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1.
Monitoring of nitrate leaching in sandy soils: comparison of three methods   总被引:2,自引:0,他引:2  
Proper N fertilizer and irrigation management can reduce nitrate leaching while maintaining crop yield, which is critical to enhance the sustainability of vegetable production on soils with poor water and nutrient-holding capacities. This study evaluated different methods to measure nitrate leaching in mulched drip-irrigated zucchini, pepper, and tomato production systems. Fertigation rates were 145 and 217 kg N ha(-1) for zucchini; 192 and 288 kg N ha(-1) for pepper; and 208 and 312 kg N ha(-1) for tomato. Irrigation was either applied at a fixed daily rate or based on threshold values of soil moisture sensors placed in production beds. Ceramic suction cup lysimeters, subsurface drainage lysimeters and soil cores were used to access the interactive effects of N rate and irrigation management on N leaching. Irrigation treatments and N rate interaction effects on N leaching were significant for all crops. Applying N rates in excess of standard recommendations increased N leaching by 64, 59, and 32%, respectively, for pepper, tomato, and zucchini crops. Independent of the irrigation treatment or nitrogen rate, N leaching values measured from the ceramic cup lysimeter-based N leaching values were lower than the values from the drainage lysimeter and soil coring methods. However, overall nitrate concentration patterns were similar for all methods when the nitrate concentration and leached volume were relatively low.  相似文献   

2.
Few studies have examined the water quality impact of manure use in no-tillage systems. A lysimeter study in continuous corn (Zea mays L.) was performed on Maury silt loam (fine, mixed, semiactive, mesic Typic Paleudalf) to evaluate the effect(s) of tillage (no-till [NT] and chisel-disk [CD]), nitrogen fertilizer rate (0 and 168 kg N ha(-1)), and dairy manure application timing (none, spring, fall, or fall plus spring) on NO3-N, atrazine (2-chloro-4-ethylamino-6-isopropylamino-s-triazine), and alachlor [2-chloro-2'-6'-diethyl-N-(methoxymethyl)acetanilide] concentrations in leachate collected at a 90-cm depth. Herbicides were highest immediately after application, declining to less than 4 mug L(-1) in about two months. Manure and manure timing by tillage interactions had little effect on leachate herbicides; rather, the data suggest that macropores rapidly transmitted atrazine and alachlor through the soil. Tillage usually did not significantly affect leachate NO3-N, but no-tillage tended to cause higher NO(3)-N. Manuring caused higher NO3-N concentrations; spring manuring had more impact than fall, but fall manure contained about 78% of the N found in spring manure. Nitrate under spring "only fertilizer" treatment exceeded 10 mg L(-1) 38% of the time, compared with 15% for spring only manure treatment. After three years, manured soil leachate NO3-N exceeded that for soil receiving only N fertilizer. Soil profile (90 cm) NO3-N after corn harvest exceeding 22 kg N ha(-1) was associated with winter leachate NO3-N greater than 10 mg N L(-1). Manure can be used effectively in conservation tillage systems on this and similar soils. Accounting for all N inputs, including previous manure applications, will be important.  相似文献   

3.
Minimizing the risk of nitrate contamination along the waterways of the U.S. Great Plains is essential to continued irrigated corn production and quality water supplies. The objectives of this study were to quantify nitrate (NO(3)) leaching for irrigated sandy soils (Pratt loamy fine sand [sandy, mixed, mesic Lamellic Haplustalfs]) and to evaluate the effects of N fertilizer and irrigation management strategies on NO(3) leaching in irrigated corn. Two irrigation schedules (1.0x and 1.25x optimum) were combined with six N fertilizer treatments broadcast as NH(4)NO(3) (kg N ha(-1)): 300 and 250 applied pre-plant; 250 applied pre-plant and sidedress; 185 applied pre-plant and sidedress; 125 applied pre-plant and sidedress; and 0. Porous-cup tensiometers and solution samplers were installed in each of the four highest N treatments. Soil solution samples were collected during the 2001 and 2002 growing seasons. Maximum corn grain yield was achieved with 125 or 185 kg N ha(-1), regardless of the irrigation schedule (IS). The 1.25x IS exacerbated the amount of NO(3) leached below the 152-cm depth in the preplant N treatments, with a mean of 146 kg N ha(-1) for the 250 and 300 kg N preplant applications compared with 12 kg N ha(-1) for the same N treatments and 1.0x IS. With 185 kg N ha(-1), the 1.25x IS treatment resulted in 74 kg N ha(-1) leached compared with 10 kg N ha(-1) for the 1.0x IS. Appropriate irrigation scheduling and N fertilizer rates are essential to improving N management practices on these sandy soils.  相似文献   

4.
Understanding water and nutrient transport through the soil profile is important for efficient irrigation and nutrient management to minimize excess nutrient leaching below the rootzone. We applied four rates of N (28, 56, 84, and 112 kg N ha(-1); equivalent to one-fourth of annual N rates being evaluated in this study for bearing citrus trees), and 80 kg Br- ha(-1) to a sandy Entisol with >25-yr-old citrus trees to (i) determine the temporal changes in NO3-N and Br- distribution down the soil profile (2.4 m), and (ii) evaluate the measured concentrations of NO3-N and Br- at various depths with those predicted by the Leaching Estimation and Chemistry Model (LEACHM). Nitrate N and Br concentrations approached the background levels by 42 and 214 d, respectively. Model-predicted volumetric water content and concentrations of NO3-N and Br- at various depths within the entire soil profile were very close to measured values. The LEACHM data showed that 21 to 36% of applied fertilizer N leached below the root zone, while tree uptake accounted for 40 to 53%. Results of this study enhance our understanding of N dynamics in these sandy soils, and provide better evaluation of N and irrigation management to improve uptake efficiency, reduce N losses, and minimize the risk of ground water nitrate contamination from soils highly vulnerable to nutrient leaching.  相似文献   

5.
Potato ( L.) is a N-intensive crop, with high potential for nitrate (NO) leaching, which can contribute to both water contamination and indirect nitrous oxide (NO) emissions. Two approaches that have been considered for reducing N losses include conventional split application (CSA) of soluble fertilizers and single application of polymer-coated urea (PCU). The objectives of this study were to: (i) compare NO leaching using CSA and two PCUs (PCU-1 and PCU-2), which differed in their polymer formulations, and (ii) use measured NO leaching rates and published emissions factors to estimate indirect NO emissions. Averaged over three growing seasons (2007-2009), NO leaching rates were not significantly different among the three fertilizer treatments. Using previously reported direct NO emissions data from the same experiment, total direct plus indirect growing season NO emissions with PCU-1 were estimated to be 30 to 40% less than with CSA. However, PCU-1 also resulted in greater residual soil N after harvest in 2007 and greater soil-water NO in the spring following the 2008 growing season. These results provide evidence that single PCU applications for irrigated potato production do not increase growing season NO leaching compared with multiple split applications of soluble fertilizers, but have the potential to increase N losses after the growing season and into the following year. Estimates of indirect NO emissions ranged from 0.8 to 64% of direct emissions, depending on what value was assumed for the emission factor describing off-site conversion of NO to NO. Thus, our results also demonstrate how more robust models are needed to account for off-site conversion of NO to NO, since current emission factor models have an enormous degree of uncertainty.  相似文献   

6.
Application of biochar has been suggested to improve water- and fertilizer-retaining capacity of agricultural soil. The objective of this study was to evaluate the effects of bagasse charcoal (sugarcane [ L.] bagasse-derived biochar) on nitrate (NO) leaching from Shimajiri Maji soil, which has low water- and fertilizer-retaining capacity. The nitrate adsorption properties of bagasse charcoal formed at five pyrolysis temperatures (400-800° C) were investigated to select the most suitable bagasse charcoal for NO adsorption. Nitrate was able to adsorb onto the bagasse charcoal formed at pyrolysis temperatures of 700 to 800° C. Nitrate adsorption by bagasse charcoal (formed at 800° C) that passed through a 2-mm sieve was in a state of nonequilibrium even at 20 h after the addition of 20 mg N L KNO solution. Measurements suggested that the saturated and unsaturated hydraulic conductivity of bagasse charcoal (800° C)-amended soils are affected by changes in soil tortuosity and porosity and the presence of meso- and micropores in the bagasse charcoal, which did not contribute to soil water transfer. In NO leaching studies using bagasse charcoal (800° C)-amended soils with different charcoal contents (0-10% [w/w]), the maximum concentration of NO in effluents from bagasse charcoal-amended soil columns was approximately 5% less than that from a nonamended soil column because of NO adsorption by bagasse charcoal (800° C). We conclude that application of bagasse charcoal (800°C) to the soil will increase the residence time of NO in the root zone of crops and provide greater opportunity for crops to absorb NO.  相似文献   

7.
Controlling nitrate leaching in irrigated agriculture   总被引:3,自引:0,他引:3  
The impact of improved irrigation and nutrient practices on ground water quality was assessed at the Nebraska Management System Evaluation Area using ground water quality data collected from 16 depths at 31 strategically located multilevel samplers three times annually from 1991 to 1996. The site was sectioned into four 13.4-ha management fields: (i) a conventional furrow-irrigated corn (Zea mays L.) field; (ii) a surge-irrigated corn field, which received 60% less water and 31% less N fertilizer than the conventional field; (iii) a center pivot-irrigated corn field, which received 66% less water and 37% less N fertilizer than the conventional field; and (iv) a center pivot-irrigated alfalfa (Medicago sativa L.) field. Dating (3H/3He) indicated that the uppermost ground water was <1 to 2 yr old and that the aquifer water was stratified with the deepest water approximately 20 yr old. Recharge during the wet growing season in 1993 reduced the average NO3-N concentration in the top 3 m 20 mg L(-1), effectively diluting and replacing the NO3-contaminated water. Nitrate concentrations in the shallow zone of the aquifer increased with depth to water. Beneath the conventional and surge-irrigated fields, shallow ground water concentrations returned to the initial 30 mg NO3-N L(-1) level by fall 1995; however, beneath the center pivot-irrigated corn field, concentrations remained at approximately 13 mg NO3-N L(-1) until fall 1996. A combination of sprinkler irrigation and N fertigation significantly reduced N leaching with only minor reductions (6%) in crop yield.  相似文献   

8.
Nitrate leaching in intensive grassland- and silage maize-based dairy farming systems on sandy soil is a main environmental concern. Here, statistical relationships are presented between management practices and environmental conditions and nitrate concentration in shallow groundwater (0.8 m depth) at farm, field, and point scales in The Netherlands, based on data collected in a participatory approach over a 7-yr period at one experimental and eight pilot commercial dairy farms on sandy soil. Farm milk production ranged from 10 to 24 Mg ha(-1). Soil and hydrological characteristics were derived from surveys and weather conditions from meteorological stations. Statistical analyses were performed with multiple regression models. Mean nitrate concentration at farm scale decreased from 79 mg L(-1) in 1999 to 63 in 2006, with average nitrate concentration in groundwater decreasing under grassland but increasing under maize land over the monitoring period. The effects of management practices on nitrate concentration varied with spatial scale. At farm scale, nitrogen surplus, grazing intensity, and the relative areas of grassland and maize land significantly contributed to explaining the variance in nitrate concentration in groundwater. Mean nitrate concentration was negatively correlated to the concentration of dissolved organic carbon in the shallow groundwater. At field scale, management practices and soil, hydrological, and climatic conditions significantly contributed to explaining the variance in nitrate concentration in groundwater under grassland and maize land. We conclude that, on these intensive dairy farms, additional measures are needed to comply with the European Union water quality standard in groundwater of 50 mg nitrate L(-1). The most promising measures are omitting fertilization of catch crops and reducing fertilization levels of first-year maize in the rotation.  相似文献   

9.
Land application of wastewater presents potential for ground water pollution if not properly managed. In situ breakthrough tests were conducted using potato (Solanum tuberosum L.)-processing wastewater and a Br tracer to characterize P leaching in seasonally frozen sandy outwash soils. In the first test, P and Br breakthrough were measured in a 7-m deep well following wastewater [2.94 mg L(-1) total P (TP); 280 mg L(-1) Br] application at the site that had 13.1 mg water-extractable P (WEP) kg(-1)and 94.4 mg Bray-1 P kg(-1). Bromide was detected in the well after approximately 0.4 pore volumes, but there was no P break-through after 7 pore volumes. In the second breakthrough test, wastewater containing 3.6 mg L(-1) TP and 259 mg L(-1) Br was applied on 1.5-m deep lysimeters at low (0.8 mg WEP kg(-1); 12.1 mg Bray-1 P kg(-1)) and high soil test P sites (104 mg WEP kg(-1); 585 mg Bray-1 P kg(-1)). Leachate TP concentration during the test remained constant (0.04 mg L(-1)) at the low P sites but increased from approximately 3.5 to 5.6 mg L(-1) at the high P sites. These results indicate no P leaching in low P soils, but leaching in high P soils, thus suggesting that most of the P leached at the high P sites was mainly due to desorption and dissolution of weakly adsorbed P from prior P applications. This was consistent with P transport simulations using the convective-dispersive equation. We conclude that P concentration in land-applied wastewater should be regulated based on soil test-P level plus wastewater P loading.  相似文献   

10.
Leaching to the ground water of metabolites from the herbicide metribuzin [4-amino-6-(1,1-dimethylethyl)-3-(methylthio)-1,2,4-triazin-5-one] has been measured in a Danish field experiment in concentrations exceeding the European Union threshold limit for pesticides at 0.1 microg/L. In the present work, degradation and sorption of metribuzin and the metabolites desamino-metribuzin (DA), diketo-metribuzin (DK), and desamino-diketo-metribuzin (DADK) were studied in a Danish sandy loam topsoil and subsoil from the field in question, using accelerated solvent extraction and liquid chromatography-tandem mass spectrometry (LC-MS/MS) analysis. Fast dissipation of metribuzin and the metabolites was observed in the topsoil, with 50% disappearance within 30 to 40 d. A two-compartment model described degradation of metribuzin and DA, whereas that of DADK could be described using first-order kinetics. Part of the dissipation was probably due to incorporation into soil organic matter. Degradation in subsoil occurred very slowly, with extrapolated half-lives of more than one year. Sorption in the topsoil followed the order DA > metribuzin > DK > DADK. Subsoil sorption was considerably lower, and was hardly measurable for metribuzin and DK. Abiotic degradation was considerably higher in the topsoil than the subsoil, especially concerning the de-amination step, indicating that organic matter may be related to the degradation process. The present results confirm observations of metribuzin and transformation product leaching made in the field experiment and demonstrate the need for knowledge on primary metabolites when assessing the risk for pesticide leaching.  相似文献   

11.
Phosphorus leaching in relation to soil type and soil phosphorus content   总被引:6,自引:0,他引:6  
Phosphorus losses from arable soils contribute to eutrophication of freshwater systems. In addition to losses through surface runoff, leaching has lately gained increased attention as an important P transport pathway. Increased P levels in arable soils have highlighted the necessity of establishing a relationship between actual P leaching and soil P levels. In this study, we measured leaching of total phosphorus (TP) and dissolved reactive phosphorus (DRP) during three years in undisturbed soil columns of five soils. The soils were collected at sites, established between 1957 and 1966, included in a long-term Swedish fertility experiment with four P fertilization levels at each site. Total P losses varied between 0.03 and 1.09 kg ha(-1) yr(-1), but no general correlation could be found between P concentrations and soil test P (Olsen P and phosphorus content in ammonium lactate extract [P-AL]) or P sorption indices (single-point phosphorus sorption index [PSI] and P sorption saturation) of the topsoil. Instead, water transport mechanism through the soil and subsoil properties seemed to be more important for P leaching than soil test P value in the topsoil. In one soil, where preferential flow was the dominant water transport pathway, water and P bypassed the high sorption capacity of the subsoil, resulting in high losses. On the other hand, P leaching from some soils was low in spite of high P applications due to high P sorption capacity in the subsoil. Therefore, site-specific factors may serve as indicators for P leaching losses, but a single, general indicator for all soil types was not found in this study.  相似文献   

12.
Management of animal manures to provide nutrients for crop growth has generally been based on crop N needs. However, because manures have a lower N/P ratio than most harvested crops, N-based manure management often oversupplies the crop-soil system with P, which can be lost into the environment and contribute to eutrophication of water bodies. We examined the effects of N- vs. P-based manure applications on N and P uptake by alfalfa (Medicago sativa L.), corn (Zea mays L.) for silage, and orchardgrass (Dactylis glomerata L.), leaching below the root zone, and accumulation of P in soil. Treatments included N- and P-based manure rates, with no nutrient input controls and inorganically fertilized plots for comparison. Nitrate concentrations in leachate from inorganic fertilizer or manure treatments averaged 14 mg NO(3)-N L(-1), and did not differ by nutrient treatment. Average annual total P losses in leachate did not exceed 1 kg ha(-1). In the top 5 cm of soil in plots receiving the N-based manure treatment, soil test P increased by 47%, from 85 to 125 mg kg(-1). Nitrogen- and P-based manure applications did not differ in ability to supply nutrients for crop growth, or in losses of nitrate and total P in leachate. However, the N-based manure led to significantly greater accumulation of soil test P in the surface 5 cm of soil. Surface soil P accumulation has implications for increased risk of off-field P movement.  相似文献   

13.
14.
Dynamics of potassium leaching on a hillslope grassland soil   总被引:1,自引:0,他引:1  
There have been only a few studies of potassium (K) losses from grassland systems, and little is known about their dynamics, especially in relation to nitrogen (N) management. A study was performed during the autumn and winter of 1999 and 2000 to understand the effects of N and drainage on the dynamics of K leaching on a hillslope grassland soil in southwestern England. Two N application rates were studied (0 and 280 kg N ha(-1) yr(-1)), both with and without tile drainage. Treatments receiving N also received farmyard manure (FM). Higher total K losses and K concentrations in the leachates were found in the N + FM treatments (150 and 185% higher than in 0 N treatments), which were related to K additions in the FM. Drainage reduced K losses by 35% because of an increase in dry matter production and a reduction in overland and preferential flow. The pattern of change in K concentration in the leachates was associated with preferential flow at the beginning of the drainage season and with matrix flow later in winter, and was best described by a double exponential curve. Rainfall intensity and the autumn application of FM were the main determinants of K losses by leaching. The study provided new insights into the relationships between soil hydrology, rainfall, and K leaching and its implications for grassland systems.  相似文献   

15.
Wildfire effects on soil nutrients and leaching in a tahoe basin watershed   总被引:1,自引:0,他引:1  
A wildfire burned through a previously sampled research site, allowing pre- and post-burn measurements of the forest floor, soils, and soil leaching near Lake Tahoe, Nevada. Fire and post-fire erosion caused large and statistically significant (P < or = 0.05) losses of C, N, P, S, Ca, and Mg from the forest floor. There were no statistically significant effects on mineral soils aside from a decrease in total N in the surface (A11) horizon, an increase in pH in the A11 horizon, and increases in water-extractable SO4(2-) in the A11 and A12 horizons. Burning caused consistent but nonsignificant increases in exchangeable Ca2+ in most horizons, but no consistent or statistically significant effects on exchangeable K+ or Mg2+, or on Bray-, bicarbonate-, or water-extractable P concentrations. Before the burn, there were no significant differences in leaching, but during the first winter after the fire, soil solution concentrations of NH4+, NO3-, ortho-P, and (especially) SO4(2-) were elevated in the burned area, and resin lysimeters showed significant increases in the leaching of NH4+ and mineral N. The leaching losses of mineral N were much smaller than the losses from the forest floor and A11 horizons, however. We conclude that the major short-term effects of wildfire were on leaching whereas the major long-term effect was the loss of N from the forest floor and soil during the fire.  相似文献   

16.
17.
The soil organic partition coefficient (Koc) is one of the most important parameters to depict the transfer and fate of a chemical in the soil-water system. Predicting Koc by using a chromatographic technique has been developing into a convenient and low-cost method. In this paper, a soil leaching column chromatograpy (SLCC) method employing the soil column packed with reference soil GSE 17201 (obtained from Bayer Landwirtschaftszentrum, Monheim, Germany) and methanol-water eluents was developed to predict the Koc of hydrophobic organic chemicals (HOCs), over a log Koc range of 4.8 orders of magnitude, from their capacity factors. The capacity factor with water as an eluent (k'w) could be obtained by linearly extrapolating capacity factors in methanol-water eluents (k'w) with various volume fractions of methanol (symbol in text). The important effects of solute activity coefficients in water on k'w and Koc were illustrated. Hence, the correlation between log Koc and log k'w (and log k') exists in the soil. The correlation coefficient (r) of the log Koc vs. log k'w correlation for 58 apolar and polar compounds could reach 0.987, while the correlation coefficients of the log Koc -log k' correlations were no less than 0.968, with (symbol in text)ranging from 0 to 0.50. The smaller the (symbol in text), the higher the r. Therefore, it is recommended that the eluent of smaller (symbol in text), such as water, be used for accurately estimating Koc. Correspondingly, the r value of the log Koc -log k'w correlation on a reversed-phase Hypersil ODS (Thermo Hypersil, Kleinostheim, Germany) column was less than 0.940 for the same solutes. The SLCC method could provide a more reliable route to predict Koc indirectly from a correlation with k'w than the reversed-phase liquid chromatographic (RPLC) one.  相似文献   

18.
Pesticides applied to agricultural soils are subject to environmental concerns because leaching to groundwater reservoirs and aquatic habitats may occur. Knowledge of field variation of pesticide-related parameters is required to evaluate the vulnerability of pesticide leaching. The mineralization and sorption of the pesticides glyphosate and metribuzin and the pesticide degradation product triazinamin in a field were measured and compared with the field-scale variation of geochemical and microbiological parameters. We focused on the soil parameters clay and organic carbon (C) content and on soil respiratory and enzymatic processes and microbial biomass. These parameters were measured in soil samples taken at two depths (Ap and Bs horizon) in 51 sampling points from a 4-ha agricultural fine sandy soil field. The results indicated that the spatial variation of the soil parameters, and in particular the content of organic C, had a major influence on the variability of the microbial parameters and on sorption and pesticide mineralization in the soil. For glyphosate, with a co-metabolic pathway for degradation, the mineralization was increased in soils with high microbial activity. The spatial variability, expressed as the CV, was about five times higher in the Bs horizon than in the Ap horizon, and the local-scale variation within 100 m(2) areas were two to three times lower than the field-scale variation within the entire field of about 4 ha.  相似文献   

19.
Long-term application of phosphorus (P) with animal manure in amounts exceeding removal with crops leads to buildup of P in soil and to increasing risk of P loss to surface water and eutrophication. In most manures, the majority of P is held within inorganic forms, but in soil leachates organic P forms often dominate. We investigated the mobility of both inorganic and organic P in profile samples from a noncalcareous sandy soil treated for 11 yr with excessive amounts of pig slurry, poultry manure, or poultry manure mixed with litter. Solution 31P nuclear magnetic resonance spectroscopy was used to characterize NaOH-EDTA-extractable forms of P, corresponding to 64 to 93% of the total P concentration in soil. Orthophosphate and orthophosphate monoesters were the main P forms detected in the NaOH-EDTA extracts. A strong accumulation of orthophosphate monoesters was found in the upper layers of the manure-treated soils. For orthophosphate, however, increased concentrations were found down to the 40- to 50-cm soil layers, indicating a strong downward movement of this P form. This was ascribed to the strong retention of orthophosphate monoesters by the solid phase of the soil, preventing orthophosphate sorption and facilitating downward movement of orthophosphate. Alternatively, mineralization of organic P in the upper layers of the manure-treated soils may have generated orthophosphate, which could have contributed to the downward movement of the latter. Leaching of inorganic P should thus be considered for the assessment and the future management of the long-term risk of P loss from soils receiving large amounts of manure.  相似文献   

20.
Various N fertilizer sources are available for lawn turf. Few field studies, however, have determined the losses of nitrate (NO(3)-N) from lawns receiving different formulations of N fertilizers. The objectives of this study were to determine the differences in NO(3)-N leaching losses among various N fertilizer sources and to ascertain when losses were most likely to occur. The field experiment was set out in a completely random design on a turf typical of the lawns in southern New England. Treatments consisted of four fertilizer sources with fast- and slow-release N formulations: (i) ammonium nitrate (AN), (ii) polymer-coated sulfur-coated urea (PCSCU), (iii) organic product, and (iv) a nonfertilized control. The experiment was conducted across three years and fertilized to supply a total of 147 kg N ha(-1) yr(-1). Percolate was collected with zero-tension lysimeters. Flow-weighted NO(3)-N concentrations were 4.6, 0.57, 0.31, and 0.18 mg L(-1) for AN, PCSCU, organic, and the control, respectively. After correcting for control losses, average annual NO(3)-N leaching losses as a percentage of N applied were 16.8% for AN, 1.7% for PCSCU, and 0.6% for organic. Results indicate that NO(3)-N leaching losses from lawn turf in southern New England occur primarily during the late fall through the early spring. To reduce the threat of NO(3)-N leaching losses, lawn turf fertilizers should be formulated with a larger percentage of slow-release N than soluble N.  相似文献   

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