (2.9 microg g(-)(1)), Se (6.3 microg g(-)(1)), Th (2.1 microg g(-)(1)) and Mo (0.762 microg g(-)(1)).     

Changes in the dry tropical forests in Central India with human use

Understanding changes in forest composition and structure is important to help formulate effective policies that promote future ability of forests to provide local livelihood needs, habitat and ecosystem services. This is particularly important in dry tropical forests that are ecologically different from other forests and are heavily used by local, forest-dependent residents. In this study, we identify biophysical, demographic and use factors associated with differences in species diversity, vegetation structure (abundance at different size classes), biomass and relative abundance of species across the Kanha–Pench landscape in Central India. We sampled vegetation in twenty transects across different human and livestock population densities and frequencies of use. We found that biomass, species diversity and vegetation (abundance at different size classes) are negatively associated with increasing population density, and species composition at different size classes is significantly different at higher frequencies of use at low population densities. Lack of difference in species composition at high population densities may be due to colonization and growth of individuals at some of these sites due to creation of new ecological niches and gaps at high human use. Relative abundance of species at different size classes also varies with frequency of use and population density. Results suggest that human use is altering relative abundance of species, which may change long-term forest composition and thus alter biomass and vegetation structure of the forest. We conclude that human use is an agent in altering long-term composition that can alter availability of tree species for local use and other ecosystem services.     

Trends in food production and nitrous oxide emissions from the agriculture sector in India: environmental implications

We studied trends in food production and nitrous oxide emissions from India's agricultural sector between 1961 and 2000. Data from Food and Agricultural Statistics (FAO) have been gathered covering production, consumption, fertilizer use and livestock details. IPCC 1996 revised guidelines were followed in studying the variations in N₂O-N emissions. Results suggest that total N₂O-N emissions (direct, animal waste and indirect sources) increased ~6.1 times from ~0.048 to ~0.294 Tg N₂O-N, over 40 years. Source-wise breakdown of emissions from 1961–2000 indicated that during 1961 most of the N₂O-N inputs were from crop residues (61%) and biological nitrogen fixation (25%), while during 2000 the main sources were synthetic fertilizer (~48%) and crop residues (19%). Direct emissions increased from ~0.031 to ~0.183 Tg. It is estimated that ~3.1% of global N₂O-N emissions comes from India. Trends in food production, primarily cereals (rice, wheat and coarse grains) and pulses, and fertilizer consumption from 1961–2000 suggest that food production (cereals and pulses) increased only 3.7 times, while nitrogenous fertilizer consumption increased ~43 times over this period, leading to extensive release of nitrogen to the atmosphere. From this study, we infer that the challenge for Indian agriculture lies not only in increasing production but also in achieving production stability while minimizing the impact to the environment, through various management and mitigation options.     

Livestock losses and hotspots of attack from tigers and leopards in Kanha Tiger Reserve,Central India

Carnivore attacks on livestock are a primary driver of human–carnivore conflict and carnivore decline globally. Livestock depredation is particularly threatening to carnivore conservation in Central India, a priority landscape and stronghold for the endangered tiger. To strengthen the effectiveness of conflict mitigation strategies, we examined the spatial and temporal patterns and physical characteristics of livestock depredation in Kanha Tiger Reserve. We combined livestock compensation historical records (2001–2009) with ground surveys (2011–2012) and carnivore scat to identify when and where livestock species were most vulnerable. Between 400 and 600 livestock were reported for financial compensation each year, and most (91–95 %) were successfully reimbursed. Tigers and leopards were responsible for nearly all livestock losses and most often killed in the afternoon and early evening. Cattle and buffalo were most at risk in dense forests away from villages and roads, whereas goats were most often killed in open vegetation near villages. A spatial predation risk model for cattle revealed high-risk hotspots around the core zone boundary, confirming the significant risks to livestock grazing illegally in the core. Such ecological insights on carnivore–livestock interactions may help improve species-specific livestock husbandry for minimizing livestock losses and enabling coexistence between people and carnivores.     

Determination of non-steroidal anti-inflammatory drug (NSAIDs) residues in water samples

Pharmacologically active substances used to treat human and animal illnesses can enter the aquatic environment via effluents from wastewater treatment plants or in the case of veterinary drugs directly through liquid manure discharge. Some of these substances enter the environment either as the parent compound or as active/inactive metabolites. Due to their pharmacological activity, their determination and understanding their behavior and fate in the environment are important. The scope of this paper was to develop an analytical procedure to determine common pharmaceutical residues in wastewaters. Pharmacologically active substances were chosen according to their wide spread application in Slovenia and Central Europe and are members of analgesics, e.g., non-steroidal anti-inflammatory drugs: ibuprofen, naproxen, ketoprofen and diclofenac. Selected compounds were isolated from synthetic water using a novel SPE sorbent Strata X. Due to the non-volatile nature of these compounds they were first silylised prior to gas chromatographic-mass spectrometric detection. The developed procedure was tested with synthetic wastewaters and their extraction efficiency (>84%) and method limits of detection (2-6 ng L(-1)) were determined. Our procedure has been adopted and optimised for "real" water samples and applied to eleven drinking and ten river water samples from Slovenia. The results showed no traces of NSAIDs in all potable water samples and low-range contamination (ng L(-1)) of Slovene rivers. These results show that NSAIDs contamination of Slovene waters is comparable with published results of water contamination in Central Europe.     

Social sustainability in supply chain decisions: Indian manufacturers

The purpose of the paper is to assess the inclusion of social sustainability in the decisions of supply chain in multinational manufacturing organisations in India. Indian organisations are resorting to sustainability-based reporting for greater transparency and for creation of brand value for their organisations. There are tremendous economic upheavals and changes across the complete value chain, and thus, responsible business practices are becoming a necessity for the long-term survival of organisations. Sustainability, as a strategy, is responsible utilisation of resources and is reported through social, economic and environmental factors in an organisation. For sustainability as a strategy, there has to be a complete organisational inclusion and employee engagement through decision making at operational levels along the value chain. The research paper is an empirical study done through a survey using a structured questionnaire to collect information to evaluate decision criteria particularly for social sustainability, from the middle and top level executives in Indian manufacturing organisations. Multinational manufacturing organisations in India are trying to be more responsible because of mandated CSR policy, and thus, sustainability through social factors is getting more prominence. A multiple linear regression analysis is used to explain the correlation and inclusion of social factors on the decision-making process in the supply chain of multinational manufacturing organisations in India. This study reveals that decision making in the supply chain of multinational manufacturing organisations in India specifically in manufacturing industry is incorporating social sustainability. The study highlights that decision making involving social sustainability needs larger frameworks for organisational preference. While the study provides evidence of social sustainability-based practices in multinational manufacturing organisations in India, it does not deal with social sustainability practices. The study also has limitation as has been limited to organisations which follow sustainability practices and make disclosures through GRI framework.     

Occurrence and risk assessment of pharmaceutically active compounds in wastewater treatment plants. A case study: Seville city (Spain)

The occurrence of four anti-inflammatory drugs (diclofenac, ibuprofen, ketoprofen and naproxen), an antiepileptic drug (carbamazepine) and a nervous stimulant (caffeine) in influent and effluent samples from four wastewater treatment plants (WWTPs) in Seville was evaluated. Removal rates in the WWTPs and risk assessment of the pharmaceutically active compounds have been studied. Analytical determination was carried out by high performance liquid chromatography (HPLC) with diode array (DAD) and fluorescence (Fl) detectors after sample clean up and concentration by solid phase extraction. All pharmaceutically active compounds, except diclofenac, were detected not only in wastewater influents but also in wastewater effluents. Mean concentrations of caffeine, carbamazepine, ketoprofen and naproxen ranged between 0.28-11.44 microg l(-1) and 0.21-2.62 microg l(-1) in influent and effluent wastewater, respectively. Ibuprofen was present in the highest concentrations in the range 12.13-373.11 microg l(-1) and 0.78-48.24 microg l(-1) in influent and effluent wastewater, respectively. Removal rates of the pharmaceuticals ranged between 6 and 98%. Risk quotients, expressed as ratios between the measured environmental concentration (MEC) and the predicted no effect concentrations (PNEC) were higher than 1 for ibuprofen and naproxen in influent wastewater and for ibuprofen in effluent wastewater.     

Inequality in water supply in India: an assessment using the Gini and Theil indices

Provision of drinking water is considered to be an essential public service. Ensuring adequate water supply remains a challenge in Indian cities that are experiencing rapid growth and often exhibit a mismatch between increasing demands and inadequate supply infrastructure. This study quantifies the existing inequality in water supply within Indian cities through Lorenz curve, Gini coefficient as well as Theil indices. Two types of Theil indices are estimated to gain different perspectives: water supply and population-weighted. Both the Theil indices are disaggregated, according to economic and regional categorisation of the cities, to explore the within- and between-group inequality. The water supply and population-weighted Theil indices provide different outlook of the inequality amongst the cities. But the population-weighted index is often better and pragmatic. Further, the inequality in access to tap water in India is studied by estimating modified Lorenz curves and Theil indices. Again, the Theil indices are decomposed into within and between components according to economic and regional grouping of states. The results suggest that there is disparity in supply of water in India, and infrastructure has to be boosted to meet the growing demand. This study is a step towards quantification of water supply inequality. The approach used in the study can contribute to monitoring of water supply equity as well as in formulating sustainable and equitable water policies.     

Promoting e-mobility in India: challenges,framework, and future roadmap

The purpose of the research is to identify the critical challenges that are impeding the adoption of e-mobility in India. It also aims to give a roadmap how to address these challenges while taking into considerations concerns of all the relevant stakeholders. Based on an in-depth literature review, an exploratory research design is employed to delve deep into various aspects of e-mobility. This is followed by a three-phase Delphi technique to identify and rate the e-mobility challenges in the Indian context. The study successfully identifies four different categories of challenges and proposes integrative framework for e-mobility. Further, the research goes on to lay out the future roadmap for mass adoption of electric vehicles (EVs) in India. The research is novel in terms of presenting a holistic viewpoint on e-mobility in India. Its originality lies in identifying the major inhibitors obstructing EVs adoption in India and then suggesting the roadmap how to overcome these impediments for mass adoption of e-mobility.     

Methane emissions from dairy farms: case study from a coastal district in South India

Environment, Development and Sustainability - India has the largest dairy industry in the world and accounts for a significant share of the global emission of livestock methane ( $$\hbox...     

Distribution of U-Th nuclides in the riverine and coastal environments of the tropical southwest coast of India

A reconnaissance study has been made on the distribution of 238U, 234U, 232Th and 230Th in soils, water, suspended particulate matter (SPM) and bottom sediments in the Kali river basin around Kaiga, its estuarine region and the adjacent Arabian Sea to obtain the baseline data of U-Th series nuclides in view of the commissioning of nuclear power reactors at Kaiga, near Karwar, on the southwest coast of India. Drainage basin soils developed over greywackes (the dominant litho-unit upstream) are lower in 238U/Al and 232Th/Al ratios by factors of 3-5 in comparison with those developed over tonalitic gneisses (the dominant litho-unit downstream). The dominance of the former type of soils is reflected in the composition of river-bottom sediments derived from the upstream drainage basin during the monsoon. The 232Th in bottom sediments tends to increase towards the estuarine and coastal areas, presumably due to deposition of heavy minerals and onshore transport of coastal sediments into the estuary. The dissolved U in the Kali river is low (0.001-0.02 microg/l) when compared to the major Indian rivers as the Kali river flows through U-poor greywackes. Thus, the input of dissolved U to the Kali estuary is dominated by sea water. Although there is some evidence for the removal of dissolved U at low salinity during estuarine mixing, its behaviour is conservative in the lower estuary (at higher salinities). The removal rate of dissolved U from the Kali river basin is similar to that reported from other tropical river basins. The U flux from all the west-flowing rivers of Peninsular India is estimated at 26.3 x 10(6) g/yr to the Arabian Sea which is about 2% of the flux from the Himalayan rivers to the Bay of Bengal.     

四川省畜禽粪便排放时空分布及污染防控

掌握畜禽粪便的时空分布,有利于高效防控其污染环境的可能。采用排污系数法,估算出2000～2015年间四川省畜禽粪便、COD及氮磷产生量,在此基础上,分析了2015年四川省畜禽粪便的排放时空分布特征与畜禽粪便、氮、磷污染情况。结果表明：（1）2000～2015年,四川省畜禽粪便平均产生量约2.10亿t猪粪当量,其中猪、牛、家禽是当地环境威胁的主要畜禽种类;（2）2015年四川省产沼气潜力可观,但大部分地区受到畜禽粪便污染,其中德阳市、雅安市两地预警级别达Ⅵ级,对环境影响严重;（3）2015年四川省氮、磷耕地负荷的平均值分别为78.45 kg/hm2和13.57 kg/hm2,均低于欧盟的限量标准（氮170 kg/hm2、磷35 kg/hm2）,但大部分地区面临氮、磷污染风险。其中成都市、德阳市、雅安市氮、磷污染风险均较高,自贡市、泸州市等氮、磷污染风险整体不高,但畜禽养殖量近50%环境容量,这些地区应做好畜禽养殖总量控制及污染物消减措施。 关键词： 畜禽养殖;粪便污染;时空分布;污染防控;四川     

Airborne reduced nitrogen: ammonia emissions from agriculture and other sources

Ammonia is a basic gas and one of the most abundant nitrogen-containing compounds in the atmosphere. When emitted, ammonia reacts with oxides of nitrogen and sulfur to form particles, typically in the fine particle size range. Roughly half of the PM(2.5) mass in eastern United States is ammonium sulfate, according to the US EPA. Results from recent studies of PM(2.5) show that these fine particles are typically deposited deep in the lungs and may lead to increased morbidity and/or mortality. Also, these particles are in the size range that will degrade visibility. Ammonia emission inventories are usually constructed by multiplying an activity level by an experimentally determined emission factor for each source category. Typical sources of ammonia include livestock, fertilizer, soils, forest fires and slash burning, industry, vehicles, the oceans, humans, pets, wild animals, and waste disposal and recycling activities. Livestock is the largest source category in the United States, with waste from livestock responsible for about 3x10(9) kg of ammonia in 1995. Volatilization of ammonia from livestock waste is dependent on many parameters, and thus emission factors are difficult to predict. Despite a seasonal variation in these values, the emission factors for general livestock categories are usually annually averaged in current inventories. Activity levels for livestock are from the USDA Census of Agriculture, which does not give information about animal raising practices such as housing types and grazing times, waste handling systems, and approximate animal slurry spreading times or methods. Ammonia emissions in the United States in 1995 from sources other than livestock are much lower; for example, annual emissions are roughly 8x10(8) kg from fertilizer, 7x10(7) kg from industry, 5x10(7) kg from vehicles and 1x10(8) kg from humans. There is considerable uncertainty in the emissions from soil and vegetation, although this category may also be significant. Recommendations for future directions in ammonia research include designing experiments to improve emission factors and their resolution in all significant source categories, developing mass balance models, and refining of the livestock activity level data by eliciting judgment from experts in this field.     

Effects of moderate pollution on toxic and trace metal levels in calves from a polluted area of northern Spain

This study evaluated the contribution of anthropogenic pollution to toxic metal residues (Cd, Pb and As) in cattle in an industrialized area of Asturias (northern Spain), and investigated possible implications of toxic metal exposure for metabolism of essential metal elements (Cu, Zn, Fe, Mn). Samples of liver, kidney, muscle and blood from animals aged 9-12 months were obtained from an industrialized area (78 calves) and from a rural area (92 calves). Samples were acid-digested, and levels of metals determined by atomic absorption spectrophotometry. Cadmium and lead contents in the liver and kidney were moderately and significantly higher in calves from the industrialized area (Cd: liver 29.6, kidney 161; Pb: liver 38.1, kidney 38.3 microg/kg wet weight) than in calves from the rural area (Cd: liver 22.9, kidney 96.4; Pb: liver 20.7, kidney 15.9 microg/kg kg wet weight). Although these toxic metals were only moderately raised, our results suggest that they may nevertheless have interfered with trace element metabolism, as reported previously for severely polluted regions. Notably, copper levels in calves from the industrialized area were generally low, and nearly half of these animals showed tissue copper levels indicating risk of copper deficiency.