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1.
Physicochemical analyses and cyanobacterial diversity of Ramgarh Lake water were performed at five sampling sites during winter, summer, and monsoon seasons. Higher load of solids, carbon, and nutrients were persistent throughout the analysis that indicates the conversion of lake from oligotrophic to eutrophic nature. High nutrients load enhanced cyanobacterial biomass, while low nutrients load produced relatively less biomass. The physicochemical parameters of water samples revealed minimum 2.9 mg L?1 dissolved oxygen (DO) at site-1 during summer, while maximum (5.6 mg L?1) at site-4 in monsoon season. Maximum biochemical oxygen demand (BOD) (40 mg L?1) and chemical oxygen demand (COD) (126 mg L?1) were recorded at site-1 during summer, whereas minimum BOD (18 mg L?1) and COD (52 mg L?1) were evident at site-3 in monsoon season. Minimum concentration of nitrate (0.72 mg L?1) was recorded at site-3 in summer, whereas maximum 2.7 mg L?1 was present at site-5 in winter season. The phosphate concentration was maximum (0.52 mg L?1) at site-5 in summer, and minimum (0.18 mg L?1) was observed at site-4 in monsoon season. Cyanobacterial diversity was higher during all the seasons, and dominated by the species of Microcystis at all the five sampling sites.  相似文献   

2.
The physicochemical characteristics of the River Challawa in the Kumbotso Local Government Area of Kano State were studied across four seasons (warm and dry, cold and dry, hot and dry, and warm and wet seasons) between October 2006 and August 2008. Physicochemical parameters like pH, electrical conductivity (EC), total dissolved solids (TDSs), total suspended solids (TSS), alkalinity, turbidity, hardness, dissolved oxygen (DO), biological oxygen demand (BOD), chemical oxygen demand (COD), ammonia, chloride, nitrate, sulfate, and phosphate were analyzed and compared with standard permissible limits. The mean range of parameters determined across the seasons revealed: 8.36–8.59 for pH; 209.57–335.27 µS cm?1 for EC; 134.05–208.5 mg L?1 for TDS; 182.4–273.45 mg L?1 for TSS; 125.3–276.07 mg L?1 for hardness; 16.11–40 mg L?1 of CaCO3 for alkalinity; 2.76–3.78 mg L?1 for DO; 1.9–43.33 mg L?1 for BOD; 231.67–310.06 mg L?1 for COD; 221.67–441.67 mg L?1 for turbidity; 17.98–35.89 mg L?1 for chloride; 5.12–8.89 mg L?1 for nitrate; 37–558.83 mg L?1 for sulfate; and 0.47–0.81 mg L?1 for phosphate. Data showed that all parameters determined were significantly different among the various sampled sites across seasons. With the exception of COD, EC, and phosphate, all other parameters determined were within the WHO and USPH standard limits.  相似文献   

3.
The study aimed to examine the contamination status of arsenic (As) in excavated small water bodies, commonly known as ponds – the integral part of daily life in the arsenic-affected rural areas of West Bengal, India in comparison to the unaffected areas. The ponds of the contaminated area had higher levels of As: water 2–174 µg L?1 (mean 31 ± 2 µg L?1) and sediment 1.3–37.3 mg kg?1 (mean 10.3 ± 0.4 mg kg?1), than those from the unaffected area: water 1–8 µg L?1 (mean 4 ± 0 µg L?1) and sediment 1.4–5.3 mg kg?1 (mean 3.0 ± 0.1 mg kg?1). A moderate positive correlation was observed between the water and sediment arsenic content of the ponds of the arsenic-affected region (r = 0.688, n = 277, p < 0.0001). Contaminated ground water, either as direct input or through agricultural washings, was found to be the major contributor of arsenic pollution to these ecosystems. Seasonal variations were not prominent. This study emphasized the beneficial role of using the studied ecosystems over the highly contaminated ground water for various livelihood activities in the Gangetic delta region.  相似文献   

4.
This article aims to determine the significant differences of the seasonal changes of pH, chemical oxygen demand (COD), biological oxygen demand (BOD), and total suspended solids (TSS) parameters in a wastewater stabilization pond. The variation of these parameters followed the seasonal pattern of temperature. The mean seasonal pH of the influent wastewater ranged between 7.8 (in spring) and 7.9 (in summer), while in the final effluents it was between 7.9 (in winter) and 8.3 (in summer). The mean seasonal COD of the influent wastewater ranged between 650?mg?L?1 in spring and 600?mg?L?1 in autumn, whereas in the effluents it was between 150?mg?L?1 in autumn and 270?mg?L?1 in spring. The mean seasonal BOD5 of the influent wastewater ranged between 360?mg?L?1 in autumn and 390?mg?L?1 in winter, whereas in the effluents it was between 66?mg?L?1 in summer and 130?mg?L?1 in winter. The results showed that the percent removals of COD, BOD5 and TSS from final effluents were maximum in summer for COD and BOD5 (76%), summer (83%) and for TSS in winter (78%), respectively. Data analysis showed that there were significant differences between parameters of pH, COD, BOD5 and TSS at four different seasons (p?相似文献   

5.
The toxic effects of an organophosphorous insecticide, monochrotophos (MCP) were investigated on Paramecium caudatum in static acute toxicity tests (10?min and 2?h). The lethal concentrations (50%) were determined by probit method, for technical monocrotophos as 60 and 40.6?mg?L?1, respectively. We have combined conventional light microscopy and a computerized video tracking system to determine behavioural and morphological changes in paramecium on exposure to MCP. Paramecia exposed to highest concentrations (90–100?mg?L?1) used for 10?min exposure, exhibited initial increase with subsequent decrease in mobility with enormous blebbing, leading to lysis of cells. In the second set of experiments, the cells exposed to lethal concentration (40.6?mg?L?1) for 2?h were under stress, and reduced their locomotor behaviour, i.e. distance travelled per unit time (mm in 6?min) and swimming speed (mm?s?1) with increased time of exposure. In the third set of experiments, the number of generations and generation time in 24?h was evaluated with respect to the different sub lethal concentrations (5, 10, 15 and 20?mg?L?1) of toxicant. The number of generations decreased and generation time extended significantly in a concentration dependent manner. The results indicate that the Paramecium toxicity assay could be used as a complimentary system to rapidly elucidate the cytotoxic potential of insecticides.  相似文献   

6.
Mutagenic and genotoxic effects of polycyclic aromatic hydrocarbons, anthracene and benzo [a] pyrene (BaP), in milkfish Chanos chanos were determined using micronucleus (MN) test and comet assay (CA). Distinct mean frequencies of nuclear abnormalities such as MNs; binucleated micronuclei, nuclear bud, and fragmented apoptotic cells were measured. Significant increase in DNA damage with five classes of damage level was observed and expressed in terms of arbitrary unit (AU). Mean frequencies of total nuclear abnormalities were 0.5?±?0.25 cells in control; 0.67?±?0.33 cells in solvent control; 70?±?9.60 cells in 0.176?mg?L?1 anthracene, and 91.83?±?6.25 cells in 0.031?mg?L?1 BaP. The greatest DNA damage of 170AU was observed in 0.176?mg?L?1 anthracene-exposed group and 182AU was observed in 0.031?mg?L?1 BaP-treated fish. This study confirmed that the CA and MN assays are useful tools in determining potential genotoxicity of water pollutants and might be appropriate as a part of monitoring program.  相似文献   

7.
Spatial and temporal distributions of water quality using multivariate statistical techniques for the evaluation of nutrients (NO2-N, NO3-N, NH4-N, PO4-P, SiO4-Si, total N, total P) in relation to some physico-chemical features (DO, BOD, TSS, TDS, SO42−, Cl) were studied for 31 different stations of the Mahanadi river–estuarine system in the eastern part of India. The seasonal nutrient variations (except SiO4-Si) exhibit higher values during monsoon season in unpolluted stations and the reverse trends for polluted stations, which are related to agricultural run-off and regional anthropogenic activities respectively. Silicate shows a well defined pattern of distribution with a higher concentration during the monsoon, which is slightly removed from the estuarine water of Mahanadi during the pre-monsoon season. The results of R-mode factor analyses revealed that anthropogenic contributions are responsible for the increase in nutrients and the decrease in DO and pH levels of the water. The magnitude of BOD with respect to total N and P demonstrates the intensity of organic pollution in the system. The removal of silicate in the saline system is clearly visible through factor analysis and the different mode of association of TSS is reflected seasonally. The relationships among the stations are highlighted by cluster analysis, represented in dendograms to categorize different levels of contamination.  相似文献   

8.
The Leça River and two beaches close to the north and south margins of the estuary, nowadays an important seaport harbor, show signs of contamination. However, the chemical nature of that contamination is uncertain. Therefore, this study checked for the presence of 11 endocrine disrupting compounds (EDCs) of animal (17β-estradiol and estrone), pharmaceutical (17α-ethynylestradiol), and industrial (alkylphenols, alkylphenol ethoxylates, and bisphenol A) origins in water samples collected from six points at the river gradient and at two sites in the coastline (Atlantic Ocean). Along with the EDCs, evaluated by gas chromatography – mass spectroscopy (GC-MS) during spring, summer, and autumn, physico-chemical parameters were also assessed and particular attention was given to dissolved oxygen (DO) levels. Data showed the presence of high amounts of estrogens (up to 10?ng?L?1 for estrone) and industrial compounds (up to 2?µg?L?1 for the nonylphenol ethoxylates) at both river and seacoast. Along with this, clear signs of hypoxia were found in the river (DO??1 at several sampling sites). Taking into account these issues, it was concluded that there are local conditions for the occurrence of endocrine disruption in aquatic animals.  相似文献   

9.
The insecticide formulation, dicofol (18.5% EC) was evaluated for its toxic potential in developing chick embryo. Fertilized eggs of Gallus domesticus on 4th day of incubation were immersed in aqueous emulsions of dicofol at concentrations of 250?mg?L?1, 500?mg?L?1, and 1000?mg?L?1 for 60?min at 37°C. These concentrations were corresponding to those used in plant protection practice (500?mg?L?1). Two control groups of eggs were used: one group was immersed in distilled water (vehicle) and the second group was kept as untreated to study background toxicity. On embryonic day 7; recovered embryos were evaluated for mortality rate, wet body weight, gross morphological malformations, and some biochemical changes. The result revealed that administration of dicofol did not result in significant changes in wet body weight of embryo but the survival rate of dicofol treated embryos were markedly reduced as compared with controls. Among the survivors, the number of malformations was exhibited by dicofol treated embryos in dose-dependent manner. Among biochemical changes, only total protein content of embryo significantly (p?≤?0.05) reduced to 500?mg?L?1 and 1000?mg?L?1. Among enzymes, alkaline phosphatase and glutamate pyruvate transaminase activities were affected, which showed significant elevations.  相似文献   

10.
In current research, the combined effects of copper oxide nanoparticles (CuO NPs) and titanium dioxide nanoparticles (TiO2 NPs) on the histopathological anomalies of gill and intestine tissues in common carp (Cyprinus carpio) were studied. Common carp were exposed to TiO2 NPs (10.0?mg L?1), CuO NPs (2.5 and 5.0?mg L?1), and mixture of TiO2 NPs (10.0?mg L?1)?+?CuO NPs (2.5 and 5.0 mg?L?1) for two periods of exposure (10 and 20 days) and recovery (30 and 40 days). The most common histopathological anomalies in the gill of common carp such as hyperplasia, oedema, curvature, fusion, aneurism, and necrosis were observed. The synergistic effect of co-existing TiO2 NPs and CuO NPs reduced the length of secondary lamella and increased the diameters of the gill filaments and secondary lamellae. Moreover, the presence of TiO2 NPs increased the CuO NPs effects on the histopathological anomalies of intestine tissue and the synergistic effect of TiO2 NPs and CuO mixture leads to an increase in the severity of histopathological lesions such as degeneration, swelling of goblet cells, and necrosis - erosion in the intestine tissue. In conclusion, the presence of TiO2 NPs increased the toxicity of CuO NPs.  相似文献   

11.
Metal pollution produces damage to marine organisms at the cellular level possibly leading to ecological imbalance. The present investigation focused on the acute and chronic toxicity of lead (Pb) and zinc (Zn) by examining the effects of biomarker enzymes in post-larvae of Penaeus monodon (Tiger prawn). Antioxidant biomarker responses such as lipid peroxidation (LPO) and catalase (CAT) activity for Pb and Zn were determined following chronic exposure. Acute Lethal Concentration 50 (LC50) values observed in the study at 96?h for Pb and Zn at 5.77?±?0.32?mg?L?1 and 3.02?±?0.82?mg?L?1, respectively. The estimated No Observed Effect Concentration and Lowest Observed Effect Concentration values for Pb were 0.014 and 0.029?mg?L?1 and that recorded for Zn was 0.011 and 0.022?mg?L?1, respectively. Among the two metals studied, toxicity of Zn was found to be greater to P. monodon than Pb. The activities of antioxidant defense enzymes and total protein content differed significantly from control following exposure to both metals. Overall, the biomarker studies demonstrated that alterations in antioxidant enzymes and induction of LPO reflect the consequences of heavy metal exposure in P. monodon.  相似文献   

12.
The Kasargod District is the northernmost district of Kerala State and is bound between the north latitudes 12°02′27″ and 12°47′35″ and east longitudes 74°51′54″ and 75°25′25″. The present study highlights the contamination levels of organochlorine pesticides in open wells of the Kasargod District from 2010 to 2011. Maximum contamination of organochlorine pesticides (OCP's) was observed for endosulfan followed by hexachlorobenzene (BHC). Contamination levels of α-endosulfan were higher at Panathur (58?µg?L?1) and next to Periya (37?µg?L?1) in the postmonsoon season of 2010. During premonsoon 2011, the residue levels of α-endosulfan were higher at Panathady (56?µg?L?1) followed by Rajapuram (40?µg?L?1). Contamination levels of the BHC isomers exhibit the order of γ-BHC?>?α-BHC?>?β‐BHC, showing that γ-BHC represents 62% of the total OCP residues in premonsoon 2010. Among the studied OCP's, concentration levels of DDT were below detection limit. Maximum concentrations of the sum of all OCP residues were observed at Mulleria and Cheemeni (premonsoon 2010), followed by Panathur and Periya (postmonsoon 2010), and lowest in Panathady and Rajapuram (premonsoon 2011). Residues of OCP's were lowest in Paettikundu and Cheravatur in all the three seasons.  相似文献   

13.
The mosquito larvicidal activities of different solvent extracts (chloroform, ethyl acetate, and methanol) from the leaves of Coccinia indica were studied. Among the extracts tested, the methanol extract showed the highest larvicidal activity against early fourth instar larvae of Culex quinquefasciatus (LC50?=?142?mg?L?1), Aedes aegypti (LC50?=?158?mg?L?1) and Anopheles stephensi (LC50?=?161?mg?L?1) after 24?h of exposure period. The lowest larval mortality was observed with the ethyl acetate extract with the LC50 values of 927, 872, and 730?mg?L?1 against Cx. quinquefasciatus, Ae. aegypti, and An. stephensi, respectively. The chloroform extract showed the moderate larvicidal activity against the mosquito species tested with the LC50 values from 446 to 546?mg?L?1. A new triterpene was isolated from the methanol extract using bio-assay guided separation and identified as an oleanolic acid derivative by NMR, IR and mass spectral studies. The compound showed prominent larvicidal activity against Cx. quinquefasciatus, Ae. aegypti and An. stephensi with the LC50 values of 5.6, 5.0, and 4.8?mg?L?1, respectively. The results of the present investigation offer an opportunity for developing alternatives to rather expensive and environmentally hazardous organic insecticides.  相似文献   

14.
The concentration and potential ecological risk of Mn, Zn, Cu, and Cd in the surface soils (0–30?cm) belonging to 12 soil profiles and 4 soil types (Vertisols, Chernozems, Calcisols, and Cambisols) from the cultivated soils and the corresponding uncultivated soils were investigated. Long-term cultivation caused a considerable build-up diethylene-triamine pentaacetic acid (DTPA)-extractable Mn (7–55%), and Cd (12–31%) as well as the total form of Zn (3–14%), Cu (8–25%), and Cd (33–78%) in all soil types. Following long-time cropping, total Zn (mean?=?73?mg?kg?1), Cu (mean?=?33?mg?kg?1), and Cd (mean?=?3.14?mg?kg?1) and DTPA Zn (mean?=?1.2?mg?kg?1) and Cu (mean?=?2.44?mg?kg?1) were below their maximum allowable limits. However, the average amount of DTPA Cd in the tilled soils (min?=?0.4, max?=?0.75, mean?=?0.55?mg?kg?1) was above its maximum permissible limit mainly due to the over application of phosphate fertilisers and the pesticides. Considering the potential ecological risk (RI) assessment of the cultivated soils (min?=?44, max?=?70, mean?=?54), the soil types were categorised as low (RI?≤?50) to moderate (50?相似文献   

15.
Metal contents of waste mobile phones represent a major environmental risk, especially considering the adoption of inappropriate management options in developing countries including open burning and disposal into surface water bodies. In this study the metal contents of mobile phone printed wiring board (PWB) samples were assessed. Sixty-two waste mobile phones of 15 brands were collected, dismantled, and their PWB samples were analyzed for Cu, Pb, Ag and Cd. The metal concentrations in the samples varied widely between and within brands. Among these metals, Cu and Pb were found to be at very high concentrations. The range (mean?±?SD) of Cu and Pb concentrations were 94.1–532?g?kg?1 (250?±?92.3?g?kg?1) and 7.0–46.2?g?kg?1 (20.1?±?8.4?g?kg?1), respectively. All Cu and Pb concentrations exceeded toxicity threshold limit concentration (TTLC) regulatory limits used in characterizing wastes as hazardous in the state of California, USA. The mean Cu and Pb concentrations exceeded the corresponding TTLC limits by factors of 100 and 20, respectively. The Ag and Cd concentrations were in the range 59.4–759?mg?kg?1 (mean 227?±?104?mg?kg?1) and ND – 15.6?mg?kg?1 (2.1?±?3.3?mg?kg?1), respectively.  相似文献   

16.
Acetaldehyde is a naturally found chemical in food substances characterized by a fruity aroma at low levels. However, high levels of acetaldehyde can add to or change the taste of foods and beverages. More importantly, acetaldehyde has recently been found to be possibly carcinogenic to humans (Group 2B). In this investigation, the amounts of acetaldehyde in several alcoholic and non-alcoholic beverages consumed in Greece, including red or white wine, retsina, tsipouro, grappa, fruit-based liqueurs, beers with different alcohol content as well as mineral water, soft drinks, and fruit juices were measured. The analytical method used is based on derivatization of acetaldehyde with 2,4-dinitrophenylhydrazine and its subsequent measurement using high performance liquid chromatography. High concentrations (median, min–max) were detected in grappa (29.4, 29.2–52.7 mg L?1) and tsipouro (17.1, 0.8–55.6 mg L?1), followed by beer (6.8, 6.7–6.9 mg L?1) and red wine (3.7, 1.6–29.4 mg L?1); the lowest levels were detected in soft drinks (0.067, 0.033–0.075 mg L?1) and mineral water (0.04, 0.002--0.096 mg L?1). Levels of acetaldehyde in retsina were very high (68.1, 63.9--68.3 mg L?1) when after opening, the wine remained in plastic bottles for a long time, much higher than in samples taken from just opened bottles (7.2, 7.1–7.4 mg L?1). The amount of acetaldehyde shows some positive correlation to the alcoholic content. These results suggest that regulatory measures and consumer guidance may be necessary for acetaldehyde in beverages.  相似文献   

17.
The spatial distribution of the C/N ratios and variations in δ13C and δ15N of suspended particulate matter were used to characterise their source in Asia’s largest brackish water lagoon, Chilika, India. In addition, the significance of re-mineralised nutrients in the primary productivity of the shallow lagoon was also determined through quantification of the subsurface nitrogen uptake conditions at two relatively stable locations in the lagoon. The results indicated that the influence of terrestrial organic matter was the maximum in the northern sector and was relatively limited at the central and southern part of the lagoon. In situ 15N uptake experiments (daytime) under biogeochemically stable conditions revealed that the N uptake by phytoplankton ranged between 0.24 and 1.01?mM?m?3?h?1 during pre-monsoon and post-monsoon seasons. New production and regenerated production in the shallow lagoon was also estimated by calculating f-ratios (ratio of nitrate assimilation by phytoplankton to total nitrogenous nutrient assimilation, have been estimated), which varied from 0.52 in the post-monsoon to 0.38 in the pre-monsoon. Lowering of the f-ratio from post- to pre-monsoon indicated a dominance of mineralisation over the new production.  相似文献   

18.
A flow injection (FI) spectrophotometric method for the determination of the herbicide pinoxaden (PXD) has been proposed. PXD was converted in alkaline media with hydroxylamine hydrochloride to the hydroxamate salt. The salt was reacted with iron(III) chloride, and the absorbance of the red colored tris iron hydroxamate complex was measured at 500?nm using a FI system. The method was found to be linear between 0.5 and 40?mg?L?1 with a molar absorptivity of 1.53?×?104?L?mol?1?cm?1. The limit of detection and limit of quantification were found to be 0.1?±?0.01?mg?L?1 and 0.6?±?0.05?mg?L?1, respectively. Any interference of fenoxaprop-p-ethyl (FE) was avoided by the separation of PXD by liquid chromatography with a mixture of dichloromethane and n-hexane (1?:?1) as eluent. The method was applied to the determination of PXD in soil, water, and wheat grains with percent recoveries of 98?±?2, 100?±?2, and 98?±?5, respectively. Sample throughput of 60 samples per hour was achieved under optimized conditions.  相似文献   

19.
采用半静态法测定了4种甲氧基丙烯酸酯类杀菌剂原药及制剂对斑马鱼(Brachydonio rerio)急性毒性。结果表明,以实测浓度计,250 g·L~(-1)嘧菌酯悬浮剂对斑马鱼的96 h半数致死浓度(LC50)值为0.539 mg·L~(-1),急性毒性为高毒,95%嘧菌酯原药和50%嘧菌酯水分散粒剂对斑马鱼的LC50(96 h)值分别为1.09和1.21 mg·L~(-1),急性毒性均为中毒;98%啶氧菌酯原药和22.5%的啶氧菌酯悬浮剂对斑马鱼的LC50(96 h)值分别为0.0974和0.0972 mg·L~(-1),急性毒性均为剧毒;95%吡唑醚菌酯原药、15%吡唑醚菌酯悬浮剂和250 g·L~(-1)吡唑醚菌酯乳油对斑马鱼的LC50(96 h)值为0.0613、0.0549和0.0487 mg·L~(-1),急性毒性均为剧毒;95%醚菌酯原药和50%醚菌酯水分散粒剂对斑马鱼的LC50(96 h)值分别为0.468和0.702 mg·L~(-1),急性毒性均为高毒。这4种甲氧基丙烯酸酯类杀菌剂对斑马鱼均有较高风险,会对其他水生生物也存在潜在的风险。  相似文献   

20.
The monsoon-dominated Mandovi estuary is located in Goa state – a global tourist destination along the centralwest coast of India. In addition to factor analyses of water quality data, the water quality index (WQI), trophic state index (TSI) and percentage of freshwater volume in the estuary are calculated in order to infer the general waste assimilative capacity and prevailing water quality conditions. Factor analysis showed a dominance of PO4–P, NO2–N, NH3–N, total suspended solids (TSS) and turbidity during southwest (SW) monsoon relative to other seasons. The WQI suggested that an increase in nutrients, turbidity and TSS during SW monsoon increase the WQI values beyond 2, rendering the water at some locations slightly polluted. During pre-monsoon, considerable increase in the WQI is observed at all the upstream stations rendering slightly polluted water at these stations. The TSI showed an average value of 46.95 during SW monsoon, 42.43 during post-monsoon and 48.42 during the pre-monsoon seasons, suggesting better productivity level during pre-monsoon, followed by SW monsoon, but the least during the post-monsoon. All the seasons, however, indicated a mesotrophic condition in the estuary and the assimilative capacity of the estuary is found to be in good to fairly good state (pre-monsoon?相似文献   

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