Evaluating the longevity of a PFAS in situ colloidal activated carbon remedy

The remediation of per‐ and polyfluoroalkyl substances by injection of colloidal activated carbon (CAC) at a contaminated site in Central Canada was evaluated using various visualization and modeling methods. Radial diagrams were used to illustrate spatial and temporal trends in perfluoroalkyl acid (PFAA) concentrations, as well as various redox indicators. To assess the CAC adsorption capacity for perfluorooctane sulfonate (PFOS), laboratory Freundlich isotherms were derived for PFOS mixed with CAC in two solutions: (1) PFOS in a pH 7.5 synthetic water that was buffered by 1 millimolar NaHCO₃ (K_f = 142,800 mg^1‐a L^a/kg and a = 0.59); and (2) a groundwater sample (pH = 7.4) containing PFOS among other PFAS from a former fire‐training area in the United States (K_f = 4,900 mg^1‐a L^a/kg and a = 0.24). A mass balance approach was derived to facilitate the numerical modeling of mass redistribution after CAC injection, when mass transitions from a two‐phase system (aqueous and sorbed to organic matter) to a three‐phase system that also includes mass sorbed to CAC. An equilibrium mixing model of mass accumulation over time was developed using a finite‐difference solution and was verified by intermodel comparison for prediction of CAC longevity in the center of a source area. A three‐dimensional reactive transport model (ISR‐MT3DMS) was used to indicate that the CAC remedy implemented at the site is likely to be effective for PFOS remediation for decades. Model results are used to recommend remedial design and monitoring alternatives that account for the uncertainty in long‐term performance predictions.     

火电厂烟气脱硫工程总承包的造价控制

简述了烟气脱硫工程和总承包的主要特点。并根据其特征提出了控制FCD各阶段工程造价的原则和方法。只有做好造价控制，才能在提高社会效益的同时实现企业利润最大化。     

湿法石灰石/石膏烟气脱硫泵的选材及选型

简述了湿法烟气脱硫生产中浆液的性质，并根据浆液特点阐述了耐磨耐蚀泵的选材与选型．为湿法石灰石／石膏烟气脱硫浆液输送泵的研发提供参考。     

脱硫控制系统的选型

结合石灰石-石膏湿法烟气脱硫控制系统的特点,通过比较DCS和PLC两种系统控制器的处理能力、数据通信、组态维护、人机交换装置、安全性以及发展方向等,给出了脱硫控制系统选型建议。     

燃煤电厂袋式除尘器滤袋材料选择

结合某电厂“上大压小”改建工程中2台600 MW机组配套电袋除尘器的实际情况,分析了滤袋材料的选择原则及更换原因,论述了袋式除尘器滤袋材料对烟气的适应性,为燃煤电厂袋式除尘器滤袋材料的选择提供参考.     

陕西省发展低碳农业的路径选择

陕西是我国西部地区文化、科技的强省。虽然能源资源相对丰富,但是生态环境脆弱。农业经济发展受地理环境和发展理念的制约,发展水平较之东部发达地区存在很大的差距。低碳农业随着低碳经济的发展应运而生,发展低碳农业不仅是统筹城乡发展、实现社会循环经济发展一体化的切入点,而且是保护生态环境"双赢"的重要途径,同时也是转变陕西农业发展方式的必然选择。试析在建设陕西新农村背景下如何选择符合陕西省低碳农业发展的新模式和如何选择促进陕西区域经济又好又快发展的有效对策。     

The active role of state laws in superfund cleanups

The Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA or Superfund) did not ignore the fifty individual states when establishing responsibility, authority, and liability for cleaning up hazardous waste sites. Although CERCLA gives EPA the ultimate authority to select a remedy for a contaminated site, the law was drafted not only to allow for state activity without EPA, but also for significant state input when EPA is involved. The relationship between a state (and its environmental laws) and EPA can help decide the remedial and financial interests of any potentially responsible party (PRP). This article discusses the relevant CERCLA provisions, recent court decisions, and resolved and unresolved issues in federal-state Superfund involvement, and recommends several common-sense strategies for PRPs when working with a state in a Superfund cleanup.     

Performance evaluation of an in situ source area combined remedy for the remediation of commingled chlorinated ethanes and ethenes

The chlorinated volatile organic compounds (CVOCs), tetrachloroethene (PCE), trichloroethene (TCE), and 1,1,1‐trichloroethane (1,1,1‐TCA), often found as commingled contaminants of concern (COCs) in groundwater, can degrade via a variety of biotic and abiotic reductive pathways. In situ remediation of a groundwater contaminant source area containing commingled 1,1,1‐TCA, PCE, and TCE was conducted using a combined remedy/treatment train approach. The first step was to create geochemically reducing conditions in the source area to degrade the CVOCs to lesser chlorinated CVOCs (i.e., 1,1‐dichloroethane [1,1‐DCA], 1,1‐dichlorethene [1,1‐DCE], cis‐1,2‐dichoroethene [cis‐1,2‐DCE], and vinyl chloride [VC]) via enhanced reductive dechlorination (ERD). Carbon substrates were injected to create microbial‐induced geochemically reducing conditions. An abiotic reductant (zero‐valent iron [ZVI]) was also used to further degrade the CVOCs, minimizing the generation of 1,1‐DCE and VC, and co‐precipitate temporarily mobilized metals. An in situ aerobic zone was created downgradient of the treatment zone through the injection of oxygen. Remaining CVOC degradation products and temporarily mobilized metals (e.g., iron and manganese) resulting from the geochemically reducing conditions were then allowed to migrate through the aerobic zone. Within the aerobic zone, the lesser chlorinated CVOCs were oxidized and the solubilized metals were precipitated out of solution. The injection of a combination of carbon substrates and ZVI into the groundwater system at the site studied herein resulted in the generation of a geochemically reducing subsurface treatment zone that has lasted for more than 4.5 years. Mass concentrations of total CVOCs were degraded within the treatment zone, with near complete transformation of chlorinated ethenes and a more than 90 percent reduction of CVOC mass concentrations. Production of VC and 1,1‐DCE has been minimized through the combined effects of abiotic and biological processes. CVOC concentrations have declined over time and temporarily mobilized metals are precipitating out of the dissolved phase. Precipitation of the dissolved metals was mitigated using the in situ oxygenation system, also resulting in a return to aerobic conditions in downgradient groundwater. Chloroethane (CA) is the dominant CVOC degradation product within the treatment zone and downgradient of the treatment zone, and it is expected to continue to aerobically degrade over time. CA did not accumulate within and near the aerobic oxygenation zone. The expectations for the remediation system are: (1) the concentrations of CVOCs (primarily in the form of CA) will continue to degrade; (2) total organic carbon concentrations will continue to decline to pre‐remediation levels; and, (3) the groundwater geochemistry will experience an overall trend of transitioning from reducing back to pre‐remediation mildly oxidizing conditions within and downgradient of the treatment zone.     

试论电信企业在ICT电子废弃物循环利用中的作用

电子废弃物回收再利用是发展循环经济的重要抓手。针对ICT(Information and CommunicationTechnology,信息和通信技术)行业发展带来日益严峻的电子废弃物问题,剖析了现有电子废弃物的回收再利用体系存在的弊端,在解读现有法律法规政策的基础上,提出优化原有体系的设想,即充分认识电信企业"管家式"运营特点有利于低成本高效率地实现电子废弃物回收再利用,电信企业介入的回收再利用模式是政府、企业与社会多赢的模式,在当前可通过签订环境合同,实现政府与电信企业的合作。     

The potential role of compost in reducing greenhouse gases.

The contribution of the agricultural sector to emissions of climate change gases is becoming better understood. At the same time, the potential role of the sector as a means through which to tackle climate change, widely neglected in the past, is becoming more widely acknowledged. The absorption potential of agricultural soils could contribute significantly to constraining growth in greenhouse gas emissions, while also contributing to improvements in soil quality in some areas. In addition to the measures listed above, other benefits of compost application may have some relevance. Some of these measures include replacement of chemical fertilizers (implying avoidance of greenhouse gases related to their production) reduced use of pesticides (avoiding emissions associated with their production), improved tilth and workability (less consumption of fuels). Typically, life-cycle analyses (LCAs) exhibit limitations related to assessing the effects of 'time-limited' carbon sequestration in soils. This has tended to obscure the potentially important effect of composting, in which biogenic carbon is held in soils for a period of time before the carbon is released. The paper seeks to understand these effects and offers comments on the contribution of biological treatments to tackling climate change issues. Key issues include the replacement of fertilizers, reduction of N2O emissions, and peat replacement.     

Assessing the true cost of landfills

The most common means for disposing of municipal solid waste is burial in a sanitary landfill. However, many landfill owners significantly underestimate the total cost of landfill disposal by considering only land and operating costs, ignoring external physical and social costs associated with landfills. This paper proposes an approach to estimating (in monetary terms) the external costs arising from the development and operation of a landfill. All cost information is based on typical U.S. landfill cost structures. The approach is illustrated by applying it to a case study of a proposed landfill in Durham, North Carolina (U.S.A.). This case study demonstrates that the method can be applied easily and yields reasonable results.     

The development of low cost adsorbents from clay and waste materials: a review

Increased energy consumption due to industrial growth has increased the levels of carbon dioxide (CO₂) emission being released into the atmosphere. CO₂ emission is a type of greenhouse gas which is a major cause of global warming. Since the issue of CO₂ emissions has drawn much attention in recent years, the development of CO₂ capture technology has become a necessity. Although CO₂ adsorbents are still at the early development stage, it has been suggested that CO₂ adsorbents are the most effective technology in controlling CO₂ emissions. Solid adsorbents have great potential as an alternative method to conventional adsorbents in adsorbing CO₂. In this paper, low cost adsorbents including activated carbon, zeolites, mesoporous silica and clays are discussed in terms of adsorbent preparation methods and CO₂ adsorption capacity. The low cost adsorbents are mainly derived from waste materials such as fly ash, steel slag, red mud, bagasses wastes and wood wastes. Besides that, natural resources such as clays have also been applied as low cost CO₂ adsorbents. Surface modifications have also been applied to the low cost adsorbents, including metal ion exchange and amine impregnation to enhance CO₂ adsorption capacity. In the last section, the current status of CO₂ adsorbents is summarized and future trends are discussed briefly to predict the potential materials which can be applied as CO₂ adsorbents.     

Collection and transportation cost of household solid waste in Kuwait

The specific aim of this funded research project was to examine and evaluate the efficiency and the effectiveness of the municipal solid waste collection and transportation system in the State of Kuwait. The contract resources of the seven contracting firms, the annual contract budgets, and the district area and population of each service contract are presented. Service efficiency and effectiveness indicators for each collection/disposal contract are also computed and discussed. The cost of collection and transportation of household waste in Kuwait is also compared with those of a number of urban areas in other nations. The low energy and manpower costs are mainly responsible for the favorable cost of management, collection and transportation of residential waste in Kuwait.     

火电厂烟气脱硫工程快速估价方法

为解决目前国内火电厂烟气脱硫工程造价计算方法研究不足的问题，应用模糊数学原理和平滑指数预测方法，结合工程实际，提出了一种火电厂烟气脱硫工程快速有效的估价方法，为烟气脱硫工程的投资估算及概预算工作提供参考。     

企业在发展循环经济中的地位和作用

发展循环经济,建设节约型社会是当前的热点、难点问题.企业是发展循环经济的主体,它对于整个经济的可持续发展具有非常重要的作用,制定企业循环经济发展战略应该是整个经济增长中的重要环节.探讨了企业在发展循环经济中的主体地位,发展循环经济对企业的作用,分析了制约企业在循环经济中发挥作用的因素,最后提出了提高企业自身发展循环经济能力的措施.     

Degradable polymers: The role of the degradation environment

The degradability of several degradable polymers was examined using three types of degradation environments. These include exposure in a laboratory-scale composting test system containing material representative of the organic fraction of municipal solid waste (MSW), exposure in a thermal hydrolytic environment consisting of water at 60‡C, and exposure in a thermal-oxidative, dry oven environment of 60‡C. The results of the investigation clearly indicate that, in addition to chemical and biological activity which can lead to polymer degradation, physical restructuring and reorganization of the macromolecular structure may also occur at temperatures typically found in a compost environment, resulting in changes in the mechanical properties of the polymer films. In the case of the polyethylene-modified polymers evaluated in this study, all behaved similarly, but differently from the other polymer types. The polyethylene-based films appeared to be susceptible to oxidative degradation and should degrade in a composting environment providing that there is sufficient air in contact with the film for a sufficient period of time. However, when exposed in a laboratory composter, it appears that although ideal temperature-time curves may be obtained, the test time period was insufficient in comparison to the induction period required to achieve the desired thermal oxidative degradation. Issued as NRCC No. 37620.     

The role of intergenerational influence in waste education programmes: the THAW project

Whilst the education of young people is often seen as a part of the solution to current environmental problems seeking urgent attention, it is often forgotten that their parents and other household members can also be educated/influenced via home-based educational activities. This paper explores the theory of intergenerational influence in relation to school based waste education. Waste Watch, a UK-based environmental charity (www.wastewatch.org.uk), has pioneered a model that uses practical activities and whole school involvement to promote school based action on waste. This methodology has been adopted nationally. This paper outlines and evaluates how effective school based waste education is in promoting action at a household level. The paper outlines Waste Watch's 'Taking Home Action on Waste (THAW)' project carried out for two and half years in Rotherham, a town in South Yorkshire, England. The project worked with 6705 primary age children in 39 schools (44% of primary schools in the project area) to enable them to take the "reduce, reuse and recycle message" home to their families and to engage these (i.e. families) in sustainable waste management practices. As well as substantial increases in students' knowledge and understanding of waste reduction, measurement of the impact of the project in areas around 12 carefully chosen sample schools showed evidence of increased participation in recycling and recycling tonnages as well as declining levels of residual waste. Following delivery of the project in these areas, an average increase of 8.6% was recorded in recycling set out rates which led to a 4.3% increase in paper recycling tonnages and an 8.7% increase in tonnages of cans, glass and textiles collected for recycling. Correspondingly, there was a 4.5% fall in tonnages of residual waste. Waste Watch's THAW project was the first serious attempt to measure the intergenerational influence of an education programme on behaviour at home (i.e. other than schools' own waste). It clearly shows that household recycling behaviour can be positively impacted by intergenerational influence via a practical school-based waste education model. However, although the model could potentially have a big impact if rolled out nationally, it will require seed funding and the long-term durability of the model has not yet been fully quantified.     

Design and cost estimation of permeable reactive barriers

Cost-effective use of permeable reactive barriers for groundwater treatment requires properly estimating the amount of reactive material required and choosing the best means of emplacing it. The weight of reactive material per unit cross section of the plume can be estimated from laboratory reaction kinetics data and basic knowledge of the plume and the remediation goals. This parameter has implications regarding the choice of permeable barrier design and emplacement method. The use of tremie tubes, trenching machines, high-pressure jetting, and deep soil mixing may be appropriate for different situations depending on the amount of reactive material required, the dimensions of the plume, and other factors. The specific application considered here is the use of granular iron to treat groundwater contaminated with chlorinated solvents.